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By Horace Freeman

The sulphur consumed in Canadian pulp mills and acid plants is worth approximately three million dollars annually and amounts to one hundred and fifty thousand long tons, all of which is imported from the United States. Concurrently with a decline in the value of newsprint there has been a gradual increase in the price of this raw material. Most pulp mills in Canada are situated within reasonable distance of domestic pyrite deposits; nevertheless it has not yet been found possible to mine these deposits and utilize the contained sulphur in competition with the imported material. It is the purpose of this paper to elucidate the reasons therefor, and to describe? a commercial-scale experiment undertaken with the object of introducing a native raw material into the Canadian pulp industry on the purely economic basis. Reasons for the Preferred use of Sulphur The known sulphur deposits in the United States are very large, so that at least a twenty-year supply of this material is assured. It is recovered cheaply and in pure condition. Although large deposits of pyrite are known in Canada, nothing has yet been developed to compare in size, cost of mining, or purity with the United States material. It has been necessary to handle and transport more than two tons of pyrite to equal a ton of sulphur.

Jan 1, 1930

By Bradley Stoughton

It is very easy to reduce iron ore at a temperature well below its melting point and produce a more-or-less-pure metal which can be used directly for implements, tools, or machines. This simplicity has been the cause of much money loss by persons who were so satisfied with the successful operation of a process that they paid all too little attention to the commercial aspects of it. How easy a direct process is may be gleaned from the fact that it was practised with some -success by primitive man, and has been in almost continuous operation in one form or another for a period of probably 4,000 years. The production of steel in ton lots, beginning about 1860, brought a new phase into the economic situation, which, however, had been already greatly modified in 1784 by Henry Cort's invention of purifying pig iron. Direct processes survived both of these revolutions, under special geographical conditions, even up to the last few years of the nineteenth century, but ceased to have any general use as the basis of supply for structural, machine, or tool industries even in countries which could have manufactured iron by a direct process, but, instead, imported the product of established iron and steel processes. And this is still the situation today, notwithstanding the invention of an incredible number of 'new' processes since 1900, most of which are abandoned, and only survived as along as their financial backers were willing and able to Jose money. Probably none of these processes failed to work pretty well, and all seemed to show a handsome profit on paper.

Jan 1, 1930

By Mory Ghomshei

As fossil fuels become depleted over the next century, it is imperative that Canada and other countries examine ways to transition to other sources of energy, particularly renewable resources. A critical obstacle to developing Canada?s renewable energy resources is the scarcity of infrastructure to wheel the generated electricity to a viable market. For each megawatt of renewable electrical power, a maximum of 1 km of connecting power line is typically feasible. This means that hydropower, geothermal, and wind power projects with capacities up to 100 MW must be located within a maximum of 100 km of a main power line in order to be economically viable. With a total length of about 1200 km, the proposed Northern Gateway oil pipeline project creates an excellent opportunity to become a corridor that can seed renewable energy projects in Northern British Columbia and Alberta. Utility companies must build new infrastructure to provide the electricity for constructing and operating the proposed pipeline. The pipeline and linked power line infrastructure therefore, should be designed and built with consideration to create an energy highway to the significant renewable energy resources, such as hydro, wind, and geothermal, in the vicinity of the proposed pipeline. Some of the important renewable energy resources in northern British Columbia can be developed in connection with the proposed pipeline. It is estimated that close to 2,500 MW of commercially viable wind, geothermal and run-of-river power resources are present in the proximity of the proposed pipeline corridor. While oil flows westward from the Alberta bitumen fields, the generated green power can flow eastward to help the Canadian oil sand industry to offset as much as 10 Megatons of carbon emissions per year. The generated carbon credits are equivalent to 75% of the emissions associated with extraction of the 525,000 barrels per day of oil from oil sands, intended to be carried by the pipeline.

Aug 1, 2013

By Derek Perkins

"Brenda Mines Ltd. operates an open pit copper and molybdenum mine located in south central British Columbia. The main economic mineralization is chalcopyrite and molybdenite. Pyrite, galena and sphalerite are also present in varying quantities. The mineralization is present in small veins and fractures in a porphyritic quartz diorite host rock.The mill processes approximately 30,000 tonnes of ore daily. The ore is crushed in three stages and then ground in conventional rod mill - ball mill circuits with cyclone classification. The cyclone overflow is fed to the bulk flotation circuit as a pulp with a density of 50% solids. The particle size distribution is approximately 35% plus 65 mesh. Bulk rougher and cleaning flotation produce a concentrate grading approximately 20% copper and 4% molybdenum. This concentrate is fed to the separation circuit, where the copper is depressed with sodium hydrosulphide and the molybdenum is floated. These products are further ground and then upgraded by column flotation. The molybdenum concentrate is pumped to the leach plant to reduce concentration of lead and copper. It is then washed, filtered, dried and packed for shipment to Europe. The copper concentrate is filtered, dried and subsequently shipped to Japan.Prior to November 1977, the mill flotation control was carried out by the assay laboratory using a Philips PW 1540 sequential x-ray spectrograph. The assay set consisted of twelve samples, analysed on a two hourly basis for copper, molybdenum, lead, iron and silica.In order to provide elemental composition information on a much shorter sampling interval and to produce speedier control analysis for automating process control, an Applied Research Laboratories PCXQ on stream analyser was purchased. The installation of this analyser, reduced the turnaround time of the control analyses from (2) hours to (20) minutes. At Brenda, the following assays are used in the mill control strategies."

Jan 1, 1989

By R. Hendricks

"IT IS a pleasure for me to appear before yon today and to have this opportunity of reviewing with you recent developments in the world lead and zinc industry. To provide essential background material, I propose reviewing the period from 1950 to the present, a period which has undoubtedly been the most hectic in the long history of the industry.In capsule form, the pattern for this period is one of repeating cycles of boom and recession, of failure through research to develop adequately new markets and new uses for lead and zinc, of surplus production and growing inventories, of price instability, and lastly, of an abdication in some sections of the industry of responsibility for control of its own destiny by turning to governments for support in time of stress. This is not a pretty picture but, as the 1950 decade ends, there are signs of a new maturity and of a growing determination on the part of the industry to put its own house in order.The difficulty suffered by the world's lead and zinc industry in the current decade originated with the support extended to it in 1950 by the U.S. Government at the time of the Korean conflict. Recalling the shortage of base metals in World War II and fearing that the Korean conflict might develop into World War III, the U.S. Government in 1950 adopted a policy to encourage the production of lead and zinc, both domestically and abroad by means of development loans and long-term floor priced purclu.se contracts."

Jan 1, 1960

By A. W. Lovett

"THE last two years have been years of recession or, perhaps, years of marking time, depending upon whether the observer is a pessimist or an optimist. There has been a slackening in the industrial tempo that has been reflected in many ways in the national economy. As one of the chief barometers of economic health, the consumption and supply of energy reflect this slowing up.These same two years have also seen significant changes in the relation between the sources of energy. In periods of declining demand, it has happened in the past that coal, as the basic or residual source of energy, has shown the effects to a greater extent than the other energies. In these two years, however, in addition to this usual effect, there has been the acceleration in the Joss of market to diesels in the railway consumption category and the continuing decline in domestic consumption. The story of these years is presented in the statistical tables that form the foundation of this paper. Statistics, particularly in the form of tables, are rather dry and are sometimes difficult to follow but the overall developments are illustrated by graphs which present a more striking picture."

Jan 1, 1959

By C. W. Drake, J. H. Walsh

"The Canadian Carbonization Re-search Association was formed during 1965, with seven founding members representing four integrated steel companies, two coal companies and one high-temperature tar processing company. The purpose of this paper is to review the circumstances which led to the formation of this new research association and to discuss its general objectives. Also discussed will be the organization of the Association, the nature of its relationship with the Department of Energy, Mines and Resources in the early stages, and some of the technical programs which have now been initiated."

Jan 1, 1967

By F. E. Millett

The following notes deal chiefly with changes from steam to electric drives, or, in the case of the Bellevue pumps, from air to electric. Where electric power can be purchased or generated cheaply it can be used to advantage and is generally more economical than steam, especially in places remote from the central power-plant. Nothing could be more simple than the operation of electrical gear. It does not require a competent engineer constantly on the alert, oiling and watching bearings, and maintenance is at a minimum. The ease with which the current is transmitted from its source to where it must do its work is one of its greatest advantages. Transmission losses are very low. Generally speaking, the smaller the plant the lower the loss and 90 per cent, and better, efficiency is easily attained. In and around Bellevue 2300-volt, three-phase, is the standard distributing pressure; our power requirements and the distances transmitted, for the present, do not require more than this. Most of the heavier motors are 2300-volt .machines, which eliminates the cost and possible troubles of step-down transformers, and makes for a cheaper and less bulky motor. This applies to two fan, two hoist, and two compressor motors, the smallest being 75 and the largest 520 horse power. The standard pressure on power lines to all inside pumps is 550 volts, and 220 volts is general for the the tipple. While 110 volts is used for house and office lighting service, it is not economical around and in the mine. No matter what kind of device is used to lock and protect the lamps, they are invariably missing.

Jan 1, 1926

By John A. Teeter

"A SHORT WHILE AGO I enquired about The Mining Society of Nova Scotia. In all honesty I was apprehensive about addressing such a body if it was highly geared to the technical aspects of discovering and obtaining mineral resources. I was told that this would not be the case. Rather, there would likely be in attendance a broad cross section of people from business, industry and government and from across Canada and the U.S.A. Thus there would be an interest in a free-wheeling discussion of the prospects for industrial development in Cape Breton. Accordingly - being one who hates to miss an opportunity - I intend to exploit the invitation of your executive by being, over the next short while, frankly promotional. I would like to talk about what I consider to be some of the most important attributes of Cape Breton for industrial development and identify some of those prospects. Secondly, I will quickly review some of the things the Cape Breton Development Corporation is doing these days to stimulate some of that industrial development."

Jan 1, 1972

By Gordon L. Draeseke

"Before getting into more specific aspects of my talk today I should put in one disclaimer - one week in Mainland China and one day with Premier Kosygin does not make me an expert on Sino-Soviet affairs nor on Canadian-Chinese relations. Perhaps though there is a message in the fact that one meeting took place in relative openness in China and the other was at least partly in a bullet-proof limousine in Canada. I thought it might be interesting and appropriate to explain something of the forest industry to you who are engaged in the mining industry. Our industry, like yours, is based on a natural resource and the basic activity that we engage in is the extraction and conversion of that resource into saleable materials. However, the fundamental difference between our industries is that our resource is on top of the ground - easily visible and easily measurable, whereas yours is under the ground - difficult to find and, having been found, expensive to measure. A second difference is that ours is renewable while yours is extractive, and you must keep finding more to keep up reserves."

Jan 1, 1971

By Howard W. Tipper, Richard B. Campbell

"The Quesnel Trough is underlain by a thick sequence of mainly Upper Triassic and Lower Jurassic volcanic-clastic and sedimentary rocks that lie between the highly deformed Proterozoic and Paleozoic rocks in the Omineca Geanticline to the east and the Upper Paleozoic Cache Creek Group in the Pinchi Geanticline to the west. Broad areas of the Trough between Kamloops and Williams Lake are covered by Eocene volcanics and sediments and by Miocene-Pliocene plateau lava. Granitic intrusions were apparently mainly confined to two major episodes; one about 200 m.y. ago (coeval with the Guichon batholith) and one about 100 m.y. ago. In addition, the region includes small granitic and syenitic intrusions, some porphyritic, that may be all or partly still younger. Exposures in the region are generally small and scattered, obscured by widespread, not necessarily thick glacial deposits. This, together with the extensive Tertiary cover, makes prospecting difficult. The part of the Quesnel Trough discussed here is the direct northwest-ward extension of the copper-rich Kamloops-Merritt-Princeton region. It contains the Boss Mountain molybdenum mine, related to a breccia zone induced in a batholith of the oldest group by a younger intrusion, and the Cariboo Bell copper deposit in Lower Jurassic volcanic-elastic rocks and syenitic intrusions. The Gibraltar deposit, in a 200-m.y. intrusion, is within the Pinchi Geanticline close to the margin of the Trough. Molybdenum prospects are mainly restricted within or near the 100-m.y. granitic rocks. Copper prospects, on the other hand, are most prominent in the volcanic-elastic rocks and in the 200-m.y.-old granitic rocks, although they can also be spatially related to younger intrusions. Copper thus has a wide potential distribution.The writers believe that the region is deserving of careful and comprehensive exploration by directly applying the knowledge and techniques developed in the important producing areas to the south. All of the major pre-Tertiary geological elements seem to have potential for mineral deposits; none should be ignored. A thorough knowledge of the thickness and distribution of the Tertiary rocks and the development of geophysical methods to ""see through"" them is of particular importance."

Jan 1, 1970

By K. E. Waters, M. Mirnezami, R. Gauvin, A. Jordens, K. W. Malas

"There is currently very little information on the physico-chemical properties of rare earth elementbearing minerals, or on their processing. With the increasing demand for rare earths, this is something that needs to be addressed. This paper introduces some surface chemistry analysis of fergusonite (YNbO4), and the bubble-particle attachment. Zeta potential measurements indicate adsorption of sodium oleate and, to a lesser degree, potassium amyl xanthate onto the surface, and an increase in attachment to an air bubble is observed at pH 4.5 and 6.5. At a pH of 10.5, no attachment is observed, whether in the presence of the reagents or not. This analysis, although initial, will be used to initiate flotation tests, in order to facilitate the selective recovery of fergusonite. INTRODUCTIONRare earth elements (REE) are increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. An article in the New Scientist highlighted the importance of a number of REE, many of which most people are be unlikely to have heard mentioned (Crow, 2011). From batteries (lanthanum and cerium) to magnets (dysprosium and neodymium) and lighting (yttrium), the REE are crucial to the advancement of technology and energy saving devices. For example, neodymium is finding most use in the high end magnets that keep the motors turning that power wind turbines and electric cars. In the case of yttrium, the demand outstripped the supply in 2010, emphasising the need to develop deposits containing this and other REE (Crow, 2011). The impact of our dependency on REE has become even more apparent with the reduction in exports by China, which currently controls 97 % of the world’s rare earth production (Pitts, 2011).With the increasing demand for rare earth elements (REE), there is a drive to exploit the known resources around the world. However, the physical beneficiation of the rare earth element bearing minerals is a subject which will require a great deal of investigation to fill the knowledge gaps surrounding these developing rare earth projects. There are numerous articles on REE mineralogy as well as the hydrometallurgical processing of REE concentrates (Alex, Suri, & Gupta, 1998; Peter Gromet & Silver, 1983; Ring et al., 1993; Schnetzler & Philpotts, 1970; Uda, 2000), however a common feature amongst these resources is the lack of detailed descriptions of the physical beneficiation processes required to concentrate REE-bearing minerals. There is work being conducted into reagents and methods for use in recovering some rare earths from their associated ores (Bulatovic, 2010; Ni, Parrent, Cao, & Liu, 2011), but much more in-depth research is required."

Jan 1, 2012

By G. B. Bosworth, M. J. Lake, J. W. Hogg

The Quintette Coal operation in northeastern British Columbia has one of the world's largest Preparation Plants, with a design capacity of 6.5 million tonnes per year of clean coal.This paper will discuss several innovative aspects of the flowsheet and plant design with particular reference to the selection of process equipment, materials handling and control systems.The operations and maintenance experience during the first two years of production will be described and discussed in relation to the design objectives.

Jan 1, 1987

By D. Asefi

A new method to detect microstructural features such as recovery and recrystallization as well as cold rolling reduction in low carbon steels was developed based on magnetic hysteresis loop measurement. To this aim, a hysteresis loop measuring apparatus, specifically designed and assembled for plate samples was employed. It is shown that maximum field (Hmax) of hysteresis loop, measured at constant maximum flux density (Bmax) of 0.5T, is an adequatemagnetic property to monitor different stages of changing microstructures during annealing.

Oct 1, 2011

By J. Trojacek

A large-scale development in exploration and production of uranium ores in the Czech Republic was done in the 2nd half of the 20th century. Many uranium deposits were discovered in the territory of the Czech Republic. Over a period of 50 years approximately, 110 000 tons of uranium in concentrate were produced. Different mining methods were developed and used. One of the most considerable deposits in the Czech Republic is the site Hamr na Jezere ? Straz pod Ralskem where both mining methods ? the underground mining and the acidic in-situ leaching ? were used. The extensive production of uranium led to widespread environmental impacts and contamination of groundwaters. Over the period of ?chemical? leaching of uranium (ca. 32 years), a total of more than 4 million tons of sulphuric acid and other chemicals have been injected into the ground. Most of the products (approximately 99.5 %) of the acids reactions with the rocks are located in the Cenomanian aquifer. The contamination of Cenomanian aquifer covers an area larger than 27 km2. The influenced volume of groundwater is more than 380 million m3. The total amount of dissolved SO4 2- is about 3.6 million tons. Approximately 0.5 % of the contamination is located in the Turonian aquifer. After 1990, a large-scale environmental program was established and the Czech government decided to liquidate the ISL Mine and start the remediation in 1996. The remediation consists of contaminated groundwater pumping, removing of the contaminants and discharging or reinjection of treated water. The objectives of the remedial activities are the followings : to restore the aquifer to a condition guaranteeing continuing usability of Turonian water of Northern Bohemia Cretaceous, to decommission boreholes and surface installations and to incorporate the surface of leaching fields into the ecosystems taking into account regional systems of ecological stability and urban plans. Nowadays four main remedial technological installations for reaching of these aims are used - the ?Station for Acid Solutions Liquidation No. One?, the ?Mother liquor reprocessing? station, the ?Neutralization and Decontamination Station NDS 6? and the ?Neutralization and Decontamination Station NDS 10?. Total capacity of this complex is sufficient to reach the target values of remedial parameters in 2037. The remediation action consists of: pumping of residual solution to the surface, separating uranium from the solution and reprocessing contaminants into commercially usable or ecologically storable products. It is expected that the amount of withdrawn contaminants will vary from 80 000 to 120 000 tons per year. Total costs of all remediation activities are expected to be in excess of 1.5 billion EUR.

Aug 1, 2013

By S. R. McCutcheon, D. R. Lentz

"Abstract - The 12.1 Mt Brunswick No. 6 Zn-Pb-Cu-Ag massive sulfide deposit (New Brunswick, Canada) lies between two subaqueous felsic volcanic formations near the base of the Middle Ordovician Tetagouche Group. The footwall comprises rhyodacitic pyroclastic rocks (Nepisiguit Falls Formation), whereas the hanging wall comprises a sequence of rhyolitic flows, breccias, and hyaloclastites (Flat Landing Brook Formation), with an age difference of less than 3 m.y. The Brunswick No. 6 deposit is a proximal autochthonous deposit with a well-zoned massive sulfide body and a basal Cu zone that, at depth, develops into a stockwork stringer sulfide (feeder) system. The massive sulfides are capped sharply by a layered magnetite-chert unit that extends regionally beyond the deposit. The deposit has a keel shape (sheath) formed by the F1F2 interference pattern. The heterogeneous ductile deformation and upper greenschist-grade regional metamorphism has transposed many of the epigenetic stockwork structures and alteration within the host sequence. Hydrothermal alteration is much more extensive, both vertically and laterally, in the footwall (a few 100 m) than in the hanging wall (<100 m). Anomalies farther up in the hanging wall sequence seem to be associated with independent alteration systems related to the rhyolite domes. The least-altered footwall units exhibit keratophyric alteration (albite or adularia) and weak Mg enrichment (chlorite). More intense micaceous (sericite and Mg-rich chlorite) alteration occurs around the footwall sequence. The transposed stockwork stringer sulfides are typically composed of Fe-rich chlorite (± sericite, ± silica) with pyrite, pyrrhotite, chalcopyrite, arsenopyrite, and sphalerite. The (Fe2O3T+MgO)/(Na2O+K2O) and base metal alteration indices are the best practical lithogeochemical vectoring tools at this deposit. Sommaire - Le gîte de 12.1 Mt de sulfures massifs de Zn-Pb-Cu-Ag Brunswick No.6 est localisé entre deux formations volcaniques felsiques sous-marines situées près de la base du Groupe de Tetagouche d’âge Ordovicien Moyen. Le mur consiste en roches pyroclastiques rhyodacitiques (Formation de Nepisiguit Falls) tandis que le toit consiste en une séquence de coulées, de brèches et d’hyaloclastites de composition rhyolitique (Formation de Flat Landing Brook); la différence d’âge entre les deux est de moins de 3 m.y. Le gisement Brunswick No. 6 est un gîte autochtone proximal comprenant un corps de sulfures massifs clairement zoné ainsi qu’une zone cuprifère basale qui passe progressivement à un stockwork de filonnets de sulfure en profondeur (feeder). Les sulfures massifs sont abruptement surmontés d’une unité laminaire de chert et de magnétite dont l’extension par delà le gisement est régionale. Le gisement affecte la forme d’une quille (fourreau) résultant d’un patron d’interférence F1F2. Plusieurs des structures épigénétiques du stockwork et des patrons d’altération de l’encaissant ont été transposés par la déformation ductile hétérogène ainsi que par le métamorphisme régional au faciès des schistes verts. L’altération hydrothermale est beaucoup plus importante, tant verticalement qu’horizontalement, dans le mur (quelques 100 m) que dans le toit (<100 m). Les anomalies situées plus haut dans le mur semblent être reliées à des systèmes d’altération indépendants associés aux dômes de rhyolite. Les unités les moins altérées du mur une altération kératophyrique (en albite ou en adulaire) ainsi qu’un faible enrichissement en Mg (chlorite). Une altération en mica (séricite et chlorite magnésienne) plus intense est présente autour de la séquence du mur. Les sulfures du stockwork de filonnets transposés consistent typiquement en chlorite ferrifère (± séricite, ± silice) accompagnée de pyrite, de pyrrhotite, de chalcopyrite, d’arsénopyrite et de sphalérite. L’indice d’altération (Fe2O3T+MgO)/(Na2O+K2O) et l’indice des métaux usuels sont les outils d’exploration les plus appropriés dans ce gisement."

Jan 1, 2006

Stellite-6 coatings were formulated on two Ni-base superalloys, namely Superni 75 and Superni 600, by a shrouded plasma-spray process, and the oxidation behaviour of these coatings has been investigated in air and in an aggressive environment of Na2SO4- 60%V2O5. Accelerated oxidation tests were conducted in a silicon-carbide tube furnace under cyclic conditions at an elevated temperature of 900°C for 50 cycles. Each cycle consisted of 1 h heating and 20 min cooling in air. A thermogravimetric technique was used to approximate the oxidation kinetics. The corrosion scales were characterised by XRD, SEM/EDAX and EPMA analysis. It has been observed that the coatings nearly followed the parabolic rate law of oxidation. Overall weight gain conceived in air was just 51% of that in the aggressive environment in the case of coated Superni 75, whereas in case of coated Superni 600, the cumulative weight gain in air was found to be one-third of that in the Na2SO4-60% V2O5 atmosphere. Furthermore, the coating showed very good adherence to both of the substrates during the course of air oxidation, whereas some superficial cracks were observed near the edges of the specimens during the molten salt induced oxidation. XRD analysis revealed the presence of phase-like CoO, CoCr2O4 and Cr2O3 in the oxide scales, which are reported be protective against high-temperature oxidation. The XRD results were further supported by SEM/EDAX and EPMA.

Jan 1, 2005

By S. V. Ulianov, A. Y. Senchenko, A. A. Shvets, A. V. Aksenov

Development of an efficient technology to process complex ores containing gold and antimony as well as silver is described in the paper. The results from the testwork aimed at the valuables recovery by means of flotation are presented. A process sample of antimonite gold-bearing ore was studied in TOMS institute aiming at development of a technology to process such an ore with generation of antimony concentrate and sulphide gold-containing concentrate. Material composition study indicated that the ore included 5.3% of sulphides: arsenopyrite – 2.4%, pyrite -2.4%, and antimonite – 0.5%. Gold is present as an isomorphic dissemination in arsenopyrite. At sighter testing stage a direct selective flotation flowsheet was chosen to process the ore. Antimonite flotation was activated due to addition of lead nitrate. A single cleaning of a rougher flotation concentrate resulted in antinomy concentrate with 30% Sb content and 71% recovery. Au recovery into antimony concentrate did not exceed 1%. Sb flotation tailings were used to float the remaining sulphides and gold. The resulted sulphide concentrate was characterized by Au content of 20 g/t at about 80% recovery, arsenic content - 10% at ~80% recovery, and sulphur content - 18% at ~81% recovery. The sulphide concentrate can be forwarded to further processing aiming at gold recovery. Given that the concentrate is highly refractory it should be pretreated (bacterial or pressure oxidation, Albion process) prior to cyanidation in order to liberate gold from sulphides. The proposed technology allows one to solve the problem of precious metals recovery from antimonite ores.

Jan 1, 2016

By S. Hunt, S. Jayasekera, J. Kyle, N. Perera, K. Stone

A preliminary investigation has been conducted to determine the conditions for the precipitation of phosphate from the liquor produced after a hydrochloric acid pre-leach and rare-earth recovery from a rare earth containing fluorapatite concentrate from the Nolans rare earth deposit in the Northern Territory of Australia. The results show that at 50oC the phosphate can be precipitated in two stages using limestone to produce a Stage 1 precipitate containing most of the impurities including iron (94%), aluminium (92%), fluoride (98%), uranium (84%) and thorium (94%), followed by a relatively pure Stage 2 dicalcium phosphate precipitate (DCP) containing only 0.05% Fe, 0.05% Al, 0.1% F, 0.01% U, and <0.01% Th. The initial Stage 1 precipitate contained about 25% of the phosphate while the remaining 75% reported to the Stage 2 phosphate precipitate. Depending on the required radioactivity specifications, the amount of phosphate in the Stage 1 precipitate could be reduced. Reagent requirements were 11.4 kg limestone (as pure CaCO3) per cubic metre of solution for the Stage 1 precipitate and 39.7 kg limestone (as pure CaCO3) per cubic metre for Stage 2. The analysis of radionuclide balance indicated that radionuclides deported mainly to the final filtrate (86.4%) compared to Stage 1 precipitate (5.4%) and Stage 2 precipitate (8.2%). Settling and pressure filtration tests indicated the precipitates were both readily settled and filtered. The final moisture contents of the Stage 1 and Stage 2 precipitates were 62.5% and 49.3%, respectively.

Jan 1, 2014

By T. R. C. Aston, C. M. K. Yuen, J. L. Gilby

"The access tunnels for the Donkin-Morien Mine in Cape Breton, Nova Scotia, comprise two parallel tunnels driven through a sedimentary sequence of sandstone, siltstone and mudstone to intersect the Harbour Coal Seam under the Atlantic Ocean, approximately 3.5 km offshore (Fig. 1). The No. 2 tunnel was driven a total distance of 3579 m using a 7.6 m diameter Loyat full-face tunnel boring machine (TBM) and was supported by steel sets. The No. 3 tunnel was initially driven a distance of 1027 m using drill and blast methods (dimensions 7.6 m wide by 5.3 m high) supported by rock bolts and shotcrete. This tunnel was then completed (front March 1986 to February 1987) using the tunnel boring machine to a distance of 3573 m.During the period May 1983 to December 1984, a major geotechnical research program was undertaken in the Donkin-Morien tunnels by Golder Associates in conjunction w,ith CANMET and the Cape Breton Development Corporation (Yuen et al., 1985). The research program included the monitoring of the performance of the TBM and drill and blast drivages, and the study of the thrusting characteristics and rock-interaction of the TBM excavation. The main emphasis of the research program was on the collection of field data which was to be made available in the form of a comprehensive report for the future use of others who might wish to carry out a detailed interpretation and analysis. The information gained from the program was also used during the tunnel"

Jan 1, 1988