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By D. Van Tonder, C. Edwards

ABSTRACT Solvent extraction is used in many acid leach uranium circuits to upgrade and purify the uranium-bearing solution prior to final product precipitation. A number of strip options are available to recover the uranium from the loaded organic. This paper compares seven of these options on the basis of typical capital and operating costs for the solvent extraction circuit and downstream uranium processing and also considers other related issues. The aim is to provide an objective comparative assessment of these options that could be used as a qualitative guide in process selection or improvement.

Jan 1, 2013

By A. C. Ross

"The paper will deal with non-destructive testing in general, and its advantages to those responsible for the maintenance of wire rope. An outline of the main features of the M.D. 6 Defectograph will be given, and the method of operation and results obtained will be described.The instrument will accommodate ropes at 7 /16-to 2 %-inch diameter at reasonable speeds, and is capable of detecting the most minute defects in even the largest-diameter wire ropes."

Jan 1, 1969

By R Zavadil, S Kuyucak, F Fazeli

Proton exchange membrane (PEM) fuel cells generate electricity by reacting hydrogen and oxygen. A thin, bipolar electrode material provides a medium for electron exchange with the electrolyte, alternately serving as anode at the hydrogen-rich side and cathode at the oxygen-rich side. Stainless steels have sufficient corrosion resistance to qualify as bipolar plate materials. However, the protective chromite layer increases the contact resistance, the battery’s internal resistance; and thus, decreases the electrical efficiency of the fuel cell. A heat-treatment is proposed and investigated via simulation by ThermoCalc / Dictra and experimentally, to generate a sufficient quantity of conducting surface carbides that breach the protective layer. Once carbide growth is arrested, a subsequent heat-treatment is also needed at a higher temperature to restore the corrosion resistance by filling-in the Cr-depleted layer (sensitization) around the carbide particles.

Jan 1, 2014

By J R. O Walli

Large production shafts can be successfully sunk through the ubiquitous Blairmore formation of southern Saskatchewan by employing the freezing process and by the installation of a cast iron tubbing lining. Although the freezing technique for shaft sinking and the use of cast iron tubbing to preserve the shaft are new to the North American continent, these procedures have been employed in Europe for the past eighty years. More than 200 shafts, covering a wide variety of ground conditions, have been sunk by the freezing process, and most of these have been lined with cast iron tubbing. The No. 1 shaft of International Minerals and Chemical Corporation, near Esterhazy, Saskatchewan, comprises the first major example in Canada of the employment of European methods to overcome extremely difficult ground conditions. The Blairmore formation was solidified by the deep freezing process, employing a lithium chloride solution as the refrigerant, with input temperatures ranging to -55°F

Jan 1, 1964

By D. Krippner, C. Nexhip, D. George-Kennedy, P. Gebski, R. Kaur, W. L. Ying

ABSTRACT Water-Cooled Tapblocks Are Essential Components Of Modern Smelting Furnaces. Uninterrupted Operation Of A Tapblock Is Critical For The Optimal Operation Of A Furnace. This Critical Function, Together With Exposure To Extreme Conditions, Drives The Need For An Efficient And Reliable Means For Tapblock Monitoring. The Main Objective Of Tapblock Monitoring Is To Help Optimize The Life Of The Tapblocks By Better Scheduling Inner Refractory Relining And Protecting Operators By Preventing Sudden Deterioration Of The Tapblock. A Taphole Acoustic Monitoring (TAM) System Was Developed To Meet The Above Requirements. This Paper Describes The Principles Of The TAM System And Selected Case Studies.

Jan 1, 2013

By J. Suarez Condezo, E. Herrera Alarcon

The Ilo Smelter Modernization Project will require treating the slag from the Peirce Smith converters in Slag Cleaning Furnaces using pig iron technology. Currently the slags from the converters show variable magnetite contents. The copper contained in this slag is recovered in Reverberatory Furnaces, where the smelting rate was improved due to the high silica content of the converter slag. Preliminary industrial tests where developed to clean the slag from converters using pig iron. The results showed that the magnetite content has a significant influence in this process. This work describes the actions that are being implemented in the converter operation to control the magnetite content in the slag in order to maintain the high copper recovery of the smelter when the new facilities are commissioned. This task will demand a strong control of both the slag chemistry and converter practices in order to get the copper recovery considered as the design criteria (~97.4%).

Jan 1, 2007

By M. S. Moats, F. Elnathan

"The effect of current reversal on two commercially manufactured electrodes (RuO2-TiO2 and IrO2-Ta2O5 coated Ti) in a chloride bearing electrolyte was evaluated. Accelerated lifetimes were found to decrease with increasing current density and increasing reversal frequency. Ru: Ti coated electrodes exhibited longer lifetimes than Ir: Ta coated electrodes even though they had one-third as much precious metal content. Chloride concentration did not affect lifetime in the range examined. Using energy dispersive X-ray spectroscopy (EDS), scanning electron microscopy (SEM) and electrochemical impedance spectroscopy (EIS), the failure mode of the electrodes was determined to be coating dissolution leading ultimately to passivation by the presumed growth of a highly resistive oxide at the coating/substrate interface.INTRODUCTIONCatalytic titanium anodes (CTAs) were developed in the 1960’s to replace graphite anodes in chlor-alkali cells. CTAs exhibited much better dimensional stability than graphite leading to lower operating potentials by promoting smaller electrode gaps and better operational efficiencies as they had to be replaced less often. CTAs are simply Ti substrates coated with precious metal oxides (such as IrO2 and RuO2) mixed with other components (such as TiO2 and TasO5) (Trasatti, 2000).CTAs are used in many other electrochemical industries, including water disinfection, wastewater treatment, cathodic protection and metal plating. RuO2 based coatings are typically used for chlorine evolution. IrO2 based coatings are for the most part utilized for oxygen evolution (Comninellis & Nerini, 1991; Forti, Olive, & De Andrade, 2001; Kotz, Stucki & Carcer, 1991; Trasatti & Lodi, 1981)"

Jan 1, 2016

By J. Peterson

A review of blast designs and improved blasting practices at the Ekati??Diamond Mine is presented along with the results of three blast-monitoring experiments. Blast monitoring was undertaken to investigate blast damage mechanisms in the mine's well jointed rock mass. Rock mass damage caused by production, pre-shear and wall control blasts was measured. Ekati??uses 270mm holes for production blasting, and 165mm holes loaded with a decoupled charge for pre-shearing. The production blasts are loaded with bulk emulsion / ANFO blends. The mine plan involves using 30m double benches. A 30m high pre-shear is drilled and blasted prior to the production blasting that is done with sequential 15m benches. This paper summarizes the monitoring equipment and data gathered to date.

May 1, 2001

By Ian McC. Stewart

"Seam gas flow in coal mines takes place through a medium which has both capacity and resistance and can therefore be expressed in terms of the basic diffusion equation, provided that the characteristics of the system can be adequately described. It may be possible to lump the variations from point to point in a seam together as an effective diffusivity. The paper discusses the characteristic flow-time patterns for various types of openings and the particular features of coal and seam which influence the diffusivity.Two field experiments are described in which gas make to a heading and to a borehole were measured in a mine for which considerable data on coal sorption properties were available. Incremental gas flow measured from the borehole experiment predicted the actual flow from the heading measurements remarkably well. The effective permeability adjacent to the face was much higher than expected from the properties of the coal. The incremental flow measurements to a horizontal (in-seam) borehole showed a striking picture of advancing 'relaxation' behind the face which is not discernible by other experimental means."

Jan 1, 1971

By C. Hilgendorf, J. Gingerich, J. R. Boniwell, M. Drouin, D. David on, J. Boldy

The initial discovery of gold in the Eastmain River area, 310 km northeast of Chibougamau, was made by Placer Development Limited in 1970. This discovery resulted from the drill testing of an airborne E .M. Target located in an area of extensive glacial overburden, within an unexplored Archean greens tone belt considered prospective for base metal deposits. Intermittent exploration by another company between 1973-1977 failed to obtain promising results and the existing claims were allowed to lapse. In 1981, Placer reactivated the project and initiated intensive exploration during the next two years which included aerial E .M. surveys, claim staking, ground E .M. and magnetic surveys, geological mapping, diamond drilling and attendant borehole P,E.M. surveys. Beginning in 1983, exploration has been conducted on a joint venture basis with Eldor Resources Limited, The greenstone belt under investigation has an arcuate distribution pattern relative to a centrally located granitic core. Occurrences of gold mineralization defined to date are located to the south of the granite along a strike length of 7 km, and appear to be restricted to the lowermost of two mafic volcanic cycles. This lower cycle is dominated by basaltic flows with subordinate rhyolitic flows and pyroclas ties. Concordant, variably magnetic, massive to talcose ultramafic units occur towards the stratigraphic top of the lower mafic volcanic cycle and appear to crudely define areas considered prospective for gold on a regional bases. Economic interest in centered on a s tratabound, siliceous, sulphide-bearing unit hosted in a 15- 25 metre thick sequence of rhyolite tuffs, basalts and intercalated ultramafics, The siliceous ore bearing unit ( interpreted as a recrystallized chert) contains from 10%-30% pyrrhotite and pyrite with subordinate chalcopyri te and minor sphaleri te. Alteration is characterized by mica development, silicification and carbonatization. Garnets are also occasionally present in close proximity to the ore horizon. The sequence is south facing, and overturned to the northeast at 35°-55°. Explora tory drilling in the vicinity of two conductive targets has been on 100 metre centres along a 1 km strike length of the prospective sequence. To the end of 1983, two ore zones (A and B) have been partially drill tested with estimated indicated and inferred geological reserves of 1 million tonnes grading 11.7 g/t gold , 14.7 g/t silver and 0.26% copper. The system is open at depth. This discovery is the result of the effective integration of geophysics and geology with contributions by many over a long period of time. Key events that can be emphasized are: ( 1) initial area selection of a remote greenstone belt in 1969 - albeit for base metal deposits , (2) utilization of an airborne E .M. system which successfully targeted the A Zone in 1970 , (3) the timely reactivation of the project in 1981 and the subsequent recognition that the original discovery represented a sulphide bearing stratabound horizon with implicit volcanogenic connotations , (4) the intensive effort in 1982-83 deploying aerial and ground geophysics coupled to volcanogenic concepts of ore distribution which resulted in the discovery of the B and C Zones in 1982, and (5) the integration of downhole P . E.M. surveys and geology to successfully delineate ore at increasing depths . To the end of 1983 , $2.6 million has been expended, and it is hoped that continued effort will result in the eventual delineation of an economically viable ore deposit for the joint venture partners .

Jan 1, 1984

By A. Brown

The swift decline of coal during the period of unprecedented expansion in the Canadian economy is a phenomenon deserving careful examination, because the underlying forces contributing to this decline may have broader implications in our national economy. At the present level of technology, coal is more difficult to process, transport and utilize than liquid and gaseous fuels. Fundamentally, it is a matter of limitation in technique. Because coal is a vast store-house of energy in Canada, the reduction of these limitations is in the long-term national interest.

Jan 1, 1967

By S. Averill, B. Schreiner, V. Sopuck

The La Ronge. Kisseynew, Glennie Lake and Flin Flon domains. the main focu for gold exploration in the southeast part of the Saskatchewan Shield, were subject to continental glacial ice advances from the northeast during the Quaternary. Based on forty-four auger hole along with surficial mapping, the general Quaternary stratigraphy in this area is observed to be composed of a lower till unit , an overlying stratified unit of glaciofluvial sand and gravel and/or a glaciolacustrine silt-clay unit. an upper till. and an upper tratified unit. The lower till is commonly found throughout the geological domains except where it has been eroded in glaciofluvial or fluvial channels. Glacial Lake Agassiz fo rmerly covered most of these prospective domains. The lacustrine deposits associated with the lake impede surficial geochemical surveys including soil. lake sediment. and biogeochemical surveys. The approximate extent of clay cover can be predicted from beach elevations. For instance. in the Waddy Lake area. clay i not known to occur above about 1,400 feet (425 m) elevation. Exploration techniques are hampered by clay in at least one third of the volcanic belt. Thi s influence is indicated by the fact that nearly all gold prospect found to date are located above 1,400 feet (425 m) while the area of clay cover is vi rtually unexplored. The upper till i related to a minor ice readvance. This till is the medium often sampled during soil surveys in the area . lts value as a geochemical ampling medium is dependent on the extent of erosional contact with bedrock highs on the lower till. Those areas which are relatively free of lacustrine and fluvial deposits are those where surface geochemical methods work best. In the Waddy Lake volcanic belt approximately 25-50% of the area may be suitable for surficial surveys. The area of the Star Lake prospect occurs above the 1,500 foot (460 m) elevation and was not covered by Lake Agas iz. The effectivene of till sampling as a surface sampling medium was tested in those areas above the clay level. Till orientat ion surveys were carried out at the Star Lake property and the Tower Lake prospect (Waddy Lake area) within the La Ronge Domain . Gold grain counts and analy es of heavy mineral concent rate from 7 kg surface ti ll samples were used to delineate dispersion trains down-ice from mineralization. In addition, the clay fraction and a 30 g (-80 mesh) subsample from the same till sample, were analyzed for gold . In the Star Lake area, ice direction is subparallel to the strike of several narrow northeast trending auriferous structures. arrow dispersion trains down-ice from known

Jan 1, 1986

By R. C. Tait

The gold at Giant Yellowknife is intimately associated with a complex mixture of sulphides, including pyrite, arsenopyrite, stibnite, and a wide variety of antimony sulpho-salts. Direct cyanidation has never been feasible. Recovery is almost entirely dependent upon flotation, roasting of flotation concentrate, and cyanidation of calcine. In November 1958, an Edwards-type roaster and an early prototype, two stage Fluosolids roaster, were replaced by a large two-stage Fluosolids roaster of improved design. The new roaster was started at "safe" medium temperatures, but early in 1959, temperatures in both stages were gradually and deliberately lowered to determine whether continuous autogenous roasting could be maintained under exacting low temperature conditions necessary for good extraction. Operation is smooth and continuous with first and second stage temperatures controlled at 925° and 875°F respectively. Plant cyanide ex-traction compares very favourably with extraction from low

Jan 1, 1961

By R. Holmestad, M. Gazizov, S. Wenner, R. Kaibyshev, J. K. Sunde

"Mechanical properties and microstructure of an Al-4.7Cu-0.74Mg-0.51Si-0.48Mn-0.10Cr-0.09Ti-0.02Fe (wt. %) alloy subjected to various thermomechanical processing (TMP) have been investigated and compared to conventional ageing at 170°C (designated T6). Three TMP routes involving cold deformation of solution treated samples were tested. These were (i) 3%-stretching (T8-3%), (ii) equal-channel angular pressing (ECAP) to true strain (e) of ~1 (T8-1) and (iii) ECAP to e~2 (T8-2), all with subsequent ageing at 170°C for 0-96 h. At peak age conditions, both yield stress, ultimate tensile strength and elongation-to-fracture decreased for the T8-3% state as compared to the T6 condition. Intermediate ECAP (T8-1 and T8-2) lead to significant increase in maximum yield stress, ultimate tensile strength and elongation-to-fracture. The changes in mechanical properties were related to microstructure evolution, encompassing changes in grain sizes, dislocation densities, precipitate morphology and phase fractions, which were characterised using transmission electron microscopy. Relations between TMP, precipitation behavior and contributions to different strengthening mechanisms are evaluated.INTRODUCTION Al-Cu-Mg-Si alloys are widely used as structural materials in aerospace industry due to their attractive combination of high specific strength, good fracture toughness and enhanced creep resistance. These properties are largely due to the formation of a large number of nano-sized metastable precipitates during artificial ageing (Polmear, 2006; Eskin, 2003; Gazizov, Dubina, Zhemchuzhnikova, & Kaibyshev, 2015). The precipitation behaviour in these alloys is complicated and depends among other things on Cu concentration and the Mg:Si ratio (Wolverton, 2001; Chakrabarti, & Laughlin, 2004). In general, the precipitation sequence has been presented in a prior study (Eskin, 2003) as follows:"

Jan 1, 2018

By Hammenm R., J. Hammen, C. Hammen

"The production of salable Rare Earth Element (REE) products necessitates a sequence of chemical separation steps between the mine and market commodities. The effectiveness of the chemical separations that purify REE salts is critical to the success of the producer, as the purity of REE salt products affects their market price. This is due to the fact that impurities in REE salts, even at low levels, can be deleterious to the function and usability of the end product. The purification of REE by removal of low levels of contaminant has been referred to as "product polishing". The technologies commonly in use for product polishing, solvent extraction (SX) and ion exchange (IEX) are challenged by the availability of separation chemistries to separate the contaminant from the desired REE salt. In simple terms, if a product specification is 99.9% purity, the SX or IEX separation reagents need to have at least a 999:1 selectivity ratio. Significant testing has been carried out on the use of solid phase extraction (SPE) columns to extract low-level impurities such as aluminum or zinc from REE product streams. The SPE columns are nano-composite materials that have rapid equilibration kinetics with the solutes being processed by the columns. The SPE matrices have been modified with chelating ion exchange ligands that bind the contaminating ion with great selectivity in residence times of a few seconds. Thus, REE streams with 1 to 2% of contaminating aluminum ions, have been polished to >99.99% purity. In this paper, results are presented on the removal of aluminum impurity from a didymium (neodymium+praseodymium) product stream using SPE technology. The selection of the SPE medium and the process steps to treat the feed solution for aluminum removal and ultimate stripping and recycle of the solid phase extractant are discussed."

Jan 1, 2014

By C. D. Rowe, H. S. Mitri, J. Malki, I. Vennes

Ore extraction at great depths creates high stresses around mine openings, which can result in violent rock failure in one of various forms of strainburst. This is especially true with strong and brittle rocks, which can store a large amount of strain energy that is suddenly released at failure. The strength and brittleness of rocks have been extensively investigated in the past. The most widely accepted method for the determination of rock burstability is the strain energy storage index obtained from a non-destructive uniaxial load–unload test. However, the results of this method are not always conclusive, showing less repeatability when the target test load is changed. This study concerns itself with the introduction of microscopic analysis as a tool to help validate the strain energy index results when burstability cannot be warranted based on mechanical property tests alone. In this study, two types of rocks, namely, basaltic komatiite (BK) and felsic norite (FNOR) obtained from Canadian underground mines are examined. The selection is based on the premise that felsic norite is known to be burstable from the mine experience, whereas basaltic komatiite is not necessarily burstable. A total of 60 mechanical properties tests were conducted including uniaxial compressive strength, Brazilian tensile strength, and load-unload tests. Laboratory tests on FNOR consistently exhibit high burstability; however, the results for the BK tests are not conclusive. To seek explanations for the mechanical rock behavior, 18 thin sections were examined with optical microscopy and image analysis. The findings show the tested BK specimens are dominated by alteration products, and all primary igneous minerals are lost. There is minor quartz, garnet, carbonate minerals, talc, and serpentine, which give the rock its ductile properties. The FNOR specimens are found to be relatively fresh and supported by a strong network of plagioclase with minor pyroxene, biotite, and secondary micas, explaining the higher stiffness. This study demonstrates how optical microscopy can complement mechanical property tests to evaluate burstability of rocks.

May 4, 2025

By A. H. Onur, S. Ural

"The Afsin-Elbistan coal deposit with its 3.4 billion metric tons of reserve is the biggest coal basin and one of the most important resources for electrical energy production in Turkey. The coal deposit is located north of Elbistan, Kahramanmaras Province, in southeast Turkey (Fig. 1).The Kislakoy sub-basin of the Afsin-Elbistan basin was selected as the first open cast mine to feed four power station blocks of 340 MW each. The mine is equipped with six identical bucket wheel excavators of the type Sch Rs (2300/5) 32. The annual coal demand of the power station is 18.5 million metric tons. The Elbistan basin encompasses an area of 900 km2, and its centre lies about 1150 m above mean sea level. The sedimentation took place mainly in the upper Pliocene period. The thickness of the coal bed varies from 20 m to 60 m, respectively. The basal part of the coal beds consists of clay, marl and sandy clay. These formations are overlain by gyttja, which may also occur in the form of calcareous ooze, enveloping coal beds. The thickness of the gyttja is up to 35 m (Otto-Gold, 1969). The coal of Afsin-Elbistan is soft coal and the quality has been found to vary considerably throughout the deposit. The thicknesses of the sterile intercalations vary from 0.50 m to 2.2 m and average 1 m in thickness. From the quality control point of view, the coal seam is regarded as upper seam where the gyttja formation occurs as sterile intercalations, and lower seam where the clay formation occurs instead of the gyttja (Fig. 2). The CaO content of upper Kislakoy coal is very high, grinding resistance is low and base to acid ratio of ash, that is, the ratio of acid oxides of metals to base, is greater than one (Ural and Onur, 2001). Contrary to upper Kislakoy coal, CaO content of lower Kislakoy coal is very low, grinding resistance is high and base:acid ratio of ash is smaller than one. Modified Impact Strength Index (MISI) tests are used to determine the grindability of the Elbistan coals (Ural, 1999)."

Jan 1, 2003

By J. C. Rudolph

"THE TOPIC on which I am speaking this afternoon is ""The Future of the Canadian Oil Industry.'' At the time of C + 100, we should take a searching look at ourselves, an honest appraisal of our achievements and a forthright accounting of our shortcomings as well as the uniquely Canadian aspects of this industry. I would like to put before you some of my views on the direction we are taking in the exploration field and in the production field. I would also like to speak briefly on some of our problems and the role of the various segments of our industry in solving these problems.First of all, let us look at the exploration picture. We are in the midst of an exploration boom. There were 133 seismic crews active in Western Canada this winter, the highest since 1957, land prices are appreciating rapidly, Canadian oil reserves increased + 16 per cent during 1966, there is a great demand for technical personnel of every kind and the whole industry, except the drilling segment, seems to be prospering. This surge of activity has its roots in two major occurrences. The first of these was the change in the pro-ration system in Alberta, the major producing province, accompanied by the change in spacing pat-terns. The proration change was designed primarily to encourage in-creased exploration and it has certainly had this effect. It has also had the unforeseen effect of put-ting everyone into what we, in the oil business, call ""elephant hunting."" In other words, the days of the development of barely economic, marginal fields are over. Oil companies today are only interested in high-reserve, high-productivity, high-quality reservoirs."

Jan 1, 1968

By M. Pearson, J. Irvine, L. Mercer, P. Lauzon

Severe service ball valve performance has a direct impact on the mechanical availability of high pressure oxidation and leach plants. The primary function of these valves is to isolate the autoclave for maintenance. Valve failure has historically contributed significantly to the maintenance downtime of these process plants. An understanding of the root causes of valve failures is the first step in increasing the reliability of the severe service ball valves. A rigorous failure analysis practice has been developed by Hatch for investigating refractory failures in furnaces and kilns based on Kepner-Tregoe methodology. The method has also been modified for valve failure analysis. From a root-cause failure tree analysis of each of the valve components, a list of all potential valve failure mechanisms was developed for ranking and evaluation, along with recommendations for further valve development. The purpose of this paper is to present the reader with the modified Kepner-Tregoe method and examples of this analysis.

Jan 1, 2004

By J. E. Gillespie

Introduction Mineral wool may be defined as "rock, slag, or glass fibres made by a process of melting and blowing by steam or air, containing a minimum of oil and unfiberized material" (U.S. Bureau of Standards CS 117-44). The earliest production of the material was in Wales, about one hundred years ago. In the United States, the industry daces from 1870 when a plant, using slag as raw material, was established in Greenfield, New Jersey. It was not until 1897, however, that large-scale production was commenced on this continent at a plant in Alexandria, Indiana, which utilized rock from nearby deposits. Today, mineral wool is manufactured in many parts of the United States and Canada, the plants for the most part being in close proximity to deposits of suitable rock or to sources of slag. In the United States there are some seventy-five producers with a total annual capacity of nearly one million tons of wool. In Canada, in 1946, eleven manufacturers produced about fifty million square feet of batt-type mineral wool insulation material. Mineral wool is, perhaps, the most efficient of all heat-insulating materials and, moreover, it is fireproof, extremely durable, and insect- proof. Its high efficiency is due to the very low thermal conductivity of the fibres themselves and to the fact that the produce as marketed contains up to 90 per cent non-conducting air space. Depending on the degree of compression of the fibres in the manufactured product, the specific gravity ranges from 2 lb. to 10 lb. per cubic foot. Products Marketed Following are the principal forms in which mineral wool is marketed: Blanket. - Mineral wool with or without reinforcing on one or both sides, with various types of confining media, all suitably bound together.

Jan 1, 1948