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By J. A. Herbst

Professor Klaus Schönert and his students used fundamental physics to develop many of the principles required for the design and scale-up of "Gutt Bett Zerkleinern" devices such as the high pressure grinding roll (HPGR) or the high pressure roll crusher (HPRC). As the equipment evolved so have the tools used for its selection and analysis. In the current paper discrete element modeling (DEM), Metso's proprietary Fast Breakage simulations, and Schönert's packed bed piston test are combined with energy based population balance models (PBM) to yield an alternative to ore characterization and equipment selection by pilot plant testing. The resulting methodology is used to take the next step in understanding these devices with a view toward predicting plant performance. This paper describes a journey beginning with precise modeling of a small HPGR including stud geometry and system hydraulics. A key to predicting performance is the accurate modeling of individual particles, their motion in the machine, the probability of breakage and redistribution of fragments, and the inter-particle breakage events that occur between the rolls at different pressures, speeds and moisture levels. Advanced DEM simulations and particle breakage characterization methods provide the necessary technology. The resulting combined models were validated using a small diameter laboratory scale unit. The validated physics based model was used then used to predict the performance of plant scale units using a specific energy based scale-up method. Scale-up results are analyzed in terms of power draw, throughput, and discharge product size distribution.

Jan 1, 2012

By F. Chiesa

Forty aluminium A356 castings were poured on a Low Pressure Permanent Mould industrial machine, 500x700mm in platen size. The 152mm wide casting comprised three steps, 25mm, 13mm, 6mm in thickness and a 2.5mm overflow which allowed to assess the thin wall capability of the process. The casting campaign, which produced 40 parts, allowed to test the influence of various production parameters including the time of application of the pressure in the crucible, artificial cooling of the mould and casting rate. The thermal history in the mould was recorded over the 40 cycles, which allowed to construct a reliable thermal model of the mould/casting assembly. The metallurgical quality of castings representative of the various conditions was assessed in the 25mm, 13mm and 6mm plates. This included measuring the level of microporosity, the dendrite fineness (DAS), along with the tensile properties in the T6 condition. The radiographic quality per ASTM E155 was also determined. Modelling filling and solidification allowed to verify the validity of the predictions based on available relationships relating microporosity, secondary dendrite arm spacing (DAS) and local tensile properties (Quality Index, Q) to the local thermal solidification parameters.

Jan 1, 2007

By G. M. Card, K. D. Card, B. V. Sanford

Abstract-The Canadian Shield and its extensions are traversed by an orthogonal system of northwest and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches influenced patterns of sedimentation and tectonism in the intervening epicratonic basins and marginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structures also triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By G. M. Card, K. D. Card, B. V. Sanford

The Canadian Shield and its extensions are traversed by an orthogonal system of north-west and northeast trending arch-style uplifts. These basement arches were formed by repeated vertical movements along pre-existing structures during compressional and extensional tectonism connected with events in surrounding Proterozoic and Phanerozoic orogens and ocean basins. The arches in?uenced patterns of sedimentation and tectonism in the intervening epicratonic basins andmarginal platforms throughout the Proterozoic and Phanerozoic. Movements on the arch structuresalso triggered minor magmatism and controlled the location and timing of alkalic rock-carbonatite, kimberlite, and related intrusions in the Canadian Shield, the Western Canada Sedimentary Basin, and West Greenland.

Jan 1, 1997

By C. S. Ha, H. S. Choi, D. Y. Shin

POSCO installed a new 100 ton oxygen bottom-blown converter in 2013 for the development of new steelmaking process named as PS-BOP which is reading POSCO-Saarstahl Basic Oxygen Process. This process was developed by the collaboration research between POSCO and Saarstahl AG in Germany that is based on substantial increase of CO post combustion in a converter by blowing hot air from the top of converter. The collaboration research has been finished successfully in November 2013 with 17% decrease in hot metal ratio (HMR) when hot air was blown from the top of the oxygen bottom-blown converter. After the collaboration research the converter has been tried to be operated as oxygen top and bottom-blown converter to reduce bottom wear and to decrease production cost with increased use of low cost Fe source by the help of increased CO post combustion. The presentation includes experience on the start up of oxygen bottom-blown converter, HMR reduction trials with hot air top blowing and transition from oxygen bottom-blown to top and bottom-blown converter operation.

Jan 1, 2015

By Jean-Marc Lulin

"Depuis 1906, pres de 130 gisements ont ere decouverts dans la inture archeenne polymetallique (Cu, Zn, Au, Ag) du nord-ouest becois. Une etude regionale du developpement du potentiel inier est presentee puis detaillee pour quatre secteurs: RouynDranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des parametres suivants: temps, ethodes de decouverte, profondeur des gisements et poids metal. ~~ courbes cumulatives illustrant le nombre de gisements decouverts fonction du temps montrent une forme generale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de ~ouverte. Initiation, realisation et stabilisation des cycles de decourte sont ainsi mis en evidence. Deux ""bourns miniers"", de 1922 a ~5 et de 1955 a 1965, rassemblent 72 % des mines identijiees squ' a present.La plupart des mines sont trouvees en subsurface: 90% ont leur fmet entre 0 et 100 metres de profondeur dont 70 % entre 0 et 10 etres. Dans le temps, il y ad' abord recolte par prospection puis par fphysique et enjin, developpement progressif du potentiel en proeur avec des methodes composites. Environ 80% du poids metal extrait de 4 camps miniers, couvrant 8% de Ia surface regionale quelques gros gisements dominent /a production.Ces donnees permettent de proposer une nouvelle approche pour lysed' une region miniere:La distribution de Ia profondeur des gisements en fonction du temps est indicatricede /amaturite d' uncampminieret peut servir a evaluer son potentiel residue/.L' analyse des courbes en ""S"" permet d' extrapoler les taux de succes relies aux differentes methodes et met en relief le role crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1990

By M. Rafieazad, P. Fathi, M. Mohammadi, A. M. Nasiri

This study examines the impact of low-temperature heat-treatment cycles on microstructure and corrosion performance of Direct Metal Laser Sintered (DMLS) AlSi10Mg_200C alloy. It is known that the morphology and the size of eutectic silicon are the two most critical factors affecting mechanical properties of the AlSi10Mg alloy. Although high-temperature heat-treatment cycles are common practice for the strengthening of the cast Al-Si-Mg alloys, in the case of DMLS fabricated AlSi10Mg alloy, high-temperature solutionizing and low temperature annealing cycles result in mechanical properties degradation primarily due to a dramatic decrease in the solubility of Si in the super-saturated a-Al matrix of the as-printed alloy. In this study, low-temperature heat-treatment cycles that only promote precipitation of Mg2Si accompanied by the interruption of the silicon network were investigated. SEM and XRD analysis were utilized to observe the evolution of microstructure after different annealing heat-treatments at 200, 250, 300, and 350°C for 3 h. Increasing the heat-treatment temperature contributed to the Si networks interruption and an increased precipitation of Mg2Si phase. Low-temperature annealing from 200 to 350°C was found to promote the homogeneity of the microstructure characterized by a uniform distribution of eutectic Si in ??-Al matrix. Additionally, in order to investigate the impact of different heat-treatment cycles on corrosion resistivity of DMLS-AlSi10Mg_200C, the potentiodynamic polarization testing and electrochemical impedance spectroscopy were performed in a 3.5 wt.% NaCl solution. The results revealed more uniformly distributed pitting attack on the corroded surface by further increase in the annealing temperature, which was attributed to the uniformity of Si dispersion. In comparison, low temperature annealing at 200°C led to a penetrating selective corrosion attack along the melt pool boundaries, resulting in a higher corrosion rate associated with the lower absolute value of impedance of the protective passive film on the surface.

Jan 1, 2018

By Rolf Andreas Lauten, Yanhong Wang, Yongjun Peng

"In mineral flotation, bentonite as a kind of clay mineral imposes deleterious effects on the flotation of valuable minerals, possibly through its ability to increase the pulp viscosity. A higher viscosity lowers the amount of froth and affects the bubble-particle collision frequency. A previous study found that adding gypsum to a bentonite-ore mixture lowered the viscosity, possibly by inhibiting the formation of interconnected network structures. In this study, sulfate as an anion with different types of cations, Na+, K+, Mg2+ and Ca2+ were used to reduce bentonite viscosity and to improve flotation performance. It was found that at the same concentration, MgSO4 was the most effective salt in reducing bentonite suspension viscosity, while CaSO4 was not as effective likely due to the lower solubility of CaSO4. Na2SO4 and K2SO4 reduced bentonite suspension viscosity at high concentration. Flotation kinetics of ore blended with bentonite was increased with increasing the electrolytes concentration, which generally correlated with the reduction of bentonite viscosity. Meanwhile, significant discrepancies were found between flotation results and rheological measurements in the presence of monovalent ions. It is indicated that the morphology of bentonite aggregates in electrolytes solution is likely to influence the hydrodynamics in the froth zone.INTRODUCTIONClay is present in many ore bodies as a gangue mineral. Presence of clay presents several challenges in the processing of valuable minerals. They are soft compared to valuable minerals, which means that during grinding of the ore, clay particles are likely to obtain a smaller particle size than the valuable mineral. Often clay particles may be within the colloidal size domain (<20 µm). The smaller size increases the probability of entrainment in the concentrate. Another challenge is their anisotropic charge distribution, where depending upon the pH, edges (E) and faces (F) carry charges of opposite sign. This facilitates formation of aggregation structures that may impede percolation of bubbles through a froth, but also increase the viscosity more than expected from the mere change in volume fraction. In addition to lowering the froth mobility, a high slurry viscosity will have implications for the gas dispersion in the flotation column as it affects the dispersion of the suspended particles, and it modifies the bubble-particle collision rate and attachment efficiency (Bakker, Meyer, & Deglon, 2009; Shabalala, Harris, Leal Filho, & Deglon, 2011). A pragmatic approach to this problem is to blend high clay ore with ore of lower clay content, reducing the overall clay concentration. Alternatively, one may lower the solids content of the flotation slurry to counteract the viscosity-building properties of clay. While feasible, this approach has the disadvantage of increasing required flotation volume, and it also affects the properties of the froth. Thus, there are currently limited options in lowering the impact of clays and their tendencies to increase viscosity in flotation slurries."

Jan 1, 2016

By Jean-Marc Lulin

"Depuis 1906, près de 130 gisements ont été découverts dans la inture archéenne polymétallique (Cu, Zn, Au, Ag) du nord-ouest québécois. Une étude régionale du développement du potentiel inier est présentée puis détaillée pour quatre secteurs: Rouyn-Dranda, Val d'Or-Malartic, Bousquet-Cadillac et Matagami.L' analyse est conduite a l' aide des paramètres suivants: temps, méthodes de découverte, profondeur des gisements et poids métal. Les courbes cumulatives illustrant le nombre de gisements découverts fonction du temps montrent une forme générale en ""S"" dont les i'iations de pentes correspondent aux variations dans les taux de couverte. Initiation, réalisation et stabilisation des cycles de décourté sont ainsi mis en évidence. Deux ""bourns miniers"", de 1922 à 1945 et de 1955 à 1965, rassemblent 72 % des mines identifiées sqú à présent.La plupart des mines sont trouvées en subsurface: 90% ont leur mmet entre 0 et 100 mètres de profondeur dont 70 % entre 0 et 10 êtres. Dans le temps, il y a d' abord récolte par prospection puis par ophysique et enfin, développement progressif du potentiel en proeur avec des méthodes composites. Environ 80% du poids métal extrait de 4 camps miniers, couvrant 8% de Ia surface régionale quelques gros gisements dominent /a production.Ces données permettent de proposer une nouvelle approche pour analyse d' une région minière:La distribution de Ia profondeur des gisements en fonction du temps est indicatrice de la maturité d' un camp minier et peut servir a évaluer son potentiel résiduel.L’analyse des courbes en ""S"" permet d’extrapoler les taux de succès relies aux différentes méthodes et met en relief le rôle crucial de I' innovation dans I' exploration.ABSTRACTSince 1906, some 130 deposits have been discovered in the Archean polymetallic belt of northwestern Quebec. In this paper, the development of the mining potential is analyzed at the regional scale and for the following mining camps: Rouyn-Noranda, Val d'OrMalartic, Bousquet-Cadillac and Matagami.The analysis is based on the following parameters: time, discovery method, depth and weight of metal extracted. Curves showing the cumulative number of deposits discovered as a function of time are ""S"" shaped with slope variations corresponding to changing discovery rates. Initiation, realization and stabilization of discovery cycles are thus well represented. Two ""mining booms"", 1922 to 1945 and 1955 to 1965, account for 72% of the mines identified to date.Most exploitable orebodies have been found near the surface: 90 %have their top between 0 and 100 meters, including 70% between 0 and 10 meters. Early discoveries were made by prospecting, followed by geophysics while the progressive development of the depth potential is being realized by a combination of methods. Approximately 80 %of the metal extracted comes from four mining camps which cover 8% of the area, but most of the production can be allributed to only a few large deposits. Based on these data, a new approach to the analysis of a mining region is proposed:1) The distribution showing deposit depth versus time is indicative of the maturity of a mining camp and can serve to evaluate its remaining potential.2) The ""S"" curve analysis can be used to extrapolate the success rate of a specific exploration method and also stresses the crucial role of innovation in exploration."

Jan 1, 1989

By W. D. Sinclair, R. J. Cathro, E. M. Jensen

"The Cash is one of the largest porphyry copper-molybdenum Deposits found in Yukon to date. It is 80 km northwest of Carmacks, within the unglaciated portion of the Dawson Range, and is associated with the Big Creek fault, an important tectonic feature. Part of the mineralized zone is blanketed by up to 70 m of alluvial drift . The remainder is covered by a relatively thin residual soil layer. The mineralized zone, however, was not detected by conventional stream-sediment sampling because pathfinder elements, such as Cu and Mo, have not been geochemically dispersed into the main drainage system. The deposit was discovered by a combination of soil analysis and inspection of rock fragments from small pits.Twenty widely spaced, shallow drill holes have outlined an areaover 2700 m long and 550 to over 1000m wide that grades more than 0.1% copper equivalent (% CuE = % Cu + (5 x % MoS2)). Two smaller zones grading over 0.4% copper equivalent occur within the larger area. The limits of the widest end of the deposit have not been delineated.The Cash deposit is fairly typical of high-level, calc-alkaline porphyry copper-molydenum occurrrences in the Canadian Cordillera {cf, CIM Special Volume 15) and is representative of most prospects in the Dawson Range. It is associated genetically with a subvolcanic complex of small, irregular stocks and dykes of feldspar porphyry and related breccias of Late Cretaceous age. Copper and molybdenum sulphides occur along fractures, in quartz veinlets and disseminated in feldspar porphyry and in older metasedimentary and intrusive rocks. Higher-grade zones of copper and molybdenum have associated potassic alteration. Phyllic alteration is, in part, superimposed on potassic alteration. Argillic alteration occurs locally.This paper describes the history of the discovery and the geochemical and geophysical characteristics, together .with the regional geology, and the nature and distribution of the host rocks, hypogene mineralization and hydrothermal alteration."

Jan 1, 1981

By David G. Meadows

During the last decade Antofagasta Minerals? Los Pelambres Mine has dramatically increased its ore throughput following the fast initial phase ramp up through a series of planned incremental expansions. The original 85,000 mtpd, two SAG line plant was commissioned in 1999 and rapidly exceeded nameplate tonnage in only a few months. Following this, the inclusion of a pebble crushing circuit resulted in throughputs in excess of 114,000 mtpd and a recent, final third line SAG and ball mill addition have taken the plant to over 175,000 mtpd even with increasing ore hardness and changing ore feed characteristics. The progressive changes are described in this paper together with how the technical challenges have been met.

Jan 1, 2012

By K Komori

Naoshima Smelter and Refinery has treated shredder residue and incinerator fly ash in Japan since 2003. As a highlight, a new incinerating and melting furnace, as well as fly ash washing treatment plant were newly constructed for pre-treatment of shredder residue and fly ash respectively, and the pre-treated materials are ultimately treated in the existing Mitsubishi continuous copper smelting and converting process line. Since wastes such as shredder residue tend to vary in size and in shape, and contain some chlorine, the installation of a new pre-treatment line was required. The combination of the new pre-treatment line with the existing Mitsubishi Continuous Copper Process line has created a highly efficient and environmentally friendly system for recovering and recycling of valuable metals that previously used to be sent to a landfill. This paper reviews the approach that Naoshima took to establish its current recycling business strategy.

Jan 1, 2007

By W. Banda

"Trial application of air decks on a production shot improved fragmentation (32% reduction in x50). Empirical fragmentation models and digital image processing software were used to estimate fragment size distribution of the blasted muck pile. The x20, x50, and x80 passing fractions, and top size were 42, 265, 683, and 1,455 mm, respectively. Air-deck application reduced explosives load in blastholes, lowering total charging cost by US$20/hole (15% decrease) and the powder factor to an average of 0.86 kg/m3 (12% decrease). Blast results were 443,624 t of blasted material from the block (90% of total muck pile) was smaller than 900 mm.RÉSUMÉ L’application pilote de trous d’air dans le cadre du coup de mine effectué pour commencer la production a amélioré la fragmentation (une réduction de 32 % des x50). Des modèles empiriques de fragmentation et un logiciel de traitement numérique des images ont permis d’estimer la composition granulométrique des fragments du tas de déblais abattus. Les fractions de passé de crible de x20, x50, x80 et la dimension supérieure étaient représentées par des dimensions respectives de 42, 265, 683 et 1 455 mm. L’application de trous d’air a permis de diminuer la charge d’explosifs nécessaires dans les trous de mine, réduisant ainsi les coûts totaux de chargement de 20 $ US/trou (soit une réduction de 15 %) ainsi que le facteur de chargement (facteur poudre) à une moyenne de 0,86 kg/m3 (soit une réduction de 12 %). Les coups de mine ont résulté en 443 624 tonnes de matériaux abattus du bloc (soit 90 % du tas de remblais total) mesurant moins de 900 mm. INTRODUCTIONThe main objectives of production blasting are to achieve optimum rock fragmentation and to minimize overall production costs. Because blast fragmentation significantly affects the profitability of a mine, blasting is the first step of the size reduction in mining: An optimum size distribution is required to maximize the performance of mining and subsequent milling processes. If the fragmentation size distribution can be modelled and controlled, operations performance will improve. Blast fragmentation modelling is important in mineto- mill optimization: It allows the estimation of blast fragmentation distributions that can be modelled in downstream mining processes to determine the optimum blast design."

Jan 1, 2018

By S. Gorzalczynski

The recent trend in underground mine developments is “bigger is better.” This is most certainly evident in the mine shaft and conveyances that operate within its compartments. Today, there are several new installations requiring mine cages that can transport up to 170 passengers. The technology in mine hoisting is advancing to address a combination of higher capacity requirements, deeper hoisting depths and faster winding rates, however, some areas of the hoist plant have not changed in the past 50 years. The most notable of these areas is the shaft compartment guide string and the conveyance mounted safety arrest mechanism. The technology in use today for the protection of passengers in a shaft conveyance from a hoist rope severance incident remains conceptually unchanged from Elisha Otis’ design of 1850. The actual retardation components, the safety dogs, have taken on several forms since Elisha’s invention with the last major design change occurring in the late 1940s. The arrest of a free falling shaft conveyance requires that the shaft guides withstand the energy imparted on them by the safety dogs. There are some very real limitations presented by the use of wood for this application. The new hoisting era will most certainly continue to demand larger capacity equipment, but also an increased awareness toward safety

Jan 1, 2002

By Dale A. Sketchley

The objective of Quality Assurance and Quality Control programs on advanced exploration projects is to ensure that data from sampling, assaying, and recording of geological observations are of high integrity for the purpose of obtaining reliable mineral resource and reserve estimates. National Instrument 43-101 Standards of Disclosure for Mineral Projects states that all scientific and technical reports must be prepared and certified by a Qualified Person in accordance with professional and industry standards following Mineral Exploration Best Practices Guidelines and Definitions, and Guidelines of the CIM Standards on Mineral Resources and Reserves. Additional information is given in Companion Policy 43-101CP and Technical Report Form 43-101F1. Although the Qualified Person must discuss and describe the Sampling Method and Approach; Sample Preparation, Analyses, and Security; and Data Verification; there is little specific information in the guidelines on Quality Assurance and Quality Control programs. Examples from the Oyu Tolgoi Cu-Au Project are given for optimizing sampling protocols, following proper sample preparation procedures, safeguarding sample shipments through chain of custody, ensuring quality of assaying with Round Robin monitoring programs, verifying transcribed data, and validating data with check assays to ensure high integrity for resource and reserve estimation. Oyu Tolgoi, also known as Turquoise Hill, is in the South Gobi desert, Mongolia, about 550 km south of the capital city of Ulaanbaatar, and 875 km northwest of Beijing, China. The project covers a major copper-gold system, which consists of the South West, South, Central, and Far North deposits, comprising high sulphidation and porphyry mineralization with oxide, supergene, and hypogene ore types. Exploration is done by multiple diamond drill rigs, and samples are prepared on-site and shipped to laboratories in Mongolia, Canada, and Australia for further preparation and analysis.

May 1, 2003

By Hulbert A. Lee

"A REVIEW OF MINERAL DISCOVERIES IN CANADA, and in particular the Canadian Shield, using the physical aspects of overburden reveals a trend in the art of exploration. At an early time of exploration (1847-1954), float and heavy clasts were used successfully to find ore deposits with little knowledge of Quaternary environments. At a later time (1955 to present) , use of Quaternary rock-units for sampling have made possible tracing indicator trains of float, heavy clasts and other ore-type clasts to the source bedrock. The basal till of retreat ice is now recognized as a1l favourable sampling environment and as such has been used to successfully discover hidden orebodies. The esker massive gravel is beginning to be recognized as a favourable environment and use of it has met with technical success. An understanding of those changes that have taken place during the transportation of the material and after its deposition is essential to proper sampling and treatment of the samples from the basal till and the esker massive gravel. Use of float and heavy clasts in search of orebodies is continuing in present-day exploration on the Shield. Lessons learned from it are being incorporated into exploration using favourable Quaternary rock-units for sampling. Hence, both subjects have a need for review and are discussed in this paper."

Jan 1, 1971

By W. J. Cherones

This paper describes the history of the development and application of the electric mining shovel in open-pit mining, dea1ing particularly with far-reaching advancements in three primary areas: metallurgy, mechanical design and electrical systems. Hoist drives and crowd drives, including the Magnetorque and Electrotorque systems, and the integral propel drive are given close attention.

Jan 1, 1972

By O. K. Mahabadi, A. Lisjak, B. S. A. Tatone, N. Vlachopoulos

"Numerical simulations are widely adopted in the design of several types of rock structures, including tunnels, caverns, rock cuts, and open pit and underground mines. In recent years, analyses based on the hybrid finite-discrete element method (FDEM) have been shown to provide a realistic representation of rock mass deformation and fracturing processes. To date, the FDEM approach has successfully yielded qualitative and quantitative results for several practical rock engineering applications, yet it has lacked the ability to consider the implementation of rock-reinforcement measures. Since rock reinforcement is often used in civil and mining applications to improve the strength and deformational behaviour of a rock mass, the ability to incorporate such features into FDEM analyses is essential to extend its applicability to a broader range of problems. The work presented in this paper represents an important first step towards developing a simulation tool that can be used for practical rock engineering applications, including the design of underground excavations and rock slopes.INTRODUCTIONRock support and reinforcement measures are often employed in civil and mining rock engineering projects in order to maintain or improve the strength and deformational behaviour of rock masses. The preferred type of reinforcement or support elements along with the preferred layout and timing of installation depend on the in-situ ground conditions, the nature of the rock mass and excavation method. Over the last two decades, numerical modelling has been increasingly used to design and attempt to optimize rock reinforcement and support systems. As such, most rock engineering-specific modelling software now offers various approaches for modelling different rock reinforcement and support elements."

Jan 1, 2015

By Jr. Fackler

The ionization potentials of gaseous Group 11elements are similar, with Au(0) being 1.5 eV greater than the next highest member of the group, Cu(0). The ionization potentials are all very much greater than the alkali metals, making these ?coinage? elements rather unreactive to chemical oxidation. Ionization from the first oxidation state shows a different pattern, with Ag(I) being the most difficult of the Group 11 ions to lose an electron. Gold(I) is noble and only normally oxidized in the presence of strongly coordinating ligands such as thiols or cyanide. Gold(I) compounds are 2-, 3- and 4- coordinate, with 3-coordinate species generally showing visible photoluminescence under UV excitation. Dinuclear Au(I) compounds with strongly coordinating S or C ligands can be oxidized to form isolable metal-metal bonded Au(II) compounds which are often readily isolable. Many have been structurally characterized. T he ease with which electrons are lost from closed shell dinuclear sp ecies (with anti-bonding M-M interactions) increases when metalmetal bonded compounds are formed. T his observation was made by our group with oxidative-addition studies of dinuclear gold(I) ylide complexes. It was superbly demonstrated recently by Cotton?s group who reported the isolation and characterization of a dinuclear closed shell transition metal species which is more readily oxidized than cesium. Trinuclear Au(I) pyrazolates, TR(pz), carb eniates, TR(carb), and benzylimidazolates, TR(bz), are well known and undergo electron loss through oxidative addition forming Au(I,III) mixed valence species and ultimately trinuclear Au(III) species. Au(II) species are absent from isolation in these oxidations. These carbeniates and benzylimidazolates also are excellent bases for metals ions such as Tl(I) and Ag(I). The acidic, neutral trinuclear compound [Hg(C6F4)3]3 also interacts with these bases. We have also shown that the neutral organic pi acids C6F6 and TCNQ form stacked pi-acid pi-base products with the trinuclear Au(I) compounds. In this paper, the structure of the octafluoronaphthalene acid-base product will be described. It displays a feature not observed previously in that the product is photoluminescent with a bright yellow emission. The 3.5 ms lifetime is very long and reminiscent of the long lifetimes observed by Balch for the stacked methyl,methoxy Au(carb). The electrochemical oxidation of tetragold(I) clusters, [Au4(form)4] have been studied in 0.1 M Bu4NPF6/CH2Cl2 at Pt working electrode at different scan rates. Three waves are obtained at 0.75, 0.95, and 1.09 V vs Ag/AgCl at scan rate 500 mV/s. The potential of the three reversible waves is independent of the scan rate in the range 50 mV/s to 3 V/s. The current at the third wave is larger than those at the first two waves. These tetranuclear species app ear to be effec tive catalyst precursors for the oxidation in air of CO. Introduction. The electronic structural relationships of the coinage elements and the alkali metals are similar in the sense that each have a [closed shell]ns1 configuration, yet their ionization energies (Table) and chemistries are clearly vastly different. The Group 11coinage elements have an underlying nd10 level immediately below the ns1 level. Unlike the alkali elements, ionization leaves the filled d electron shell the next accessible for further ionization. The coinage elements are all relatively ?noble?, much less reactive to environm ental conditions than the alkali metals. With the coinage elements, oxidation becomes very much dependent upon the types of ligand s availab le to bo nd to the ionized state.

Oct 1, 2003

By V. Vakiloroaya

The paper aims at developing a hybrid solar-assisted air conditioner system for performance enhancement and energy efficiency improvement. To increase sub-cooling of the refrigerant at partial loads, we propose a new discharge bypass line together with an inline solenoid valve, installed after the compressor to regulate the mass flow rate of the refrigerant vapour passing through a hot water storage tank. For control design, a lumped parameter model is first developed to describe the dynamics of the system in an explicit form of input-output relationship. The system has been fully-instrumented to examine its performance under different operation conditions. The system model is then validated by extensive experimental tests. The predictions from the models exhibit a good coincidence with experimental results, judging by an RMS error less than 15%. Based on the obtained dynamic model, a linear quadratic regulator (LQR) is applied to optimize a cost function of the output errors and control efforts. The key challenge is to regulate the refrigerant temperature entering the condenser by controlling the valve opening. The design approach is then tested in a transient simulation tool to predict the system performance in transient conditions. The experimental results obtained from implementation with PLC demonstrate that the proposed system delivers higher system efficiency owing to the higher refrigeration effect in the direct expansion evaporator. Thus, the novel development is promising for improvement of energy efficiency, enhancement of the system performance while fulfilling the cooling demand. Consequently, between 25 and 43% of monthly electricity can be saved on average.

Aug 1, 2013