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By V. A. Zanadvoroff

THE mine and concentrator of the Howe Sound Co., Chelan Division, are at Holden, in a remote section of the Cascade Mountains of northwestern Washington. Holden is at an elevation of 3200 ft., in the narrow valley of Railroad Creek. This creek drains into Lake Chelan, at a point some 40 miles up the lake from the town of Chelan. The concentrator treats 2000 to 2500 tons of low-grade copper-gold-zinc ore per day. Concentration is achieved by the differential flotation process, with recovery of 94 per cent copper and 82 per cent gold in the copper concentrate, followed by the recovery of 65 to 70 per cent zinc in the zinc flotation circuit. The final flotation tailing is deslimed, and coarse sands, representing 60 to 70 per cent of the total, are cyanided. The tonnage of tailing material amounts to 1900 to 2370 tons per day. GENERAL CONSIDERATIONS The property is within the Chelan National Forest. Railroad Creek is a fishing stream, being stocked regularly with trout from State hatcheries. Consequently, in planning a milling operation, the Howe Sound Co. was obliged to avoid any pollution of the stream by tailing material, and also destruction of valuable stands of timber. Moreover, the selected tailing disposal sites should not mar the natural beauty of the valley. In addition to these requirements, the problem of tailing disposal at Holden was complicated by topography and climatic conditions. The valley is long and narrow, averaging 1200 to 1500 ft. in width. Its walls are flaring at a steep angle. There are no extensive flat areas suitable for deposition of tailing. All valleys tributary to Railroad Creek, also the well-marked paths of snowslides, must be avoided. Finally, the direction of prevailing winds and possible dust hazard arising therefrom dictated the necessity of selecting the tailing-disposal sites downstream from the mill building and two campsites. Heavy snowfall during the winter months of November to March, inclusive, impedes building of the retaining dike, making it necessary to prepare the needed storage space during the summer months. It is inadvisable, also, to do any dike building during the freezing weather, because the dike becomes unstable with the spring thaws, producing inevitable "sloughing" of the built-up borders. TAILING-DISPOSAL SITES The existing tailing-disposal areas are near the south wall of the valley. They were developed, and put to use in the following sequence: No. I. Area.-Covers approximately 10 acres. Built up to the height of 60 ft.

Jan 1, 1946

By Martti Hagfors, Mervi Hokkanen

The Finnish Defence Forces has destroyed obsolete and spoiled ammunition in open surface mass detonations at Hukkakero fell, in municipality of Kittilä, in Lapland since 1988. The de-struction method was learned from Sweden in 1987. The disposal camp is organized every au-tumn and it lasts four to six weeks. A gross weight of an average charge varies from 150 to 250 tons and the net weight of explosives from 15 to 25 tons. As a booster there have been used 2 to 3 tons of emulsion explosives. The explosives mainly consist of trinitrotoluene (TNT) containing smaller a mounts of amatol and hexotol. The Finnish Defence Forces Tech-nical Research Centre (PVTT) has studied the environmental effects of these mass detona-tions since they began in 1988.

Jan 1, 2011

By D. A. Shock

Utilizing the technology developed for oil well stimulation by hydrofracing, a disposal system which permanently fixes the waste has been proven. Large quantities of radioactive waste can be processed by a single well system making this method an attractive method for permanent radioactive waste disposal. The system depends on locating a relatively thick formation of impermeable, but easily fracturable rock such as a shale, creating a horizontal fracture, pumping the waste into the fracture in a form which will subsequently solidify and seal the fracture from the well system. The paper presents the theoretical considerations from creating and extending horizontal fractures and how these considerations were used in designing a waste disposal system which is now operating.

Jan 1, 1964

By Devraj Sharma

This paper presents technical issues in the design and management of a retorted oil shale disposal site. Major physical and geochemical mechanisms which affect the disposal are: heat transport, moisture migration, chemical species transport, auto-ignition, and mechanical behavior alterations of the retorted oil shale pile. The interaction of these mechanisms and their relative magnitude will affect the environmental behavior of the pile. The paper discusses the coupling between the mechanisms, presents a framework to quantify the processes by laboratory and field measurements, and in addition discusses the use of mathematical models to provide quantitative predictions.

Jan 1, 1981

By Watters R

Modem open cut and underground mining in the tropics inevitably expose partially weathered and unweathered rocks to oxygen and water, leading to weathering and the release of solutes and often acidity as well. Historical monitoring data can demonstrate these phenomena. Three case studies from open cut mines in the north of the Northern Territory illustrate the deterioration in quality of pond water receiving drainage from waste rock dumps. The potential for deterioration of water quality was not recognised in many mine Environmental Impact Statements prepared and accepted in the 1980s. The examples documented indicate the importance of adequately planning for this near inevitable process. Retrofitting a mine water management system to 'no' or minimal release can be very difficult and expensive, and may not be feasible, leading to downstream pollution. The characterisation of acid and solute production potential of ore and waste rock, and improved dumping strategies and water management are very important to minimise the environmental impact of mining in the tropics.

Jan 1, 1994

By V. Steve Reed, Ed L. Reed

The in situ leach mining process generates a waste stream that is high in sulfates, total dissolved solids, and radium 226. During the mining phase, the volume of the waste stream is relatively low and consists primarily of the bleed stream. During the restoration phase, larger volumes of waste water are generated. These waste streams require environrnentally sound disposal. The low net evaporation rate in the Coastal Bend area precludes pond evaporation as a feasible disposal alternative. Reverse osmosis is a practical method of reducing the volume of the waste water handled, but the concentrated waste stream from the reverse osmosis unit must be disposed properly. Deep well injection into highly saline reservoirs is considered a sound method of disposing of the liquid waste generated by in situ mining in the Gulf Coast uranium district. Thirteen injection wells have been permitted to serve the disposal needs of the leach mining industry in Texas. Of these 13, 11 have actually been drilled. Seven applications are pending. The injection zones for the permitted wells range from depths of 3050 to 6200 feet. Pressure limitations imposed on these wells range from 500 psi to 1350 psi. The following criteria are used to determine the desirability of a disposal well site: 1. A minimal number of nearby, improperly plugged borings which penetrate the disposal zone; 2. Minimal crustal disturbance; 3. Sufficient salinity of the water contained in the disposal zone; 4. Protection of oil and gas producing zones; and 5. Sand of sufficient permeability and areal extent to handle the desired volume without fracturing the reservoir. 1. Improperly plugged borings: During the early part of the century, oil wells, gas wells and test holes were drilled using cable tool equipment, often with a minimum amount of surface casing. Production casing, when it was set, was often partly removed when the holes were abandoned. Thus, wells drilled prior to 1940 frequently have less than 100 feet of surface casing and either no production casing or the upper part of the production casing removed. Additionally, these holes are often plugged only with mud. The close proximity of these holes to an injection well location are a concern in that they can provide an avenue for injection-depth fluids to migrate up the bore hole and jeopardize shallower fresh water reservoirs. Usually, where there are more than 6 or 8 poorly plugged borings in a 2 1/2 mile radius of the well site, it is preferable to examine deeper zones for disposal well potential. The deeper zones are especially attractive where the borings are not in a cluster, which renders monitoring more difficult. Often, even the deeper disposal zones are penetrated by a few improperly plugged borings. When this condition arises, the potential for leakage through the borings can be addressed in the following ways. a. Demonstration that the static head in the boring is higher than the anticipated increase in bottom hole pressure generated at the boring by the disposal well. A 100 psi differential between these two pressures is recommended. The calculated increased pressure at a boring caused by injection should be refined using annual bottom hole pressure measurements in the disposal well. Figure 1 illustrates an injection pressure map which can be overlain on the oil well map to determine the anticipated increase in pressure expected at each oil, gas or abandoned hole. b. Shallow ground water monitoring. A shallow monitor well is drilled next to the boring and both pressure and quality measurements are made periodically in the shallow well. c. Disposal zone monitoring. Recently there has been a tendency for regulators to require disposal depth monitor wells instead of shallow well monitoring. We consider disposal depth monitoring to be a less effective method of monitoring because it provides only indirect evidence of potential problems. Assumptions have to be made for the unplugged borings, such as mud weight, that are not addressed by the disposal zone monitoring program. There is little improvement with this system to that discussed in "a" above. A shallow zone monitoring program, however, yields direct evidence of a developing problem with an unplugged boring. Leakage by the boring will be detected quickly by an abnormal increase in pressure in the shallow well. Quality monitoring will detect upward migration of poor quality fluids. The pressure data provide an early warning of impending leakage; the quality monitoring will detect actual fluid migration.

Jan 1, 1980

By Emmanuel Pornillos

Dado que en el Perú, la actividad minera utiliza el minado subterráneo para la explotación de minerales, se revalúa el uso de estos en pasta cementada para el relleno de las labores subterráneas, así como los relaves desaguados para su disposición superficial. En ese sentido, el presente texto señala las experiencias de diseño y operacionales de sistemas múltiples para la aplicación de relaves en superficie y subterráneo en el Perú, de forma que se pueda optimizar la selección de equipamiento y una operación robusta.

Sep 1, 2013

The arbitration process, and its drawbacks: Any time you have taken part in a major arbitration, and the decision, when it comes out, is not what you thought it would be (which is bound to happen occasionally), the normal reaction is something like æthe arbitrator got it wrongÆ. Again normally, when you have cooled down a bit, and you look in more detail at the decision, you can see, probably, æwhere he got it wrongÆ (it is only male arbitrators who get it wrong). Ultimately, when reason prevails, and you reflect on it, you can see that what really happened was that you failed to get the arbitrator to see what you were getting at in the point or points concerned. This is doubly frustrating, when you consider what has been involved in getting to this point, having been through it all at least twice. An alternative to this process may be the dispute review board.

Jan 1, 1999

By James F. Holzbach

Although Disputes Review Boards have been used for some time, they had not received wide publicity at the time Monroe County first used one. Public owners frequently resist adopting new contracting practices. This paper discusses an owner's experience with Dispute Review Boards, from learning about them to their use on two (2) projects. The experiences of potential and actual contractor claims are compared to a claim on an earlier contract and the ensuing litigation. Suggestions for possible use for Owner-Engineer disputes and recommendations for use are provided.

Jan 1, 1995

By Jian Liu

The dissolubility of a natural sphalerite (ZnS) in the entire pH range was theoretically calculated, and its practical dissolution in an aqueous solution at different pH values in an inert environment, together with its surface properties after dissolution, was fully investigated. The results of the investigation indicate that the total concentration of Zn (CZnT) decreases significantly with the increase of pH value, while the pH value is set below 8; however, it reverses when the pH value reaches 8. Such a tendency is similar to that of the theoretical calculations, although the experimental CZnT were much higher than those of the theoretical calculations. The X-ray photoelectron spectroscopy (XPS) of the sphalerite surface after its dissolution under alkaline solution shows that a polysulfide (Sn 2-) surface layer with a binding energy (BE) value of 162.96-163.25 eV is present on the surface, and the percentage of Sn 2- increases significantly with an increase in pH value; the undissolved and dissolved sphalerites under the acidic solution have a negligible difference in S2p peaks. The surface S/Zn ratio of all dissolved sphalerites shows a marked Zn enrichment and S deficiency. An atomic force microscope (AFM) view of the sphalerite surface, after its dissolution under the alkaline solution at a pH of 12, shows that the surface is significantly different in morphology from that of the undissolved one.

May 1, 2012

By E. Uzun

"In this study, H2SO4 and HCl leaching behaviour of an ore sample containing 1.87% of Ni, obtained from the Karaçam (Eskisehir-Turkey) lateritic deposit that started operation recently was investigated. Acid concentration, temperature and reaction time were investigated as variables by comparative leaching tests and the optimum leaching conditions were selected on teh basis of Ni, Fe, Co and Mg behaviour. For H2SO4 leaching, optimum leach parameters were 95°C, a 12 normal H2SO4 concentration and 90 minutes of reaction time, and under these conditions Ni and Fe dissolutions were 97.6% and 95.4% respectively. On the other hand, 70°C, an 8 normal HCl concentration and a reaction time of 90 minutes were found to be the optimum parameters for HCl leaching, and Ni and Fe dissolutions found were 97.1% and 97.8%, respectively.INTRODUCTION Today, nickel and various nickel compounds are obtained from sulphide and lateritic nickel ores (Moskalyk & Alfantazi, 2002). Even though about 72% of the world's nickel reserves constitute lateritic ores, only about 42% of nickel is produced from these ores. The decrease in production from sulphide deposits, on the other hand, and increases in the use of nickel in the iron and steel, and battery production sectors, and especially the production of nickel cast irons in recent years, have accelerated the importance of making use of lateritic deposits (Luo et. al., 2010; Chang et. al., 2010). In the beneficiation of sulphide nickel ores, mostly pyrometallurgical methods are used. On the other hand, about 39% of lateritic ores are beneficiated by pyrometallurgical, and 61% are beneficiated by hydrometallurgical methods (USGS, 2009). In laterite beneficiation, the ore properties are of significance; that is to say, limonitic ores are eneficiated by high pressure acid leaching or via the Caron process, nontronitic ores are beneficiated by high pressure acid leaching or heat treatment (smelting), and ores containing serpentine by pyrometallurgical methods (Berezowsky, 2004; McDonald & Whittington, 2008a; Dreisinger et. al., 2015)."

Jan 1, 2017

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By M. Clotilde Apua, A. F. Mulaba-Bafubiandi

"The efficiency of hydrochloric acid (HCl) leaching of gold from low grade gold-bearing material has been investigated in the presence of sodium hypochlorite (NaOCl) to produce in situ chlorine gas which is an oxidizing agent able to oxidize gold metal to its soluble forms. The effect of concentrations of HCl, NaOCl, and mixtures of HCl + NaOCl was sought. Iron and potassium present in the feed were leached and consumed all the HCl. Gold found as inclusion in pyrite was not exposed to the lixiviant. Therefore, leaching of gold from low grade gold-bearing material in aqueous chlorine solution is not an effective process for now.INTRODUCTIONHydrometallurgy of gold is commonly based on cyanide leaching solution. Due to the environmental concerns related to cyanidation and mercury processes, and inefficiency of cyanide gold leaching to dissolve refractory ores, sustainable alternative lixiviant systems, capable of generating gold (I) and gold (III) complexes must be studied. Amongst non-cyanide gold lixiviants there is the chloride/chlorine system (Hilson and Monhemius, 2006; Senanayake, 2004; Pilsniak and Trochimczuck, 2007; Wang et al., 2007; Reeves et al., 1999; Khodadad et al., 2008).In practice, the most oxidizing agents utilized for the leaching of gold as chloride, are chlorine (Cl2) or hypochlorite (HOCl) which are either generated in situ by suitable reaction or added in solution (Adamson, 1972). The dissolution of gold concentrate using hydrochloric acid, sodium chloride and sodium hypochlorite (Cl-/HOCl system) were studied (Puvada and Murthy, 2006). The effect of NaOCl and NaCl concentrations were also investigated. The leaching was performed under the following conditions; time: 4h, solid–liquid ratio = 1:4, at room temperature. It was found that the increase of the NaOCl concentration from 25 to 75 g/L did not have any meaningful effect on the recovery of gold which was about 30% (experimental conditions; S/L ratio = 1:4, NaCl concentration: 25 g/L, HCl concentration: 0.35 M). It was also found that from 25 g/L to 200 g/L NaCl, the recovery of gold rose from 30% to 40% (experimental conditions; S/L ratio: 1:4, NaOCl concentration: 25 g/L, HCl concentration: 0.35 M)."

Jan 1, 2012

By VÍCTOR VÁZQUEZ-VÁZQUEZ, GUILLERMO TIBURCIO-MUNIVE, María M. Salazar-Campoy, JESÚS L. VALENZUELA-GARCÍA, OFELIA HERNÁNDEZ-NEGRETE

This study examines a process for the recovery of precious metals from difficult minerals that exhibit refractory characteristics to cyanidation: low extraction of metals and high consumption of leaching reagent. A mineral sample from Monte del Favor Mine, located in Hostotipaquillo, Jalisco, Mexico, was physically and chemically characterized by X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), fire assay and atomic absorption spectroscopy (AAS). Two stages of leaching were carried out, first to eliminate manganese from the sample using sodium sulfite (Na2SO3) as a reductive reagent along with sulfuric acid (H2SO4), and second to dissolve gold and silver with hydrochloric acid (HCl) and sodium hypochlorite (NaClO). The results show extractions of around 96 percent for manganese (Mn), 98.73 percent for silver (Ag) and 83 percent for gold (Au). The usefulness of high acidity and Na2SO3 to obtain better results in Mn and Ag leaching are discussed along with the roles that HCl and NaClO play in Ag and Au dissolution values.

By Batric Pesic

Silver dissolution with thiourea was studied by using the rotating disk technique. The major parameters studied were: thiourea concentration (0-0.5M), ferric sulfate concentration (0-0.5M), sulfuric acid concentration (0-0.5M), and the effect of many foreign ions (Mn, o.i, Co, Ca, Na, etc.). Temperature effect was studied in the range 5-35 .C. The activation energy was 5.4 Kcal/mole. The dissolution of silver was first order with respect to ferric sulfate, and the secord order with respect to thiourea. Among the additives, copper had a dramatically negative effect. The strong oxidants such as hydrogen peroxide and manganese dioxide were also detrimental for silver dissolution. Silver does not dissolve with thiourea in the absence of ferric ions. Sulfuric acid does not participate in the dissolution reaction either. Chemically, the most important parameter for silver dissolution is the ferric sulfate/thiourea ratio. Thus, in the solutions with excess of ferric sulfate, a solid silver-thiourea complex is formed, which precludes transfer of silver into solution. In the solutions with the excess of thiourea, the free thiourea reacts with formed solid silver-thiourea complex and silver goes into the solution. The solid silver-thiourea complex was characterized according to its chemical composition. The complex contains 6.54%C, 2.49\H, 14.77%N, 16.09%0, 21.62%8, and 37.13% Ag. This composition corresponds to a Ag2so4.3'1U.2ff:i0 compound The soluble silver species are present in the solution as the dimers of AgTU+3 complexes.

Jan 1, 1989

By Elizaveta Cheremisina

In steelmaking process lime serves as flux. Rapid lime assimilation and slag formation of the desired composition have a significant effect on the refining reactions. It is important to know the rate limiting step of lime dissolution to control and improve the converter process. Kinetics of pure CaO and industrial lime dissolution in model slag has been studied in the range of temperatures 1300 –1600°C. Lime samples were prepared in cylinder form and immersed in the melt for predetermined time. Considering the total mass balance of CaO in the slag and linear dimensions of lime samples, mass transfer coefficients were derived. Diffusion coefficients were calculated under conditions of non-stationary diffusion. The derived activation energy of less than 200 kJ/mol indicates that diffusion is the limiting step in the process of lime-dissolution in slag.

Oct 30, 2017

Distal air-fall ashes are widespread deposits that may record volcanism many hundreds of kilometres from their source. They are characteristically thin, fine-grained and have a low preservation potential usually being either eroded, or reworked and incorporated in overlying sediments following deposition. The most likely sites of accumulation are deep sea, lake and swamp environments where low energy conditions favour preservation. Post-depositional alteration of predominantly glassy volcanic ash is commonly extensive hampering identification of such layers in the geological record. As a result air-fall tuffs are poorly represented in the rock record and furthermore are commonly misinterpreted. Southeast Queensland during the late Triassic hosted active silicic volcanism and a number of fault-controlled basins in which coal-bearing sediments were accumulating. Silicic volcanics of late Triassic age are represented by the Brisbane Tuff in the Brisbane city area, the Chillingham Volcanics to the south of Brisbane and extending into New South Wales, the North Arm and Mount Byron Volcanics to the north of Brisbane, the Aranbanga Beds exposed around Gayndah and the Agnes Waters and Muncon Volcanics which occur northwest of Bundaberg. Stephens (1986) interprets these Volcanics as the remnants of a major silicic igneous 'province which he likens to modern continental orogenic margins. The Ipswich, Tarong and Callide Basins of southeast Queensland all contain coal measure sequences of late Triassic age that accumulated in alluvial plain environments. A Dicroidium flora is common to all and palynol.ogical evidence indicates a late Triassic (Carnian) age (de Jersey, 1975; Stevens, 1981). The coal seams of the three basins are characterised by their thickness (up to 25 m) and the presence of abundant thin, laterally persistent, kaolinite claystones (tonsteins) that show a marked similarity of morphology, texture and mineralogy. Detailed studies of the Ipswich Coal Measures (Falkner, 1986) suggest a volcanic air-fall origin for the tonsteins of the Ipswich Basin. Similar.tonsteins from the Tarong and Callide Basins provide evidence for widespread silicic volcanism during the late Triassic in southeast Queensland.

Jan 1, 1987

By Zhiguo Chang, QINGXIANG CAI, Ebelia Manda, IZHAR MITHAL JISKANI, XIANG LU, Wei Zhou, Saleem Raza Chalgri

The concept of mine safety is highlighted in the literature of sustainable mining but not extensively discussed. This study analyzes various aspects of underground and surface mine safety and emphasizes its importance in the context of sustainable mining. More specifically, this research attempts to find the relationship between mine hazards and demographic characteristics, examine and compare the perceptual difference among miners, and determine the impact of mine hazards on workplace safety and safety climate. Descriptive analysis, chi-square test, independent samples t test, and linear regression modeling were conducted to achieve study objectives. Results confirmed that mine hazards were significantly associated with age and experience. Miners perceived lower levels of management safety practices, followed by supervisor safety, coworker safety, and job safety. The analysis showed that underground miners reported lower safety scores than surface miners. There was a statistically significant difference between miners’ perception of safety climate (p < 0.05). The results showed that the higher prevalence of mine hazards predicts poor workplace safety and a low safety climate. The regression models revealed that mine hazards have a significant effect on workplace safety (p < 0.05) and safety climate (p < 0.05). In conclusion, the distinctive model of mine safety presented here contributes to the monitoring and design of comprehensive safety interventions and helps to better understand how certain factors interact on multiple levels to influence the overall safety of the industry. In this study, some suggestions are put forward to provide directions to develop a sustainable mine safety system.

Mar 27, 2020

By J Chan, T Baumgartl, A Plante, C Peltre, P D. Erskine

Mine soils are often organic matter and carbon poor due to disturbance, topsoil stockpiling and mixing with spoil. They present an opportunity to observe the accumulation of soil carbon arising from rehabilitation or ‘green carbon’ through organic matter inputs and may be considered for carbon credits. Soil carbon is known to improve multiple soil characteristics and is viewed as an indicator of soil health.When attempting to estimate soil carbon levels in the Australian coal mining regions, both coal and black carbon (BC) need to be quantified. Coalmine soils contain coal particles that are difficult to distinguish from organic matter using standard carbon analyses. BC, a material arising from the incomplete combustion of organic matter and fossil fuels, displays some similar characteristics to coal and is ubiquitous in Australian soils due to bushfires. The presence of coal and BC complicate the determination of green carbon levels in mine soils.A method to quantify coal and BC in mine soils from the Bowen Basin using thermal analysis and multivariate curve resolution is presented. By determining BC and coal contributions it is then possible to calculate green carbon levels in rehabilitated mine soils. Calculated green carbon levels are compared with bulk density as soil quality indicators.CITATION:Chan, J, Baumgartl, T, Erskine, P D, Peltre, C and Plante, A, 2014. Distinguishing carbon fractions in coalmine rehabilitated soils, in Proceedings Life-of-Mine 2014 , pp 491–498 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 16, 2014

By R N. Lamb, A N. Buckley

Experiments have been carried out to establish whether time-of-flight secondary ion mass spectrometry (ToF-SIMS) is able to differentiate monolayer and multilayer coverage of thiol collectors on sulfide minerals. The systems investigated were those for which x-ray photoelectron spectroscopy is able to provide an independent determination of the extent of coverage, and included diethyldithiophosphate (DTP) and 2-mercaptobenzothiazole (MBT) on chalcocite, DTP on Ag2+MS prepared by sulfidising metallic silver, and isobutyl xanthate (BX) and MBT on galena. For monolayer adsorption of MBT on chalcocite, peaks from MBTû but not Cu(MBT)û ions were evident. For multilayer coverage, Cu(MBT)2û ions were clearly present, notwithstanding the fact that other data had identified the principal multilayer species as Cu(MBT). For adsorbed DTP on copper and silver sulfides, DTPû and metal(DTP)Hû peaks were observed for monolayer and multilayer coverage. Although the multilayer species was expected to be predominantly metal(DTP), metal(DTP)2û ions were evident for multilayer (but not monolayer) coverage. For the PbS/BX system, intact Pb(BX)2 or Pb(OH)BX ions were not detected for multilayer coverage, although Pb-containing ions heavier than PbBX were. Indeed, for all the systems studied, ToF-SIMS was able to differentiate monolayer from multilayer coverage. In general, however, the SIMS evidence alone might not be sufficiently definitive to effect the differentiation. In the case of collector adsorption on copper and silver sulfides, if the multilayer species detected had been the metal monothiolate only, and had not involved the formation of some metal dithiolate, then ToF-SIMS might not have been able to provide an unequivocal differentiation of the two coverage conditions.

Jan 1, 2005