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By I. Nolet

Matte tapping is one of the most critical operations of a matte smelter. Every smelter has developed particular matte tapping practices and tap-hole repair strategies that are often based on the experience of the smelter personnel. As a result, very little information has been published on these critical topics. This paper aims at providing the information gathered from a survey conducted in the PGM and Ni industries on matte tapping practices and tap-hole maintenance strategies for different PGM-Ni matte smelting operations.

Jan 1, 2014

By J. Illescas, N. C. Murray

This paper provides an economic comparison and technical evaluation of different approaches for copper recovery from small-scale resources such as historic tails, dumps, pond and pit water as well as acid mine/rock drainage. Factors such as the location, the availability and cost of reagents, power availability and cost and a local market for end product alter the preferred processing technique. A number of scenarios are presented and technologies considered include; solvent extraction, ion exchange, sulphide precipitation, cementation, copper sulphate crystallization, membrane (RO) and copper cathode production.

Jan 1, 2014

By M. Bryson, S. Broom-Fendley, A. E. Brady, W. Dawes, G. Beer, N. Sehlotho, S. Al-Ali, F. Wall

The Songwe Hill Rare Earth Element (REE) Project in Malawi is a near surface carbonatite-hosted deposit with synchysite and apatite as the key REE bearing minerals. A strong focus has been placed on understanding the REE mineralogy of the Songwe Hill carbonatite as REE mineralogical characterization is a crucial component at all steps, ranging from exploration to production, in the development of REE deposits. Extensive mineralogical work has been completed at Camborne School of Mines (CSM), Natural History Museum (NHM) London, British Geological Survey (BGS), Nottingham, Aberystwyth University, Wales, Mintek, South Africa, and SGS Inc. Canada (SGS). The following analytical techniques were used: scanning electron microscopy (SEM), electron microprobe analysis (EMPA), laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), and QEMSCAN®. The detailed studies have demonstrated that while synchysite is light-REE enriched as expected, apatite, abundant in all stages of carbonatite emplacement at Songwe, is anomalously enriched in mid- to heavy-REE relative to apatite in other carbonatite deposits. The distribution of REE within synchysite and apatite at Songwe has had important implications for the direction of the metallurgical work with respect to the behaviour of light and heavy REE through the flotation and hydrometallurgical stages of the flow sheet.

Jan 1, 2014

By Leopoldo Gutierrez, Esau Arinaitwe, Marek Pawlik

"The effect of various polymers, including: anionic carboxymethyl cellulose (CMC), polystyrene sulfonate (PSS), humic acids (HA) and non-ionic hydroxypropyl cellulose, on the wettability of Athabasca bitumen was evaluated through dynamic contact angle measurements using the captive bubble technique. The tests were carried out as a function of pH at a constant ionic strength (0.01 mol/L sodium chloride). The evolution of the three-phase contact angle between the solution, bitumen and an air bubble was followed as a function of time over a period of ~6 minutes. The contact angle data were modelled using a first-order kinetic equation. The results were analyzed in terms of the initial contact angle, the evolution rate constant, and the steady-state contact angle value. In the case of anionic polymers, a pronounced decrease in the initial contact angle value was observed at pH 3. Under acidic conditions, there was no significant effect of CMC observed on the steady-state contact angle value but PSS and HA significantly decreased the steady-state contact angle value. At pH 8.5. the anionic polymers did not affect the wettability of the bitumen surface but they significantly decreased the contact angle evolution rate. These results suggested that CMC is not capable of permanently lowering the hydrophobicity of bitumen, and the polymer only slowed down the evolution of the contact angle to the steady-state value. The results also showed that polystyrene sulfonate and humic acids were capable of making bitumen hydrophilic but only under acidic conditions. Only hydroxypropyl cellulose (HPC) produced a large decrease in the steady-state contact angle under alkaline conditions (pH 8.5). The kinetics of contact angle evolution in the presence of HPC was also drastically lowered. The results were discussed in terms of the chemical composition of the polymers and their different affinities towards the bitumen surface."

Jan 1, 2014

By Yang Jian-guang, Deng Zi-xiang, Zhang Xu-liang, Li Jun-yuan

"Hyperaccumulator biomass harvested after heavy-metal phytoremediation must be considered as hazardous waste that should be contained or treated appropriately before disposal or reuse. As a potential method to detoxify the biomass and to convert this material to a suitable bio-energy resource, the hydrothermal upgrading process was applied to remove heavy metals and upgrading crude bio-oil from Pteris vittata stems and leaves harvest. Parameters such as material granularity, temperature, Liquid/Solid (L/S, ml/g), pressure, duration and catalysts were examined for their effect on the removal efficiency of heavy metals and upgrading efficiency of crude bio-oil. Maximum heavy metal removal efficiency of>99% and crude bio-oil upgrading efficiency of 83% were attained with an 200 mesh (75 µm) granularity, LIS 40:1and23 MPa at 380°C in the presence ofO.l mol L-1 K2C03 for 30 min. GC-MS analysis results show that the resulting bio-oil mainly consists of benzene 11 %, ketone 42%, alcohols 14%, alkene 15% and ester 11 %, etc., and the relative molecular weight distribution lies in 94-282, carbon number distribution lies in 6-18, calorific value is 32MJkg-1.IntroductionPhytoremediation of soil or water with hyperaccumulator has been extensively explored in recent years [1-4]. Living plants can clean up soils or waterways. This approach exploits the ability of various plant species to thrive in high metal environments where large amounts of toxic elements are accumulated, such as heavy metals, and is particularly appropriate when slow remediation of relatively low metal concentrations is acceptable. Advantages compared with existing remediation methods include the minimal site destruction and destabilization, low environmental impact, and favourable aesthetics; advantages compared with biosorption include continuous in situ regeneration of the biomass, and the ability of living plant cells to supplement passive sorption of metals with metabolic mechanisms of metal uptake and detoxification [5-8]."

Jan 1, 2014

The status quo of ecological rehabilitation in metal mine in China and progress in the technology for ecological rehabilitation are presented, including soil reconstruction, soil improvement, plant selection. The present and future research fields are suggested: basic theory of ecological rehabilitation, operative technology of ecological rehabilitation, new technology application research and ecological rehabilitation plan, management and policy.

Jan 1, 2014

New technology for on-line particle size analysis of mineral slurries has opened up new applications for particle size measurement. In some cases the particle size distribution of the final concentrate is an important quality issue. This paper discusses established on-line particle size analysis technologies and presents experiences on the use of a new technique employing laser diffraction in several minerals processing operations. The main innovations in the new instrument are a simple dilution system and multiple scattering correction algorithm, which allows wide solids content variations of diluted sample in the measurement cell. Representative sample for laser measurement is produced by a simple and reliable dilution system. The applications discussed are; Blaine number measurement of Fe concentrate before pelletizing, grinding of variable batches of ore and paste thickener control.

Jan 1, 2014

By R. Salimi

Tricalcium aluminate hexahydrate (TCA) is used as filter-aid for security filtration in the Bayer alumina process. TCA is typically produced on-site by mixing Bayer liquor with slaked lime. Specific properties are required from the TCA to ensure adequate filter throughput, lifetime and importantly effective reduction of solid/colloidal impurities from the solution. The effect of reaction time on morphology and particle size distribution of tricalcium aluminate was studied for a batch experiment at simulated process conditions. It was found that reaction time plays a critical role on the morphology, crystal structure (diameter and crystallinity) and particle size distribution. In the early stages of the reaction, nucleation dominates the crystallization process followed by growth dominated by agglomeration up to a mean particle size of 10 µm. The particle morphology shifted from an irregular shape to more spherical throughout the course of the reaction.

Jan 1, 2014

By R. Marandi

The effective removal of heavy metals from aqueous wastes is among the most important issues for many industrialized countries, How ever biosorption, i.e. the uptake of heavy metals by non- living biomass, has gained increased credibility during recent years. Biosorption of Cr(VI) from aqueous solution, on pretreated and immobilized Aspergillus niger was investigated in a batch and countinuous reactors. A.niger biomass pretreated by boiling in 0.5 N NaOH solution for 15 min, exhibited higher Cr(VI) removal capacity than autoclaved biomass. The optimum adsorption pH value observed for Cr(VI) ions was 2. The Cr(VI)removal rate increased with a decrease in pH. The influence of contact time, pH, Cr(VI) concentration, biomass concentration and temperature on Cr(VI) removal were also evaluated. Biosorption of Cr(VI) on pretreated biomass followed the Freundlich and Langmuir adsorption models.In this study A.niger biomass was immobilized in Na-alginate matrix. The biomass beads packed in a column were able to remove metal ions.In this study we used two different flow rate in a column, 1.5 mL/min and 3 mL/min.The breakthrough data obtained for Cr(VI) was adequately by the Thomas and Yan models and the adsorption capacity of the biomass was found to less than the adsorption capacity obtaind in the batch study. When the beads containing biomass become saturated with metal ions, the adsorbed metals were eluted using 0.5 N NaOH solution. Therefor nearly 90% of Cr(VI) was desorbed by NaOH solution.

Jan 1, 2014

By D. Tang

The froth zone in a flotation cell is recognised as a region which contributes to the overall flotation performance. Froth recovery is a measure of the efficiency with which the froth phase delivers particles arriving at the pulp-froth interface to the concentrate. Poor froth recovery in scavenger stages is generally attributed to poor froth stability. The key indicators of froth performance: froth recovery, entrainment and water recovery were measured in an OK3 pilot cell installed at a zinc concentrator in Australia and supplied with scavenger feed. Cell hydrodynamic and pulp chemical conditions during the operation of the cell were also measured as well as bubble growth across the froth phase. The objective of the work was to assess the impact of a number of commercial frothers on the froth performance in the OK3 cell and assess the suitability of using bubble growth as an indicator of froth stability.

Jan 1, 2014

By Ana Elisa Casas Botero

The Rhodococcus opacus microorganism was evaluated as a biocollector for flotation of barite. The electrophoretic behaviour of the mineral, before and after R. opacus interaction, was evaluated and showed that the cells adhesion shifted the mineral zeta potential curves. Adhesion tests were suggested a high affinity of the bacteria for barite. The experiments of the adsorption rate of the R. opacus on the mineral surface showed fast kinetics, achieving a maxim of cell adsorption after 5 minutes. Adsorption isotherm curves for barite could be categorized as Langmurian (L) type II. The best bioflotability results for barite achieved values around 75% for a R. opacus concentration of a R. opacus concentration of 250 ppm in the pH around 5.0. The studies were compared with the flotation of barite using a traditional collector. The bioflotation experiments were discussed considering the obtained adhesion tests. The results were supported by the Thermodynamic approach for selected pH values. The fundamental flotation studies showed the paramount potential that R. opacus presents as a biocollector and its possible application in the mineral flotation industry.

Jan 1, 2014

By Jacob Masliyah, Zhenghe Xu, Lujie Yan

"Understanding adsorption mechanism of polymeric organic process modifierssuch as carboxymethyl cellulose (CMC) on talc hasbeen a major challenge due to anisotropic nature of talc basal planes and edge surfaces. The main objective of this study is to investigate the adsorption of CMC on the basal planes and edge surfaces of talc.Smooth basal plane and edge surfaces of talc were prepared successfully by simple cleavage and sophisticated ultramicrotome cutting method, respectively. The prepared surfaces were characterized by atomic force microscope (AFM) imaging to be sufficiently smooth for colloidal probe force measurements using AFM. Anisotropic surface charge characteristics were determined,with the basal planes to carry a permanent negative surface charge and edge surfaces featuring a pH-dependent charge characteristic. The adsorption of CMC on talc basal plane and edge surfaces at pH 9 in KClaqueous solutions of various ionic strengths wasinvestigated by in situ AFM imaging technique. Themorphology of adsorbed CMC on talc basal planes and edge surfaces was found to be significantly different, due to different binding mechanisms involved. Interaction of CMC with the talc basal plane was found to bedominated by hydrophobic interactions while its binding with the talc edge surface was mainly through chemical complexation and hydrogen bond. The amount of CMC adsorbed on both talc basal planes and edge surfaces increased with increasing ionic strengthof solutions. The methodology developed in our study opens the door to probe polymer adsorption on anisotropic phyllosilicate surfaces, which can help us better understand the mechanism of polymer adsorption on specific mineral faces."

Jan 1, 2014

By G. X. Du

Improving reaction effectiveness of asbestos tailings and acid is main means to increase the productivity of magnesium hydroxide and amorphous silica and to reduce production costs. In this paper, the process optimization of acid-leaching reaction process of asbestos tailings is reported. Through the orthogonal experiments of four influence factors, such as acid consumption, reaction temperature, reaction time and initial acid concentration in the leaching reaction. The experiment results indicated that the optimal process parameters were as follows: reaction temperature was 95?, reaction time was 1.5h, acid consumption was 218.9g hydrochloric acid(37%) per 100g asbestos tailings and initial acid concentration was about 25%. The influence significance sequence of the four factors was as follows: reaction temperature > reaction time > mass concentration of hydrochloric acid > hydrochloric acid consumption. Under the optimum process conditions, the leaching rate of MgO was 97.3%, total iron 98.15% and Al2O3 57.9%.

Jan 1, 2014

By R. Marandi

Biosorption of heavy metals can be an effective process for the removal of heavy metal ions from aqueous solutions. In this study, the adsorption properties of nonliving (boiling in NaOH) biomass of phanerochaete chrysosporium. For Pb (II) and Zn (II) were investigated by using batch adsorption techniques. The effects of initial metal ion concentration, initial pH, biosorbent concentration, stirring speed, effect of temperature and contact time on biosorption efficiency were studied. Experimental results indicated that the uptake capacity and adsorption yield of one metal ion were reduced by the presence of the other metal ion. In the experiments the optimum pH value was found out 6.0. The experimental adsorption data were fitted to the Langmuir and Frundlich adsorption models. The highest metals uptake was calculated for Zn (II) and Pb (II) were 57 and 87 respectively. desorption of heavy metal ions was performed by 50 mM HNO3 solution. The results indicated that the biomass of p.chrysosporium is a suitable biosorbent for removing heavy metals ion from aqueous solution.

Jan 1, 2014

By S. J. Ma

To look into the ionic release laws of the sulphide tailings in some copper mine, the effects of the soaking period, temperature, oscillating speed, and pH of the solution on the heavy metals ionic re-lease were investigated through static soaking leaching experiments. The results show that Cu2+, Zn2+, Pb2+, Cr3+ are of different leaching behaviors with soaking period. The ionic concentration in soaking solution for four ions has a great gap. Zn2+ is more easily released out of sulfide tailings than Cu2+, Pb2+, Cr3+ , and the ion release concentrations are not proportion to their contents in the tailings. The time for each ion to reach its maximum concentration are different. The minimum concentration do not occur at the first day. Each ion concentration shows different fluctuation characteristic during soaking process. Solution pH, oscillating speed, and temperature affect the releases of Cu2+, Zn2+, Pb2+, Cr3+ out of the tailings to different extent. The effect of pH value on ion re-lease for the four ions ranks as Zn2+>Cu2+>Pb2+>Cr3+, the oscillating speed ranks as Pb2+>Zn2+>Cu2+>Cr3+, and the temperature ranks as Cr3+>Pb2+>Zn2+>Cu2+.

Jan 1, 2014

By C. G. Anderson

Industrially proven and applied nitrogen species catalyzed (i.e. NSC) acidic pressure leaching has been utilized to treat a number of ores, concentrates and recycled materials. This versatile technology offers many advantages including low temperatures, low pressures, low capital costs, low operating costs, faster throughput and less costly materials of construction than conventional pressure oxidation. This paper will elucidate the application of this technology for production of gold, silver, palladium, rhodium, zinc, germanium, gallium, cobalt, copper, molybdenum, rhenium and nickel. Recycled material applications will also be elucidated. In addition, details of an application for treatment of a refractory chalcopyrite copper and gold bearing ore will be presented and pertinent economics discussed.

Jan 1, 2014

"Editor’s note: Each year, Mining Engineering features an industrial minerals review. Several people put in a fair amount of time in developing the material for this issue, all the while doing their own jobs. Thank you to the industrial minerals annual review editor, to the Industrial Minerals and Aggregates Division technical committee chair and vice chairs, and to the authors of the individual commodity profiles.Jim Norman, member SME, of Tetra Tech, is the industrial minerals annual review editor.Vishal Gupta, member SME, of EP Minerals LLC, is chair of the Industrial Minerals &Aggregates Division’s Technical Committee.The technical committee vice chairs include:• Vishal Gupta, member SME, of EP Minerals LLC, Agricultural Materials.• Joe Garska, member SME, of Imerys, ceramics and refractory materials.• Stanley Krukowski, member SME, of the Oklahoma Geological Survey, chemical raw materials.• Russell Winn, member SME, of R.E. Janes Gravel Co., chemical raw materials.• Justin Zdunczyk, member SME, of Pike Industries, construction aggregates.• Jerry Gauntt, member SME, of Golder Associates, fillers and pigments.• Ebrhaim K. Tarshizi, member SME, of the Michigan Tech, sorbents, filters and process aids.• Daniel T. Eyde, member SME, of St. Cloud Mining, specialty minerals.Their help makes possible this July industrial minerals issue. On behalf of ME readers, the editors thank them.Virta, R.L. U.S. Geological Survey, National Minerals Information CenterFour companies - H.C. Spinks Clay Co., Inc., Imerys, Old Hickory Clay Co., and Unimin Corp. - mined ball clay in four states in 2013. On the basis of preliminary data, production was 1 Mt (1.1 million st) with an estimated value of $47 million. Production increased by 3 percent in tonnage from 973 kt (1.1 million st) with a value of $45.1 million in 2012. Tennessee was the leading producer state accounting for 64 percent of domestic production, followed by Texas, Mississippi and Kentucky. About 67 percent of total ball clay production was airfloat, 22 percent was crude or shredded and 11 percent was water-slurried.ConsumptionIn 2013, domestic ball clay producers sold clays to the following markets: ceramic floor and wall tile (44 percent); exports (21 percent); sanitaryware (18 percent); miscellaneous ceramics (9 percent); fillers, extenders, and binders, and unspecified uses (4 percent each), based on 2012 end use patterns and current markets. Other markets accounted for less than 1 percent of the remaining ball clay sales or use. Sales reported for the manufacture of fiberglass or most filler, extender, and binder applications were likely to have been mainly kaolin mined or purchased by the ball clay producers.PricesThe average value of domestically produced ball clay was approximately $47/t ($43/st) in 2013 compared with $46/t ($42/st) in 2012, on the basis of a preliminary survey of domestic ball clay producers. The unit values of exported and imported ball clay were $126/t ($114/ st) and $373/t ($338/st), respectively, in 2013, compared with $62/t ($56/st) and $314/t ($285/st), respectively, in 2012. Unit values for most large export shipments increased in 2013, and a larger number of low-tonnage, high-value export shipments were shipped in 2013 than in 2012, resulting in a doubling of the average export value. Two low-tonnage, high-value shipments in 2013 accounted for the increased value of imports."

Jan 1, 2014

By D. J. Zhao

The reduction and nitridation of preoxidized ilmenite pellets were investigated with the prospect of creating grain refiners containing titanium oxides and titanium nitride dispersoids. All the reduction and nitridation reactions were conducted in a furnace with a thermogravimetric analysis system under a H2-N2 gas mixture of 5 L/min. The ilmenite pellets were reduced at 1100°C for 4 hours under 80%H2-20%N2 gas mixture, and then respectively nitrided at 700°C, 800°C, 900°C and 1000°C for 12 hours under 10%H2-90%N2 gas mixture. The products were characterized by X-ray diffraction (XRD) and Scanning Electron Microscopy (SEM), and analyzed by Energy Dispersive Spectrometers (EDS) and Electron Probe Mapping Analysis (EPMA). Iron oxides were reduced into metallic iron, and oxides of titanium were found, but titanium nitride particles were not identified in the products under the prevailing conditions.

Jan 1, 2014

By Shahriar Vandani, Andy Herlache, Andrew Bro, Wei-Yu Chen

"The Presidio Parkway Project will reconstruct approximately 1.6 miles (2.6 km) of highway, including seven new bridges, three new cut-and-cover tunnels, and a new undercrossing connecting the Golden Gate Bridge to the City of San Francisco, California. The project site is approximately 5.6 miles (9 km) from the San Andreas Fault, capable of producing magnitude 8 earthquakes. Seismic hazards include strong ground shaking, soil liquefaction, ground settlement, and lateral spreading. The Main Post Tunnels (MPT) are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) long. The MPT site underlain by loose sandy soils susceptible to liquefaction and lateral spreading. Excessive racking and permanent displacement due to lateral spreading are identified as the main seismic vulnerabilities. Analyses showed that without ground improvement, tunnel racking of over 5 inches (13 cm) and permanent lateral tunnel displacement of up to 15 feet (4.6 m) could be anticipated. Cement Deep Soil Mixing (CDSM) is proposed to mitigate slope displacements and increase lateral stiffness of the foundation materials to reduce tunnel racking. A series of 2-D fully dynamic time domain analyses were performed to evaluate the performance of CDSM, confirm that performance criteria are met, and optimize the CDSM geometry and replacement ratio. The use of CDSM reduced the permanent tunnel displacement from over 15 feet (4.6 m) to less than 1 inch (2.5 cm). Tunnel racking was also reduced significantly. The adopted analytical approach presented herein can be considered for future tunnel design projects in seismically active areas.Introduction The Main Post Tunnels (MPT) are an integral component of the Presidio Parkway project which will replace the existing facility with a new multi-lane roadway between the Golden Gate Bridge and the City of San Francisco. The MPT are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) in length. As shown on Figure 1, the project site is located in a seismically active area, about 5.6 miles (9 km) east of the San Andreas Fault and 12.5 miles (20 km) west of the Hayward Fault. The San Andreas Fault can generate magnitude 8 earthquakes while the Hayward Fault is capable of producing magnitude 7.3 earthquakes. The design Peak Bedrock Acceleration (PBA) is 0.46g for the upper level design earthquake. The project alignment is shown on Figure 2."

Jan 1, 2014

By Rafal Misa

In order to prevent the formation of mining damage or to reduce its reach, it is advisable to look for technical solutions which would enable effective protection of construction sites from the impacts of underground mining. So far, other authors have mainly focused on developing methods of securing construction sites in order to minimize the damage resulting from underground mining; the issue of geotechnical methods for protecting buildings against mining damage has not been thoroughly covered in those articles. It should be noted that there are relatively few publications directly related to this issue, nor are there practical examples of geotechnical protection. In this paper, a geotechnical solution available for securing building structures is discussed. Trenches presented in this research reduce the size and range of mining deformation. The results of numerical modelling for sample protective solutions, aimed at reducing the impact of mining activity on the terrain surface under various conditions, are presented. The calculations were performed with the aid of the Abaqus 6.10-2 software, based on the Finite Element Method.

Jan 1, 2014