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It is shown that factors associated with conditions whIch are thermodynamically favourable for the formation of CuS04 in roasting lead to high copper recoveries on leaching. One of these factors is the ratio of the air to solids used for roasting. This can be varied widely without loss of temperature control in the sulphating roasting of many Australian copper concentrates.Thus, the prediction of the air to solids ratio corresponding to a maximum p(SO3) value, for a given concentrate and temperature, is of importance in fluidized bed roasting, since this could be associated with the formation of a maximum quantity of CuS04. Calculations are presented which predict this air to solids ratio, not only for a given concentrate composition, temperature, and pressure, but also for air which is enriched with sulphur dioxide or oxygen.

Jan 1, 1968

By Haijian Shi, Drew Pizzo

This article focuses on the appropriate application of subsurface investigation methods for transmission structures, which are typically designed to resist lateral rather than vertical loads. Currently, the three methods used most often for the subsurface investigation of transmission structures in the field are the Standard Penetration Test (SPT), the Cone Penetration Test (CPT), and the Flat Dilatometer Test (DMT). Each of these methods has advantages and disadvantages, and each is more applicable to some scenarios than to others. To gain a better understanding of these test methods and the implications of using them for various kinds of applications, a comparison study was conducted in the field in Maryland, for three boring locations. Each boring location was explored using each of the three tests as stated. The results of the tests and lessons learned are presented and compared, and these comparisons show that the three test methods agree on the majority of the findings. The results from each test method were also used to derive key parameters such as the soil friction angle for given foundation designs considered in order to establish a clear basis for comparison. Recommendations for performing transmission structure subsurface investigations are made in order to optimize the use of each method and thereby optimizing subsequent foundation designs. INTRODUCTION For overhead transmission structures, the most important structural requirement for determining the foundation design differs from the requirement for other structures such as buildings and bridges in accord with the conditions the transmission structures will need to withstand. In addition to the ability to bear a given vertical load consistent with its use, the foundation must bear lateral loads arising from wind and other weather conditions. The foundation types used most often for overhead transmission monopole structures include concrete drilled pier, vibratory caisson, and direct embedment. In order to determine an appropriate and even an optimum foundation design for any given set of conditions, an appropriate subsurface investigation method or approach is needed. Currently, the standard penetration test (SPT), the cone penetration test (CPT), and the flat dilatometer test (DMT) are the three most commonly used subsurface investigation methods.

Jan 1, 2018

By Dongok Kim

Regardless of the advantages of the Friction Stir Process (FSP), for age-hardened aluminum alloys, the mechanical properties such as hardness in the stir zone decreased after FSP due to the growth or dissolution of strengthening precipitates. Here, as a new technique, FSP was introduced to alloy copper nanopowders in Al7075 T651. Mechanical properties of copper nanopowder- alloyed Al7075 T651 together with micro and nanostructures were compared with those of as-FSPed Al7075 T651 using SEM, TEM, and Vickers hardness testing to understand structure-property relationships. It was observed that Vickers hardness of the stir zone in copper nanopowder alloyed Al7075 T651 increased by 20% compared to that of the heat affected zone, while the as-FSPed samples did not show a noticeable increase in hardness in the same zone. Xray mapping showed traces of copper nanopowder after the process. TEM is being used to verify if there was CuAl2 formed in the copper alloyed sample.

Jan 1, 2006

During the initial portion of the contract several alternative designs were considered, as set out step by step in the monthly reports. The conclusions reached during this period were - to use on INTERDATA Model 70 as the system minicomputer - to drop the idea of multiplexing and digitizing the inclinometer outputs downhole due to the greater complexity and cost that that alternative would imply - to use a multitasking software monitor to enable synchronization of the several tasks that the system would have to perform simultaneously - to use a common controller for all I/0 devices except those which were available off the shelf from Interdata - to use a sheave counter to meter off equal increments of probe travel, but to supplement this information with the use of an encoder on the winch drum in order to be able to measure total probe travel unambiguously. - to place all I10 device interfaces in a bin connected to the common controller. During this period considerable attention was dedicated to the design of the mechanical components contemplated it the original contract. Of these, only those required for vertical probe was complete at the time that it was decided to forego the mechanical subsystem and concentrate on developing the necessary electronics and software to interface with the probes being developed by the Bureau of Mines.

Jan 1, 2012

By Joseph T. Coe, Siavash Mahvelati, Alireza Kordjazi

This paper introduces recent advances in stress-wave NDT systems for use in assessments of in-service foundation integrity and drilled shaft construction. The primary results of the laboratory experiments are very promising, as the acquired image was capable of differentiating changes in pile cross section as low as 0.3 cm. The preliminary results with the same hardware components on a relatively large scale cemented sand model were also promising. A brief overview is provided of both systems including hardware, survey methods, and data processing techniques, followed by a discussion on application of the results to QA/QC of deep foundations. INTRODUCTION There are two main applications in which current QA/QC NDT technology fails to provide sufficient information regarding deep foundation conditions: (1) detection of flaws in outside cover concrete of drilled shafts and corrosion in steel piling; and (2) evaluation of anomalies beneath the bottom of drilled shaft excavations. Previous studies have demonstrated the capabilities of high frequency stress waves for geotechnical and foundation evaluation purposes (Lee and Santamarina 2005; Coe and Brandenberg 2010; Coe and Brandenberg 2012; Coe and Kermani 2016). Higher frequency waves can visualize smaller anomalous features at the expense of higher attenuation and smaller propagation distance. Therefore, the goal of this study was to advance the state of NDT practice by development of a prototype high resolution stress-wave imaging system as proof-of-concept. The equipment and hardware were modular, which allowed simultaneous development of two system configurations for application to in- service foundations as well as drilled shaft excavations during construction. Results are presented based on two large scale soil models. The first laboratory model simulated section loss in an in-service steel pipe pile and drilled shaft foundation (Fig. 1a). The second model simulated anomalous conditions beneath drilled shafts excavations as might be encountered in areas with significant karst (Fig. 1b). For both models, evaluation of foundation conditions relied on the propagation of small amplitude seismic stress waves using hardware similar to those described in Coe and Brandenberg (2010) and Coe and Brandenberg (2012).

Jan 1, 2018

By Scott A. Walker, Frank L. Rollo

"The San Francisco Museum of Modern Art (SFMOMA) in downtown metropolitan San Francisco, California, is supported on a mat foundation. Although the mat foundation of the original museum was designed to accommodate a future expansion, the plans for expansion that developed in 2010 required a larger footprint to accommodate the new space requirements of the museum. The new, larger expansion was designed by lead architect Snohetta. It will be a tall 12-story, steel-framed building occupying an area that was once the eastern part of the existing museum as well as two adjacent and newly acquired parcels.As designed, the expansion includes a 30-foot-deep excavation which is surrounded by adjacent buildings and improvements. Because of variable subsurface conditions at the site, geotechnical challenges included mitigating anticipated differential settlement between the existing and new foundations, preventing overstressing of the existing mat foundation, controlling groundwater to prevent settlement of surrounding improvements, and providing temporary support of adjacent structures during excavation for the new basement.To address several of the geotechnical challenges, soil-cement mixed (SMX) ground improvement was recommended by Treadwell & Rollo. However, during contract negotiations and construction, the specialty contractor proposed using jet grouting as an alternative technique for ground improvement. The jet grouting approach was accepted in principal, but when implemented was only marginally successful. Accordingly, the contractor eventually installed SMX panels using a Cutter Soil Mixing (CSM) machine. Because the CSM machine was a late arrival during construction, the contractor was not able to take advantage of the ground-improvement technique to install many of the shoring elements that we had originally recommended (such as the cut-off shoring wall). In the end, SMX panels were installed as ground-improvement beneath the new mat foundation to (1) reduce the potential for liquefaction in clean sand below the groundwater by providing increased rigidity to the soil, (2) reduce the potential for disturbing a weak underlying marsh deposit during construction, and (3) transfer vertical building loads to a layer of underlying dense sand.This paper also discusses the quality control and quality assurance programs that were implemented to check that the ground-improvement techniques used were thorough and complete and provided the required strength to transfer the new foundation loads to the underlying strata."

Jan 1, 2014

By Michael E. Meadows

The results of tests to determine the .regional applicability of four synthetic unit hydrograph models are presented. The SCS curvilinear (Haan), SCS single triangle, Williams and TVA double triangle unit hydrograph models were tested on 271 events from 38 USDA experimental watersheds in 14 physiographic provinces. Though inconclusive due to the limited number of events analyzed, the results indicated a regional tendency for each model, with the SCS curvilinear unit hydrograph method generally performing best overall. It outperformed the SCS single triangle by predicting better shape; they differed less than 2 percent in time of peak and peak rate predictions. The Williams model performed well at Oxford, Mississippi and Coshocton, Ohio, which suggests it may be applicable to surface mined lands within the Northern and Central Appalachian Plateau and Texas coal producing regions. The TVA model is applicable to the Appalachian Plateau, specifically the Cumberland Plateau. A second test using only the SCS curvilinear unit hydrograph on 11 small watersheds and 50 events was conducted to investigate the effect of the excesss rainfall pattern on simulation results. A Green and Ampt infiltration model was coupled with the SCS unit hydrograph model to determine if peak rate and timing errors noted in the regional test could be minimized with an alternate to the SCS curve number model for determining infiltration losses. The results confirm the curve number model is the better approach to determining the excess rainfall pattern for unit hydrograph simulation.

Jan 1, 1983

By Emma Arakelova

?2?2 (98 %) vapour passed through a reactor at 25Pa where a Zn? target was placed at 273K- 373?. Experiments were carried out on a flow- type vacuum device. ?2?2 decomposition on Zn? surface accompanied by formation of a Zn-containing volatile complex which transferred to the gas phase, and Zn? deposited on a substrate at condensation. As the substrate, five sequentially located quartz cylinders were used at 293K- 423 K (?n). Decomposition of the Zn-containing complex on quartz substrates carried out as a first- order reaction. ?The complex decomposition constant (??) increased with the substrate temperature (?n=293 K, ??=7.05 sec-1;?n = 373 K, ?? = 87 sec-1;?n = 423 K, ?? =158 sec-1). ?The complex decomposition constant did not practically vary when the target temperature increased; the complex formation rate increased slightly.

Jan 1, 2006

From time to time efforts have been made to classify rocks according to their hardness, toughness and abrasiveness, and to use these classifications to provide an indication of the ease or difficulty with which they may be drilled. However, rocks classified as of similar type on this basis may vary considerably in their .resistance to the penetration of a rock drill bit due to differences in their physical state.For instance, fine grained rocks of granular texture are more difficult to drill than equivalent' rocks of coarser structure, altered rocks drill more readily than unaltered ones, and silicified rocks usually exceedingly hard and tough may be so shattered by movement as to be drilled at a rate comparable to quite soft rocks. Therefore, considerable latitude has existed in this method of defining their drillability, and no values generally acceptable have materiaJised; so that, when the drilling properties of rocks are discussed, it is common practice to refer to their hardness or toughness in a greater or lesser degree depending to some extent on the emotional state of the drill runner.REFERENCES AND STANDARDSThe 'introduction of tungsten-carbide tipped rock-drill bits for use with percussion rock-drills has thrown increasing emphasis on the need for defining a rock's resistance to penetration in a more concise and generally acceptable...

Jan 1, 1950

By Peter White

A bridge reconstruction project involved driving pipe piles for the new foundations. Disturbances within soil layers at depth caused sinkholes to open up within the construction site. After a near fatal accident, the pile driving installations were suspended. The solution involved ground im­provement through cement grouting with sleeve pipes and special grout additives to minimize migration of cement grout.

Jan 1, 1997

By E. R. Palowitch

Two samples of the Lower Hartshorne (Spadra) bed were collected: A sample of the raw coal with the machine cuttings excluded, and a sample of the machine cuttings exclusively. Analysis of the 5-inch by 200-mesh size fraction of the raw coal, excluding machine cuttings, showed that a product meeting minimum quality specifications could be produced by washing at 1.60 specific gravity, yielding a theoretical 93.7 percent of clean coal. A negligible amount of near-gravity material at the separation gravity indicated an easy washing problem. The sample of machine cuttings had a maximum size of 2 inches and contained about 50 percent ash. Washability tests of the 2-inch by 200-mesh size fraction indicated that a theoretical yield of 30.0 percent of specification-grade coal could be achieved by washing at 1.49 specific gravity. As the machine cuttings represent an estimated 10 percent of the total coal mined, their inclusion in the mine output would increase the theoretical net yield of salable coal by only 3.7 percent. Because the machine cuttings contained a high percentage of sink 1.80 specific-gravity material, they had neither an effect on the separating gravity required to clean the raw coal nor on the difficulty of separation. Gabbing underground versus transporting the cut-tings to the surface for disposal or washing either separately or combined with the raw coal involves a number of practical, economic; and intangible factors; hence, no specific recommendations could be made. A discussion of some of the factors involved in dealing with a similar problem is given by Gandrud and Riley.4

Jan 1, 1962

By R L. Brathwaite

Previous paleodepth studies of low-sulphidation epithermal Au-Ag deposits in the Coromandel region indicated that economic gold mineralisation was generally limited to a depth zone of 100 to 400 m below the paleosurface. Notable exceptions are Waihi and Karangahake, where ore shoots extended to depths of about 750 and 900 m respectively. These studies have been extended to include Au-Ag, Hg and Sb epithermal deposits in Northland and the Taupo Volcanic Zone. The main paleodepth indicators used are sinters and hydrothermal eruption breccias, hydrostatic pressures estimated from homogenisation temperature measurements on fluid inclusions, and hydrothermal alteration mineralogy. Also the occurrence of lacustrine and fluvial sediments is an indicator of the paleosurface at their time of deposition. Selected paleodepth indicators have been compiled and mapped in a GIS environment. The distribution of the paleodepth indicators are used to define regional variations in erosion levels, and may be useful in predicting areas most likely to preserve the optimum depth window for gold deposition. In the Coromandel region, regional stream sediment geochemical data has also been used to broadly define erosion levels in terms of Zn, Pb and Cu representing deeper base metal zone mineralization and Hg and Sb representing shallower cinnabar and stibnite mineralisation. The interpretations of paleodepth and potential reconstruction of paleosurfaces are limited by the paucity of data, poor age control on the paleodepth indicators and the epithermal deposits, and marked relief and complex stratigraphy in the volcanic terranes.

Jan 1, 2003

By Peter J. Clarke

The Soviet-controlled Government in Afghanistan continued to emphasize development of the country's mineral resources, primarily to supply raw materials and fuel to industrial areas in the Soviet Central Asian republics. In addition to expanding production of natural gas for export to the U.S.S.R., a $600 million2 Soviet-Afghan cooperation project, 1 of 167 such projects established since 1981, was devoted to exploiting the Ainak copper deposit, south of Kabul in Logar Province. Also being developed was the large Hajigak iron ore deposit in the Hindu Kush Mountains, 100 kilometers northwest of Kabul. In addition to these minerals, Afghanistan already produced small quantities of barite, cement, coal, gypsum, salt, and possibly some lapis lazuli. Afghanistan was the world's leading producer of lapis lazuli, a semiprecious gem stone, prior to the Soviet invasion in 1978, but production, although no longer reported, has probably been significantly reduced. It was also reported that Soviet mining engineers and technicians have commenced producing uranium from Lashkangah in the mountainous Khawaja Rawash area near Kabul.3 The Government was also considering mining chromite from Herserak and Mohammed Agha Kulanger, near the border with Pakistan.4 Afghanistan's overall economy remained stagnant in 1983, a result of continuing armed resistance to the Soviet-installed government. The gross domestic product (GDP) was estimated at about $2.8 billion, only marginally higher than the 1982 level. The value of exports was estimated at $720 million, up less than 2% over that of 1982, while imports rose approximately 8% over the same period. Natural gas was by far the leading export, earning about $295 million, up 4% over that of 1982. Approximately 90% of Afghanistan's natural gas production was exported to the U.S.S.R. Gas exports were used to pay the country's debt to the U.S.S.R., and also to pay for its supplies of petroleum products and other goods, which were imported almost exclusively from the Soviet Union. Some of Afghanistan's petroleum products were supplied by the U.S.S.R. as grants in aid, as Afghanistan did not have any domestic petroleum refining capacity.

Jan 1, 1985

By Juan Anes, Dominic Fragomeni, Tim Edwards, Dave Scott, Simon Yu

"The Montcalm concentrator operation was successfully commissioned in fall of 2004 at the Xstrata Copper’s Kidd Creek Metallurgical Site, Timmins. The start-up met or exceeded the Type 1 profile as defined by McNulty. Since the life-of-mine was estimated at seven years, concentrator optimisation endeavours had to be fast-tracked. These joint endeavours between the Kidd Creek Metallurgical Site staff and Xstrata Process Support were focussed on increasing ore treatment capacity and metallurgical performance. This paper reviews these endeavours. A flotation circuit survey, together with appropriate Process Mineralogy measurements, identified recovery opportunities in both locked and overground pentlandite in final tailings. The bypassing of first rougher concentrate directly to final concentrate was also recommended, given the composition of that stream. A subsequent grinding circuit survey identified a low circulating load due to poor classification performance. Modelling of these data suggested a change to the cyclone nest and pumping arrangements in the grinding circuit. Implementation of these recommendations has led to a 25% gain in milling circuit capacity as well as improved flotation circuit performance. These improvements amount to nickel and copper recovery gains of 2.57 and 1.83% respectively.INTRODUCTIONHistoryThe Montcalm Ni/Cu Ore is processed in a spare division of the Xstrata Copper’s Kidd Creek concentrator, located near Timmins in Northern Ontario. The flowsheet had been specified by earlier work, and the project fast-tracked so as to commission production operations into a time of rising nickel and copper prices. The Montcalm flow sheet starts with on-site ore crushing to - 19 mm. The crushed ore is trucked to the concentrator. This off-site crushing minimizes contamination with the Kidd Creek Cu/Zn ore. In the concentrator, rod and ball mill grinding to a target p80 of 39 µm produces the Rougher Flotation Feed. Flotation to Bulk Concentrate follows as Cu/Ni roughing and two stages of cleaning. Bulk concentrate is subjected to Cu/Ni separation using conventional column cells. Xanthate is the collector and MIBC is used as frother. Depramin C, a CMC (Carboxy Methyl Cellulose) is added to depress ferromagnesian silicates in the flotation process."

Jan 1, 2009

By E Apaza, R Neumayr

This paper aims to summarise the discovery of the QTS Central resource, a previously unidentified +1 Mt inferred resource that lies between two major CSA resource systems.The 1.7 Mt at 5.76 per cent Cu, QTS Central ore system represents 1/6th of the CSA mineral resource and was discovered in 2014 based on the accumulation of historic exploration records dating back to 1989.The CSA deposit consists of five ore systems hosted within turbidite-derived siltstones (CSA Siltstone) and lesser sandstones (five per cent) of the Devonian Amphitheatre Group. The host sediments strike approximately north–south with a steep westerly dip and exhibit a well-developed east dipping cleavage. Most CSA mineralisation is hosted within dilation zones at the intersection of cross-cutting structures and is interpreted as epigenetic in origin.Alteration and weak mineralisation, up plunge to the reported QTS Central mineral resource, was initially detected in 1990 during a downhole electromagnetic conductivity (EM) study, where one hole indicated an off-hole conductor, later tested with four diamond holes. One of these diamond holes intersected 3 m at 7.5 per cent Cu at 200 m. Development of the 9070 Subway drive in 2005/2006, linked the QTS North and QTS South workings and intersected structures interpreted to host QTS Central mineralisation. Subsequent drilling proximal to the 9070 Subway in 2007 identified an up plunge extension to the QTS Central zone (UDD07152: 1.8 m at 6.3 per cent Cu from 10.7 m). Work on QTS Central was largely forgotten until 2012 when the mining of a 450 m infrastructure drive provided a platform to test the anomalous grades. In December 2013, drill hole UDD13055A intersected 20.9 m at 7.2 per cent Cu from 378 m. By the end of 2014, the QTS Central inferred resource was 1.0 Mt at 6 per cent Cu and 18 g/t Ag (Hosken and Apaza, 2014). Late in 2016, further infill drilling occurred from two fronts to increase confidence in the QTS Central resource. The results of this drilling are expected late in 2017.The current interpretation indicates the QTS Central system consists of two main lenses hosted within closely bedded sandstones and siltstones. The sandstone in general is not mineralised, being heavily silicified, while the siltstone is mineralised and chloritised. The main mineralised lens is 75–200 m along strike and 450 m high. Massive sulfide feeder structures lie at the core of the two main lenses, although the characteristics of the QTS Central system tend toward the mineralisation being more chlorite-rich than in QTS North and QTS South.CITATION:Apaza, E and Neumayr, R, 2017. The discovery of the QTS Central ore system, CSA mine, Cobar, NSW, Australia, in Proceedings Tenth International Mining Geology Conference 2017, pp 151–156 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

Recently discovered Carboniferous bentonites are variable in charadeI and thickness, but being altered aeolian, ash-fall tuffs, they are probably extensive. Most are the Ca-montmorillonite type without the natural swelling characteristics of the Wyoming deposits, but their situation, thickness, and response to beneficiation through cation exchange may give them some potential as sources of future economic deposits.INTRODUCTIONLoughnan and See (1959) gave an account of bentonites and fuller's earth deposits of New South Wales. The most likely potential industrial sources were those occurring in the uppermost formations of the Newcastle and Singleton Coal Measures (Permian) in the Hunter Valley and deposited during epochs not marked by strong contemporary vulcanicity.One feature of the record of known occurrences at that time was the absence of bentonites from the thick volcanic sequences of the Carboniferous, but since this paper appeared, many bentonite beds have been discovered by the writer in the Carboniferous facies formerly known as the "Kuttung Series".The purpose of this contribution is to report briefly on the occurrence, genesis, mineralogy, and economic potential of these deposits which augment possible sources of bentonite near major industrial centres on the eastern seaboard.The potential world demand for bentonite would increase markedly with the trend to pelletization in the steel industry, if its use in this field became more general. More detailed mineralogical studies will be presented in later publications.STRATIGRAPHIC DISTRIBUTIONBentonite occurs at irregular intervals throughout a thick sequence of dominantly continental, plant bearing strata...

Jan 1, 1965

By Gerhard Nel, Huziel Masiiwa, Marthie Kotze, René du Preez, Simon Donegan

Tati Nickel is currently operating a hydrometallurgical demonstration plant in Botswana, using the Activox® process developed by LionOre Technology, to produce nickel cathode and a cobalt salt from a sulphide concentrate. Cobalt is extracted using Cyanex 272. This reagent also extracts all the iron, aluminium, copper, zinc, and manganese from the nickel stream. Versatic 10 carboxylic acid is then used as extractant to recover nickel from the stream, separating it from calcium and magnesium, and upgrading it to provide a suitable advance electrolyte for nickel electrowinning. However, the selectivity of Versatic 10 for nickel over calcium is limited, and gypsum formation in the extraction circuit is a problem when it is attempted to maximise the recovery of nickel. Mintek has developed a synergistic system with Versatic 10 for improved separation of nickel from calcium and magnesium. Laboratory test work was conducted on the raffinate of the cobalt solvent extraction circuit to optimise the Versatic 10/Nicksyn? (Mintek synergist) system to be employed. Extraction and stripping parameters suitable for this stream were optimised in the laboratory and then applied on the demonstration plant. A commercial batch (0.5 tons) of Nicksyn? reagent was produced for the demonstration plant. The laboratory test work results and the demonstration plant performance are discussed in detail in this paper.

Jan 1, 2007

By S. Lubbe

South Africa and Australia are the biggest suppliers of zircon sand to the international zirconium industry. However neither South Africa nor Australia is well known for zircon beneficiation. Geratech Zirconium Beneficiation Ltd (GZB) continued with additional research on sodium hydroxide (NaOH) cracking of zircon sand during 2002-2003. In 2003 GZB started extracting zirconium from zircon sand by means of NaOH cracking on a commercial scale. Experience has shown that temperature profile and atmospheric control inside the furnace is crucial for the beneficiation of zircon sand. Silica carryover to zirconium chemicals could result if a high temperature is used. Once the sodium silicate is extracted from the sodium zirconate and dissolved in hydrochloric acid, two distinct routes can be followed to precipitate various zirconium chemicals. The most common route is to precipitate zirconium oxychloride crystals (ZOC), with subsequent purification from all contaminants (crystal route). Less known is the process (liquid route) that involves the direct precipitation of zirconium basic sulphate (ZBS). This route will yield a less pure product, with contaminants such as silica and titanium. An important factor in this route is the prevention of silica gel formation, which could hamper final product filtration. For applications like paint drying (zirconium octoate) or antiperspirants (zirconium hydroxychloride) low levels of contaminants have no effect on the final product. The advantage of the liquid route is fewer production stages compared to the crystal route. The disadvantage of the liquid route is that the market for the products will be significantly smaller. The optimum solution could be a plant design that could cater for both routes. Another example of an application of zirconium chemicals is the use of ammonium zirconium carbonate (AZC) in the paper industry. Zirconium basic carbonate (ZBC) is dissolved in ammonium carbonate to produce AZC solution. AZC is used mainly in European countries in the paper industry. For example, carton boxes were initially produced with formaldehyde as the binder, however, it has now been replaced with AZC since formaldehyde is considered toxic. AZC reacts with the cellulose fibres in the paper to act as the binder. The resulting product is not toxic, and printing ink dries very quickly due to the porous paper structure. Other applications of zirconium chemicals involve the use of acid zirconium sulphate tetrahydrate (AZST), zirconium orthosulphate (ZOS), potassium zirconium carbonate (KZC), and zirconium hydrous oxide (ZHO). Fluoride-based zirconium chemicals like zirconium tetra-fluoride (ZrF4) and hexafluoro-zirconic acid (H2ZrF6) are used in the aluminium industry. Zirconium oxide (Zr02) can be produced from any of the abovementioned precipitated chemicals via a high-temperature decomposition process. The physical properties of such oxides can differ tremendously, depending on the final application. The fired density of sanitaryware is typically 5.8 g/cm3, compared to milling media at >6.1 g/cm3. The required fired density is achieved by controlling the precipitation and decomposition conditions for these two oxides. The same applies to stabilized and mixed oxides, for example where zirconium oxide acts as an oxygen carrier in fuel cells.

Jan 1, 2012

Your Excellency, on behalf of the Council of the Australasian Institute of Mining and Metallurgy, and, indeed, on behalf of everyone present, I extend to you a welcome, and our thanks for your gracious acceptance of the invitation to be here to-day and, later on, to present Honorary Membership Certificates. I also welcome the several official representatives of our Allies, of Great Britain and our sister Dominions.To Messrs. E. C. Driffield and E. J. Rigby, two of the original Foundation Members, who are with us to-day, I extend greetings.The present occasion is opportune to express, on behalf of a representative body of professional men, deep appreciation of the sacrifice which His Majesty the King has made, and will continue to make, by appointing His Royal Highness the Duke of Gloucester as Governor General of Australia and, therefore, His Majesty's senior personal representative in this country.I suppose, that as the primary reason for our assembly to-day is to celebrate the Fiftieth Year of the Institute's existence, I should properly on this occasion, give an account of its history and development. However, as this subject was ably covered by Mr. L. V. Waterhouse, in his Presidential Address in 1938, I trust I may be excused for selecting some other subject. I shall, therefore, exercise my privilege as President and give you a short history of the Mining and Metallurgical Industry of this country with special reference to its effect on the development of the Commonwealth and on the national economy. I apologize in advance for any statistics which I inflict upon you; some of these will be three or four years out of date, because of censorship restrictions. I shall as far as possible refer firstly to the industry prior to and including 1893, the Institute's foundation year, and then to subsequent development.Australia, is pre-eminently a pastoral and agricultural country and it leads the world in the production of wool. Nevertheless, it has an international reputation as a producer of gold and various metals and of minetal products.The development of gold mining in the decade 1840-50 was an epoch-making event in Australia's history, because, to quote one writer's apt phrase, "it precipitated Australia into nationhood." It was certainly responsible for a rapid increase in population. Thus, during the period 1841-1861 the population of Australia increased fourfold, from 221,000 to 1,170,000.The effect of the discovery of gold in Western Australia was even more striking. In 1890 the population of that State was 49,000 and in 1900 it was 180,000.Statistics in respect of gold are reasonably complete, even for the years prior to Federation, and it is interesting to note that the gold declared as...

Jan 1, 1944

By Richard F. Sliwoski

The Virginia State Capitol was designed by Thomas Jefferson and constructed in 1785. The Capitol is of great historic and architectural significance to not only the Commonwealth of Virginia but to the nation. It is the oldest operating Capitol in the U.S. and required a total restoration/renovation as well as an expansion to continue to remain functional. Site conditions dictated that the expansion (a new visitor center) be placed underground on the south side of the Capitol building, requiring a 40-foot deep excavation approximately 5 feet from the Building. Because of its historic significance, every measure had to be taken to ensure the safety and function of the Capitol during construction. The construction techniques that were used to make the deep excavation and protect the historic Capitol included a tied back concrete slurry wall, jet grouting, compensation grouting, and instrumentation monitoring. This paper describes the history of the Capitol building, the techniques that were employed for construction of the deep excavation, results of the latest movement monitoring, and factors contributing to meeting the restrictive movement goals.

Jan 1, 2006