High Temperature Oxidation Behavior Of Nanostructured CoNiCrAlY

A nanostructured CoNiCrAlY coating was obtained by thermally spraying cryomilled feedstock powder using the high-velocity oxy-fuel (HVOF) process. The oxidation behavior of the nanostructured powder and coating were compared to their conventional counterparts by performing static oxidation tests at 1000°C for durations ranging from 1 to 96 hours. It has been found that oxidation of the conventional powder yielded a duplex oxide scale composed of an inner layer of Al2O3 and an outer layer composed of Cr2O3, NiAl2O4 and other spinels. Interestingly, oxidation of the as-sprayed nanostructured coating yielded a similar duplex oxide scale while oxidation of the polished coating resulted in a single Al2O3 layer. These findings indicated that surface oxide seeds act as nucleation sites for the growth of the mixed oxide layer. Also, it was determined that nanostructuring of the coating promotes the nucleation and growth of a single and adherent a-Al2O3 layer by increasing both the number of diffusion channels and the aluminum concentration at grain boundaries.