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By Matthew Janes

The RC Harris Filtration Plant, which treats the majority of the fresh water for over 2.5 million Torontonians, is a Canadian Architectural Heritage site demonstrating a classic example of Art Deco Architecture. The facility is undergoing an expansion to install an underground sludge treatment capability. Perched atop a bluff on the North shore of Lake Ontario the structure enjoys a commanding presence on the Lake Ontario shoreline. A series of underground tanks were proposed for the hillside below the structure, which when covered would preserve the building?s architectural presence. However, the plan required two, stepped excavations 12 m and 10m deep into compact, wet sands over stiff clays and clayey silts. Concerns regarding the original structure influenced designers to set the lateral deflection limit for the front footing of the existing structure at 4 mm, (0.03% excavation depth). The design-build team indicated at the time of tender that the movement criteria was unattainable using the tender design. Analysis indicated installation effects and overall elastic movement of the soil mass beneath the building would result in movements of 7 to 9 mm at the structure. Through extensive FLAC analysis and a novel construction geometry the design-build team crafted an alternative that produced significant savings over the original concept. Based upon the analysis the design-build team negotiated a new deflection criteria dictating a maximum of 2.0 mm of movement across the critical expansion joint between the Filter Building front footing and the tank slab beyond. The contractor invested in additional pre tender soils investigation to support the refined design process. The FLAC analyses indicated the Filter Building movements would be elastic and distributed up to 50 m back beneath the front footing of the structure. An extensive precision monitoring program proved construction related movements of 6 to 10 mm horizontal at the front footing. Extensometers placed at two locations over the critical interior tank expansion joint showed no measurable movements. The overall monitoring program, including inclinometers, tilt meters, tie back extensometers (smart cables) and tie back load cells indicated a good match between recorded movements and loads and those predicted by FLAC Analysis.

Jan 1, 2006

By John E. Lens

How much trouble can narrow vertical fissures in bedrock cause on a shallow bedrock site? Enough trouble so end-bearing H-piles range between 8 and 100 feet long in a single pile cap and tiebacks range from 40 to over 100 feet long within a 10 foot wall span. Sloped bedrock surfaces also complicated the tieback installation as the drill casing followed the sloped rock surface while drilling and caused unanticipated bending (and sometimes breaking) of the drill string. Warned via pre-construction rock probes and cores reaching over 80 feet deep at the Winooski, Vermont project site, the design and construction team expected anomalies in pile driving and tieback drilling due to fissures in the bedrock filled with soil and weathered-rock. The degree of abruptness in the variability in the rock surface, and its impact on pile driving and tieback drilling were less predictable. Close monitoring of pile and tieback installation, redesign of pile caps, and lengthened tiebacks overcame these anomalous fissures. This paper shares the lessons learned for overcoming these geologic challenges to benefit designers, contractors bidding the work, and ultimately, the owner, with lower contingencies.

Jan 1, 2006

The Pilbara region, located in the north-west of Western Australia, is significant as the second-largest source of iron ore on the planet. Iron ore mines owned and operated by Pilbara Iron are located within the Hamersley Basin. This paper refers to the Greater Paraburdoo mines, the 4WEST and 4EAST pits, located on the southern margin of the Hamersley Basin. The groundwater model refers to ephemeral watercourses: Seven Mile and Pirraburdoo creeks, which are adjacent to the two pits, and Ratty Springs, located upstream from 4WEST and within Pirraburdoo creek. The spring and creeks hold cultural heritage significance for local Aboriginal communities. Two of these, the Gobawarrah Minduarra Yinhawanga (GMY) and Innawonga native title claim groups, initiated hydrological work on the two creeks and Ratty Springs, with the aim of determining the affects of dewatering on the natural water flows of these systems. The numerical model used to simulate drawdown in the Pirraburdoo and Seven Mile Creeks was derived from PMWIN Pro software and covered an area of 77 km2. The modelling period was from January 1998 to December 2004, and the prediction period was from January 2005 to December 2015. The model has four layers and incorporated effects caused by mining voids, 4WEST and 4EAST pits, creek bed material, weathered bedrock below creeks and surrounding banded iron formations (BIF). The model has been calibrated using the trial-and-error method set down by Middelmis et al (2001). The current dewatering schedule (12 ML/day) in the 4WEST and 4EAST mining areas does not affect the water table levels in the adjacent creeks significantly or for any considerable periods of time. However, changes to mine plans may occur, for example, in response to changed commodity price and may lead to significant increase in rates of vertical advancement. This, in turn, affects dewatering schedules, as greater vertical advancement requires increased dewatering effort. When an accelerated mine plan is applied to the model and dewatering rates increased to 18 ML/day, drawdowns in the creeks are more noticeable. The model has therefore helped to indicate the extent to which increased dewatering rates may be acceptable, especially in terms of immediate and longer-term damage to riparian species, ie Melaleuca and Eucalypt. Predictions from the model may also allow mine planners to schedule decreased rates of vertical advancement, where these are required to meet environmental constraints.

Jan 1, 2006

Quay Magnesium Limited (QMG) listed on the Australian Stock Exchange in late September 2004 having raised approximately A$30 million with the object of designing, constructing, commissioning and operating a 15 000 tpa magnesium alloy production facility in Nanjing, China. Site construction commenced in February 2005, with installation of all major components completed by the end of October 2005. Hot commissioning was simultaneously commenced with the final stages of installation, leading to the first stage of continuous ingot casting by mid November 2005. Since that time, ramp-up to the name plate capacity has been undertaken. This presentation highlights some of the more significant technical and logistical hurdles that have had to be overcome in order to meet the high quality product specifications required by a range of QMG customers.

Jan 1, 2006

BHP Billiton Olympic Dam produces copper cathode, uranium oxide concentrate and refined gold and silver. The operation is comprised of an underground Mine and Processing Plant and is located 560 km north of Adelaide. Water for the operation is sourced from two wellfields located 120 and 200 km from the operation in the Great Artesian Basin (GAB) at a rate of approximately 36 ML/d. Regulatory drawdown limits were established to protect regional GAB springs and are monitored at compliance bores. Drawdown was predicted in the æOlympic Dam Environmental Impact StudyÆ (Kinhill, 1997); however, pumping at higher volumes may have the potential for increased drawdown resulting in a trend towards the compliance limits. In recent years increased usage of water in the Concentrator and Hydromet sections of the Processing Plant has caused excess process water reporting to the Tailings Retention System (TRS). This has resulted in excessive amounts of liquor ponding on the tailings cells with a potential impact being contamination due to seepage of liquor to groundwater. Effective management of water by the operation is necessary to both reduce GAB drawdown and reduce the amount of liquor on the tailings cells. A site working-group has been established to investigate and pursue opportunities to improve the water use efficiency of the operation. This paper will highlight the issue of water management at Olympic Dam and discuss the various options currently being investigated to improve management of this important resource.

Jan 1, 2006

By D Craw, J Pope

The Greenland Group, Westland, can be characterised with respect to environmental issues by the application of a GIS database (DAME), and specific sampling campaigns. Waters draining gold mineralised areas have a distinctive chemistry characterised by neutral pH and arsenic as a trace element. The acid neutralising capacity (ANC) from carbonates usually exceeds the maximum potential acidity (MPA) from sulphides resulting in circum-neutral pH. These waters are readily distinguishable from waters draining coal mine related areas, which commonly have low pH (~4) and low As concentrations (~0.1 ppm). In contrast, dissolved arsenic mobilised from Greenland Group historic gold mining areas is up to 2.4 ppm. This As mobilisation is controlled by the secondary As mineral, scorodite (FeAsO2+2H2O). Maximum dissolved As concentrations increase with increasing pH, corresponding to the increasing solubility of scorodite with increasing pH. Dissolved As is attenuated by dilution, precipitation of scorodite, and/or adsorption to iron oxyhydroxide (HFO). Adsorption to HFO is an important attenuation mechanism in and adjacent to many mine sites. HFO is abundant at mine sites where pyrite was abundant in fresh rock, such as where the mineralised zone is dominated by disseminated pyrite. Pyrite, and resulting HFO, are relatively rare where mineralisation occurred as well-defined quartz veins. Localised HFO occurs also where ankerite oxidises in host rocks. Arsenic output flux (ca. 25 g/day) from historic gold mine sites is commonly less than the natural background flux from mineralised rocks (>5000 g/day).

Jan 1, 2006

Increasingly, mineral operations need to manage water as a key business asset. Managing water solely as an environmental issue leaves a business exposed to social, cultural and economic risks associated with water. Adopting a company-wide strategic approach, which takes account of the true value of water will provide businesses with opportunities and risk protection. Rio Tinto has recognised the business imperative for water stewardship and has responded by producing the Rio Tinto Water Strategy. This strategy commits the company to managing water assets in a responsible manner, taking account of environmental, social and economic values. To incorporate the true value of water in site decision making, a new set of tools is required at the operational level. A key part of the strategy focuses on developing a framework to value water based on case study examples from around the Group. This paper presents progress on the companyÆs experiences in developing and implementing the water strategy.

Jan 1, 2006

By Ruilin Lang

This paper presents an application of 3-D plots and non-linear regressions to define a sitespecific form of the charge weight scaled distance. The PPV (PPA) of single hole blasts is normally considered as a function of two independent variables - the charge weight and the distance. It is of great importance to obtain the relationship of the function accurately for a concerned site in terms of blast vibration analysis and modeling. However, in pre-computer time it was difficult to plot 3-D graphs. Consequently, a charge weight scaled distance was used to plot the PPV (or PPA) against the scaled distance as 2-D graphs. Blast vibration investigators use several forms of the charge weight scaled distances to plot data. We can exemplify them with the cube root of charge weight scaled distance, the square root of charge weight scaled distance, and other forms (Hossaini and Sen, 2004). Each of these scaled distances assumes relative contributions of the charge weight and the distance to the vibration attenuation. For example, the charge weight is assumed to have a less contribution to vibration in the cube root scaled distance than it is assumed in the square-root scaled distance. In reality, for different sites the relative contribution of the charge weight and the distance may be different and site-specific. This may explain that in some cases, the blast vibration data plots using these charge weight scaled distances are scattered. This could be largely due to the fact that the definition of the form of the charge weight scaled distance is not adequate for the particular site condition.

Jan 1, 2006

By P Lindsay

A numerical model has been developed to simulate the effectiveness and costs of a number of conceptual remedial measures aimed at reducing acidity and metal concentrations in the Ngakawau River and its tributaries near the Stockton Coal Mine, situated on the West Coast of New Zealand. The Stockton Coal Mine has been in operation over the past 100 years. During that time, seepage from waste rock dumps has contributed to elevated acidity and metal concentrations in the Ngakawau River and some of its tributaries. The yearly mean rainfall at the mine site is 6000 mm. The model, developed using GoldSim software, simulates rainfall, run-off and stream discharge for 26 tributaries. It then calculates acidity and metal concentrations in the mine impacted tributaries and the dilution downstream from the mine. The model has been calibrated to measured flow and acidity and metal concentrations in the Ngakawau River and some of its tributaries. Acidity and metal loads are removed from the system in accordance with specified efficiencies and capacities of the respective conceptual remedial measures. The user can compare specific remedial measures, or a combination of conceptual remedial measures. The model predicts the acidity and metal concentrations at a number of monitoring stations for any remedial strategy selected by the user. It also calculates the capital and operational costs for that particular remedial strategy. This paper presents the development of the numerical model and describes how the end-user can use it to compare the efficiency and costs of various remedial strategies by running different æwhat ifÆ scenarios.

Jan 1, 2006

By D Crequer

Land rehabilitation at Golden Cross is reviewed, 8 years after mine closure in 1997/98, from the perspectives of a Peer Reviewer (land rehabilitation) and a Regional Council Officer (Resource Consents compliance). Land rehabilitation items we discuss include: management of restored pastures, native plantings (on-site riparian and block plantings and off-site environmental riparian enhancement plantings), wetlands (on-site tailings lake and sediment ponds littoral zone plantings, and basement of the open pit; and off-site wetlands enhancement plantings), pine plantations on-site and on surrounding land, stabilization of the Tailings Lake Embankment (landslide) and Open Pit capping, capping of acid-mine-rock, stability of discharge channels, buildings and amenities, public access for recreation, educational uses, and future management of the site. Pest control has helped to conserve the rare and endangered HochstetterÆs (Leiopelma hochstetteri) and ArcheyÆs (L. archeyi) frogs, and a regionally significant stand of rare swamp maire (Syzygium maire) has been conserved and fenced.

Jan 1, 2006

By R Vleggaar

In addressing a short-term operational need for the relocation of a tailings storage facility reclaim pond, a mine has achieved a host of water management objectives. Through effective planning and adoption of a strategic æwhole of mine lifeÆ approach, the mine has achieved significant environmental, social and economic benefits. A review of all water management aspects across the site identified a host of other interrelated water issues and concerns which, if dealt with individually, would prove too costly for individual operational departments. When considered as a whole, however, the issues became opportunities and provided the stimulus for integration of the site water management system. The development of site water and solute balance models provided the tool by which a number of water management options/strategies could be evaluated. The conceptual design and costing of the proposed water infrastructure further facilitated the evaluation of the multiple benefits to be gained from each option. A business case could then be made to mine management for the preferred option. The recommended water management strategy finally recommended to the mine not only provided a tailings storage facility (TSF) reclaim pond, but also provided for:increased wastewater recovery from the TSF, the capture of all waste rock dump run-off, additional water harvesting from local creeks, increased wastewater reuse, improved environmental water management, infrastructure that could be used by the local community after mine closure, and overall cost savings. This paper illustrates how effective water management planning can provide both short-term economic and environmental benefits, as well as long-term social benefits.

Jan 1, 2006

By Lyn Jones, Mike Bratty, Rick Lawrence, David Kratochvil

"The treatment of water is required at many mining operations to remove metals and prevent the discharge of contaminated water to the environment. In other cases, water treatment is used to provide better quality water for recycle to the processing plant, or to process bleed streams in hydrometallurgical operations in order to prevent deterioration in metallurgical performance or process equipment. BioteQ Environmental Technologies Inc. has developed and commercialized the BioSulphide® Process which can provide an alternative for these treatment needs and which can also be used for profitable metal recovery, particularly in cases where conventional metal winning techniques are not economical. The BioSulphide® Process is a high rate anaerobic biotechnology for on-site production of H2S from sulphur species, although for smaller flows and metal loadings, the use of chemical sulphide reagent might be more cost effective. Both new projects and existing commercial operations, used for removal and/or recovery of copper, nickel, and zinc, and which range in sulphide generating capacity from 50 kg/day to 3.7 tonnes/day, are discussed. Particular focus is placed on the results of operations at the Raglan Mine in Northern Quebec where dissolved nickel is removed from contaminated water at a high efficiency through the precipitation of nickel sulphide. Plant effluent is discharged directly to the receiving environment and the high-grade nickel sulphide product is combined with the nickel flotation concentrate produced at the mine. The plant at Raglan will replace the existing conventional water treatment plant and will eliminate the need for on-site storage of treatment plant sludge.INTRODUCTIONThe BioSulphide® Process, which produces low cost H2S for use in selective metal precipitation, offers a low capital cost alternative which can operate efficiently and cost-effectively within a wide range of flows and solution grades. Since the technology can be used to recover metals from solutions with low flows and metal grades, the technology is also applicable to environmental applications for water treatment, with the sale of recovered metals providing an offset to treatment costs. For environmental control, the technology has a distinct advantage in being able to meet strict effluent discharge criteria due to the very low solubility of metal sulphides. To date, BioteQ Environmental Technologies has designed and constructed three plants for metal sulphide precipitation, with another three projects in the advanced development stage."

Jan 1, 2006

Accurate geometric models of orebodies establish the framework for reliable mineral resource estimates that provide a basis for further exploration and mine planning, as well as for financial models that ultimately determine the economic viability of a deposit. Traditional, explicit geometric modelling techniques that are utilised for resource modelling by the general mining software packages, such as MineSight«, involve manually digitising interpreted ore outlines that must be carefully linked to create valid geometric solid models. An alternative, implicit modelling method, employed by LeapfrogTM software relies on a fast method of global interpolation, which offers several advantages over traditional modelling techniques. Although previous case studies have documented the relative efficiencies of the two approaches, the accuracy of the two methods has not been previously quantified and compared. This study quantifies the accuracy of solid models created using explicit and implicit methods, and compares the differences between the models. Solid models of the Doris Hinge vein gold deposit (located in the Hope Bay district, Nunavut, Canada) are constructed from preliminary and follow-up drilling data using both modelling techniques. The accuracies of the solid models generated using preliminary drilling data are determined by measuring the 3D distance between the surface of the models and the actual contact location defined by the follow-up drilling data. Additional comparisons based on volume, cross-sectional area and surface differences were made between both phase 1 solid models and solid models constructed from phase 2 drilling information. The overall results of this study find that the MineSight« and LeapfrogTM solid model accuracies are virtually the same, and that their volume, cross-sectional area, and surface differences are comparable. This study concludes that the implicit modelling technique generates accurate solid models that can be used in place of explicit models as ore shells for resource estimation in certain circumstances.

Jan 1, 2006

By Robert Lee, Jeff Corace, Rob Cyr

Blasting in the heart of the historic Byward Market District of Canada’s capital, Ottawa, presents a unique set of challenges. The obvious difficulties arising on projects requiring blasting within 3 m (10 ft) of 125 year old buildings in various states of disrepair have been encountered and successfully dealt with countless times before. The complexities increase exponentially when tenuous property boundaries, unknown structural details, litigious histories and the need for encroachment agreements lead to individuals with competing interests all able to impact the same operation. Blasting on three projects in the Market was started in early 2005 after months of negotiation. Ultimately, the potential for the projects to proceed hinged on the ability to successfully disseminate blast data to the various stakeholders. As part of the agreements drawn up, property owners demanded immediate notification of the measured vibration levels with contract provisions including clauses such that any exceedance of the USBM criteria immediately triggered project shut down and complete blasting program redesign, and approval by all parties. With stakeholders located in various cities and, in some instances, on various continents, a conventional attended monitoring strategy would not satisfy the requirements. In response to the critical reporting need, Explotech Engineering Ltd. installed unattended monitoring stations around the sites, all incorporating wireless telemetry. After each blast, data was automatically transferred from the monitoring stations to a web-linked server via the wireless network, where it was immediately available to project stakeholders through a password protected website. The solution required a unique blend of data acquisition, telemetry, database, and security technologies, all married to produce a reliable system that was easy to maintain and use. While these types of systems were originally developed for use as permanent monitoring networks in operating mines and quarries, monitoring professionals are increasingly benefiting from the technology on temporary building projects that have typically been the realm of attended monitoring strategies. Globally, this has emerged as a solution to provide more timely access to data for stakeholders, and to minimize the legal exposure from multiple violations of vibration limits. As this trend is likely to continue, the regulated vibration control industry is likely to see a continued shift in technology development to leverage wireless networks and the Internet to continue to improve data transfer, archiving and distribution.

Jan 1, 2006

By Khaled Morsy

The studied mine extracts the Sewickley seam using room-and-pillar method. The overburden at study site ranges from 400 to 800 ft. Eight years earlier, the Pittsburgh seam was mined 80 ft underneath the Sewickley seam. Parts of the mains at the study site experienced problems of rib spalling associated with floor heave. Numerical modeling was used to explain the mechanism of ground control problems encountered at the mains of the upper seam. The modeling results show that the ground control problems encountered were caused by multiple seam interactions with the previously mined longwall panel of the lower seam. Based on the modeling results, a criterion to predict the probability of multiple seam interactions was proposed.

Jan 1, 2006

By Richard F. Sliwoski

The Virginia State Capitol was designed by Thomas Jefferson and constructed in 1785. The Capitol is of great historic and architectural significance to not only the Commonwealth of Virginia but to the nation. It is the oldest operating Capitol in the U.S. and required a total restoration/renovation as well as an expansion to continue to remain functional. Site conditions dictated that the expansion (a new visitor center) be placed underground on the south side of the Capitol building, requiring a 40-foot deep excavation approximately 5 feet from the Building. Because of its historic significance, every measure had to be taken to ensure the safety and function of the Capitol during construction. The construction techniques that were used to make the deep excavation and protect the historic Capitol included a tied back concrete slurry wall, jet grouting, compensation grouting, and instrumentation monitoring. This paper describes the history of the Capitol building, the techniques that were employed for construction of the deep excavation, results of the latest movement monitoring, and factors contributing to meeting the restrictive movement goals.

Jan 1, 2006

Water is an integral and essential part of mining business. Two issues crucial in the management of this resource, scarcity and excess, are increasing awareness of the importance of water and changing the value perceptions of the industry because they affect both the existence and continuation of the business. Therefore its value should be reflected in the water management that is practised on site. Historically water in mining has been perceived to be of low value so management practices have not been good or well implemented. Political and social transformation in South Africa has been accompanied by the promulgation of new legislation. South African water law is now underpinned by Integrated Water Resource Management (IWRM) principles. It impacts water pricing, provides for water pollution charges, prioritises water users, has specific mining and water related components and requires water licensing as part of the licence to mine. Mining no longer has a priority on water resources and has to compete with other water users to gain access to resources. New institutional arrangements are being put in place to implement the regulations. All this requires a paradigm shift in miningÆs view of water. Generally the sector is still catching up with the new requirements, principles and philosophies. However, the way in which South African mining values water is changing. This is demonstrated in partnerships between the industry and other water users. These partnerships are Integrated Water Resource Management (IWRM) in practice and they achieve sustainable development goals. These partnerships are essential for mining to stay in business, expand operational capacity, reduce impacts, prevent legal action and reduce reputational risks.

Jan 1, 2006

By P. S. Arthur

The ISASMELT? process is a submerged lance smelting technology operating in smelters in Australia, the USA, Belgium, India, Germany, Malaysia and China. Further plants are under construction in Peru and Zambia. Following the invention of the Sirosmelt lance technology Mount Isa Mines recognised the commercial potential in the novel top blown bath smelting process and embarked on a development program that has lasted more than 25 years. After successful operation of pilot plants and demonstration plants producing copper and lead, Mount Isa Mines decided to license the technology to external companies. Since the purchase of Mount Isa Mines by Xstrata in 2003, Xstrata Technology has assumed responsibility for transferring the technology to ISASMELT? licensees. In the 15 years since the first commercial furnaces started operation plants have been constructed (or are under construction) with a combined annual smelting capacity of more than six million tonnes of concentrates or secondary raw materials. Process development continues on the commercial scale plants at Mount Isa and elsewhere. Many of the improvements implemented by plant operators have been passed on to, and adopted by, other licensees. Exchange of ideas and technical improvements occurs through ad hoc visits to fellow licensee sites and through regular licensee workshops arranged by Xstrata Technology. This paper updates the reader on the status of various ISASMELT? plants either operating or under construction. It highlights the important role that the technology provider?s operational experience plays in ensuring that new smelting plants ramp up quickly to nameplate capacity.

Jan 1, 2006

By A. Noël, R. Lapierre, M. Provencher

"Modem aluminum smelters are facing significant operating cost pressure. Key methods used by smelters to manage this pressure are automation and production-information systems to optimize processes, manage quality, anticipate problems and reduce operating costs. In 2002, Aluminerie Alouette Inc. began its Phase II Expansion project, and retained the joint venture of SNC-Lavalin and Hatch (SLH) as its engineering, procurement and construction management (EPCM) team. Alouette had the distinction of being one of the most efficient aluminum smelters in the world. Alouette already understood the importance of systems integration in project delivery. For Phase II, key objectives were identified to ensure ""a state of the art"" integrated architecture that would support Alouette's production goals to integrate the existing facilities with the expansion, to form a single efficient facility and meet project schedule and budget targets. Achieving those objectives within the context of a large project often creates major challenges due to the nature of the traditional EPCM delivery model, which relies on several vendors and third-party-systems integrators. In this case, an integrated Alouette-SLH team was made responsible for all aspects of the systems integration, taking over the task from most suppliers. The integrated team was responsible for delivering an automation system and plant-wide-production IT system for the new facilities while accommodating migration for the existing systems. Through the use of rigorous methodology and advanced state of the art technology, the IT and automation strategy led to significant value creation and is recognized today as one of the key factors of the project's success. The primary results were: fast and efficient start-up of facilities, due to quality programming and implementation; a plant able to operate as a single entity; automation and IT systems delivered before time and under budget; standard programming methods implemented throughout the plant; and reduced and simplified maintenance."

Jan 1, 2006

By Maria de Campos

The pre-reduction behaviour of chromite particles in methane-argon and methane-hydrogen gas mixtures was investigated between 1050°C and 1250°C. Loose bed of chromite particles were reacted in a vertical tube furnace under a pre-set gas mixture predetermined time intervals. Metallization results were obtained for the Cr and Fe components by chemically analyzing the reaction products. SEM-EDAX techniques and X-ray diffraction were employed to elucidate the reduction mechanism. It was found that higher reduction kinetics and higher Cr:Fe ratios in the metal phase would be achieved when hydrocarbon gas was used in comparison to classical carbothermic reduction at a given temperature. The reduction rate was generally bulk gas mass transfer controlled to the reaction site for initial stages which then was followed by ionic diffusion rate control. It is proposed that methane did not partake directly in the reduction but cracked, presenting the reaction site with hydrogen gas and atomic carbon, which was able to immediately react at the immediate area of reduction regeneration CO and H2 and thus maintaining a low partial pressure of oxygen at the reaction site.

Jan 1, 2006