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By D. A. Akinlade, N. L. Richards, D. C. Murray, W. F. Caley

To investigate the effect of adding Ti to a Ni-Cr-Fe powder metallurgy alloy, a thermodynamic software package was used to predict the phase transformations that occurred during thermal processing. Specifically, the effect of adding 3w/o Ti to a 6w/o Al modified ternary Ni-Cr-Fe alloy (the quaternary) was simulated and the phase transformations that might occur in the material on sintering were obtained using the thermodynamic modeling tool. These predictions were subsequently compared with experimental results obtained by X-ray diffraction and metallography. For comparison, selected compacts were prepared containing only the ternary + 3w/o Ti (no Al). Based upon compressibility curves, the optimum pressure for producing the new Ti compacts was 500 MPa vs 600 MPa for the quaternary composition with Ti. In each case, hardness of the base alloy was enhanced by the Ti addition whereas the residual porosity remained relatively constant at about 19%. Finally, although SEM/EDS failed to confirm the presence of Ti in the gamma prime intermetallic, XRD spectra showed a shift in lattice parameter on addition of Ti, suggesting that the intermetallic was of the form Ni3(Al,Ti).

Jan 1, 2010

By M. Mirnezami, J. A. Finch, M. S. Hashemi A.

This study examined the effects of pH and sulphate concentration on the surface charge and stability of alumina and pyrite dispersions. The relationship between these properties was investigated using measurements of electrophoretic mobility and settling velocity. The maximum aggregation for both minerals was observed near the iso-electric point (iep) where the force of repulsion is at a minimum. Aggregation decreased at pH values away from the iep, where an increased surface charge causes electrostatic repulsion between particles. Zeta potential data revealed that sulphate ions were adsorbed only on positively charged surfaces for both minerals. Adsorption of sulphates on the alumina surface increased aggregation by reducing the surface charge from >+25 mV to close to zero. These results indicate an electrostatic bonding of sulphate ions to alumina surface. Preliminary results on the interaction of pyrite and sulphate ions indicate a similar response.

Jan 1, 2004

"In the UK, Ireland, and Western Europe, the mineral resource and reserve reporting standard is the PERC Code, developed and maintained by the Pan-European Reserves and Resources Reporting Committee, which is a standing committee set up under the auspices of a number of professional organisations which include the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI) to develop a Pan-European reporting code. The PERC Code supercedes the old IMMM Reporting Code 2001 and is recognised by the UK securities regulators and stock exchanges.""FOREWORD1 The Pan European Reserves and Resources Reporting Committee (PERC) Code for Reporting of Exploration Results, Mineral Resources and Mineral Reserves (further referred to as 'the Code') sets out minimum standards, recommendations and guidelines for Public Reporting of Exploration Results, Mineral Resources and Mineral Reserves in the United Kingdom, Ireland and Europe. The history of development of this code is summarised in Appendix 4.This 2008 edition supersedes all previous editions of The Reporting Code and the IMM Reporting Code.INTRODUCTION2 In this edition of the PERC Code, important terms and their definitions are highlighted in bold text. The guidelines are placed after the respective Code clauses using indented italics. They are intended to provide assistance and guidance to users in interpreting the application of the clauses in the Code. The same indented italics typeface formatting has been applied to Table 1, and to Appendices 1 and 2 which form part of the Guidelines.3 The Code has been adopted by the Institute of Materials, Minerals and Mining (loM3), the Geological Society of London (GSL), the European Federation of Geologists (EFG) and the Institute of Geologists of Ireland (IGI), and is therefore binding on their individual members.Appendix 1 contains a table of generic terms and their equivalents, designed to avoid unnecessary duplication or ambiguity in the textAppendix 2 provides Rules of Conduct for Mineral Resource and Mineral Reserve estimators that should be considered in addition to the Codes of Ethics normally applying to members of professional institutions."

Jan 1, 2003

By Noko S. Phala

The energetics of CO and CO2 hydrogenation to methanol were studied on a gold surface via periodic and cluster DFT calculations. CO hydrogenation appears to be much easier than CO2 hydrogenation on an Au(111) surface. The use of a cluster model does not seem to improve the energetics of CO2 hydrogenation. It is concluded that an active support (e.g. ZnO) will be required to increase the productivity of a gold surface towards synthesis gas conversion. The energetics of CO and H2 adsorption are improved on the cluster model compared to a slab model of an Au(111) surface, suggesting that nanosized gold particles may be beneficial in CO hydrogenation.

Oct 1, 2003

By G. O. Crowell

This paper gives the history of the celestite deposit, now being mined by Kaiser Celestite Mining Ltd., near Sydney, Nova Scotia. Mining and milling procedures are covered, and the regional and local geology of the area are described, including the origin of the celestite.

Jan 1, 1971

"In conjunction with Banick Mercur , Wright Engineers Limited designed the first multi-stage aqueous pressure oxidation system in an alkaline environment in North America. A three-stage slurry heating and slurry pressure let-down with heat recovery was an innovative approach to the problem of high energy cost with the low sulphur content of the ore. The design of this system required solving a number of problems associated with heating and pumping of slurries at pressures up to 3230 kPa and temperatures in excess of 220°C. Wright received an Award of Merit in October 1989, from the Canadian Consulting Engineering Awards Committee in the Process Category for its design of the Mercur pressure oxidation system.The Mercur Mine is located at the south end of the Oquirrh Mountains in Tooele County about 65 miles by road from Salt Lake City, Utah, U.S.A. The original mill was designed to process 5000 tpd of oxidized gold ore in a carbon-in-leach (CIL) circuit. A new ore treatment system was required to treat the substantial quantities of refractory ore reserves which could not be treated economically in the existing mill. The new pressure oxidation circuit makes the refractory ore amenable to gold recovery by oxidation of the sulphides contained in the ore .Wright Engineers Limited was commissioned by Barrick Mercur Gold Mine Ltd ., a wholly-owned subsidiary of American Barrick Resources, to design the pressure oxidation facility. This followed completion of a feasibility study by Wright which showed that the project was technically and economically viable.Work on the feasibility study began in 1986, detail design commenced in February 1987, and was completed in December 1987. Mechanical installation was completed in January 1988, and slurry feed began in February 1988. The plant has operated since June 1988 without major interruption . Wright was responsible for engineering, procurement and construction management for the addition of the 750 tpd pressure oxidation circuit to the existing mill and also had commissioning responsibility.Major unit processes involved in the pressure oxidation facility are ore thickening, three-stage slurry preheating, pressure oxidation and three-stage slurry cooling with heat recovery, stearn generation, propane and oxygen storage and a video graphic display process control system were included in the scope as process anciliaries.The pressure oxidation increases gold recovery from the refractory ore by conventional CIL from as low as 35% to more than 86070. A patent has been granted for the process."

Jan 1, 1989

By R. O. Grieve

"IntroductionCALEY (1945) and Evans (1950) pointed out that certain instances of convergence between Devonian and Silurian horizons, frequently evident in wells drilled for oil and gas in Ontario, appear to be related to local thinning of salt beds in the Salina formation and they suggested that leaching of the salt beds may have occurred. Exploratory drilling by Imperial Oil Limited since 1945 has brought to light several examples of structures similar to those discussed by Caley and Evans. The writer has had the opportunity to examine cuttings and data from wells which penetrated these structures and the attempt to interpret them in the light of the theory of leaching and subsidence proposed by Landes ( 1945a) to explain the marked brecciation and deformation of Upper Silurian and Middle Devonian sediments which crop out in the Mackinac Straits region of northern Michigan has led to the observations presented in this paper."

Jan 1, 1955

By H. Salamanca

HighService has developed different equipment using wireless technology and machine vision systems that were specially designed to allow 1) the online determination of the SAG mills liner's service life, 2) the automatic detection of a missing dipper tooth in mineral extraction shovels, 3) the reduction of accident risk potential in the mineral transportation within the mine, and 4) the reduction of collision risk potential between shovels and wheel dozers during mineral extraction. For the development of all these systems at HighService, extensive research has been done in radio frequency and image processing fields. The integration of both technologies with the expert knowledge of the company on the typical harsh environment conditions of the mining industry has led to the development of heavy duty equipment that tolerate the extreme mechanical requirements of SAG mills and electrical mining shovels.

Jan 1, 2007

By T. Kalliomäki, A. T. Aji, M. Lundström, J. Aromaa

The settling properties of anode slime in copper electrorefining have crucial effect on copper cathode quality. Anode slime settling is affected by electrolyte composition and temperature, electrolyte circulation, and the sizes and density of the slime particles and agglomerates. Typically, the industrial copper electrolytes contain 40–60 g/dm3 Cu2+, 130–220 g/dm3 H2SO4, 0.04–25 g/dm3 Ni2+, 0.005–30 g/dm3 As, and have operating temperature of 55–70°C. In optimal electrorefining process, the settling rate of anode slime is sufficiently high to avoid the risk of getting the slime entrapped in copper cathodes. In this research the settling properties of copper electrorefining bottom slimes, mainly consisting of Cu, Ni, Ag, Se, Pb, As, Bi, Sb and Ba compounds, were studied by settling rate tests. The tests were conducted in water and synthetic electrolytes with known viscosities and densities. In addition, the effect of agglomeration was taken into account – it was observed that breaking the agglomerates which existed in the as-received slimes decreased the particle sizes on average 56–73%, which decreased the settling rate. The results of this study provide detailed information of anode slime settling and thus clarify the conditions causing cathode contamination risks in copper electrorefining. INTRODUCTION Settling rates of Cu-ER anode slimes affect the purity of cathode copper and faster settling rate decreases the contamination risk (Davenport et al., 2002; Shi & Ye, 2013). The settling rates are affected by the properties of anode slime particles (Wills & Napier-Munn, 2011; Aaltonen, 2014; Kiviluoma, Aaltonen, Aromaa, Lundström & Forsén, 2016) as well as viscosity and density of the electrolyte (Davenport, King, Schlesinger, Biswas, & Robinson, 2002; Shi & Ye, 2013). Thus, it is crucial to find out how the viscosity and density affect the settling rates. Small spherical particles with diameter below approximately 50 µm obey Stokes’ law (Equation 1) (Wills & Napier-Munn, 2011). v = gd 2 (ρS – ρF) (18η) -1 (1) where v is terminal velocity (m/s), g acceleration due to gravity (m/s2), d diameter of particle (m), ρS density of particle (kg/m3), ρF density of fluid (kg/m3), and η dynamic viscosity (Pa∙s). The approximate effects of kinematic viscosity (ν = η / ρS), density (ρS) and particle sizes on settling rates defined for small anode slime particles based on Stokes’ law are presented in Figure 1. However, Stokes’ law does not take into account other than spherical shapes, and it is only applicable for small particles. Consequently, the real settling rates of the particles are lower than these (Wills & Napier-Munn, 2011). Moreover, some of the anode slime particles are larger than 50 µm (Aaltonen, 2014).

Jan 1, 2019

By D. Sammut, F. Houllis, J-L. Huens, J. Moyes

The Intec Gold Process has been developed as a halide-based alternative for the recovery of gold from refractory sulphide deposits. The halide medium allows sulphide oxidation and gold extraction to be performed concurrently at moderate temperature and atmospheric pressure sourcing oxygen from direct air injection. The dissolved gold is loaded onto activated carbon and stripped in a conventional Zadra circuit. High gold extractions have been achieved from a range of refractory gold concentrates at laboratory scale, which has led to a continuous locked-cycle pilot plant program. The pilot plant operated at >99% availability, with a maximum of 96.5% gold extraction from a concentrate containing 58.6 g/t gold. >99% of the dissolved gold was loaded onto carbon at up to 1% w/w, with no loss of carbon activity detected over five loading/washing/elution cycles. This paper describes the process and presents both laboratory and pilot plant results as well as economic data from two costing studies.

Jan 1, 2005

By R. C. Gilmore, J. McMack, G. E. Bogin, J. F. Brune, C. DeRosa

"Researchers at the Colorado School of Mines are designing and building a 1:40 scaled physical model of a fully operational longwall coal mine. The purpose of the model is to minimize the occurrence of methane explosion hazards by testing various ventilation strategies and determining optimal methane sensor placement throughout the longwall face. Fluid scaling factors were analyzed using Computational Fluid Dynamics software Ansys FLUENT™ at both full and 1/40th scales. Researchers were able to identify key scaling factors and subsequently developed suitable flow parameters that would maintain full scale accuracy of flow patterns in the 1/40th model. KEYWORDS Coal, Longwall, Methane, Explosion, Scale Model, Ventilation, Fluid Dynamics, Richardson, Gob, Porous INTRODUCTION Mine ventilation systems are a key component for ensuring a safe working environment by introducing fresh air from the surface and diluting explosive gases and hazardous contaminants. This holds true for longwall coal mines where the emission of flammable methane gas from the longwall face as well as the gob can create explosive mixtures of methane and air. Therefore, an effective ventilation strategy can help mitigate the potential for accidents within a mine. Developing an effective mine ventilation system (MVS) requires a detailed understanding of the physics of gas transport and how this relates to specific geometries and obstructions in the face. Researching this phenomenon requires the development of computational fluid dynamics models capable of simulating fluid flow and methane species transport that can be validated through physical experimentation. Unique site conditions determine ventilation layouts for every coal mine. Researchers have designed a 1/40th scaled physical model of a longwall coal face and adjacent gob that includes movable shield supports and a movable shearer with rotating cutter drums that can be adjusted to a variety of ventilation conditions. The proposed work will address the need for an improved Mine-wide Atmospheric Monitoring System (AMS), and provide the ability to link existing MVS models with AMS in real time. By accurately representing the coal face, the gob area and the mining equipment, gate roads and bleeder entries, the scaled model accurately represents all relevant structures, geometry, and dynamic conditions. A Plexiglas cover allows full optical access for sensor equipment as well as visual inspection of the fluid flow and species transport."

Jan 1, 2019

By U. Dillon, G. Blackwell

"Geographic information systems (GIS) provide an efficient means for the recording, manipulation, revision, display and analysis of spatially referenced data. GIS are widely used at the exploration stage of mine development, and are increasingly used for reclamation planning. The ability of a GIS to perform spatial searches and query spatially referenced data make it a powerful tool for use at all stages of mine development. As the amount of data available for analysis increases, so does the power and flexibility of GIS as a planning tool.Starting from the exploration database, this paper describes how a GIS can be used for the development of mining plans based on topography, geology and mineralization information stored in a relational database. Planning decisions approaching the optimal can then be made for a wide range of parameters, including stockpile and waste dump locations, the location of potentially acid generating and neutralizing material for dump design, profitable and risk-controlled mine extraction sequencing, and haul road locations. This is made possible by the overlay and buffer analysis capabilities of a GIS which are explored and exploited to produce a continuous mine production planning program, as well as site remediation and reclamation using a successful case study. The Ore and ProductsThe mines in the Saskatoon area — Agrium, PCS-Cory, PCS-Allan, PCS-Patience Lake, PCS-Lanigan and IMC-Colonsay — extract the ore from the Patience Lake member. The mines in the southeast corner of Saskatchewan — IMC-K1 and K2, PCSRocanville — extract from the Esterhazy member, while IMC-Belle Plaine, near Regina, solution mines potassium chloride from both potash-bearing members.Ore from the Patience Lake member is a medium-grained mixture of sylvite and halite, with a KCl content of 36%, insolubles averaging up to 5.5%, and little or no carnallite.The ore from the Esterhazy member is a coarse-grained mixture of sylvite (KCl) and halite (NaCl) with a small amount of water insolubles, and some carnallite (a K-Mg chloride). Average run-of-mine grades are about 30% KCl."

Jan 1, 2003

By O. Alonso-Gonzalez, F. Nava-Alonso, A. Uribe-Salas, R. Pérez-Garibay, C. Jimenez-Velasco

A current problem in gold production is the presence of copper minerals which dissolve during conventional cyanidation practice. The dissolved copper causes several problems in the different stages of the process. This issue is the base for copper elimination/recovery methods such as the Sulphidization, Acidification, Recycling, and Thickening (SART) process, which is currently used in gold production plants around the world. Even though the process is well established, new challenges appear as the composition of the solution varies from ore to ore, in some circumstances affecting the performance of the SART process. This work presents a thermodynamic study and experimental tests performed to understand the role of the initial copper concentration and sulfur addition, on the efficiency of the copper removal. For a constant cyanide concentration, an increase in the initial copper concentration causes a decrease in copper removal; high sulfur/copper molar ratios favor copper removal. We demonstrated that the cuprous sulfide formed from solutions with high ionic strength, presents better sedimentation rates than solutions with less ionic strength. For solutions with low sedimentation rates, the use of some pretreatment is necessary to facilitate the sedimentation such as addition of flocculants, particle recirculation and the used ultrasonic pretreatment.

Jan 1, 2014

By S. Heusermann, S. Fahland, J. Behlau, A. Schäfers, J. Hammer

In the course of the deep subsurface use, the Federal Institute for Geosciences and Natural Resources has been carrying out extensive geological and geomechanical research and practical project work on domal salt structures, to prove their suitability e.g. for the disposal of radioactive wastes. Recent work on disposal sites has been taking into account the 3-D geological and geomechanical modelling of the underground structures. The geological models are generated using the special-construction openGEOTM code to improve the visualisation and interpretation of the geological data basis, e.g. borehole, mine, and geophysical data. For the geomechanical analysis of underground structures the JIFE finite-element tool has being developed to analyze large 3-D structures and to consider coupled THMC processes. The results of finite-element calculations, i.e. stresses, strains, displacements, and dilatant zones, are basic values for the evaluation of the stability of the structures and the long-term integrity of the geological barrier. As an example, the results of geological and geomechanical investigations of the Morsleben repository are presented including three-dimensional modelling of the entire geological structure of the central part of the mine as well as three-dimensional geomechanical model calculations to provide the necessary results for a long-term safety prediction.

Jan 1, 2015

By Jie Zhu

Coal bumps are a special form of release of geologic strain energy that has already been one of the most dangerous hazards to underground mining safety in China. A number of coal-bump models have been developed to quantify coal failure under assumption that a bump is a kind of non-gas induced outburst. However, some technical experts in charge of micro-seismic and gas monitoring have found unusual gas emissions before and after bump, which suggests that it is possible for gas to trigger coal bumps. Considering the coal reservoir as geological body composed of the coal matrix and gas, a new model based on Lippmann?s bump model is proposed to understand the initiation of coal bumps. The redistribution zone from excavation of a roadway has been calculated and analyzed regarding its relation with mining depth. It is shown that high gas pressure may push the coal seam to overstep the critical state due to extension of the plastic disturbed zone, and this is harmful to the stability of coal seam. This model successfully explains the bump phenomena of the Xinzhouyao mine at shallow depth.

Aug 1, 2013

By G. F. Miller

ONLY IN THE Province of Saskatchewan is natural sodium sulphate found in Canada in amounts large enough to make recovery economically sound. Geologists have estimated that the numerous deposits within the Province contain upwards of 200 million tons of Glauber's salt. There are twenty-one deposits in the Province which contain 500,-000 or more tons and about two dozen with lesser amounts. The first recorded production of sodium sulphate in Saskatchewan was in 1918. The company concerned, and others that attempted to develop the industry in its early stages, were unsuccessful. Their failures were caused by two main factors -lack of knowledge of efficient operating methods and the unstable market situation for the finished product. Today, the situation is changed in both respects and the product, commonly referred to as 'saltcake", is a very important chemical requirement of many industries throughout the world. Before proceeding with remarks on manufacturing methods it should be stated that, although this is a general paper on the manufacturing methods and end uses of the saltcake produced in the Province, the writer is, of course, more familiar with the plants operated by Saskatchewan Minerals than with other operations and perhaps may be excused for dealing more particularly with the plants of that Compa11y.

Jan 1, 1958

By Robert D. Irvine

"Enhanced concern for protection of the environment and attendant actions by environ-mental regulatory authorities in support of this concern are influencing, to varying degrees, the demand and supply of a range of industrial minerals in a number of jurisdictions. These influences take a variety of forms.In this paper, the author seeks to delineate certain broad trends which are occurring relative to industrial minerals and the environment and then, through a series of examples, to outline opportunities, developments, and impacts respecting a number of industrial minerals produced and consumed in Canada and the United States."

Jan 1, 1996

By S. Timbillah, R. LaDouceur, C. A. Young

A low carbon-chain trithiocarbonate ((NaOOC)CH2SCSSNa), known as Orfom® D8, was tested as an organic depressant in the differential flotation separation of chalcopyrite and molybdenite in the presence of sodium isopropyl xanthate (SIPX) or potassium ethyl xanthate (KEX). Flotation studies show that Orfom® D8 depressed chalcopyrite while molybdenite remained floatable. A study of the mechanism of adsorption indicated that Orfom® D8 adsorbs on chalcopyrite through its trithiol (CS -) functional group via both chemisorption and Orfom® D8-metal complexation. The Orfom® D8 depressant is selective and does not form any Orfom® D8-molybdenite bonds. Thus, the combination of the depressant in the presence of either collectors depressed the chalcopyrite and floated the molybdenite. Fundamental parameters of the Orfom® D8 including pKa determination as well as possible decomposition products of the depressant are reported. This study includes an economic case illustrating why using Orfom® D8 can be beneficial. INTRODUCTION Depressants are incorporated in mineral flotation units in the minerals processing industry to make or keep certain minerals selectively hydrophilic. Most reagents used are inorganic and include, for instance, sodium hydrosulphide (NaHS) which is the major reagent used for depressing sulphide minerals, particularly those containing copper, iron and lead. However, the issues with its use include high toxicity, tendency to explode, strong odour, and high consumption due to required high dosages as well as its tendency to oxidise in air. The latter can be overcome by conducting flotation in inert atmosphere such as nitrogen and recycling of the flotation process water. The use of more novel depressants that are essentially organic including homopolar reagents with hydrophilic functional groups on both ends of its structure adsorb onto a target mineral surface with one polar end, the other polar end orients into the bulk solution making the surface hydrophilic and thus, ensuring that the desired mineral does not float. The stringent environmental and safety regulations being implemented in recent times mean that the search for more environmentally friendly chemical reagents is a must have. The use of organic depressants for flotation systems such as Cu-Mo sulfide bulk concentrates has become increasingly important because of the health, safety and environmental issues surrounding the use of inorganic depressants. Nagaraj et al. (1983) investigated the Cu-Mo sulphide flotation system using a structure-activity study of depressants. They found that a major advantage of organic depressants is the ability to tailor-make organic molecules to suit many requirements and thus, eliminate the guess work approach that was predominant in the industry.

Jan 1, 2019

By Man-Chao He

One of the critical problems involved in deep coalmines is unusual gas emissions. Many researchers agree that there is a relationship between coal gas emissions and geological features such as tectonics or geological disturbances, gas content, properties of the coal and rock and the mininginduced stress state in the coal seam and rock. Thus, the present paper intends to investigate complex mechanical phenomena during the process of gas emission in underground coal-mines. A program of laboratory testing was undertaken to study the effects of temperature and pressure on mechanisms of gas emission. It must be noted that this paper describes new techniques developed to simultaneously measure deformation and gas pressure, as well as flux during the test, taking the characteristics of gas transport into consideration under certain temperature and pressure conditions. The results indicate that under certain temperature and pressure conditions, gases adsorbed to coal start to desorb, and increase the pore pressure. High pressure gases entering coal fractures can generate high tensile stresses near the crack tips, leading to crack propagation and coalescence, which in turn can cause the specimen to dilate. From the experimental viewpoint, these test results may help us discern why mining seismic events can trigger gas emissions.

Aug 1, 2013

By A. McLean, J. Hou

Waste slag is a major environmental concern within the metallurgical industry. In the steel industry, about 100 kg of slag is produced in making one tonne of liquid steel from iron in addition to that produced during ironmaking. The amount of slag from the steelmaking converter can be significantly reduced when charging hot metal with low phosphorus and sulphur contents. In this context, hot metal pretreatment is known as an effective means of preparing high quality charge material for the converter thus limiting the generation of residual slag during the steelmaking process. In the aluminum industry, about 2-4 tonnes of slag, including red mud from alumina production and dross from aluminum electrolysis and casting, are generated during the production of one tonne of aluminum. In recent years, reuse of waste slag from the aluminum industry is a topic that is receiving increasing attention. In this paper, the possibilities of using waste slag and by-products from the aluminum industry as a refining flux in the steel industry are discussed. Several successful processes to convert waste materials from the aluminum industry to steel refining fluxes are described. Some theoretical aspects of using calcium aluminate based flux for desulphurization are outlined together with results obtained from laboratory experiments on sulphur removal from hot metal. By intelligent use of waste materials, the disposal of solid waste from the metallurgical industries can be reduced.

Jan 1, 2004