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By M. Staite

This paper analyzed the feasibility of converting a 5kW natural gas SOFC power generator system designed to operate on natural gas to be fuelled by methanol. The analysis included laboratory methanol fuel processing experimentation, methanol reformate SOFC cell testing, and SOFC system mass and energy balance modelling. Methanol fuel processing experimentation indicated that theoretical reformate compositions can be achieved for high temperature (600-900°C) methanol steam reforming. A 6% open circuit voltage decrease and a 10% peak power current density decrease between cell operation on humidified hydrogen and methanol reformate was observed. SOFC system mass and energy balance modelling indicated that a natural gas SOFC system can be converted to operate on methanol fuel with minimal (1%) efficiency impacts, however the systems' thermal integration can be impacted.

Jan 1, 2005

By Horatio Sam-Aggrey, Margot Hurlbert

Small Modular Reactors (SMRs) have been touted as having the potential to spearhead a nuclear renaissance. Proponents of this view cite the relative advantages of SMRs over larger nuclear plants as reason for their optimism. Some of these merits include potential economies of mass production deriving from modular factory production, enhanced safety features, the ability to locate reactors in remote areas, and reduced requirements for technical workforces to install and maintain SMRs. Despite the optimism surrounding SMRs, nuclear power is still a contentious issue for many Canadians. The growth of nuclear power remains adversely affected by concerns over issues such as: the health and safety consequences of nuclear power generation, environmental impacts, proliferation of nuclear materials, terrorism, and radioactive waste disposal (Organisation for Economic Co-operation and Development (OECD) and Nuclear Energy Agency (NEA), 2010). Personal values, past nuclear accidents, and lack of trust in the industry are other factors influencing attitudes toward nuclear energy (IAEA, 2005). In Canada, three main areas where SMRs could be used have been identified. These include: a. Traditional, on-grid power generation, especially in provinces looking for zero-emissions replacements for CO2-emitting coal plants. B. Remote off grid communities that currently rely on diesel or fuel oil power generation. There are 279 off-grid communities in Canada, many of them being Aboriginal communities (NRCan, ND). Notably, all communities in each of Canada’s three territories qualify as remote. C. Resource extraction sites, such as mining and oil and gas extraction sites. Many of Canada’s principal producing mines and active mineral exploration projects are located within close proximity of Aboriginal communities. Any proposed implementation of small nuclear plants would, require the support of the local population, which is largely Indigenous in the northern regions. The possible deployment of SMRs raises important issue relating to consultation and accommodation of Aboriginal concerns regarding potential SMR deployment. This is especially pertinent given Canada’s pending implementation of the provisions of UNDRIP. One of the provisions of UNDRIP that has attracted a lot of attention is the one on Free Prior and Informed Consent (FPIC). Drawing on previously published information, this paper discusses some of the challenges posed by FPIC for the deployment of SMRs. The next section outlines the provisions of FPIC and its implementation in the Canadian context. Section 3, details some of the challenges posed by FPIC to the deployment of SMRs, while Section 4 provides some concluding comments.

Jan 1, 2020

By K. Bullock, M. Levesque, G. Lyle, D. L. Millar

ABSTRACT The options for reducing the carbon footprint of energy use in mining fall into three categories of activity: i) reducing demand, ii) improving energy utilization, and iii) adopting low carbon energy technologies. In addition to the environmental imperative, the economic case for these activities gains higher priority as the prices of electricity, gas, and liquid fuels increase. Low-carbon, energy-saving technology options that are available to mining industry companies lead to projects with return rates that must compete alongside other capital-intensive projects considered by mining company boards. Energy projects frequently involve longer payback periods and lower rates of return than those of competing bids for capital, such as new mineral property developments. For energy services companies that specialize in the financing, construction, efficient operation, and maintenance of energy projects, the same returns and payback periods can be considered acceptable or even attractive.

Jan 1, 2012

By J. Lu, D. G. Ivey, H. Henein

Microalloyed steels are widely used in the oil and gas industry. They are a class of high strength, low carbon steels containing small additions of niobium (Nb), titanium (Ti), molybdenum (Mo) and/or vanadium (V). These steels have good strength, toughness and excellent weldability, which are attributed in part to the presence of nano-sized carbides, nitrides and carbonitrides. In the pursuit of developing higher strength microalloyed steels, it is of great interest to quantify the size, distribution, volume fraction and chemical speciation of these precipitates. However, characterization techniques suitable for quantifying fine precipitates are limited. Possible characterization techniques include SEM, TEM and matrix dissolution. A comparison is presented of the various techniques.

Jan 1, 2005

By G. Bridgstock, S. S. Forbes, E. M. Elkin

"OPERATIONS at Canadian Cop-per Refiners Limited, since the refinery was established in 1931, have been described in previous papers ( 1,2). Since then the refinery has treated the entire copper output of Noranda Mines Limited and Hudson Bay Mining & Smelting Company Limited. With the commencement of production in 1956 at Gaspe Copper Mines Limited, this copper has also been refined. From the start of operations to the end of 1958, the following had been refined: copper, silver, gold, selenium and tellurium.Construction of new buildings and additions to other buildings have been needed to handle increased receipts. The refining capacity has been increased from 112,000 tons of copper per year to a total of 236,000 tons per year.The refinery is located at Mont-real East, Quebec, close to railway and highway facilities. Incoming materials and shipments, with some small exceptions, are handled by rail. Some finished products are sl1ipped by industrial flatcar to the adjoining plants of Canada Wire & Cable Company Limited and Noranda Copper & Brass Limited."

Jan 1, 1960

By D. H. d Hamly

THE work of Brown and others at Pittsburgh (Brown, Baum, Yant, and Schrenk, 1938)(1) and the success of their light field microprojector (Figure 1), have shown that the microscopy of dust quantitation can be greatly improved. It has been shown that dark-field microprojection of dust spots on konimeter slides is possible (Pullen, 1940), and this paper is a discussion of the new microprojector and a new counting method which is made practical by this instrument. The microscope makes possible the ready determination of the dustiness of mine ventilation air. Reduction of the dust concentration from a dangerous to a safe level involves one or more of the following: reduction of dust production, filtration of the air stream, or dilution with non-dusty air. Each of these raises important engineering problems of time and costs, and trustworthy information on the state of dustiness of the air is required ?both before and after the employment of any method of reduction. Records of this information may be divided into two broad classes concerned with safety: (1) the level of dustiness, and (2) the quantity and kind of dust produced by a machine under a given set of conditions. Though the first requires only one determination for a given time and place, numerous routine records are required to show the continuous safety of the air in an actively producing mine. Though repeated samples are required, highly accurate counts are not needed to show safety or to indicate whether a substantial increase in the non-dusty ventilation air has produced a proportionate decrease in the dustiness of the mixed air. The Devers and Gathercole konimeters have proved satisfactory instruments for this purpose in Ontario.

Jan 1, 1942

By J. Stachulak, M. Scobie

"This paper addresses the occurrence and indicated causes of conveyor fires in North American and European underground mines. Some significant convey or fires which have been experienced in recent years in Canadian hardrock mines are then reviewed. The nature of existing conveyor monitoring technology is considered in the context of such fire hazards. Experiences with new monitoring technology recently installed at several conveyor sites at Inca Ltd. mines are then reviewed.IntroductionFires associated with conveyors have long been recognized as a serious hazard in underground coal mines. Recently, however, there have been some significant conveyor fires in Canadian underground hardrock mines. These offer important evidence as to the nature and causes of potential hardrock mine fifes. They also warrant attention with a view to improving over-all mine design, ventilation and emergency preparedness.In addition, a new era in mine communications and monitoring technology has been entered which should offer improved capability to protect against such fires. This paper was motivated by the need to understand the causes and mechanisms of conveyor fires in order to improve their safety. This should be possible through implementing more effective monitoring systems, as well as improving conveyor design. Underground mines are becoming more intensively mechanized, with less human surveillance of equipment and a greater dependency on remote monitoring systems."

Jan 1, 1992

By L. Drisdelle, S. Gendron

"Survival in today's business climate requires participation of all employees in a Total Quality Management Program encompassing everything - ""safety, quality of products, quality ofet1ch and every job done, and of course production "". We all know what needs to be accomplished, but struggle with how to do it, especially in an industry which has not always experienced management/union cooperation, and mistrust is still present.This paper describes a process to improve team work and employee involvement in Inco's nickel carbonyl refinery at Copper Cliff The process involves facilitatorship training for all employees, and a system for reinforcing and accomplishing the required behavioural change. The system is described in detail and a number of examples are presented. At the refinery, the staff is starting to understand as Max DePree recently wrote ""Without Quality Behaviour, you cannot have Quality Product"". IntroductionThe Copper Cliff Nickel Refinery (CCNR) is Inco's largest and most modern nickel refinery, which celebrated its twentieth year of successful operation in April 1993.The heart of the refinery is the Inco pressure carbonyl (IPq plant which produces high purity nickel pellets and specialty powders by refining an approximate 80% nickel granule feed. The carbonyl plant is a modem chemical plant with very special and demanding requirements for safety and environmental protection due to the toxic nature of the refining gas.Since 1987, there has been an emphasis at CCNR on a comprehensive Total Quality Improvement (TQI) Program which was designed based on recognizing customers' needs for improved systems for quality management. This program is customer oriented and comprises such elements as team organizational concepts, customer audits, process assessment and internal quality auditing.A detailed review of progress was made in early 1991 and it became apparent that the ""ownership"" of the TQI program was not broad based. In fact, the program was very much a staff driven effort and fell far short of total employee involvement and relentless continuous improvement that are now considered essential to remain competitive and stay in business.Inco staff has now come to regard that early phase of our TQI program as ""the technical aspects of total quality improvement"".The safety experience was also puzzling. Even though the safety statistics were good with an average lost time frequency of 1.6 for the last five years, the perfonnance improvement had plateaued and remained pretty much the same. Clearly a new approach was required if significant progress and continuous improvement was to be made."

Jan 1, 1994

By G M. Thorpe

This paper discusses mine research at Inco, giving specific examples of research projects which illustrate the approach to mining problems. The first example covers the development of a new mining method, "undercut and fill," which was originated for mining badly broken-up pillars, but which is now rapidly replacing the square set method of pillar recovery. In the new method, ore is extracted in a series of successive horizontal cuts, progressing downward, a cut being completely mined and filled before the cut below is started. In the second example, improvements to the "cut and fill" method of mining are discussed. These improvements are the result of improved techniques and improved equipment, etc., with, in many cases, the former being made possible by the latter. The advances made have permitted the use of the "cut and fill" method at much greater depths than before. The third example is presented to illustrate research undertaken to obtain the earliest maximum advantage of the introduction of a new piece of equipment or material. For this purpose, the development of the "Under-ground use of AN /FO Blasting Agent " has been selected. Work on this project started in May, 1960, at a time when there was very little in-formation regarding the potentialities of AN /FO for underground blasting, either primary or secondary. By the end of 1961, AN /FO made up 64 per cent of the explosives used under-ground at Inco mines.

Jan 1, 1963

By Maureen A. McGuinness

Kidd Mine, an Xstrata Copper operation in Timmins, Ontario, operates a 400 t/h pastefill plant that provides paste backfill to stopes at the depth of 9000 ft. This paper will cover the operating practices of the pastefill plant both on surface and underground, highlighting tailings excavation, paste mix design and the pipe maintenance program. Kidd Mine, une opération d'Xstrata Copper à Timmins, Ontario, opère une usine de remblai d'une capacité de 400 t/h. Le réseau de distribution permet d'acheminer le remblai en pâte juste qu'à une profondeur de 9000 pi. Cet article couvrira le mode opératoire de l'usine de remblai tant à la surface que sous-terre en mettant l'emphase sur l'extraction des rejets miniers, la recette du remblai en pâte ainsi que le programme d'entretient du réseau de distribution.

Feb 1, 2008

By G. Cailletaud, I. Guillot, D. Larouche, R. Martinez, D. Massinon

The precipitation of Al2Cu particles in a 319 T7 aluminum alloy has been modeled. A theoretical approach enables the concomitant computation of nucleation, growth and coarsening, based on an implicit scheme using the finite differences. The equation of continuity is discretized in time and space in order to obtain a matricial form. The inversion of a tridiagonal matrix allows us to determine the evolution of the size distribution of Al2Cu particles at t + dt. The fluxes of solute in-between the boundaries, as well as the ones at the boundaries, are computed in order to respect the conservation of the mass of the system. The main results of the model are compared to TEM measurements. Simulations provide quantitative features on the impact of the cooling rate on the size distribution of Al2Cu particles in good agreement with the TEM measurements. This metallurgical model is integrated into FEA software in order to perform mechanical computations. This kind of multiscale approach allows new perspectives to be investigated in the process of designing cylinder heads. It enables a more precise prediction of the microstructure, its evolution as a function of continuous cooling rates and its impact on the integrity of the structure.

Jan 1, 2015

By Norma G. González

La littérature et notre expérience en Bolivie dans une communauté minière très divisée comme celle de Huanuni nous montrent le besoin d?envisager des négociations gagnant-gagnant entre communauté et entreprise minière, non pas comme un point de départ, mais comme un résultat à atteindre, qui nécessite la préparation de conditions préalables. Cela implique fondamentalement de mettre l?accent sur le processus qui permettrait par la suite aux parties de mieux traiter les questions de contenu. Suivant cette hypothèse générale, l?initiative conjointe entre le Ministère des ressources naturelles du Québec et le CECI ?Développement des mécanismes de négociation entre communauté et entreprise minière? peut dégager, après un an et demi d?expérience pilote dans le site minier de Huanuni, département d?Oruro, Bolivie, les leçons préliminaires suivantes. Ce processus requiert: ??Agir, en tant qu?organisme consultant tierce partie, selon des principes et une méthodologie qui relèvent de la Communication publique et de la Médiation ; ??Comprendre et agir à partir de la ?réalité sociale? des parties en présence: l?entreprise minière, l?État et les différents groupes de la communauté; ??Intervenir sur les ?réalités sociales? des parties, par des actions d?éducation et de diffusion dans le but de préparer les personnes, les institutions et les organisations de la société civile, à des changements durables du modèle de communications existante; Approfondir la compréhension de la ?réalité sociale? du conflit (la culture du conflit, les méthodes populaires de résolution des problèmes et de gestion des conflits) afin d?offrire aux bénéficiaires les technologies appropriées pour la transformation de cette culture de confrontation violente en gestion constructive des conflits. Par ricochet, nous espérons ainsi faciliter l?attraction des investissements dans le secteur minier.

May 1, 2001

By G. Azimi, C. A. Ang, F. Zhang

"Nickel recovery from laterite ores generates large amounts of solid and liquid wastes. This is primarily due to the low concentration of Ni (about 1.4 wt%) in the feed ore to the High-Pressure-Acid-Leaching (HPAL) process. It is known that the HPAL residue contains a high concentration of hematite, a commercially important source of iron in the steelmaking industry. However, the balance is natroalunite, containing sulfur, which is a detrimental element in the steelmaking process. Hence, to make the HPAL residue a suitable feed for steelmaking, natroalunite must be removed. The current work is focused on: 1) a thorough characterization of the HPAL residue obtained from Vale, and 2) a systematic investigation of an alkaline leach process to remove natroalunite. The characterization results indicated that there are about 83 and 12 wt% hematite and natroalunite in the HPAL residue, respectively. The leaching results indicate that sodium hydroxide is the best leaching agent, which results in 55 wt% reduction in the sulfur content. The results of this work enable the conversion of an otherwise waste product into a useful feedstock for steelmaking. Furthermore, this project could potentially have significant environmental benefits by reducing the amount of residue produced during the HPAL process.INTRODUCTION Conventionally, crude steel has been obtained by reducing iron ore containing oxides such as hematite (Fe2O3), magnetite (Fe3O4), and wüstite (FeO) in a blast furnace with coke. The product is then refined in a basic oxygen furnace to produce steel with useful properties (McGannon, 1969; Turkdogan, 1978). Steel has been sought for its desirable properties and its application is widespread throughout modern civilizations. Surpassing the growth rate of other materials, the annual demand of steel has increased at a compound growth rate of 5% over the last 20 years (Baddoo, 2008). The global demand for steel was reported to be 1501 Mt in 2016 and demand is expected to double by 2050 (Cullen, Allwood, & Bambach, 2012; World Steel Association, 2016). In recent years, to meet the rapid growth of demand, secondary resources for iron have been identified as strategic sources of iron (Das, Kumar, & Ramachandrarao, 2000; Li, Sun, Bai, & Li, 2010; Matschullat et al., 2000). The residue produced from high-pressure acid leaching (HPAL) of laterite ore has been identified as one of the important secondary sources of iron (McDonald & Whittington, 2008). Laterite ore represents 60% of the world’s nickel resources and accounts for approximately 40-50% of the world annual nickel production (U.S. Geological Survey, 2016). Therefore, the amount of iron residue produced by the process is substantial and its utilization will produce both economic and environmental benefits."

Jan 1, 2017

By G. A. Sutton

"At the San Manuel mine (Arizona, USA), in-situ copper leaching of a copper porphyry deposit was carried out from 1986 to 1999 during underground and open-pit mining. In 1993–1994, well¬field testing of the supergene zone, composed primarily of chrysocolla and copper-rich clay minerals, led to estimates that 52% of the acid-soluble copper (ASCu) could be recovered during in-situ leaching; however, the actual recovery from zone 6, which had the longest leach history, was approximately 42%. Comparing drillcore assay data from holes drilled before and after leaching also indicated an approximate recovery of 42%. The discrepancy between the predicted (52%) and actual (42%) recovery is probably related to several factors, including difficulty maintaining fluid saturation, channelling effects, and gypsum precipitation. ¦ KEYWORDS Copper oxides, in-situ leaching, Modelling, Porphyry, Solvent extraction and electrowinning (SXEW), Well-to-well RÉSUMÉ À la mine San Manuel (Arizona, États-Unis), on a procédé de 1986 à 1999 à la lixiviation in-situ de cuivre d’un gisement porphyre cuprifère pendant l’exploitation minière souterraine et à ciel ouvert. En 1993 et 1994, des essais effectués dans des champs de captage de la zone supergène, composée principalement de chrysocolle et de minéraux argileux cuprifères, ont abouti à des estimations selon lesquelles on peut récupérer 52 % de cuivre soluble dans l’acide (ASCu) pendant la lixiviation in-situ ; toutefois, la récupération réelle dans la zone 6, qui affiche l’histoire la plus ancienne en matière de lixiviation, était d’environ 42 %. La comparaison des données d’analyses de forage obtenues à partir de trous forés avant et après la lixiviation indiquait également une récupération approximative de 42 %. La différence entre la récupération prévue (52 %) et réelle (42 %) réside probablement dans plusieurs facteurs, notamment la difficulté à maintenir la saturation des fluides, les effets de canalisation et la précipitation du gypse. ¦ MOTS CLÉS d’un puits à l’autre, extraction par solvant et extraction électrolytique (SXEW), lixiviation in-situ, modélisation, oxydes de cuivre, porphyreINTRODUCTION in-situ copper leaching at the San Manuel mine, Arizona, USA (Figure 1), began in 1986. It was recognized that some of the copper oxide resource was not economically recoverable by conventional open-pit and heap leach methods using solvent extraction and electrowinning (SXEW) and a high stripping ratio would be required to access part of the resource. At the time, in-situ leaching was becoming popular in the uranium industry, but the approach was virtually unknown in the copper industry, especially at a large scale."

Jan 1, 2019

By S-E. Vandat

The goal of this work was to select an appropriate electrode for dummy load of diesel engine in fully salt-water in the DESA factory. The electrochemical corrosion rate of general structural steel, commercial pure aluminum and cathode copper calculated as weighting, volumetric and commercial in fully salt-water by city power. After several tests and then applying the fuzzy logic method, it was determined that general structural steel is the best selection for this purpose.

Jan 1, 2005

By Osvaldo A. Bascur, Curt Heftier

The lack of integrated information including the Energy/Utility Suppliers with sufficient detail for analysis causes inefficient operation in metallurgical complexes including the Energy/Utility Suppliers . Defining the right context for information use is essential for sustainable operations. This being said, what are we doing to enable people to act upon information and to be aligned to optimize the use of resources like raw materials, energy, water and consumables for an entire metallurgical complex? Collaboration between all company entities is a key component of improving efficiency. Evolution of web technology and object modeling of enterprise assets enables collaboration across the whole business. Operational troubleshooting occurs more quickly as the organization acts on issues to reduce wasteful operation. This paper presents a real time software infrastructure with tools that give users the ability to sift through available data, transform data into information for business continuous improvement and optimization. We will introduce a new technology for analyzing real time data, information and events using multidimensional analysis of information to detect anomalies based on the statistics of the data classified by time events to reduce the information into action. A new paradigm for collaboration at a local and strategic level is proposed to enable the enterprise to become proactive in dealing with wasted time and products. Three examples from the industry will presented and their benefits highlighted.

Jan 1, 2011

By Ki-Bok Min, Seokwon Jeon, Seung-Beum Choi, Taehyun Kim

"In order to investigate anisotropic characteristics of Boryeong shale in Korea, which clearly shows transverse isotropy, a series of experimental tests were carried out. Using Brazilian test, five elastic constants and tensile strength of the shale were evaluated. Elastic constants were determined by iterative procedure and in order to perform this procedure, constitutive model was modified to fit the experimental condition. The anisotropic ratios of elastic constants were evaluated and the applicability of the methodology was assessed. Apparent Brazilian tensile strength profile was investigated and the ratio of the maximum to minimum tensile strength was estimated. Results showed that the tested rock type had low to moderate anisotropic characteristics.INTRODUCTIONMechanical, thermal and hydraulic characteristics of many rocks vary according to direction, which is known as inherent anisotropy, and it is originated from stratified and/or foliated structure of intact rock and discontinuity of rock mass. Anisotropy is one of the long standing issues of rock mechanics field and it has to be taken into account in several engineering fields such as civil, mining and petroleum engineering. An anisotropic medium has 21 independent elastic constants without any assumption of symmetry. If a material has any symmetry, the number of elastic constants required to define its behavior reduces and eventually two constants are necessary if it has complete symmetry, which is known as isotropy. An anisotropic medium that has remarkable planar structure due to its stratification and foliation such as bedding is often called as a transversely isotropic medium. Transversely isotropic model is frequently adopted in many applications especially for sedimentary rock formation and five elastic constants are required to establish the constitutive model."

Jan 1, 2015

By J. R. Tickner

"Gold is conventionally analyzed using fire-assay or other destructive chemical methods that impose significant sample preparation, OH&S, and skilled labour requirements. Developed over the past 15 years by the CSIRO, PhotonAssay provides a new approach. A high intensity, high-energy x-ray source is used to activate atoms of gold and other elements in bulk mineral samples. The resulting activity is counted to automatically, accurately and rapidly determine metal grade. Samples weighing 0.5–1.0 kg can be measured in a few minutes with minimal preparation. As the method is matrix-agnostic, traditionally hard-to-assay materials such as highly refractory ores, carbon pulps and copper concentrates require no special treatment. We present the status of commercial PhotonAssay systems being developed by Chrysos Corporation. The first unit with a throughput of up to 80 samples per hour is to be deployed in an Australian assay laboratory in late 2017; smaller systems suitable for providing real-time assay directly at the mine-site will be progressively rolled out from mid-2018. Performance results from extensive testing using both mine-sourced and standard reference materials are presented, demonstrating the sensitivity and accuracy of the method. Implications for replacing conventional gold assay in exploration, mining and processing operations are discussed.INTRODUCTION Accurate methods for assaying ore grade are essential throughout the exploration, mining and mineral processing value chain. The discovery and evaluation of new ore deposits, reserve and resource definition, mine operations planning, ore processing, metal accounting and product quality evaluation all rely on accurate measurement of the valuable metal content of bulk materials. The analysis of gold presents particular challenges, stemming from the very low concentrations at which commercial operations run (often part-per-million (ppm), or equivalently one gram-per-tonne levels or below), and the highly heterogeneous nature of many gold deposits. These challenges mean that any analytical method must have high sensitivity and be capable of measuring large-mass samples. The most widely used quantitative analytical method for gold is fire-assay (Hoffman, Clark and Yeager 1998). An initial ore sample typically weighing several kilograms is dried, crushed and pulverized to allow a small sub-sample (10–50 g is common) to be representatively drawn. The sub-sample is mixed with flux, litharge (lead oxide), a reducing compound and other reagents. The mixture is fired at a temperature of 1000–1200°C until molten. After cooling, the slag is removed and the lead button containing any gold present in the sample is remelted in a porous cupel. The lead is absorbed into the cupel, leaving a gold prill which is either weighed directly, or dissolved in acid and analysed via atomic absorption spectroscopy (AAS) or inductively coupled plasma spectroscopy (ICP or ICP/MS)."

Jan 1, 2017

By G. Goodall, D. Mercier, M. Brochu, C. Kaplin

A nanostructured CoNiCrAlY coating was obtained by thermally spraying cryomilled feedstock powder using the high-velocity oxy-fuel (HVOF) process. The oxidation behavior of the nanostructured powder and coating were compared to their conventional counterparts by performing static oxidation tests at 1000°C for durations ranging from 1 to 96 hours. It has been found that oxidation of the conventional powder yielded a duplex oxide scale composed of an inner layer of Al2O3 and an outer layer composed of Cr2O3, NiAl2O4 and other spinels. Interestingly, oxidation of the as-sprayed nanostructured coating yielded a similar duplex oxide scale while oxidation of the polished coating resulted in a single Al2O3 layer. These findings indicated that surface oxide seeds act as nucleation sites for the growth of the mixed oxide layer. Also, it was determined that nanostructuring of the coating promotes the nucleation and growth of a single and adherent a-Al2O3 layer by increasing both the number of diffusion channels and the aluminum concentration at grain boundaries.

Jan 1, 2010

By Ben C. McLellan, Philip J. Bangerter, Andrew Murphy, Glen D. Corder, Damien Giurco

Sustainability now forms a critical part of metallurgical plant design. In addition to compliance with requirements and corporate principles, design engineers must also consider how community and societal responses to the metallurgical industry affect the way they design and build plants. Three broad areas to consider are: the design engineer’s contribution to sustainability through the design process and the relationship to the social license to operate (SLO)—the unwritten license communities give companies to safely and responsibly operate the plant and equitably share benefits; the realization of sustainability goals through methodologies emerging in the design activities; and the integration of design frameworks into a contemporary project design context and its investment objectives. This chapter explores sustainability in metallurgical plant design in the context of SLO, design tools and frameworks, and community and societal influences.

Jan 1, 2015