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By S. H. Ash

THE information obtained by examining and analyzing the core drillings from 15 diamond-drill holes shows that with the proper equipment little difficulty should be experienced while sinking the shafts at the 15 selected sites. Although a number of holes penetrated formations containing a high percentage of silica,, the health hazard from dust can be removed by using proper dust-control equipment. Methane was detected in small amounts in only one (hole 5) of the boreholes. The methane hazard should present no difficulty if adequate ventilation is employed while sinking the shafts.

Jan 1, 1952

By GERALD A. WARING

ALASKA'S coal consumption is now about 130,000 tons annually. About one-quarter of this amount is used in the southeastern part of the territory and in settlements on the western coast and comes from Seattle and from British Columbia mines. About 60,000 tons is sub-bituminous coal from the Healy River mine in central Alaska, and is used mainly at Fairbanks, sixty miles to the north, for heating and the development of electric energy, for the city and the gold-dredging operations of the Fairbanks Exploration Co. The remaining 40,000 or 50,000 tons is bituminous coal from Matanuska Valley, in the south-central part of the territory. These coal deposits extend intermittently for about forty miles along the valley, which trends eastward from the upper end of Cook Inlet.

Jan 1, 1934

By R. Krentz, P. D. Cordingley

The nickel-cobalt sulphides produced from limonitic laterite ores by Moa Nickel S.A. in Cuba are refined at the Corefco nickel-cobalt refinery in Canada. Major changes to the refining process were required when the Moa sulphide feed, with its unusually high cobalt content, was introduced in the early 1990's. In the period 1994 to 2005 the production capacity of the refinery has increased dramatically to match increases at Moa, and significant process improvements incorporated. The process flowsheet consists of the original ammonia leach process, optimized for cobalt chemistry and overall leaching capacity. Extraction of metal values is followed by the unique nickel-cobalt separation technology, in which most of the cobalt is separated from the ammoniacal nickel sulphate leach solution by precipitation as a nickel-cobalt hexammine salt. This salt is refined from a Co:Ni ratio of 1:1 to over 10,000:1 by selectively leaching nickel, redissolution and recrystallization in ammonium sulphate solution. Nickel and cobalt are recovered using the well-known Sherritt hydrogen reduction technology. This paper reviews the chemistry described above, examines some of the changes in operating conditions made over the years and highlights some of the recent physical changes made to the refinery.

Jan 1, 2005

By J. Budac, J. Dennett, D. Mayne, P. Nawrocki

"The Nickel/Cobalt operation in Fort Saskatchewan, Alberta has successfully used an oxidative ammonia leach process to refine a variety of feeds into high quality nickel and cobalt products for over 60 years. Fundamental changes to the refining process were made when the major feed was converted from nickel concentrate to cobalt rich mixed sulphides in the early 1990s. Since the early 1990s, the production capacity of the refinery has expanded to match increases in both mixed sulphides and other feeds. In addition to increasing the production capacity of the refinery, other changes have been required in order to improve the operability and reliability of the refinery as well as to deal with increasingly stringent safety and environmental requirements. This paper describes recent changes at the refinery including changes to the flow sheet, improvements in unit operations, incorporation of new feeds, management of byproducts, and control of impurities.INTRODUCTION The Cobalt Refinery Company (Corefco) plant in Fort Saskatchewan processes nickel-cobalt mixed sulphide intermediate produced at the lateritic nickel mine and high-pressure acid leach (HPAL) facility in Moa Bay, Cuba. Both operations are jointly owned and operated by Sherritt International and General Niquel of Cuba. The mixed sulphide, along with other feed materials, is processed at the Fort Saskatchewan refinery using a pressure ammonia leach-hydrogen reduction process to produce nickel and cobalt metal. This refinery was originally constructed in 1954 to treat nickel concentrate from Sherritt’s Lynn Lake mine in Manitoba. (Benson and Colvin, 1964; Boldt and Queneau, 1967; Forward, 1953; Forward and Mackiw, 1955; Kerfoot, 1989) From the mid-1970s until the early-1990s, the facility operated as an independent refinery, treating nickel-bearing feeds from around the world. The flowsheet was changed in 1992 to address the increased cobalt content of the feed. (Cordingley and Krentz, 2005; Kerfoot and Cordingley, 1997) The flowsheet was adapted further in 2009 to improve cobalt speciation in the leach process, which allows better cobalt-nickel separation. The 2009 iteration is shown in Figure 1. Three ammonia leach stages were used to ensure high recoveries of nickel and cobalt. Underflow solids from the final leach stage contained mainly iron oxides. One of the features of the leach process is the innovative recycling of ammonia. Ammonia vented from the leach process in tail gas and from atmospheric tanks is recovered and recycled into the refinery using water based scrubbers and a high pressure distillation process. Indeed, roughly 250 t NH3/d is recovered as distillate and recycled back into the process. Also, air enriched with ammonia which is vented from the later first stage autoclaves is recycled to the lead first stage autoclaves to maximize oxygen and ammonia utilization."

Jan 1, 2017

By Rayner J. G, Leckie J. F, Moorehead C. F

The Coronation Hill gold-platinum-palladium prospect is located in the valley of the South Alligator River (latitude 13'35'S, longitude 132'36'E), about 80 kilometres east of Pine Creek in the Northern Territory. Coronation Hill was one of thirteen sites in the South Alligator Valley at which uranium was mined between 1955 and 1964 after initial discovery by the Bureau of Mineral Resources in 1953. Most of the mines were operated by United Uranium No Liability. The Sleisbeck mine 25 kilometres south of Coronation Hill was operated by North Australian Uranium Corporation and the group of mines at Rockhole about 20 kilometres to the north-west of Coronation Hill was operated by South Alligator Uranium No Liability. The uranium mine at Coronation Hill produced about 26000 tonnes of ore averaging 2.6 kg/t U308 with an estimated average gold grade of 10.4 g/ gold. Gold was commonly associated with the uranium mineralisation and was recovered at the gravity treatment plant at El Sherana. Gold was also recovered in 1986 by Pacific Gold Mines Limited by treating the tailings from the Moline and Rockhole uranium leach plants at a CIP plant at Moline. With the completion of uranium contracts in 1964 mining in the South Alligator Valley ceased. Exploration for uranium continued in the area during the 1960s and 1970s with no success. The Coronation Hill Joint Venture (BHP Gold Mines Limited 45 per cent, Pioneer Minerals (Gold) Pry Ltd 45 per cent, Notgold Limited 10 per cent)carried out the first exploration specifically targetted at gold in 1984 with the drilling of five vertical drill holes which indicated high potential for a substantial gold resource at Coronation Hill with no associated uranium. The Joint Venture has sub- sequently drilled about 25000 metres of diamond drill holes at Coronation Hill alone. Analytical results from 1985 drilling established that platinum and palladium were associated with gold. An indicated resource of 3.49Mt at 5.12g/t Au, 0.21g/t Pt and 0.56g/t Pd has been calculated using a lg/t Au cut off.

Jan 1, 1991

By M. J. Brodie

"The decision to proceed with mine decommissioning, generally involves a number of complex and independent factors. These factors, including potential for re-opening, legal requirements, contingent liability, asset depreciation, due diligence, and public relations are discussed in the context of the financial implications on a net-present- value basis. It is concluded that the decision to delay mine decommissioning is commonly not in the best financial interests of the mine operator. Some measures to reduce decommissioning costs and expedite the process are presented.IntroductionThe primary audience for this paper is mining executives, although it should be of interest to all professionals involved in the planning and carrying out of mine decommissioning. Historically, mines were abandoned, not decommissioned. Then, as decommissioning became required, it was assumed that salvage revenue would pay for decommissioning. During the I980s, it became apparent that mine decommissioning costs would exceed salvage revenue for nearly all sites, and that a substantial net cost for decommissioning would be realized for some sites. Throughout this period, the approach to decommissioning has evolved through the sequential addition of measures to meet the increasing regulatory burden. This has resulted in a process in which the elements of decommissioning may not be optimized with respect to each other for the most favourable net present value to the corporation. Additional considerations which are not specific to mine decommissioning, such as environmental policy, due diligence and public relations, may now come to bear on the decision-making process.This paper addresses the issue of mine decommissioning as a three-step process. The first step involves identification and evaluation of all of the issues that relate to mine closure, the most importantof which is the potential for re-opening of a mine. Assuming that it is decided that a mine is unlikely to re-open, the second step is to determine when to carry out the decommissioning work. This aspect is examined through a net present value (NPV) approach. Finally, details regarding who does the work and how the various tasks are divided up must be resolved.Every mine is a unique concentration of minerals at some specific location, hence the development, operation and closure of a given mine must be regarded as a special case. Superimposed on the site-specific considerations are the size, history and financial status of the associated corporation."

Jan 1, 1995

By V. Budinsky

In recent years the global mining industry has addressed its social and environmental responsibilities and numerous factors have contributed to this. Corporate Social Responsibility (CSR) is an important part of mining company strategy for practical implementation of the goals of sustainability, transparency, accountablity and good relationships with stakeholders:- investors, employees and communities. A key stakeholder for all mining companies is the local community which is affected by the mining operations. Companies must identify the emerging social and environmental trends, study the interests and concerns of various communities, address their needs and maintain a positive relationship. The CSR programmes of Czech coal mining companies are focused on surrounding community initiatives and sustainable responsible business. Mining in the Czech Republic is subject to strict rules and regulations and supervised by the State Mining Authority. Mining projects undergo rigorous approval procedures which encompass all operational measures at the different planning levels ? such as public participation in the authorisation process for mining projects, the application of the Environmental Impact Assessment Directive, environmental sustainability programmes, innovative solutions and flexible options offered by the mining company. One very important part is the preparation of the mining-technology preconditions and developing the integrated planning process in which all socially and politically relevant subjects in the mining operation surroundings are included. In an in-depth debate, all stakeholders may jointly develop the concept, in accordance with democratic principles. The optimally conducted dialogue process needs broad communication bases, including setting up theme-related joint taskforces, together with good moderation and the highly qualified support of technical experts. Using a case study of Severoceske doly a.s. Chomutov (SD Company) and the Czech Coal Group ? Czech leaders in the extraction of brown coal, this paper aims to examine the community development approaches and the CSR effectiveness of large scale mining companies. This paper brings a review of CSR and other such voluntary initiatives in the mining industry's proactive steps to contribute to societal well-being in a meaningful way. Key studies are provided by the projects ? Region with Better Perspective?, ?Stop Dust for Healthy Brezno Village?, ?Clever Heads for the North? and ?Coal Safari?. CSR issues are managed throughout all stages of the mine operation and beyond, long after the mine closes (e.g. post-closure programmes of new landscape, alternatives for reclamation including generation of lakes in former surface mines, conceptualization of industrial heritage). Communities need to be given the opportunity to help themselves through participation in CSR projects rather than being recipients of financial gifts from the company. A fair balancing of interests is the basis of any successful cooperation.

Aug 1, 2013

By E. A. Adey, C. Baciu, P. Whitbread-Abrutat, M. Varul, T. Ejdemo, R. K. Shail, F. Wall

Responsible mining requires stakeholder engagement throughout all operational stages and after mine closure. By assessing the current and anticipated future socio-economic and environmental impacts, a company can maximise the positive impacts they can have on a community, whilst minimising any negative impacts. Despite the current emphasis on companies maintaining effective stakeholder relations to gain their ‘social license’ to operate, findings of the present study reveal a wide variation in community expectations, with different degrees of ‘acceptability’ evident across seven sites in Romania (Rosia Montana), Sweden (Kristineberg), the United Kingdom (Cornwall), Bosnia Herzegovina (Vihovici) and Russia (Karabash, Gay and Mednogorsk). These variations reflect the current status of mining within a community, as well as its socio-economic background and the nature of existing engagement with mining companies already operating in the region.

Jan 1, 2011

By James E. Brewer

Procedure for approval by the U. S. Army Corps of Engineers of a new source of aggregate is in three phases. Phase 1 consists of an investigation of a quarry or proposed quarry by district geologist and laboratory geologist and/or petrographer. The quarry face or suitable outcrop is logged in detail or, if exposures are poor, cores may be taken to determine whether further investigations are warranted. Phase 2 consists of thorough laboratory testing. Cores and crushed material are subjected to a number of acceptance and quality tests for soundness, absorption, abrasion, reactivity, and other properties. Petrographic analysis is also made. Phase 3 is a physical and economic study of the site and involves determining quantity of stone avail- available, amount-and character of overburden, condition of haul roads and distance to rail shipping point, plant flow sheets and capacity, aggregate sizes produced, and approximate price of material at plant.

Jan 1, 1966

By Frank C. Canney

The word "other" in paragraph 4, line 11, column 1, page 205, should read "over;" the correct version of reason 2, this paragraph, is: 'L. . . 2) to evaluate the usefulness of certain geo-chemical techniques, V. C. Kennedy and S. W. Hobbs of the USGS had already studied the distribution of copper, lead, and zinc in the soils (both in background areas and over veins) and in the water and plants, providing a criterion for measuring the magnitude and effect of soil contamination; ...9 On page 206, in the top left hand corner of Fig. 1 (in the area bounded by 47°35' and 116°10), the reference to Fig. 3 is incorrect. The area of Pine Creek, South Fork Coeur d'Alene River, and portion of Big Creek (the area which includes, from left to right, Kingston, Pinehurst, Smelterville, and Kellogg) should be identified as that of Fig. 2A. The headings for columns 1, 3, and 4, Tables I and 11, page 209, column 2, were reversed when the paper was printed. The corrected tables are:

Jan 1, 1961

By E C. Holloway

"The financial valuation of mining assets has a number of fundamental differences to the valuation of many other asset groupings. One such difference is that typically, the greater proportion of both the cost and revenue sides of the cash flow are inherently governed by systemic market forces.As a result, the range of outcomes for the valuation of each mining asset is more unpredictable, with higher levels of risk and uncertainty. In contrast, the management function of many other non-mining businesses or industry groups can control at least a portion of the cash flow by maintaining the margin or controlling the sales price. The management teams of mining businesses and operations typically have limited options, and are thus price-takers for both costs and revenues. As mining is an inherently cyclical industry, large, long-life operations can exist through several price cycles, making valuation both subjective and challenging.The outcomes of both static- and stochastic-based valuations, as well as the internal probabilities of the associated cash flow statements, are significantly impacted when the correlations between the appropriate parameters are quantified, modelled and incorporated into the valuation framework. The appropriate parameters for correlation modelling primarily include those that are governed by systemic market forces. Applying this process results in a different risk profile for the asset by allowing the risks resulting from systemic market movements to be more accurately quantified and then objectively minimised. This process also reduces the level of residual uncertainty in the valuation outcome.This paper presents a valuation methodology to pragmatically incorporate this level of valuation sophistication and statistically quantify the associated increase in the level of confidence of the valuation outcomes reported.CITATION:Holloway, E C, 2016. Correlated valuation methodology, in Proceedings Project Evaluation 2016, pp 181–200 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 8, 2016

By Randy Martin, Jessie Bonner, Peter Boyd, Mark Leidig, Timothy Rath

We conducted the Vermont Damage Experiment in central Vermont during July 2008. Five single-hole explosions with yields ranging from 60.8 kg (134 lbs) to 122.5 kg (270 lbs) were detonated in homogeneous, low fracture density granite. The goal of the experiment was to quantify the different levels of rock damage around the source and then relate the seismic wave generation to the degree and distribution of damage and fragmentation. In addition, explosives with different velocities of detonation (VOD), including black powder (0.53 km/sec; 1737 ft/sec), heavy ANFO (4.8 km/sec; 15734 ft/sec), and COMP B (8.1 km/sec; 26574 ft/sec) were detonated to relate the VOD to seismic wave generation and extent of damage zones in the source region. Over 120 seismic stations were deployed to record the explosions at distances between 5 m and 30 km (15 ft to 19 miles).

Jan 1, 2010

By A. Mainza, H. Hill, L. S. Bbosa

"Impact breakage is the most elementary size reduction mechanism in comminution devices. In comminution research, characterization of breakage is primarily concerned with the energy expended to cause it. The main challenges of this approach have been quantifying the actual energy requirements of impact breakage and developing mechanistic models to accurately describe the process. For engineering load analysis, fracture is characterized in terms of strengths such as yield stress and ultimate tensile stress, which govern the maximum loads specific materials can be subjected to before irreversible inelastic deformation and subsequently complete fracture occur. With this approach, the main challenge has been to elucidate the underlying mechanism, in the means that the load causes weaknesses in the material microstructure to act as sites for stress concentrations, leading to crack initiation, propagation and eventual failure. Studies dedicated to investigating particle fracture under impact loading have led to the development of several devices for conducting breakage characterization tests. These devices include the drop weight tester, split Hopkinson pressure bar, rotary breakage tester and the short impact load cell. All these have different particle loading and breakage methods, and thus can yield distinct information which can be compiled together to study a material and the nature of breakage. This work analyses the single impact breakage data obtained across the listed devices. A homogenous ore commonly known as blue stone is used for all breakage tests. The work is conducted using standard procedures specific to each device as closely as possible. Drop weight and rotary breakage tests were used to obtain hardness parameters based on an existing t10 breakage model, while split Hopkinson pressure bar and short impact load cell measurements provided properties based on conventional engineering load analysis. The results were used to highlight the significance of the loading geometry, impact mechanism and impulse on the extent of breakage."

Jan 1, 2018

By C. Blawert

In spite of various corrosion studies on HPDC AZ91, there is no clear indication which microstructure gives the best corrosion performance. The skin with its fine microstructure is sometimes reported to have the best corrosion resistance, but there is no clear definition of the skin. If the skin is the outermost part of the casting and nothing is removed from it, then it is contaminated and the corrosion resistance is low. If the outermost skin is removed (about 25 µm) then a better corrosion resistance can be obtained. However this does not automatically mean that there is no other region in the bulk of the casting which could have a similar or even better corrosion resistance. Indeed, the corrosion measurements including potentiodynamic polarization and long term electrochemical impedance spectroscopy (EIS) revealed a lower corrosion resistance of the original as-cast skin about 100 pm thick. The thickness of this region is more or less independent from the thickness of the casting section. The surface region is free from any dendritic grain growth which influences the amount and distribution of the 13-phase and therefore the distribution of the most important alloying element Al. This could explain the different corrosion behavior. Further reason can be found in the enrichment of some impurities such as Fe in the near surface.

Jan 1, 2006

By Luis E. Vallejo

The strength measured by the uniaxial compression test is a parameter that is widely used for the engineering classification of rocks. Sedimentary rocks such as shales, however, are difficult to evaluate by uniaxial compression tatting because the rocks slake during the preparation of the standard samples required for the tests. Indirect methods such as the point load test have been proposed to determine the unconfined compressive strength of shales and other soft rocks. It is current practice to use 24 as the conversion factor between the point load strength, Is, and the unconfined compressive strength, sf (sf = 24 Is). The present study investigated index-to-strength conversion factors for shales and sandstones obtained from surface coal mining sites in the Appalachian region. Regression analyses indicate that a conversion factor of 12.5 best correlated the strengths obtained from the point load and unconfined compression tarts in the case of shales. For the sandstones, a value of 17.4 best correlated the strengths.

Jan 1, 1989

By Stefan Larsson, Jan Ekström, Jennie Kock-Larsen, Håkan Garin

"This paper describes the testing procedure (or protocols) for quality control of dry deep mixing columns in a major ground improvement project carried out in Sweden. Quality control was mainly based on column penetration tests performed at different stages in the project and on two occasions after installation. In the paper, the results from the tests are compared with tests on the unimproved clay. As expected, the results show that the correlation between undrained shear strength in the columns and in the unimproved soft soil depends mainly on the in-situ stress. However, the correlation probably depends on when the tests were performed after mixing. When the influence of the in-situ stress was excluded from the analysis, no significant correlation could be identified. This means that the undrained shear strength in the columns and in the unimproved soft can be considered to be uncorrelated when the strengths and the corresponding variability are evaluated with depth from groups of tests.INTRODUCTIONQuality control and quality assessment of deep mixing (QC/QA) constitute a key component in verification of the limit state design. Due to the complex mixing process and varying geological conditions, it is normally not possible to sufficiently assess the strength and deformation properties in advance. In Sweden, the most commonly used QC/QA method for verification of the limit state is the column penetration test (Axelsson and Larsson 2003; Bergman et al. 2013). The method works well but is time-consuming and requires many tests since property variability is normally high. The column penetration test can be used to assess the undrained shear strength Cu,col. However, it is not clear how the strength correlates to the undrained shear strength of the unimproved soil Cu,soil. There are common factors such as the in-situ stress state and the natural water content, which makes a positive correlation probable, i.e. as Cu,soil decreases, Cu,col also decreases and vice versa. The unimproved soil has a natural spatial variability, but it is not known if the improved soil follows the same variation. The mixing process has a substantial influence on the strength variability and may supersede the influence of other factors. However, if a sufficiently good correlation exists between Cu,col and Cu,soil, information from the geotechnical ground investigations can be used in the design and planning of QC/QA of deep mixing in a more stringent manner. Information about the correlation is also essential in reliability based design, where a strong positive correlation may have a negative influence on reliability. However, as discussed by Al-Naqshabandy and Larsson (2013), this correlation may be weak or insignificant for a representative failure domain where the mixing process may have a dominant influence on the strength variability. It is thus of interest to assess the correlation."

Jan 1, 2015

By Kain Petterson, P D. Katsabanis

Blast fragmentation, determined using image analysis was correlated to drill monitoring parameters in an open pit operation. Average fragment size and 80% passing size showed strong correlation with specific energy of drilling as well as with torque, while the same passing sizes did not correlate well with the rate of penetration. It was also determined that the uniformity of fragmentation decreases with the specific energy of drilling. Thus drilling monitoring parameters appear to be valuable in determining the blastability of the rock mass, enabling adjustment of blast loading to respond to changing conditions in the rock mass.

Jan 1, 2013

By E. J. Peterson

Oil shale retorting induces mineral and chemical reactions to occur on the macroscopic and microscopic levels in the kerogen-bearing marlstone. The nature and extent of the reactions is dependent upon process variables such as maximum temperature, time at temperature, atmosphere, and raw shale composition. This report describes the investigation of the mineral, chemical, and trace element release properties of spent shales retrieved from an experimental in situ retort at Occidental Oil Shale, Inc. 's Logan Wash site in Garfield County, Colorado. Correlation between mineralogy of the spent materials and the mobility of major, minor, and trace elements are indicated, and relationships with important process parameters are discussed. The progress .of carbonate decomposition reactions and silicat ion reactions is indicative of the processing conditions experienced by the shale materials and influences the mobility of major, minor, and trace elements when the solids are contacted by water. Shale minerals that are exposed to the extreme conditions reached in underground retorting form high temperature product phases including akermanite-gehlenite and diopside-augite solid solutions, kalsilite, monticellite, and forsterite. The persistence of relatively thermally stable phases, such as quartz, orthoclase, and albite provide insight into the extremes of processing conditions experienced by the spent shales. Leachate compositions suggest that several trace elements, including vanadium, boron, fluoride, and arsenic are not rendered immobile by the formation of the high-temperature silicate produce phase akermanite-gehlenite.

Jan 1, 1981

"After the non-destructive testing is completed, the data must be compiled, evaluated, and interpreted. During this process, the data may indicate that there is an anomaly warranting further investigation, which may eventually be determined to be a flaw or defect. The definitions of an anomaly, flaw, and defect can be described as follows (after Amir, 2002):Anomaly - Any irregular feature identified in the NDT graphic results. An anomaly may be due to the testing instrumentation (such as noise), to the means used to perform the test (e.g. access tube debonding in CSL) or to the shaft itself. It is the responsibility of the NDT practitioner to gather and analyze all relevant data and try to resolve every anomaly before it is declared a flaw or defect.Flaw - Any deviation from the planned shape, size and/or material of the shaft.Defect - A flaw that, because of either size or location, may detract from the shaft’s intended performance or durability. The geotechnical engineer and the structural engineer are jointly responsible to decide which flaw comprises a defect.This section describes the process of evaluating the data, determining if an anomaly exists, and if so, deciding whether the anomaly is actually a flaw or a defect. If the anomaly is determined to be a defect, its effect on the performance of the shaft must be evaluated, and if necessary, the can be re-engineered, repaired, or replaced."

Jan 1, 2004

By John Shirokoff, Ladan Khaksar

"Cyclic polarization technique and also potentiodynamic measurements were applied to study corrosion behavior of 13% chromium steels in chloride containing environment. Potentiodynamic measurements were performed at 25 and 75 °C with 0, 10 and 20 g/l NaCl in 0.01 M hydrochloric acid solution. At the same time, the significant pitting parameters such as corrosion potential (Ecorr), pitting potential (Epit), protection potential (Epro) and passive current (Ipass) of cyclic polarization curves with various NaCl concentration were analyzed and compared to describe the corrosion behavior of 13% chromium stainless steel. Surface measurement techniques such as SEM and EDS were used for morphology and analysis of corrosion products. The results showed that both temperature and Cl- concentration had significant effects on corrosion behavior of 13% chromium stainless steel in acidic solution.INTRODUCTION Of all the corrosion resistant alloys (CRA) used in oil and gas developments, martensitic stainless steels (MSS) are some of the most common ones these days. These steels not only have the advantages of normal steels: high strength, cost-effective, easy to manufacture, available in a wide variety of product forms, but they also have good CO2 corrosion resistance at higher temperatures as a result of their 11% minimum chromium content. One of the most common types of MSS used in the oil and gas industry is 13% chromium steel. NACE and API standards both reference several different varieties of 13% chromium steels for use in oil and gas projects(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013). All types of 13% chromium steels have about 12 to 14% chromium and other minor alloying additions, and can be placed into two general groups: conventional and modified. Conventional 13% Cr steels (13Cr) are those most common in oil and gas, some of which are CA6NM (UNS J91150), AISI 410(UNS S41000), and AISI 420 (UNS S42000). These alloys have excellent corrosion resistance when compared to carbon steels up to about 300°F (150°C) and are used for a variety of wellhead, tubular, and downhole components however they have very limited resistance to cracking in H2S (Vallourec Group, 2015). Modified 13% Cr (M13Cr) steels came from the need for increased corrosion resistance at higher temperatures, increased H2S cracking resistance, and increased yield strength above 85 ksi (586 Mpa) primarily for tubular goods and other downhole equipment. These features were developed by taking a conventional 13Cr steel and adding nickel (Ni), molybdenum (Mo), copper (Cu), and other alloying elements. M13Cr provides better corrosion resistance than 13Cr up to about 350°F (177°C), yield strengths up to 110 ksi (758 Mpa), and also improved H2S cracking resistance(“Corrosion Resistant High Cr Steel for Oil and Gas Wells,” 2013)."

Jan 1, 2017