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By Ruilin Yan, Kameron Ray

This paper reports a simple approach to model the waveform change due to travel distances based on the field measurement. A linear interpolation is used to estimate the waveform at a distance from two vibration waveforms recorded at two different distances. The resulted waveforms are compared with actual recorded waveforms at the point in both time and frequency domains. It shows that the proposed method to estimate the waveform change yield reliable results. The advantages of the proposed method are that it does not require assumptions that a transfer function does and that it is based on purely the measured waveforms that are encoded with in-situ rock properties. The method could be more reliable for far field seismic waveforms and could be an approximation for near field waveform estimation.

Jan 1, 2014

By Jorge Gibson, P. Chris Pistorius, Megha Jampani

"The main reason for the significant carbon intensity of integrated steelmaking (approximately 1.8 tons of CO2 per ton of steel) is the use of carbon-based reductants in blast furnace ironmaking. Several changes to blast furnace ironmaking have been proposed as ways to reduce carbon intensity and cost. A conceptually simple two-zone blast furnace mass and energy balance can be used to quantify the expected impact of such process changes on coke rate, carbon intensity, and productivity. Examples to be discussed include top gas recycling, combining lower blast temperatures with increased coal injection to produce a rich top gas, using prereduced feed, and tuyère injection of natural gas. The use of the operating window – which illustrates how allowable flame temperatures and top-gas temperatures constrain feasible oxygen enrichment levels – is illustrated. Increased use of natural gas would lower the carbon intensity of blast furnace ironmaking.IntroductionBecause of the significant carbon intensity of steelmaking (approximately 1.8 tons of CO2 emitted per ton of steel produced) and the high production rate of steel (more than 1.4 billion tonnes per annum), steelmaking is responsible for a large percentage, approximately 6.7%, of world anthropogenic CO2 emissions [1]. By far the largest input of the carbon into conventional steelmaking is as coke, which is essential to blast furnace ironmaking. A typical fuel rate for blast furnace ironmaking is 450 kg of fuel per tonne of hot metal (THM). (""Fuel"" includes coke and injectants which partially replace coke; pulverized coal and natural gas are typical injectants.) Assuming the fuels to contain 90% carbon on average, and since nearly all of this carbon exits the steel plant as CO2, a fuel rate of 450 kg is equivalent to a CO2 intensity of 1485 kg/THM – by far the largest part of the total CO2 intensity of steelmaking.Blast furnace ironmaking is expected to remain the main source of new iron units; this paper gives some estimates of the extents to which further reductions in carbon intensity from blast furnace ironmaking is possible. A recent European assessment suggested that blast furnace process intensification options such as increased pulverized-coal injection or natural gas injection would yield only modest energy savings [2]. However, if the focus is on CO2 emissions rather than on total energy use, there would be an advantage to using fuels – such as natural gas – which have lower carbon contents relative to energy content."

Jan 1, 2014

By F. C. Araújo, T. Tavares, J. Leite

"This work presents the small-scale mining cluster of kaolin in Rio Grande do Norte (RN) and Paraiba (PB), both Brazilian states, including the following information: number of companies, process flowcharts, production numbers, mineralogical (XRD) and chemical (XRF) composition, granulometric distribution (screen and laser granulometer) and image analysis (SEM). Some social indicators in the region of the RN and PB States are presented in association with these data. The number of companies and their flowsheet were obtained through in situ visits and sample collection for technological characterization. The comparative study of the different flowsheets for kaolin production in the world was done using the databases and presenting the state of the art of kaolin processing. The results indicated that the mean feed typically contains 35-39% kaolin with quartz, muscovite and kaolinite as main mineralogical components and SiO2 (65.83%), Al2O3 (21.19%), K2O (3.9%), and Fe2O3 (0,63%) as main chemical constituents. The products of mineral processing are twofold, one between 74 µm and 37 µm, and the other smaller than 37 µm. The wastes of operation had major quantities of kaolin. The average Human Development Index (HDI) of the cluster region is approximately of 0.61, which shows an association between mineral processing plant and social indicators. The kaolin recovery, however, is between 30-55% for the three most common types of flowsheets that are currently used in the small kaolin mining cluster, indicating a need for technological improvement to achieve regional development. These data could be used incrementally to adapt the process plant currently used in the small-scale mining cluster of kaolin."

Jan 1, 2014

By Rick Ellman, Ian Chaney

"The Hampton Roads area encompassing the Norfolk, Virginia Beach and Newport News metropolitan region experiences some of the worst traffic congestion in Virginia. With continued growth of the ports and increasing demand, the Virginia Department of Transportation (VDOT) initiated the Downtown Tunnel/Midtown Tunnel/MLK Expressway Project, a complex undertaking critical to addressing the Hampton Roads area’s transportation needs. The project is a $2.1 billion Design/Build/Finance/Operate (DBFO) endeavor most notably involving the construction of a new two-lane vehicular tunnel utilizing the Immersed Tube Tunnel (ITT) method. The tunnel will pass under the Elizabeth River parallel to the existing Midtown Tunnel between Norfolk and Portsmouth, Va. It will be the largest design-build project constructed in the history of the Hampton Roads District.The New Midtown Tunnel will extend approximately 6,450 ft (1,966 m) along the north side of the existing tunnel where it ties into the existing Midtown Tunnel approaches in Norfolk and Portsmouth. It is being installed in a pre-excavated trench of which approximately 2,250 ft (686 m) required bracing on the Portsmouth side and approximately 1,000 ft (305 m) required bracing on the Norfolk side. The remaining 3,200 ft (975 m) of trench excavation was open cut dredging with laid back side slopes, optimized to reduce dredging, disposal and backfill quantities while also reducing the risk to the existing tunnel. The braced excavation portions of the tunnel alignment were divided into distinct segments which include: Portsmouth Approach Boat Section, Portsmouth Approach Cut-and-Cover Section, Portsmouth Dredge Section, Norfolk Dredge Section, Norfolk Approach Cut-and- Cover Section and the Norfolk Approach Boat Section. All “approach” excavations were performed in the dry and all “dredge” excavations were performed in the wet. Eleven ITT segments are being fabricated in the Sparrows Point Dry Dock facility in Baltimore, Md., and each 14,000 ton (12,700 tonne) segment is being towed approximately 220 mi (354 km) to the site. The ITT segments will extend under the Elizabeth River, with the deepest crossing 90 ft (27 m) at the Federal Navigation Channel. Once beyond the channel limits the ITT rises at an approximate 4.5% slope. Controlled screeding and element lowering operations will be performed primarily from floating barges."

Jan 1, 2014

By Scott A. Walker, Gabriel J. Alcantar, Brian Zuckerman, Ramin Golesorkhi

"The new San Francisco 49ers Levi’s Stadium is part of the next generation of sporting facilities. Constructed in Santa Clara, Calif., the new structure has 68,500 open-air bowl seats and includes a 7- story tower housing more than 150 suites. The overall project includes the stadium structure, elevated open pedestrian walkways, commercial community space, three new pedestrian bridges and improvements to the adjacent light rail station. Sustainable design for the project includes a green roof, photovoltaic panel and a ground source geothermal system. Stadium-wide next-generation Wi-Fi capability is another feature. The design-build project team included HNTB (project architect), Magnusson Klemencic Associates (MKA, structural designer) and a joint venture of Turner Construction and Devcon Construction (TDJV, general contractor).During preconstruction, the 49ers’ original design team and the design-build team formed later worked together to facilitate communication and provide continuity. This helped to meet the project’s aggressive schedule. Working directly for the 49ers, with the design-build team, Treadwell & Rollo (T&R) served as the geotechnical engineer of record for the project from preliminary to final design and through construction. Although not contracted directly to TDJV, the stadium ownership encouraged direct interaction between T&R and TDJV and improved responsiveness to geotechnical issues during design and construction.Subsurface ConditionsThe new stadium lies within the Santa Clara Valley, a deep alluviumfilled basin resulting from historic movement on the active and potentially active strike-slip and thrust faults that bind the valley. The valley is filled with Holocene age (approximately 11,000 years old to present) alluvium, consisting of levee and basin deposits, with bedrock more than 750 ft (229 m) beneath existing ground surface. The stadium site is between two of the highly-active faults in California, the Hayward Fault 6.8 mi (11 km) northeast, and the San Andreas Fault about 11.8 mi (19 km) southwest."

Jan 1, 2014

By Peng-Fei He

CT scanning tests were used to detect the pre-existing fracture systems of 36 cubical coal blocks. Systematic procedures were developed to construct the pre-existing fracture geometry of the cubical coal blocks from the CT images. Based on the constructed fracture systems, the fracture tensor components were calculated to capture the directional effects of the fracture system of the cubical coal blocks. The effect of the pre-existing fracture system and different combinations of confining stresses on the strength and deformability of coal masses was investigated at a preliminary level using some true triaxial test results and the computed fracture tensor components. The strength of the cubical coal blocks in the loading direction was found to be closely related to the summation of the fracture tensor components in the two perpendicular directions to the loading direction and the level of the confining stress system. The deformability of cubic coal blocks in the loading direction was found to be correlated to the fracture tensor component in the same direction.

Jan 1, 2014

By R. S. C. Smart

Surface chemical factors, including the balance of hydrophobic (e.g. collectors) and hydrophilic (e.g. oxidation products, precipitates) species, are major control determinants in flotation rates of specific minerals and therefore grade and recovery. There are a number of challenges involved with the surface analysis of different mineral phases from process streams in a flotation facility. The first is to collect samples that are representative of the process and retain their surface chemistry prior to introduction into the instrument. The second challenge in studying the surface chemistry of specific minerals is to find reliable methods of mineral phase recognition. In surface analysis of mineral particles, confident mineral selection can be difficult with many multi-metal minerals and with precipitated, adsorbed, reacted and contaminant species in the outermost molecular layers. The third challenge is to provide a statistical surface analysis of multiple grains of the same mineral. Methods to achieve these aims are described. Principal component analysis (PCA) of ToF-SIMS data provides improvement in phase recognition, particle selection and associated variations in surface species. Specific examples from both lab and plant operations, demonstrate that this technique can be utilized to differentiate surface chemical factors promoting (hydrophobic species) or inhibiting (hydrophilic species) flotation. A study of copper ion transfer (inadvertent activation) from chalcopyrite to pyrite and sphalerite clearly identified a statistical difference in copper intensities between the sphalerite and pyrite phases corresponding to their flotation response. The PCA analysis applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrated extensive CuOH and NiOH transfer between chalcocite and heazlewoodite minerals. The statistical analysis has been able to identify mechanisms controlling recovery and selectivity. High intensity conditioning (HIC) tests in which sphalerite was separated from a complex sulfide ore gave a 5% increase in the overall Zn recovery. The PCA/ToF-SIMS statistical analysis revealed the discriminating depressant action of adherent aluminosilicate (gangue) fine particles and adsorbed ions on the surface of sphalerite grains. HIC conditioning resulted in the removal of these gangue fines improving surface collector attachment efficiency.

Jan 1, 2014

By Paolo Cavalcoli, Marco Ziller

"ABSTRACT: In the year 2010 the State of Denmark together with the Municipality of Copenhagen, launched a very important and complex Project : the complete construction of a new double Subway Line :the CITYRINGEN.Copenhagen is the capital with a metropolitan population of 1,9 million.This line is like a ring placed in the very town center which includes all the most historical and monumental buildings and churches, with a total length of 17 km, and the presence of 17 stations plus 4 service shafts.The buildings have been built in the last centuries in an area where the groundwater is near to the surface and there are lakes and channels: the techniques adopted were advanced for those times, but limited as far as regards settlements and resistance to horizontal movements.The soil consists in 2 main groups.1.Upper sediments of the glacial ages : thickness total = 5-20 m composed by clay- silt-sand-gravelcobbles- granite boulders and flint in blocs and in layers : frequency and size of these obstacles wherenot determined.2.Limestone layers : 2a. upper limestone : highly fractured ,highly permeable2b.Itermediate limestone : less fractured, medium permeability.2c. Lower limestone : almost not fractured, low permeability.2d Bryozoan limestone : composed by fossils with microscopic dimensionsIn all the limestone formations there are important layers of flint , having thickness variable up to 3 m and important extensions. Water : in a part of the areas of the Cityringen the water is drinkable and utilized in the public waternet.Pollution: there are polluted zones due to previous industrial activities. Benzene areas have been identified, and for those areas special protections against pollution have been implemented.METROSELSKABET ,the public owner of the Cityringen,has set as priority to operate for the construction of the Cityringen the full protection of the environment and the respect of all the stakeholders :Very strong limits for the exhausted gas emissions have been introduced, by far stronger than those applied from the State of Denmark, very strong limits for the acceptable noise emission. And last but not least very important safety measures and procedure to avoid any accident on site."

Jan 1, 2014

By J. Morris, R. Sellaro

El petrodiesel es un colector común para la flotación de carbón, pero la partición de compuestos orgánicos de diesel (DRO por sus siglas en inglés) en corrientes de proceso no ha sido ampliamente estudiada. Investigaciones preliminares sugieren que bajo esquemas de dosificación normales los contenidos residuales totales de DRO en aguas de procesos deben estar limitados a la fracción soluble en agua (WSF por sus siglas en inglés) sub-ppm. Es más, los hidrocarburos aromáticos poli-cíclicos (PAH por sus siglas en inglés) debería segmentarse de manera proporcional con los compuestos orgánicos de diesel (DRO). El propósito de este estudio fue confirmar estos resultados en pruebas de flotación realizadas en laboratorio. Se midieron los contenidos totales de DRO Y PAH en aguas asociadas con los flujos o corrientes de concentrados y relaves. Los resultados muestran que las aguas con concentrados tenían de manera consistente mayores cantidades de DRO que las aguas de relaves. Es más, los contenidos de DRO en ambos flujos generalmente se incrementaban con el aumento de la dosis de diesel. De acuerdo con la investigación preliminar, los DRO parecían estar limitados a la fracción soluble en agua (WSF) y los PAH tendían a segmentarse proporcionalmente con los DRO. Bajo condiciones de operación típicas, los DRO residuales no deberían representar una preocupación medioambiental, pero deben evitarse situaciones que permitan una sobredosis significativa de diesel.

Jan 1, 2014

By D. Auerswald, M. Kotze, V. Yahorava, T. Udayar

Uranium can be recovered from lower grade uranium ores (<800 mg/kg U3O8), leach residues, and waste dumps cost-effectively via resin-in-pulp (RIP). Using this technology, no solid/liquid separation or washing of the leach residues are required. Furthermore, the uranium recovery can be higher than with conventional methods. RIP technologies have, however, been perceived negatively due to concerns around potential resin fouling and losses. This paper highlights the advancements made in RIP and discusses a number of potential applications where the technology could deliver economic and consequential environmental benefits by reducing the uranium levels in the waste.

Jan 1, 2014

By Adnan A. Malik, Tadashi Maejima, Jiro Kuwano

"ABSTRACTTheoretical approach to estimate the ultimate pile capacity gives a rough idea at the initial stage of design that later on strengthen by the execution of static pile load test at site. The static pile load test is the only best option for the estimation of ultimate capacity of various types of piles. There are various methods based on strength, serviceability, net deflection for end bearing, shaft adhesion, graphical and extrapolation approaches for the interpretation of pile load test data to calculate the ultimate capacity. In this paper an attempt is made to evaluate the best-fit method for the estimation of ultimate capacity of single helix screw pile. The pile load tests on model scale were performed on screw piles of different helix diameter. The purpose of adopting model scale of testing was to achieve a state at which settlement increases without further increase in vertical load. The ground was compacted with dry sand at denser state. It was observed from the test results that extrapolation methods such as Chin- Kondner and Decourt predict the load settlement curve of screw piles very well, however ultimate pile capacity was on higher side which may not be suitable for the strength of helix plate. Decourt approach to plot the pile load data showed clear indication of the deformation of helix due to strong subsurface condition. A modified approach in Decourt method is proposed for estimating the ultimate capacity of screw pile having deformed helix whereas reduction factor is suggested for Chin-Kondner method for the estimation of ultimate capacity of intact screw pile.INTRODUCTIONDeep foundations are used to avoid the soft ground at shallow depth that is not suitable for carrying the structural load. Different types of piles have been used to transfer the load to deeper stratum. The screw pile is one of the new piling method and its use is considerably increasing. It consists of a cylindrical steel shaft with one or more helices at various length of the shaft. The diameter of helices (Dw) is usually 2 – 2.5 times the shaft diameter (Ds). The pile is installed to the required depth through torque and pressure. The advantage of screw pile over other piling system is its quick installation mechanism, high end-bearing and uplift resistance, noise reduction and minimum use of man power."

Jan 1, 2014

By Sarra Scherbakova, Alexander Kurkov, Andrey Egorov

"Deep concentration of iron ores involves extraction, in addition to magnetite concentrate, of hematite and martite concentrates and recovery of other valuable components. A flotation technology was designed specifically for finely disseminated hematite ore, allowing producing saleable hematite concentrate containing 64-66% Fe. The main process challenge is caused by the presence of other ferruginous minerals such as carbonates, silicates, and phosphates, and fine hematite and martite mostly concentrated in the -0.044 mm fraction. Main operations of the processing circuit are removal of slime, flotation to remove impurities (carbonates, phosphates etc.) with an anionic phosphorous collector in an alkaline environment, hematite and martite flotation using same collector in a slightly acidic environment to produce commercial iron concentrate. Tailings of wet magnetic separation of magnetite containing 24.5% Fe and finely disseminated hematite ore containing 51% Fe were processed to produce iron concentrates with a yield of 15% and 50%, respectively, containing approximately 65% Fe and 5% of silica. Hematite flotation tailings had the highest content of gold (up to 0.09 - 0.11 g/t), while in other products it never exceeded 0.02 g/t. Using a Knelson concentrator was able to recover 40 to 45% of the gold into 3.31 g/t Au gravity concentrate. The success of gravity concentration is due to high gravitational contrast of gold to mostly quartz and aluminosilicates in the hematite flotation tailings. In general, the proposed process can be used as a solution to the challenge of selective concentration of finely disseminated iron minerals."

Jan 1, 2014

By Masaki Kitazume

"Abstract The wet type and dry type of deep mixing methods have been developed and widely applied for on-land and marine constructions in Japan. The quality assurance (QA) of the methods has been usually carried out by unconfined compression test on field stabilized soil sampled by core boring in Japan. In some other countries, stabilized soil excavated by the wet grab sampling instead of core sampling is often subjected to unconfined compression test for quality assurance. There are several merits and demerits in each method, but few studies have been carried out to compare the stabilized soil strength of these two types of specimens to discuss their applicability to practical construction. The author has conducted a series of field and laboratory tests to compare the stabilized soil strength and discuss the applicability of wet grab sampling to QA for wet and dry types of deep mixing method.In this study, the wet grab sampling was carried out at two road embankment construction sites where the wet type and dry type of deep mixing were applied. The cement stabilized soil was excavated at the three depths by a wet grab sampler soon after the DM column construction. The test result is compared with the other test data in the previous study to discuss the applicability of the web grab sampling method for QA of cement stabilized soil.IntroductionThe Deep Mixing Method (DMM), an in-situ soil stabilization technique using cement and/or lime as a binder, is often employed to improve soft soils (Kitazume and Terashi, 2013). A variety of factors and their interactions affect the eventual strength of a deep-mixed column, while some of which are controllable (e.g. binder type and dose) by engineers while the others are not (e.g. soil types, ground temperature, etc.; Babasaki et al., 1997). In addition to laboratory mix tests, which in essence are a parametric study to estimate the influence of these factors on a particular soil’s strength, the quality assurance (QA) practice in Japan usually involves unconfined compression test on sampling cores from the stabilized columns after a given curing period. It has been recognized, however, that the ‘field strength’, or the strength of the retrieved core, quf is on average lower than the ‘laboratory strength’, qul, evaluated by laboratory mix test. Also allowing for the inevitable variability, existing guidelines (for example, PWRC, 2004 and CDIT, 2008) recommend the design quf /qul values of, for example, 0.5-1.0 for the CDM (Cement Deep Mixing; a wet-type technique, in which binder is added as slurry) and 0.2-0.33 for the DJM (Dry Jet Mixing; a dry-type technique, in which binder is added as powder)."

Jan 1, 2014

By N. Tsoni

The separation and recovery of fine and ultra-fine particles during the processing of mineral commodities by conventional separation methods is difficult and inefficient. This is due to the problems posed by the very small size of the mineral particles. The fine and ultra-fine mineral particles are either generated during size reduction processes or are necessitated by liberation size. This problem is expected to deteriorate, as deposits of even lower grade are processed. The inefficiency of the conventional separation methods with regards to the processing of very fine particles leads to the loss of considerable quantities of mineral commodities to the tailings. Novel methods and techniques as well combinations of known methods have been tested over the years. Among them, selective aggregation, along or in combination with flotation, has been given much attention. This study deals with the application of hydrophobic agglomeration as a separation method for very fine particles. The selected mineral system is magnesite/quartz, due to its sensitivity to physi-cochemical separation methods. The aim was the selective agglomeration of magnesite using sodium oleate. Tests on single minerals revealed that separation seems feasible and efficient. The parameters examined were: pH, quantity of sodium oleate, conditioning time, and, finally, settling time. Tests carried out on artificial mixtures of the two minerals, under various proportions, confirmed the results obtained from single mineral tests but they were slightly inferior. Finally, hydrophobic ag-glomeration tests were carried out on single and artificial mixtures of minerals using sodium oleate and petroleum as reagents. The results show that the addition of petroleum improves the results. In conclusion, hydrophobic agglomeration can be applied successfully even for fine particles of difficult-to-be-separated systems such as magnesite and quartz.

Jan 1, 2014

By Christopher Robben, Alexander Mosser

"X-ray transmission (XRT) sorting has been introduced into the minerals industry in 2006 and has found various applications in diamonds, industrial minerals and metal ore processing since. The technology offers planar projections of the atomic density of single particles similar to the principle known from airport scanners, but being capable of treating up to 150tph per metre working width. In 2010, a pilot operation using a belt-type sensor-based sorter went into production at the Mittersill mine to treat the fraction 16-28mm. After an optimisation phase, the results were superseding expectations and therefore in 2012 a bigger production plant was set up. Two XRT-based sorters are parallel in operation since. One is treating the fine fraction 16-30mm while the other one is treating the coarser fraction 30-60mm after the secondary crushing stage. The XRT sorters are operated with the objective to reject barren waste before it enters the mill and flotation plant. 105,000tpa of waste material are rejected per year and can be sold as aggregate for road construction. This means that about 22% of the run-of-mine ore are rejected at an early stage with a waste reject grade lower than 0.03wt%WO3. The installation has not only led to lower specific operating costs but also led to reduced tailings disposal in an environmentally sensitive area. This allows the mine to reduce its headgrade which allows for a longer mine life. Alternatively it is possible to produce more tungsten concentrate, which is delivered to the smelter. This article will introduce the technological principle of XRT-based sorting and will discuss the flow-sheet of the Mittersill mine. Experiences that have led to the current plant design are described as well as the impact it has on the operation."

Jan 1, 2014

By T. M. Bhatti

The main purpose of present study was to characterize the dissolution of uranium from low-grade black shale with indigenous isolated strain of Acidithiobacillus ferrooxidans (BSAF-01). The nature of shale is quartzite-schistose and contains uranium content of 0.005% U3O8 (50 ppm U3O8). Uranium is present in the tetravalent oxidation state (U4+) in the shale matrix. The main minerals identified are graphite, quartz, pyrite, mica minerals (phlogopite, biotite, sericite, and chlorite), microcline, K-feldspar and kerogen (hydrocarbon-compounds). Bacterial oxidation of pyrite was an acid-generating system and produced sulfuric acid and ferric sulfate during this biological phenomenon. A series of bioleaching experiments were conducted in shake flasks for leaching of uranium from black shale. The leaching experiments were performed at 50% pulp density using indigenous Fe- and S-oxidizing bacterium (Acidithiobacillus ferrooxidans). Bioleaching data revealed that about 90% ~ 95% U3O8 was leached out from black shale ore. Uranium dissolution from shale depends on pH (pH 1.5~1.9), redox potential (=500 mev) and the concentration of Fe2+ and Fe3+ ions in the leaching environment. The oxidative leaching of U4+ involves a redox reaction with Fe3+ as an oxidant and bacterial re-oxidation of Fe2+ in acidic leaching environment. Uranium leaching efficiency was attributed to the sulfuric acid and ferric sulfate production during bacterial oxidation of pyrite.

Jan 1, 2014

By Jennifer Williams, Donald J. Berger

Originally built between 1913 and 1916, the Ashton Dam & Hydroelectric Facility has experienced various seepage and piping incidents since completion. Ashton Dam is located within 15 miles (24 km) of the historical Teton Dam failure site and about 2.3 miles (3.7 km) west of Ashton, Idaho. Numerous repairs conducted over the years ranged from filling sinkholes on the crest of the dam to placement of rockfill on the upstream slope to improve seismic stability. In addition, the existing low level outlet works was grouted full and abandoned in 1991 due to significant vibrations induced on the dam during its operation.

Jan 1, 2014

By David F. Gearhart

A cooperative study was conducted between Signal Peak Energy and the National Institute for Occupational Safety and Health (NIOSH) to evaluate the behavior of a pre-driven recovery room under less than 200 ft of cover. The design of the support systems for a pre-driven recovery room must provide control of the roof and ribs during the changing stress environment experienced throughout the final advance of the longwall into the recovery room. It must also provide a stable area where mine personnel are not exposed to undue hazards during shield recovery operations. This recovery room was constructed in two phases; each phase mined a 21-ft-wide room that was heavily supported, and subsequently fully backfilled with 800-psi, cellular concrete. Instrumentation to monitor the recovery room performance included borehole pressure cells (BPCs) placed in the head gate and tailgate pillars, at four locations across the longwall panel, in the fill material, and in the first row of outby pillars near the center of the panel. Four roof-to-floor convergence sensors were installed in the back fill material and a vertical, multipoint borehole extensometer (MPBX) measured the displacement of the strata above the recovery room. Surface surveys were conducted to measure MPBX collar movement. The data show that the front abutment load was transferred onto the recovery room backfill and the out by pillars as the longwall panel was extracted. As the longwall approached the recovery area, the fender and shields yielded, but the backfill provided enough support to keep the room stable as the longwall advanced to its final position. The system worked as planned and the face was recovered in record time.

Jan 1, 2014

By M. Steyn

The coordination compound tetrakis(1,3-diphenyl-1,3-propanediona to)zirconium(IV), [Zr(DBM)4], (DBM = dibenzoyl methane/1,3- diphenyl-1,3-propanedionol) was synthesized and characterized by single-crystal X-ray diffraction. [Zr(DBM)4] crystallizes in the monoclinic space group P21/c (a = 24.769(4) Å, b = 10.216(5) Å, c = 19.314(4) Å, and = 101.541(5)°). The coordination geometry around the zirconium atom, formed by the eight O-donating atoms of the four -diketonates, is found to be a near-perfect square antiprism. Crystal packing is stabilized by C?H... interactions throughout the crystal lattice. This structure is a noteworthy example of the application of ambient condition synthesis of zirconium compounds in N,N&apos;-dimethylformamide (DMF) as reaction and crystallization solvent, highlighting the possibilities of aerobic condition metal purification through chelation.

Jan 1, 2014

By G. B. Harris

It has long been appreciated that chloride chemistry has a number of advantages over the more traditional sulphate route for both extracting and separating metals. Modern materials of construction, coupled with the development of a more cost-effective and efficient hydrochloric acid regeneration technology mean that chloride-based processes are now more competitive and attractive. Such processing routes are able to recover more of the contained metal values in a feed, including iron in a benign and/or marketable form, and particularly the so-called rare and rare-earth elements which are increasing in demand in our electronic age. These factors, therefore, add appreciably both to the overall economics of a project, but also offer a much more sustainable approach to our dwindling natural resources. Additionally, chloride-based flowsheets can be much more environmentally-friendly, offering practical alternatives to two of the biggest headaches faced by the industry, namely cyanide usage and the generation of red muds. This paper presents a brief theoretical background, focusing on the latest developments of ferrous iron oxidation and the low-temperature, selective hydrochloric acid regeneration process, which is the key unit operation for any chloride flowsheet, and discusses in general the advantages of the chloride approach. Several recently-developed flowsheets, which have been tested at the miniplant level, are presented for gold, base metals, titaniferous magnetites and lead-silver ores wherein the advantages of considering a chloride approach are highlighted.

Jan 1, 2014