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By Michael Moser, Brighty Dutta, David Dreisinger

"Molybdenum is widely used in the industries as an alloying element in the manufacture of steels and super alloys. The widespread use of the element encourages a growing need to develop extraction processes for recovery from both primary and secondary sources. The Solvay Group has developed a solvent extraction reagent named CYANEX®600 for the recovery of molybdenum from acidic solutions originating from both low grade (e.g. copper solvent extraction raffinates, smelter dusts and slags) and high grade (molybdenite) molybdenum sources. CYANEX®600 is a purified form of CYANEX®272 with the active component bis(2,4,4- trimethylpentyl)phosphinic acid. The extraction behavior of CYANEX®600 towards molybdenum in sulphuric acid medium was evaluated. The uptake of molybdenum increased with the increase in concentration of CYANEX®600. The approximate stoichiometry of the extracted complex was: Mo: CYANEX®600 = 1:2. Efficient back-extraction could be achieved with 0.1 M disodium EDTA and 0.1 M (NH4)2CO3, thus providing the option of recyclability of the extractant. The detailed back-extraction studies are currently under progress to find out the possible option for complete transfer of Mo(VI) to the aqueous phase so that high purity Mo salts could be precipitated from the molybdate solutions.INTRODUCTION Molybdenum (Mo) is one of the world’s valuable metals and is highly sought after by researchers due to its versatile mechanical, thermal, chemical properties. Swedish scientist Carl Wilhelm Scheele demonstrated molybdenite to be a mineral sulfide in 1778. Peter Hjelm successfully isolated dark metal powder from the mineral sulphide and named it as ‘Molybdenum’ in 1782 (Gupta, 1992). Molybdenum is a refractory metal of silver gray appearance and is an important alloying element used in the manufacture of steels and super alloys. Molybdenum compounds are widely used in formulation of catalysts (Gupta, 1992). Molybdenum occurs in nature only in chemical combination with other elements. Several molybdenum bearing minerals have been identified, but the only one of commercial significance is molybdenite (MoS2). As molybdenum is a strategic metal for the industrial sector, its widespread use acts as a factor for depletion of the natural resources. Hence, there is growing need to develop extraction procedures for its recovery from both primary and secondary sources. United States, China, Chile, Canada, Peru, and Mexico are listed as the main producers by the U.S. Geological Survey, 2016 (U.S. Geological Survey, Mineral Commodity Summaries, January 2016)."

Jan 1, 2017

By Clemens Kuhnert

"Nickelhütte Aue GmbH is specialized in the recycling of waste materials containing non-ferrous metals. We treat nickel, copper, cobalt, vanadium, molybdenum and precious metal containing materials like spent catalysts, ashes, dusts, grindings, liquids, slurries and sludge's as long as they contain one or a combination of the above mentioned metals. In our pyrometallurgical works we produce non-ferrous metal concentrates suitable for further treatment in our hydrometallurgical plant where we refine Ni-, Cu-, Co- and V-chemicals. Our production is based on synergy effects due to the combination of pyro- and hydro-metallurgy. As an example we can mention our heat recovery system and internal recycling of by-products. Furthermore, the use of alternative fuels instead of fossil fuels contributes to the economic and environ-mentally friendly treatment system.INTRODUCTION Nickelhütte Aue GmbH (NHA) can look back on nearly 400 years of tradition as a pyrometallurgical works and recycling company. The existence since its foundation in 1635 as a blue dye works shows responsible and successful action in the past. Therefore, we see highest customer service, minimization of interferences with nature by closing material cycles and maximized health and occupational safety protection by avoiding injuries and diseases, still as our future duties. These duties are evaluated and monitored by an integrated management system that meets the standards of DIN EN ISO 9001, 14001, 50001 and BS OHSAS 18001. We commit ourselves to the observance of all juridical and customized demands. The management and the department managers perceive their model function. We require responsible action from all employees. To protect the continuity of our enterprise, we will also perform in future continuous improvement of products and their quality, as well as steady progress in the areas of environment protection, health protection and industrial safety. Equally the effectiveness and propriety of the management system is checked and developed regularly. In order to obtain the objectives resulting from this policy, our company determines activities and measures by involving all employees."

Jan 1, 2017

By P. A. Christopher, R. H. Pinsent

"The Adanac molybdenum porphyry deposit near Atlin, in northwestern British Columbia, was discovered in 1905. It was explored extensively between 1967 and 1980.The deposit is within a complex, multi-phase, quartz monzonite stock that is a satellite of the post-accretionary, Surprise Lake Batholith. Biotite K-Ar dates range from 703 ± 2.4 Ma to 71.6 ± 2.1 Ma, indicating a Late Cretaceous age of emplacement.The deposit comprises an irregular-shaped ring or halo peripheral to a quartz monzonite porphyry dome, or ""cupola': The shape of the ring, and of a smal~ fine-grained quartz monzonite intrusion, and the presence of higher-grade mineralimtion on the eastern flank of the cupola, suggest partial control by a preminera/ structure. The deposit is truncated by a steep, northwesterly dipping, normal fault (Adera Fault) that down-dropped the northern half of the deposit by a minimum of 100 mThe deposit lacks strong zonal alteration but there are narrow envelopes of potassic alteration around some veins and local zones of intense wall-rock silicification. There is considerable retrograde alteration along postminera/ faults and fractures.Molybdenite occurs in veins and fractures, many of which are relatively flat-lying. They occur in all phases of quartz monzonite. Molybdenum is the only element of economic significance. There are vein and skarn occurrences with tungsten, tin, lead, zinc and precious metals peripheral to the deposit.In 1981, Placer Development Limited reported an ""undiluted mineable mineral reserve"" of 151 971 000 tonnes grading 0.063% Mo at a cutoff grade of 0.04% Mo and a strip ratio of 1.5:1."

Jan 1, 1995

By D. Ofstie, B. Kargutkar

BIM, or Building Information Modeling, is transforming the way metallurgical facilities are built, operated and maintained. BIM provides a digital representation of the facility, complete with all physical and functional characteristics - enabling collaborative planning, concurrent design, construction simulation, sustainable operations and predictive maintenance through a connected information model. Building on experience gained in other industries, Hatch is aggressively applying the BIM process to the mining & minerals processing industry to address inefficiencies inherent in traditional document-based information management. Intelligent 3D models support real-time quantity forecasting and cost trending by commodity type and construction work package. By linking procurement and schedule data, material availability and constructability reviews are visualized to verify construction critical path, ensure work front safety and minimize craft downtime. The BIM digital information model connects engineering, construction, commissioning and vendor data, aiding timely asset-centric handover to plant operating and maintenance systems.

Jan 1, 2015

By Rodney S. Read

Both crystalline and sedimentary rocks are being considered to host a deep geological repository (DGR) for nuclear fuel waste in Canada. In the past several decades, considerable research has been conducted around the world to better understand geomechanical processes associated with development and long-term performance of a DGR. The Nuclear Waste Management Organization?s (NWMO?s) technical research and development program is examining a number of potentially suitable rock formations to support implementation of Adaptive Phased Management, Canada?s approach for long-term management of nuclear fuel waste. Rock engineering will play an important role in siting, design, and construction of a DGR for nuclear fuel waste. Post-construction activities such as excavation maintenance, monitoring, decommissioning, and closure will also involve rock engineering. The type of host rock selected for a DGR will influence the scope of rock engineering activities and related research requirements. This paper outlines key rock engineering aspects to be considered in developing a DGR in sedimentary rock.

May 1, 2009

By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By J. H. Pee, Y. J. Kim, H. U. Lee, G. H. Kim

The general recycling process of tungsten scrap to produce tungsten raw materials (tungstic acid, ammonium paratungstate (APT) and WO3) have been carried out by the oxidation, milling, sodium-fusion, dissolution, and extraction processes. Many studies on the high temperature oxidation of tungsten scrap have investigated various aspects such as swelling kinetics, fracture resistance, and the effect of alloying composition. However, the accelerating factors on the scrap oxidation rate during oxidation were not considered here. In general, oxidized products were fused with sodium carbonate or sodium hydroxide to produce Na2WO4. Later in the process, solid Na2WO4 was dissolved in water. This process required considerable reaction time and was a costly process. Therefore, the aim of this study was to increase the solubility of solid oxidized products to produce Na2WO4 solution by hydrothermal reflux method. Na2WO4 solution was used to produce CaWO4 and H2WO4 by general chemical reactions with calcium chloride and hydrochloric acid. Ammonia solution was also added to the tungstic acid to produce APT. In this study, the effect of ammonia addition on the APT precipitation process was investigated in detail.

Jan 1, 2015

By F. Nava-Alonso, E. Pérez-García, A. Uribe-Salas, J. C. Fuentes-Aceituno, A. A. González-Ibarra, E. N. Castillo-Ventureño

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."

Jan 1, 2017

By A. Miura, G. Granata, C. Tokoro, A. Fuwa

"The high copper demand as well as the lack of new high-grade deposits, are pushing the copper industry to process low-grade and refractory ores containing chalcopyrite. However, for a quantitative dissolution of copper from the chalcopyrite, the leaching performances still need to be improved. In the present research, we studied and optimized the iodide-assisted leaching of chalcopyrite in H2SO4-Fe2(SO4)3 media. The evolution of surface species during leaching was determined by x-ray photoelectron spectroscopy (XPS) and mineral liberation analysis (MLA). Inductively-coupled plasma spectrometry (ICP-MS) was used to determine the dissolved copper. Significance of experimental results was assessed by statistical analysis while a kinetic analysis of the leaching process was performed by fitting the experimental data with the Shrinking-core model. Results showed the significant positive effect of iodide on copper extraction rate. In the presence of KI, the dissolution rate of copper was almost double than in the parallel experiments without KI. Whether using KI or not, elemental sulfur was generated on the surface of the leached chalcopyrite. Nevertheless, in the presence of KI, the passivation layer did not arrest the leaching. Analysis revealed that the leaching rate was limited by the chemical reaction control step.INTRODUCTION Due to the large demand of copper, processing low-grade ores containing copper sulfides such as chalcopyrite (CuFeS2) has become unavoidable (Watling, 2013). Since ores with CuFeS2 may also contain appreciable amounts of arsenic that cannot be smelted, and because low-grade ores are uneconomic to smelt, the hydrometallurgical technologies are crucial for recovering the copper (Dutrizac, 1978). Sulfate-based processes are attractive because of the lower operating costs and because the sulfate ion is more suitable in case copper would be recovered via electrowinning. In ferric sulfate solution, chalcopyrite undergoes oxidation due to the large amount of Fe(III) and dissolution due to the presence of the sulfate ion (Majima, et al., 1985). The leaching reaction in ferric sulfate medium can be represented as in (1):"

Jan 1, 2017

By Antonius Prayoga

PT Smelting adopted the Mitsubishi Continuous Technology for its copper smelter plant which has been operating since 1998. Through a series of expansion projects, the plant annual production capacity increased gradually from 200,000 to 300,000 tons of copper. There were no significant modifications for the smelter to reach the 50% additional capacity. It was mostly achieved by intensifying the operation of the furnaces by increasing the oxygen content in the furnaces blowing air. Intensive smelting furnace operation caused shorter campaign life of some furnace refractory, especially the melt zone wall on furnace outlet. During each furnace relining, which is done once every two years, severe wall erosion was found. The worst condition occurred in 2007 when the smelting furnace experienced a melt leak through the eroded wall beneath the bath-line coolers. During the 2008 furnace relining, a modification was performed by installing vertical coolers behind the melt zone wall. Additional vertical coolers were installed during the 2012 furnace relining to extend the coverage area. The modification improved melt zone wall integrity significantly by keeping them safely within the two year campaign life. Recently a modeling study was done to estimate the influences of molten waves on furnace wall erosion. The aim of the study was to predict the impact of blowing parameters, such as blowing air velocity, on the melt wave character and wall erosion.

Jan 1, 2015

By David L. Sprott

This paper presents an evaluation of underground-to-surface haulage options for a relatively large deposit. Specifically, it presents a recommended haulage option to provide the greatest value to the Project. Options considered included conventional truck, trolley-truck, conveying and shaft hoisting. The work was done at the level of a preliminary assessment as input to an internal pre-feasibility study. The Base Case for the analysis in this study was a Long Hole Open Stoping option (LHOS) using conventional truck haulage. Two scenarios were considered for the evaluation and included: 1. The current resource to ~700 m depth. 2. An expanded resource to ~825 m depth. The haulage options evaluated included three trucking options, three conveyor options and two shaft options. The paper presents the results from evaluating these options within the two mining scenarios using a Discounted Project Cost (DPC) comparison. Recommendations are made for the options that will provide the greatest overall value to the project.

May 1, 2008

By Noel Brien, O&apos

General: National Asbestos Mines Limited has operated an asbestos mine and mill near Thetford Mines, Quebec, since 1958. As a result of additional exploration of the orebody in 1962-63, it became apparent that long-range mining plans would have to be revised to allow for a large increase in both ore and waste tonnages. It was decided that the task of checking out possible mine designs could best be analyzed by a computer to obtain data from which an optimum open-pit configuration could be plotted. Object: It was desired to arrive at an optimum open-pit configuration with an over-all pit slope of 45 degrees and a minimum operational width of 200 ft. at the bottom. Calculations were based on assay values from diamond drill holes in cross sections of the mine. The computer's assignment was to select and describe, by coordinates, the optimum cross section for the mine. Mine engineers then assembled the various optimum sections to produce the pit outline. As this would not necessarily result in a practical mining arrangement, the computer also provided alternate solutions,

Jan 1, 1965

By A. Jafarnia

Aluminum alloys are frequently grain refined during solidification in order to promote the formation of an equiaxed grain structure in the casting. The application of Ti-based grain refiners and/or Ti containing master alloys for improving mechanical properties may result in formation of Al-Ti based intermetallics. Although the grain refinement produces many desirable qualities in aluminum castings such as improved castability and mechanical properties, the addition of Ti to Al-Si foundry alloys may lead to the formation of some undesirable intermetallic particles such as AlTiSi and cause a number of operational problems such as nozzle blockage due to segregation and agglomeration of aluminide particles within the nozzle. There are several questions to be clarified when minor amount of Ti is added to Al-Si alloys. They include nucleation and growth of AlTiSi particles, their morphologies and orientation relationships with aluminum matrix and the dissolution of these intermetallics during the course of solidification and/or post solidification treatments. The current study was initiated to study the process and possible mechanism of aluminide dissolution and the related phenomena such as segregation and agglomeration. It reports the results found during reheating of laboratory prepared Ti-added A356 alloy at three temperature ranges of below solidus, mushy zone and above liquidus.

Jan 1, 2004

By Quenton Johnson, W. A. Gough, David Carr

"This paper describes the application of the BrainWave Model Predictive Controller (MPC) and Advanced Control Expert (ACE) Advanced Supervisory Control System on the SAG Mill, Ball Mill, and Rougher Flotation cells for a new gold processing line at the Oceana Gold - Haile Gold mine in Kershaw, South Carolina. For this project, ANDRITZ supplied the control system design and programming, operator-training simulator and advanced control. The advanced control was tested against the IDEAS™ dynamic simulator, and commissioned during the startup of the processing plant to help achieve target production as quickly as possible. Operators were able to run the equipment in a consistent and optimized manner from an early stage of the plant operation, increasing efficiency and profitability. MPC is able to reduce process variability beyond the best performance that can be obtained with conventional Proportional Integral Derivative (PID) control methods. MPC is able to optimize the control of processes that exhibit an integrating type response in combination with transport delays or variable interaction, which are characteristic of many gold processes including SAG mill weight control and Flotation cell froth level control. The experience and benefits of applying MPC during the startup of a new gold processing plant are presented in this paper.INTRODUCTION Mineral processing operations present many challenges for automatic process control due to variations in unmeasured ore properties, material transport delays, and non-linear response characteristics. Advanced process control technologies such as expert systems and multi-variable model predictive controllers are often used to improve the control of these processes to increase productivity and recovery efficiency. Typically these systems are applied after the mine has been in operation for a period of time. For this project, a complete dynamic process simulator was developed using the IDEAS platform for the purpose of training operators before the plant was constructed. Operators were able to become familiar with the process and the control system in order to become proficient in the use of the controls before the plant was ready to start. They were able to practice abnormal condition management including startup and shutdown of the process using the simulator and develop complete Standard Operating Procedures (SOPs) for these situations. The simulator was also used to test the control system functionality and operator Human Machine Interface (HMI) configuration to reduce errors and improve the performance of the control system during plant start-up."

Jan 1, 2017

By M. Gagné, F. E. Goodwin

The mining industry represents a significant investment in infrastructure of which steel plays a key role. Many structures in a mine are made of steel including shaft structures (buntons, station steelwork and headgear); stope structures (roof supports, pipe hangers); haulageway structures (ore transfer stations, electrical stubbies); and surface structures (plant buildings, tank supports, pipe gantries, conveyor belts, stacks, stockpile structures, stairways and railings). Maintenance of structural components can often be difficult because of the environment, including those where corrosive fumes persist, or limited access, such as in shafts where access is limited, or to short maintenance shifts or where limited working space is available. Thus a cost-efficient, long-lasting and maintenance-free protection system for steel should be specified. Galvanizing provides the required high-quality, long-term corrosion protection to steel. Galvanizing provides protection in two ways, first as a physical barrier to corrosion and secondly by means of cathodic or sacrificial protection that is unique to zinc. The dual nature of corrosion protection provided by galvanizing significantly extends the service life of steel even in the most challenging environments. The unique corrosion protection properties provided by galvanized steel will be highlighted with global mining application case studies.

Jan 1, 2015

By Robert B. Parsons

"The February 18, 1987, Federal Budget contains a proposed amendment which would simplify somewhat the ""successor corporation"" rules in the Income Tax Act. Despite this amendment, though, the important successor rules will continue to be relatively complex.IntroductionThe February 18, 1987, Federal Budget papers propose an income tax amendment whereby the so-called ""successor corporation"" rules would be revised by removing the present provision which limits the application of these rules to a maximum of two ""successions"". The successor corporation rules represent one of the most complicated sets of rules in the Income Tax Act. This month, Tax Notes seeks to explain these rules and the proposed amendment in simplified terms.Basically, the successor rules provide a mechanism for transferring unused exploration and development expenses from one taxpayer to another , in specified circumstances. The aforementioned limitation of two successions refers to the rule which allows a maximum of two such transfers with respect to any particular pool of deductions."

Jan 1, 1987

The Curtin University Gold Technology Group has been involved in surveying, modelling and optimisation of batch centrifugal concentrator type gravity circuits and CIP/CIL circuits for nearly two decades. The most commonly asked question regarding gravity recovery is, “What is the benefit of a gravity circuit”, which can be hard, if not impossible, to quantify. With the help of the AMIRA P420 Project’s Integrated Liberation Leach Model (ILLM) it is now possible to evaluate the effect of gravity recovery on total gold recovery when changes are made to the grind size, gravity and/or leach/adsorption circuits. This paper demonstrates how the ILLM can be used to determine the net benefit of introducing or modifying a gravity circuit and assess the effect of operating conditions (grind size, coarse gold size distribution, leach residence time, carbon activity, etc.) on plant performance.

Jan 1, 2017

By H. Al-Kazzaz

The effects of laser power and joint gap on the welding quality of 2-mm butt joints of ZE41A-T5 sand castings were investigated using a continuous wave 4 kW Nd:YAG laser system and 1.6-mm EZ33A-T5 filler wire at a welding speed of 6 m/min and surface defocusing. The smooth weld profiles with the minor welding defects were obtained at a laser power of 4 kW and joint gap of 0.3-0.4 mm. The hardness values in the fusion zone are similar to those of the base metal but there is a drop in the heat-affected zone after a natural aging of 18 months.

Jan 1, 2006

By R. M. de Carvalho

Empirical and phenomenological models of SAG and AG mills have dominated the scene for the last few decades, being used nearly every time a mill is scale-up or an attempt is made to improve its performance. However, in spite of their success, these models fail to describe the details of both the grinding environment and the breakage mechanisms. The result is a generally good track record, with a few – but very important – instances when these models fall short in their predictions, which can be very costly. Further, nearly all of these models require detailed calibration to industrial and pilot plant data, being costly in their application, although still with limited predictive capabilities. Recognizing these challenges, a new model framework has been proposed which overcomes the limitations of currently used models by coupling the microscale population balance model, the discrete element model and functions that describe internal classification at the mill grate. This model framework has already been applied to describe breakage in ball mills, with showing very promising results. However, in the case of SAG and AG mills a much greater level of complexity is involved in the model, given the interaction between the mechanical environment that is formed totally or, in part, by the ore itself, and the breakage response in the mill. The paper describes the model framework, demonstrating how it can address appropriately effects such as mill speed, mill filling and size distribution, on the response from the mill. Some of the advantages of the model are related to its intrinsic multi-component and dynamic nature, which allows simulating appropriately mixtures of ores of different competences in a transient manner.

Jan 1, 2012

By D. N. Thurston

Luscar Stereo commenced construction of the mine at Coal Valley, Alberta, in August, 1976. It is designed to produce approximately 2.5 million clean short tons of steam coal annually - 2.0 million tons per year being committed to Ontario Hydro and 0.5 million tons per year being committed to Neptune Terminals for sale on the export market. The project involves constructing a heavy-media coal preparation plant, erecting a 42-cubic-yard dragline, constructing a shop/office complex, and developing three surface mining zones and associated facilities. As there were no existing facilities in the Coal Valley area, it was necessary to establish access roads, an airstrip, temporary utilities, fuel supplies, a construction camp, rail upgrading and communication services.

Jan 1, 1978