Predictions Of Pit-Lake Water Column Properties Using A Coupled Mixing And Geochemical Speciation Model

The flooding of open pits is now receiving considerable attention from the mining industry as an option that may minimize environmental impacts, particularly when anoxia in pit-lake deep waters can effectively eliminate oxidation of pit-wall sulfides. This paper describes a state-of-the-art, coupled physical-geochemical pit-lake model. The model is used to verify that a controlled, two-stage infilling of the open pit at the Kori Kollo gold mine, southeast of La Paz, Bolivia, would result in a cost-effective, environmentally responsible closure strategy. By filling the pit initially with highly saline surface waters and naturally saline deep groundwater and then capping with fresh river water, a very stable and strongly stratified pit lake will be developed. In addition, the stratification will result in the isolation of metal-rich saline bottom waters from surface waters of good quality. Results of this model provide defensible predictions of the physical stability and evolution of water quality in the Kori Kollo pit lake over time. The model results indicate that anoxic conditions will develop below the fresh-saline water boundary within one to two years, followed by the rapid onset of sulfate-reducing conditions in the bottom waters. Hydrogen sulfide produced by sulfate reduction will readily react with dissolved metals to form highly insoluble metal sulfides. The process results in the gradual removal of metals from the water column and the concomitant improvement of water quality over time. A notable benefit of this strategy is that it can be fully integrated with other mine site closure options as well as future environmental-management strategies. The proposed plan allows for the safe isolation of saline waters, the potential for passive treatment in anoxic bottom waters of ARD seepage from other mine site operations, should they arise, and a repository for future reactive wastes that could be effectively isolated in a physically and chemically stable environment.