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"Recycling of solid wastes plays an important role in environmental protection. However, solid wastes are often contaminated with some undesired components so that many of these solid wastes are hardly economically recycled. Therefore, effective and efficient separation of undesired components from solid wastes becomes a crucial step for sustainable recycling of the solid wastes. There exist three general strategies of separation of undesired components from solid wastes: before-process separation, post-process separation and in-process separation. In this paper, different separation strategies are discussed in terms of energy requirement and availability, implementation complexity and additional need for environmental protection. It is concluded that of all separation strategies, in-process separation has the least energy requirement, the least implementation complexity and the minimum need for additional environmental protection.IntroductionIn industries, solid wastes almost come with every production process. Multi-million tons, if not billion tons, of solid wastes are being generated globally each year. These solid wastes are lowvalue materials in general, and often have very limited markets. As a matter of fact, many of these solid wastes have been stored on site or have been disposed of at landfills for many years, not only occupying lands, but also polluting environment. Therefore, effective and efficient recycling of solid wastes has been a very challengeable task and has played a very important role in environmental protection.One of the major barriers which hinder recycling of solid wastes is contamination of the solid wastes with some undesired components. These undesired components are components which are not wanted by production processes or applications where the solid wastes are consumed or recycled, since the undesired components often degrade qualities of the solid wastes, imposing negative effects on operations, facilities and product qualities of the production processes or applications. Sometimes, the undesired components may also pose severe environmental concerns. When undesired components are present in solid wastes at over-limit levels, the solid wastes tum to become destructive, useless and non-recyclable. Consequently, effective and efficient separation of undesired components from solid wastes becomes a crucial step for sustainable recycling of the solid wastes."

Jan 1, 2014

By B. van Beek, J. H. Zietsman, A. Lexmond, N. J. Andrew

"In platinum group metals (PGMs) smelting, the slag-to-matte ratios are very high (approximately 4:1 to 9:1). The slag temperature therefore has a strong influence on matte temperature, which is a continual concern due to the low matte melting temperature and its resultant high superheat. Maintaining a stable slag temperature is therefore a critical safety and operational issue. This project aims to improve the understanding of the slag bath temperature drivers so that a more effective slag bath temperature control strategy can be implemented.With the aim of developing a multiphysics model of the furnace, extensive data analysis was performed to develop an in-depth understanding of the process before the start of modelling work. In this work, the effect of fluctuating furnace feed composition on slag temperature was examined. The results are based on equilibrium calculations using FactSage, implemented with ChemApp.A method was developed, using an equilibrium calculation at 25°C, to convert the available chemical assays to approximate mineralogical assays in order to determine the feed enthalpies. Actual 2013 furnace feed data was used and the average specific energy requirement to produce slag and matte at 1600°C was calculated to be 671 kWh/t concentrate. The furnace energy input was then kept constant, and it was found that the slag temperature varies significantly as a function of the feed composition. These results were compared to actual slag temperatures measured on site. It was found that close management of the furnace energy balance is important for maintaining a stable slag temperature."

Jan 1, 2014

By B. Waterman, D. Ramey, L. Schlink

"Water is a primary commodity for most industrial processes. It has become a global focus in light of climate change and population growth. Reuse of process water has two major benefits - minimize the amount of fresh water added now and minimize the amount of discharge water that requires treatment later.Mining and mine product processing has its share of reused water. For example, reclaim water from a tailings impoundment, overflow from thickeners and leach solution to raffinate and back again all demonstrate the use and reuse of water in mining circuits. Eventually, a mine reduces production or ceases operations completely, eliminating the option to reuse the impacted water and, thus, requires treatment of the remaining water.Current methods of water treatment remove the impacts, providing clean water for discharge, but leaves behind a concentrated waste that requires further treatment or disposal of a hazardous waste. Freeport- McMoRan is currently testing three water treatment technologies specific for sulfate and/or metal removal from mine impacted water with the approach of transformation not concentration. These technologies provide clean water for alternative use while creating byproducts that could be marketable, or disposed as a nonhazardous material, thereby reducing the cost and longterm liability of disposal.The selection of a water treatment process is site-specific. The volume of water, contaminant to be removed, disposal options, length of time for treatment, location of plant and reagents and discharge requirements are some of the factors that need to be considered when selecting a water treatment process. Common water treatment technologies for mine impacted water consist of low- or high-density sludge (LDS/ HDS), reverse osmosis (RO) and evaporative technologies. In addition to operating costs, these processes require additional handling of the concentrated sludge or brine. Advanced water treatment technologies include ion exchange, solvent extraction and metals precipitation with or without the aid of a biological system. Some of the more complex systems have a series of unit operations to achieve required discharge regulations."

Jan 1, 2014

By Alfred Guenkel, Kyle Marte, K. Nikolaisen

"The INCO SO2/air process was patented by INCO in 1985 (Borbely, Devuyst, Ettel, Mosoiu & Schitka, 1985). Well over 80 mining operations worldwide are using this process to oxidize cyanides to cyanates in the tailings from gold, silver and copper mining operations. Though it is possible to supply sulphur dioxide (SO2) in either gas or liquid form, the majority of these SO2/air operations use sulphite-based salts as the ‘SO2’ equivalent reducing agent. This is probably due to the lower capital cost, safety concerns with, and availability of liquid SO2. Sodium metabisulphite (SMBS) is commonly employed, and its cost is an order of magnitude higher than that of sulphur. The increased capital expenditures (CAPEX) for a sulphur-burning SO2 gas plant could have a pay-back of less than two years. In addition, a SO2 gas plant offers potential for significant heat recovery from the sulphur burning process. In terms of safety, the SO2 gas plant only requires the storage of relatively benign sulphur and the site inventory of SO2 will be limited to the plant gas inventory. Furthermore, a SO2 gas plant will not trigger the US Clean Air Act Section 112(r) accident prevention regulations, as may be the case for liquid SO2.Most existing mining operations using ‘SO2’ are gold operations, but in recent years there has been an increased interest in larger sulphur dioxide gas plants for hydrometallurgical facilities that employ leaching of cobalt/manganese minerals or precipitation of manganese/iron (e.g. Tenke Fungurume and Boleo).This paper discusses the different processes which require SO2 as a reducing agent and compares the capital and operational costs of a SO2 gas plant to conventional process alternatives using sulphite-based salts or liquid SO2.The heart of the SO2 gas plant is the sulphur furnace. The most economical way to produce SO2 is by combustion of sulphur in air producing up to 19.5 vol% SO2. Examples of large and small sulphur furnaces are discussed in terms of design, operation, and impacts on operational costs.The SO2 gas produced in a sulphur-burning plant has to be contacted with the liquor to be reduced. The choice of gas-liquid contacting device is important, and two contacting devices are discussed: 1) Gas sparging into the bottom of leach tanks (high, nearly constant, back pressure due to liquid head) and 2) absorption columns (low gas-side pressure drop)."

Jan 1, 2014

By A. R. House, G. W. Shepherd

Newmont USA Limited owns and operates the Phoenix Mine near Battle Mountain, Nevada, USA. The existing milling facility has operated since 2006 (House, 2010). Following the startup of the milling operation, and coupled with the upswing in the copper market, Newmont realized that Phoenix had no process option to treat transition and oxide copper ores. This meant that potentially revenue generating ore would be mined as waste. With no system in place to treat the transition and oxide copper, work began to determine the most feasible approach. After evaluating multiple options, the flow sheet was set for a runof- mine (ROM) heap leach pad and solvent extraction/ electrowinning plant (L-SX/EW). This paper will discuss the eight years of successes and challenges with developing the copper L-SX/EW plant and achieving commercial production of copper cathode.

Jan 1, 2014

By Jeffrey A. Yonkey, Timothy J. Lutz, Jacob L. Carr, Christopher C. Jobes

"Since 1984, there have been 39 fatalities involving striking and pinning of the operator and other workers by the continuous mining machine (CMM). In January 2015, the U.S. Mine Safety and Health Administration (MSHA) finalized a regulation to require proximity detection systems on all continuous mining machines except full-face machines (MSHA, 2015). Proximity detection systems are designed to stop machine motion to protect miners from striking/pinning hazards. Several MSHAapproved proximity detection systems are commercially available.NIOSH researchers have been involved in the development and testing of proximity detection technology since creating the HASARD system (Schiffbauer, 2002) and have recently conducted research intended to develop more advanced proximity detection technology for CMMs (DuCarme et al. 2013; Jobes et al. 2012; Carr, DuCarme et al. 2013 and Carr, Li et al. 2013). In addition, NIOSH has also conducted research investigating how the signals of a proximity detection system propagate (Li, Carr et al. 2013 and Li, Jobes et al. 2012) and have developed a novel method for determining the location of a personal wearable device (PWD) relative to the magnetic field generators (Carr et al. 2010 and Jobes, et al. 2012).To evaluate the performance of proximity detection systems implemented in industry, NIOSH researchers conducted tests in 2013 on three systems installed on CMMs at three underground mines in Illinois and West Virginia. The results of these tests indicated that, while generally consistent performance was observed, there were opportunities for improving performance. These results were presented at the 2014 SME Annual Meeting (Carr, Lutz, et al. 2014). Since that time, second-generation systems have become available to the industry and are becoming more commonly used.Beginning in early 2014, NIOSH researchers conducted underground testing of these secondgeneration proximity detection systems installed on CMMs. Five tests were conducted on four installations of second-generation proximity detection systems, with one installation being tested twice. The tests were conducted at mines located in Illinois, Virginia and Kentucky with seam heights ranging from 137 cm (54 in.) to 213 cm (84 in.). These tests were conducted using the same test protocol used during first-generation testing, which is summarized in the following section."

Jan 1, 2014

By M. Westendorf, T. Banerjee, S. Kaushik, D. Tinney

"Cyclones are one of the most extensively used pieces of equipment within the mineral processing industry because of their simplistic operating and maintenance philosophies. They are commonly used as classifiers within the comminution circuit to control the grinding product particle size for satisfactory performance of downstream operations.Cyclones are a key contributor to the effective operation of the plant and have a significant impact on the mineral processing plant operations. If the cyclones are not performing as they should, the results are often a combination of lost recovery, grade, capacity and reduced throughput. Similarly, an inefficient cyclone operation may also lead to low or high recirculating loads that impact the efficiency of the comminution circuit. This highlights the importance of having proper stability in cyclone operation while implementing any plant-wide optimization strategy.One of the key challenges in cyclone operation is that cyclones are highly sensitive to changes in operating conditions and are affected by process fluctuations such as feed pressure, solids concentration and flow rates. Fluctuations in cyclone feed characteristics lead to unstable cyclone performance which affects mineral liberation. For such an impactful unit operation, cyclones have historically been under-instrumented in an otherwise highly instrumented process plant. Traditionally, mill operators have relied on visual observations of the apex discharge to determine the operating state of the cyclones. Visual cues corresponding to the different cyclone operating conditions have been discussed by Neesse et al. (2004) as shown in Fig. 1."

Jan 1, 2014

By W. G. Pariseau

"The Crandall Canyon Mine (CCM) is located in the Wasatch coal field in central Utah. Extensive longwall mining at CCM preceded a decision to recover coal left in barrier pillars on each side of a set of main entries extending far into the mine. During mining in March 2007, a major bump occurred that led to cessation of mining in the barrier pillar on the north side of the mains and to the start of mining in the south barrier pillar. Subsequent loss of ground control in August 2007, through coal pillar bursts had tragic consequences with loss of six miners and shortly afterward three rescue team members. A U.S. Mine Safety and Health Administration (MSHA)report describes the events in detail (MSHA, 2008).An important lesson to be learned from CCM is the need to select a computer program suitable for pillar design. Computer programs are engineering tools and selecting the right tool for the job is essential. In this regard, minimum program requirements include capability for computing stress distribution within a pillar and adjacent roof and floor strata. The reason is simple: strength of rock is stress dependent; both vary from point to point in pillars and adjacent strata. Preferably, one should follow the evolution of stress as the mining plan is executed from start to finish to assure safety or to warn of a potentially hazardous situation developing as mining progresses.The approach to the problem posed by barrier pillar mining at CCM is conventional in the sense of applying well known finite element modeling techniques to analysis of a proposed mining plan. The engineering purpose is to evaluate the mining plan with respect to ground control questions including roof, floor and pillar safety. Results of previous two-dimensional finite element analysis indicated pillar safety was by no means assured (MSHA, 2008; Pariseau, 2008; Pariseau, 2011). Geometry of barrier pillar mining is limited in two dimensions for example, crosscuts are not seen in vertical cross sections. While three-dimensional analyses are preferred, even moderately sized regions often lead to very large problem sizes that exceed computer capabilities. However, a recent development in finite element modeling of tabular deposits allows for whole mine analysis in three dimensions. This technique involves a dual node - dual mesh concept. Both have been used separately in much earlier work, but are only now used in combination. It is possible to have an estimation of subsidence at a kilometer scale and details of stress, strain and displacement about barrier pillars, main entries and pillars, and so on at a meter scale (Pariseau, 2014). No compromise involving empirical formulas or similar guess work is required. Indeed, all calculations are based on first principles: physical laws, kinematics, and material laws. Effects of joints and in situ variability or uncertainty in strata properties, elastic moduli and strengths, may be included for greater realism. An important objective of the present study is to assess the role of three-dimensional pillar geometry in arriving at conclusions regarding barrier pillar mining versus two-dimensional results."

Jan 1, 2014

By Fredrik Sarvell, Harald. Ihler, Veli-Matti Uotinen, Jukka Rantala

"Many of the valid international building codes state that the lateral support provided by the soil is sufficient to prevent buckling of fully embedded piles. However, the development of small diameter micropiles and especially the use of high strength steel have evolved to applications including high capacity elements. The ultimate structural load bearing capacity of a pile in a cohesive soil is decided by examining which gives the lowest value, the peak buckling load and the resisting moment provided by the surrounding soil medium or the structural capacity of the pile cross section. In both cases, the initial deflection of the pile is a significant factor when the axial load bearing capacity of the pile is determined. Steel micropiles are joined commonly with mechanical splices. A less rigid mechanical splice is often a weaker hinge that allows the pile to bend and deflect more during installation increasing the initial deflection of a pile. In addition the less rigid splice element decreases the bending capacity of a jointed pile section and the ultimate axial load capacity of the entire pile. A series of FE analysis performed for various pile sizes suggest that the steel pipe piles including separate pile sections and mechanical splicing elements should have the combined bending stiffness of EIshaft = 0,75 × EIpile. This requirement yields to the buckling resistance of at least 96 % of the solid reference pile with the sameinitial eccentricity in similar soil conditions.IntroductionMany of the valid international building codes state that the lateral support provided by the soil is sufficient to prevent buckling of fully embedded piles. However, the development of small diameter micropiles and especially the use of high strength steel have evolved to applications including high capacity elements. The potential buckling of these very slender high capacity piles in soft soils may in many cases be the controlling design factor of the pile, especially with end bearing micropiles.A typical sequence of soil strata in Nordic countries, such as Norway, Finland and Sweden, constitutes of friction soil or dry crust clay on top of soft clay followed by till. This soil stratum often rests on solid bedrock of granite or gneiss. Conditions like these are suitable for slender end bearing piles subjected to buckling and especially steel pipe piles where most of the material is located at the edge of the cross section. Other reasons for using slender steel pipe piles are for example fast installation with minimal waste, efficient manufacturing and relatively well established design and execution procedures. Minimum quality criteria’s regarding splices for steel pipe piles are recommended to be set as national provisions to ensure quality and comparable procurements in foundation business."

Jan 1, 2014

By K, J. MAUNDERS

This paper briefly describes a computerised model of the South African electricity system which has been developed jointly by the Atomic Energy Board and the Electricity Supply Commission. The results of an analysis of this system have been subjected to a fairly extensive sensitivity analysis which reveals that up to the year 1990 between 680 and 700 million tons of coal will be required for electric power generation, together with between 7 000 and 10 000 tons of uranium. This result is fairly insensitive to data variations, but the prediction of a cumulative requirement up to the year 2000, of between 1 300 and 1 800 million tons of coal and 25 000 to 70 000 tons of uranium, proves to be very data-sensitive.

Jan 1, 2014

By Don Ibana

Supported by the Minerals Council of Australia (MCA) through the Minerals Tertiary Education Council (MTEC), three Australian universities–Curtin University, Murdoch University and the University of Queensland–have formed the Metallurgical Education Partnership (MEP) to jointly develop and deliver an engineering design capstone unit–Metallurgical Process and Plant Design–in their respective undergraduate programs in extractive metallurgy, in order to enhance the students’ educational experience. A unique feature of the program is the close interaction of the students in all three universities and a significant involvement of industry professionals. Now in its sixth year, it is clear that this unit is achieving its objectives

Jan 1, 2014

By Mark William Kennedy

Modern metallurgical plants typically have complex flowsheets and operate on a continuous basis. Real time interactions within such processes can be complex and the impacts of streams such as recycles on process efficiency and stability can be highly unexpected prior to actual operation. Current desktop computing power, combined with state-of-the-art flowsheet simulation software like Metsim, allow for thorough analysis of designs to explore the interaction between operating rate, heat and mass balances and in particular the potential negative impact of recycles. Using plant information systems, it is possible to combine real plant data with simple steady state models, using dynamic data exchange links to allow for near real time de-bottlenecking of operations. Accurate analytical results can also be combined with detailed unit operations models to allow for feed-forward model-based-control. This paper will explore some examples of the application of Metsim to real world engineering and plant operational issues.

Jan 1, 2014

By Yuzo Hiroshige, Kiyotaka Tahara, Hiroki Hatayama, Masaharu Motoshita, Tomohiko Akahori

Large amount of rare earth metals is stored in the used electric products. Hitachi has started to develop the environment-friendly process for rare earth metals recovery from used magnets. We report here the environmental impact of our process, in comparison with the conventional recycle process utilizing solvent extraction. As an evaluation method, Life-cycle Impact assessment Method based on Endpoint modeling ver.2 (LIME2) developed by the National Institute of Advanced Industrial Science and Technology (AIST) in Japan is applied. It was found that the environmental impact of the new process was more than that of the conventional process. For further reduction of its environmental impact, minimization of energy consumption to operate the equipment was most effective. Decreasing the amount of magnesium, used as an extractant, and the improvement of the extraction rate of rare earth metals were also considered as specific options for reducing energy consumption in the plant development.

Jan 1, 2014

By Arthur E. Morris

The primary market driver for improving process technology is innovation, which requires a skilled and educated workforce. However, many Materials Science and Engineering departments have eliminated extractive metallurgy and chemical thermodynamics from their curricula, yet these topics contain the necessary fundamentals for process innovation. As a result, most MS&E students are ill-prepared for careers in processing. The dearth of processoriented MS&E curricula has prompted some Universities to develop a “shared” effort to offer distance education between multiple institutions [1]. A target audience for a shared process simulation course would not only benefit students, but also be a basis for an on-line course for practicing engineers faced with new or changing career choices. To fill the gap, the basics of a process simulation course was developed in an abbreviated form as series of eleven articles and Excel workbooks published in Industrial Heating magazine between July 2012 and July 2013.

Jan 1, 2014

By Lloyd Robert Nelson

The historical progression in installed electric furnace smelting capacity of some 1650 calcium, chromium, manganese, nickel and silicon ferro-alloys furnaces is reviewed. Key increases in the inherent installed electrical capacity, often achieved through uprating furnaces, are identified. Possible factors facilitating such advances are explored, including: specific process engineering and pyrometallurgical enhancements (e.g., improved control over the consistency, size and chemical form of raw materials, extents of preheating and pre-reduction delivered into the furnace; and patterns of feed distribution); furnace electrical configuration (AC or DC; immersed, submerged-, shielded- or open-arc); form of electrode (graphite, self-baking or composite); furnace configuration (circular or rectangular; closed or open and 1-, 3- or 6- electrodes); better engineering and equipment designs (e.g., high-intensity cooling) and state of furnace electrical and metallurgical control systems. A view is presented on the prevailing state of evolution of the Mega-scale in ferro-alloy smelting and opportunities for still further improvements.

Jan 1, 2014

By Bing Song, Fei Xi, Xuewei Lv, Kai Zhang

The electric arc furnace process is a common method to produce high TiO2 slag from ilmenite. The pre-reduction process was proposed in recent years in order to reduce electricity consumption. In order to enhance the pre-reduction degree, high energy ball milling was proposed to improve the specific surface area of the ilmenite prior to reduction. In this study, the carbothermic reduction behavior of milled ilmenite concentrate was investigated. It was found that the ball milling method can result in a higher reduction rate and improved metallization of iron. The metallization of iron increased with increasing the time of ball milling. The metallization of iron with milling reached 89.49% when the time of ball milling was 70 min., while the FeO content decreased with 70 min. of milling from 11.84% to 4.76%.

Jan 1, 2014

By Roderick I. L. Guthrie, Donghui Li, Mihaiela Isac, Luis Calzado

The HSBC is an ideal process for the production of BMG strips. The purpose of the present work was to investigate the casting of Ca-based, bulk amorphous strips. The possibility of casting three Ca-based alloys (60Ca-20Mg-20Al, 60Ca-15Mg-10Al-15Zn and 55Ca-15Mg-10Al-15Zn- 5Cu (at.%).) was investigated, using the HSBC simulator. Numerical simulation and mathematical modeling were used to predict temperature variations and cooling rates, under different interfacial gaseous atmospheres (helium and air) near the meniscus region. Given the critical cooling rates and glass temperatures needed to be reached for the vitrification of the respective alloys, this leads to predictions of the critical thicknesses possible with this novel casting process. To validate our predictions, these alloys were then prepared and cast onto the sand-blasted, solid copper substrate mould of the HSBC simulator. The possibility of producing Ca-based metallic glassy strips via the HSBC processes was confirmed, using optical microscopy, X-ray diffraction and Scanning Electron Microscopy, to characterize the glassy properties of the cast strips. It was found that the HSBC process would be able to provide sufficient cooling to form amorphous strips for the 60CA-15Mg-10Al-15Zn and 55Ca-15Mg- 10Al-15Zn-5Cu alloys, but not the 60Ca-20Mg-20Al alloy.

Jan 1, 2014

By Thomas P. Battle

Modern-day direct reduction of iron first developed as a small-scale, low capital and operating cost alternative to the blast furnace. Since commercialization of continuous DR technology in the late 1960s, the market for the products of direct reduction has grown to more than 74 million tonnes in 2012. The initial advantages of DR plants over BF facilities have grown over the years, for several reasons, including the increased size of DR modules, lower energy and emissions (particularly CO2), along with the flexibility to use a number of different reductants. The development of DR technology over the past forty years will be emphasized in this presentation, including recent developments that allow for even more direct sustainability comparisons with the iron blast furnace – and even combine the two technologies for improved synergies. Also briefly discussed will be the possibilities of using direct reduction for non-ferrous ores.

Jan 1, 2014

By B. R. Davis, Neale R. Neelameggham, R. E. Brown

The element Calcium element has a unique place in the production of etals, intermetallics and other compounds. The unusualness arises from the fact that we have several possible reductants – metallic calcium, calcium carbide, calcium cyanamide and calcium hydride. A review of how metallic calcium is manufactured and utilized is presented. The difficulties involved in producing the metal in large quantities and price implications are noted. . Fundamental thermodynamics of how these act as reductants are shown, along with the historic application of these in metal production during the past century and a half. Alternate applications as to how to control the cost of the reductant is indicated, such as the numerous attempts in making low cost titanium utilizing direct or indirect calcium reductant.

Jan 1, 2014

By Youn-Bae Kang, Jong-Jin Pak, Min-Kyu Paek

The critical evaluation and thermodynamic optimization of Mn-Si-C and its sub-binary systems have been carried out over the whole composition range from room temperature to above the liquidus temperature. The solution properties of the liquid systems have not been clearly described because the liquid solution exhibits a high degree of short-range-ordering. In order to predict the thermodynamics of the liquid solution, the liquid phases were optimized by the modified quasichemical model. The model parameters of the solid phases were also optimized by the compound energy formalism to best reproduce the phase diagram and important thermodynamic properties in Mn-Si-C system. Using the model parameters, various thermodynamic calculations were carried out. The present database will be a part of larger thermodynamic database for the ferromanganese alloy database.

Jan 1, 2014