Leaching Alternatives to Recover Gold and Silver from Tellurides

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."