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By Ken Wood, Luc Duval

"The development and operation of the milling circuits treating the different Selbaie orebodies are discussed in this paper. The project is reviewed from metallurgical evaluation through construction to present operating status. The current flowsheets are described, with discussion of some unusual features.IntroductionThe Selbaie concentrator commenced initial production in August 1981, treating underground B zone copper ore in a single 1500 t/d circuit. Throughput was increased to 1650 t/d in 1985. The mill was expanded in 1986 to treat ore from the A-I zone open pit; an independent circuit was added to selectively treat 5000 t/d of copper-zinc ore. Current total mill throughput through both circuits averages 7200 t/d with the production of approximately 270 t/d of copper concentrate and 230 t/d of zinc concentrate.This paper describes the stages involved in bringing the project from initial laboratory testing to its current status as one of the most important producers of silver, copper and zinc in Quebec and a major employer in the region."

Jan 1, 1990

By Rory S. McLaren

"Cost per ton as it relates to mobile underground vehicle maintenance and repair is invariably astronomical. The reason: the mechanic replaced a ten micron filter with a 250 micron filter because it appeared to be physically identical; the purchasing agent bought ""Brand X's"" filter because it was 25% cheaper- the result, a filter life 30% less; the hydraulic pump was sent for repair at a cost of $2000.00 and failed shortly after installation; pumps are failing because there is no testing equipment available in the workshop.This paper will identify a number of the common pitfalls resulting in high costs, and offer solutions to bring these costs to within acceptable limits.The following key issues will be discussed:A. Genuine parts replacement versus ""Brand X""B. Evaluating outside repair shopsC. The influence of environmental conditions on optional equipmentD. Personnel trainingE. Servicing and testing equipmentIntroductionThere is an old English aphorism, ""Look after the pennies, the pounds will look after themselves"".This paper is aimed at the pennies.Genuine Parts Replacement versus ""Brand X""High interest rates and floundering mineral prices are forcing many equipment owners and operators to purchase ""Brand X"" or ""Pirate"" parts in order to survive. ""Pirate"" part manufacturers invariably offer lucrative discounts which are most appealing to the average purchasing agent whose responsibility it is to save money. Unfortunately, in most cases, there is a tradeoff involved; when the price drops so does the quality, which can adversely affect owning and operating costs. Unless totally obvious, ""original"" or ""pirate"" part metamorphosis requires scrupulous analysis by competent individuals.Hydrostatic transmissions have been used successfully for many year s in various industries. They found their way into mobile underground loaders in the early seventies and have since become very unpopular in mining circles due to their apparent ""inherent unreliability"" and near ""prohibitive"" repair costs. The big benefit of the hydrostatic transmission is compact component packaging which enables the machine to work in very small headings."

Jan 1, 1983

By G. W. R. Kuzyk

"Hydraulic drills, recently implemented at the Tantalum Mining Corporation of Canada, Limited, Bernie Lake Mine, are proving to be an economic alternative to pneumatic drilling systems. The paper describes the application of an electric-hydraulic drill jumbo to the mechanized room-and-pillar mine and its performance. The application of these drills resulted in improved environmental and working conditions.Drill rods and bits are a major cost centre in hard-rock mining applications. The paper also discusses the performance of one manufacturer's product used on the hydraulic drills.IntroductionThe Tantalum Mining Corporation of Canada, Limited (TANCO) started producing tantalum ore from its Bernie Lake pegmatite in 1969. The pegmatite, encased in amphibolite, is shallow seated and flat lying. It is defined by diamond drilling along 4,000 feet of strike and 1,500 feet down dip, ranging in thickness from 60 to 280 feet. Relatively well defined zones of mineralization occur within the pegmatite and form separate orebodies of tantalum, lithium and cesium."

Jan 1, 1981

By D. Madsen, B. Salamondra, A. Moss, D. Etienne

"Raise mining at the Namew Lake Nickel Mine in Manitoba uses 3 m diameter bored raises driven at 45 to 50 degrees dip for stope access and drilling. These raises are developed within the orebody on 20 m centres to accommodate electric-hydraulic longhole jumbos and charging wagons. Critical elements of stope development include delineation of are contacts, control of deviation during raise development, optimal stope sequencing to permit a high extraction rate, drill anchorage installation, production drilling and blasting, and ground control. Procedures to deal with these elements are described, with emphasis on the geotechnical investigation for design of open stopes and pillars.Although mining with drilled raises does not have the flexibility to follow large variations in orebody dip, results to date indicate that it can be used successfully in the thicker ore zones. Thinner zones are currently mined using a modified Avoca method. Some flexibility to accommodate variations in orebody dip in thin are zones may be obtained by using alimack raise climbers to drive access raises, and carry longhole drills and charging equipment. Rock quality has been sufficiently good to maintain stable stope walls for full-height mining of primary stapes at 20 m strike length.IntroductionThe Namew nickel deposit is located 60 km south of Flin Flon, Manitoba. It is a moderately dipping (45 to 50 degrees) pipe-like ultramafic intrusion with a sulphide halo enrichment. The diluted recoverable ore reserves at January I, 1990 are 2.2 million tonnes grading 2.05% Ni and 0.7% Cu. The operation is a joint venture between Hudson Bay Mining and Smelting (60%) and Outokornpu Mines Ltd. of Toronto (40%). The mine is budgeted to produce 530 000 tonnes in 1990. The deposit was discovered in 1984 and mine development commenced in 1987.In the raise mining area, primary stopes will be filled with a high quality backfill consisting of cement and quarried limestone. Secondary stopes will be mined out between the primaries in the second pass of mining. The design extraction rate is 94% over all.The orebody above 120 level has an average mining width of 2.4 m, so is too narrow for raise mining. A modified form of Avoca stoping is used."

Jan 1, 1991

By J. G. Henning, T. R. Yu, J. E. Croxall

"Test work was carried out to investigate the thermal response of loose and solid rock under varying environmental conditions. The primary interest was to develop a technique that could be used to increase the thermal variation between loose and solid rock for better detectability of loose rock underground with a thermal imaging infrared scanner.A variety of thermal enhancement methods were evaluated both in the laboratory and in the mine environment. Air temperature variation created by the exhaust from diesel driven, mobile mining machinery was studied in detail. When sufficient hot exhaust was supplied to the air, unsteady thermal conditions became more pronounced on the rock surf ace. This allowed a greater percentage of loose rock to be detected by a high-resolution infrared scanner within minutes.The degree of thermal enhancement of loose rock was found to be dependent directly on the thermal conductivity of rock, looseness, air temperature change, and inversely on the size of loose, airflow rate and distance downwind from the heat source. It was also found that an air temperature rise of at least r c, or rock temperature differential of1°C was necessary for minimal thermal enhancement required f or infrared detection."

Jan 1, 1990

By James L. Parks, David M. Kjos

"Designs, installation procedures and performance characteristics of martensitic cast steel concaves are reviewed. Longer wear life, fewer pieces to install and eliminating the need to scarf joints are the principal benefits of using martensitic steel to replace austenitic12% Mn (Hadfield's) steel, the traditional concave material for large gyratory crushers. Installation procedures that reduce the risk of breakage are described. Operating practices that affect concave performance are also discussed.IntroductionThe crushing machine considered to be the forerunner of the modem gyratory crusher was patented in 1878 by Charles M. Brown of the Gates Iron Works(1). The earliest gyratory crushers with receiving openings of 6 to 12 inches were fed by hand, and the crushing capacity of a mine was increased simply by installing more small crushers. The introduction of the steam shovel to open pit mining around the tum of the century provided an incentive for much larger primary crushers, and gyratory crushers with a 48 in. receiving opening were being built by 1910, followed not long afterward by machines with 54 in. and 60 in. openings to . Fortunately for the crusher maintenance people of that era, an austenitic 12% Mn steel with exceptional toughness was already available, having been discovered by Robert Abbot Hadfieldoi in 1882. Although small gyratory crushers working soft- to medium-hard rock reportedly used chilled cast iron (white iron) wear parts, these newer and much larger machines were fitted with ""Hadfield's manganese steel"" concaves and mantles to withstand the impact associated with handling large rocks .M E International first challenged the long-standing convention of using 12% Mn steel concaves in large gyratory crushers in the late 1960s when they supplied upper row concaves in martensitic cast steel for a 60-109 primary crusher at a taconite plant on the Iron Range. Since then, martensitic steels have been successfully substituted for 12010 Mn steel in concaves for more than seventy primary gyratory crushers processing iron, copper and precious metals ores, industrial minerals and crushed stone.This paper reviews materials, designs and performance characteristics of martensitic steel concaves in large gyratory crushers. The principal benefits include significantly longer wear life, fewer pieces to install and the elimination of scarfing. Obtaining the full measure of these benefits and minimizing the risk of breakage is strongly dependent on installation procedures, which are described in some detail. Operating practices that can affect performance are also discussed."

Jan 1, 1993

By R. Scheepers

"Abstract -Mineral deposits and prospects of the Pan African Saldanian orogenic belt in the south­ western Cape Province South Africa, are reviewed. Despite the entire absence of operating base or precious metal mines in the area, this study has established at !east four metal associations that offer enticing exploration potential .The poly-phase deformed, low-grade metamorphosed volcano-sedimentary Malmesbury Group constitutes a complex, poorly understood supracrustal sequence that has been loosely subdivided into the Tygerberg, Swartland and Boland tectono-stratigraphic terranes by northwesterly trending fault zones. Syn- and post-tectonic granitoids of the Cape Granite Suite selectively intruded these terranes. Early S-types preferred the Tygerberg terrane whereas the later I-types dominate the remaining areas. Anorogenic A-type granites, however, occur in all three domains. Known metallization is directly or indirectly related to the intrusives, yet syngenetic deposits are conspicuously absent from the supracrustals. Four metal associations have been identified.•,Cassiterite-wolfrarnite (± Au, Cu, Mo, Fe-sultides) in quartz and quartz/aplite veins hosted by tourmalinized and locally greissenized S-type granite. Similar exo-granitic veins occur in proximal metamorphites.•,Juxtaposed disseminated, stockwork, breccia and vein style Cu-Mo-Fe-(Au)-sultide mineralization hosted by matie to intermediate intrusives of high K calc-alkaline, 1-type affinity.•,Cu-Mo-Au-sultides hosted by hydraulic breccia pipes, stocks and veins occurring in anorogenic A-type alkali feldspar granites and amphibole quartz syenites.•,Scheelite with minor Cu-Mo-sulfides and Au-associated with endo- and exo-skarns spatially related to I-type monzogranite, granite and alkali feldspar granite .The first three associations occur along the Yzerfontein-Helderberg-Zone, a 180 km lineament in the Tygerberg terrane, a zone exploited by syn-, late- and post-tectonic intrusives and their related mineralization. The fourth association is typical of the Boland terrane. The spatial and temporal relationships between the various metal associations is interpreted as the result of sequential intrusion of relative early high level S-type, followed by intermediate level I-type and finally anorogenic A-type granitoids during the evolution of a contracting continental margin arc and its inner arc. This plate tectonic setting suggests subduction in an easterly direction underneath the Kalahari craton. The spatial configuration of the various terranes at the present erosional levels is the result of rifting and significant differential vertical displacement following cessation of subduction, a terminal tectonic event possibly synchronous with intrusion of the A-type granitoids.Near surface preserved roof zones and cupolas of both S- and I-type granitoids in the Tygerberg and Boland terranes, respectively, render these areas extremely prospective for Sn, W, Mo and Au mineralization. The presence of intermediate to mafic volcanics, a diversity of calcareous lithotypes and favorable plate tectonic setting of the Malmesbury Group suggest potential for the thus far elusive VMS, MVT and Sedex base metal and minor precious metal deposits."

Jan 1, 1994

By W. A. Gow, J. A. Vezina

"A new process for treating scheelite for the production of tungstic tri-oxide is described. The novelty of the process resides in that an ion-ex-changer is used to convert sodium tungstate to either ammonium tung-state or tungstic acid.The process consists of a conventional hydrochloric acid leach of the scheelite concentrate, and the dissolution of the impure tungstic acid thus produced with sodium hydroxide at pH 8. The sodium tungstate solution is clarified and passed through a column of Dowex 50Wx8 ion-ex-change resin to exchange the sodium ions for either hydrogen or ammonium ions, both being suitable. The tungsten-bearing column effluent is evaporated to crystallize the tungsten as ammonium tungstate; the crystals are washed with nitric acid and water and decomposed by heat to pro-duce tungstic trioxide of high purity.Ninety-six per cent of the tungsten in the concentrate may be re-covered as tungs tic trioxide (W03), and the reagents consumed are 0.7 g HCl, 0.41 g NaOH and either 1.73 g NH.Cl or 225 g HCl per gram of tungsten."

Jan 1, 1966

By Norman Orr, J. W. Gregg, Jack Wahl

The Pembina Cardium pool is a low permeability, stratified, solution-gas drive reservoir. Water-flooding has proven to be an effective means of pressure maintenance for all areas of the pool in which an economic rate of water injection can be maintained. The majority of water injection wells in the pool are converted oil well~ with capacities greater than 100 millidarcy-feet. If the average injection rate per unit of capacity can be in-creased the lower capacity areas of the pool can be economically flooded. Theory, laboratory work, and two . early miscible-flooding projects with-in the pool suggested that average water injection rates for converted wells could be increased two to three-fold by the initial injection of natural gas liquids and natural gas. How-ever, these two early projects received volumes of natural gas liquid!:' and high-pressure natural gas which would be economically prohibitive for routine stimulation. Area D, one of the Five-

Jan 1, 1962

By H. Westengen

The AE alloy family exhibits remarkable combinations of properties when utilized as high pressure die castings. This performance relies on the fact that the rapid cooling rate resulting from the direct contact between the molten alloy and the steel die walls effectively refines the structure through rapid solidification. Furthermore, the rare earth additions modify the solidification pattern, dramatically reducing the solidification interval. A solid shell forms at temperatures exceeding 500C, reducing the tendency for die sticking and inverse segregation. As a result, the die castability is excellent, giving parts with a smooth and shiny surface. Unlike other magnesium die casting alloys developed to improve elevated temperature creep properties, AE alloys do not suffer from the commonly observed tendency to introduce brittleness. This feature is attributed to the fact that the massive magnesium- aluminium intermetallic phase is substituted by a finely dispersed lamellar structure of Al-RE intermetallics. The resulting combination of excellent elevated temperature properties and good ductility, as well as excellent corrosion resistance, means superiority of these alloys for demanding automotive engine and chassis applications.

Jan 1, 2006

By P. Cleyle, J. H. Masliyah, R. S. Chow, Z. H. Xu, Z. A. Zhou

Bubble nucleation in water under dynamic conditions was investigated using an autoclave at an air saturation pressure of 7 atm. Agitation during air saturation of water was found to be crucial in enhancing tiny bubble formation. More bubbles nucleated on hydrophobic surfaces at a higher agitation rate, due to cavity formation by the more intense hydrodynamic conditions. Flotation recovery of bitumen from oil sands demonstrated a significant role of bubbles nucleated in water: more than 50-170% increase in bitumen recovery from different oil sands was obtained by using air supersaturated than the regular water.

Jan 1, 2009

By K. Johanson, M. Hubert, C. Eckert, D. Ghose

The mining industry routinely processes material with different particle sizes. Coal, nickel ore, copper ore, lignite, shale, and phosphate ore are all examples of materials with wide particle size distributions. It is often assumed that these materials are homogenous and that any particle size distribution has the same chemical activity and composition. It is entirely possible, and quite likely, that chemical composition is a function of particle size distribution. In addition, particle size distributions in ore materials are often responsible for the difference in flow behavior in process equipment. This is evident in coal electrical production facilities. Fine coal may have the same ash content, sulfur content, and BTU value as coarse coal. However, all electrical production facilities know the extreme flow problems that result when attempting to handle wet fine coal. Segregation of these bulk materials is an important issue that must be understood to prevent these cohesive flow problems. Additionally, fertilizers are mixtures of particles with different shape and sizes. These mixtures must remain homogenous to optimize fertilizer performance. Segregation leads to poor product quality. This paper presents a method of measuring the magnitude of sifting segregation occurring in bulk material and the relationship between the strength of the bulk material and the separation tendency. It shows an inverse relationship between the yield strength of the material and the bulk segregation.

Jan 1, 2004

By B. Konda, R. Lauer, D. Camilucci, D. Gladwin

"Income based taxes are significant cost elements to be considered in evaluating investment in new mine development. This paper presents the results of comparative analysis of effective income-based tax rates for mining in the Northwest Territories (NWT), selected Canadian provinces and international jurisdictions. The study was done as background to a review of royalty regulations for the NWT. ObjectiveThis paper presents results of comparative analysis of effective mining royalty1 rates, and combined effective mining royalty and income tax rates on selected mine models for the Northwest Territories (NWT), with those for several other jurisdictions in Canada and abroad which compete with the NWT for mining investment.BackgroundThe February 27, 1995 federal budget directed the Department of Indian Affairs and Northern Development (DIAND) to proceed with a comprehensive review and amendments to northern natural resource management legislation in order “to increase revenues and ensure a fair return to the Crown.” DIAND is responsible for the administration of the Territorial Lands Act, and its regulations.The Territorial Lands Act gives the Governor-in-Council the authority to “… make regulations for the leasing of mining rights in, under or on territorial lands and the payment of royalties therefor,…”. In the NWT, the Canada Mining Regulations (CMR) provide for the disposition of mineral rights for most minerals, other than coal, petroleum and related hydrocarbons, in return for the payment of a royalty to the Crown.As part of this review of the NWT mining royalty regime, several computer mine models were developed and tax regimes in a number of jurisdictions were analyzed. Effective mining royalty rates, and the combined effective mining royalty and income tax rates were compared across the jurisdictions. The results presented in this paper are a part of the background work done in preparing a discussion paper on proposed changes to the NWT mining royalty that is expected to be released for public consultation in the very near future."

Jan 1, 1997

By R. Holmwood, M. Faris, P. Holloway, M. Collins

Sulphuric acid addition is a major driver of the economics in the processing of nickel laterite ores by high pressure acid leaching (HPAL). Understanding the optimal acid addition rate is essential for the success of any HPAL operation, and this is especially true at Ambatovy, where the composition of the feed tends to vary significantly on a day-to-day basis. Most studies on the effect of acid on nickel extraction in HPAL have used laboratory testwork as their basis. Although these studies are invaluable in assessing the economics of a new project, they are limited by the range of ore composition that can be tested and the differences between the operation of the laboratory equipment and the commercial plant. To enable optimization of the acid addition at Ambatovy, operating data from the HPAL operation were obtained using OSISoft’s PI system and the data from several periods were examined to develop relationships between acid addition and nickel extraction. The initial relationships from 2014 focused on the acid required to achieve a target nickel extraction of 95%, with aluminum and magnesium in ore and feed slurry solids content as the major variables. As Ambatovy ramped up through 2015 and 2016, the calculated acid requirement was further refined to address the effects of HPAL temperature and retention time, and the oxidizing/reducing characteristics of the ore, and to generate acid requirement relationships as a function of ranges of nickel extraction. These relationships supported raising the target nickel extraction to 96% and enabled the development of an economic model between acid addition and nickel extraction.

Jan 1, 2017

By Andrzej Luszczkiewicz, Magdalena Duchnowska, KGHM Polska Miedz S. A., Witold Pawlos, Jan Drzymala, Alicja Bakalarz, Przemyslaw B. Kowalczuk

Numerous data in the literature confirm that the chemical composition and consumption of grinding media influence electrochemical properties of flotation suspension as well as effectiveness and selectivity of upgrading processes. During a milling process, attrition of grinding media is observed. Depending on the susceptibility to abrasion, the grinding media influence, to a different extent, the redox potential, pH as well as flotation efficiency. As a result, different upgradeability of sulfide minerals is observed. The paper presents laboratory scale flotation results, obtained for the copper sulfide ore from Polkowice Region of KGHM Polska Miedz S.A. in Poland ground in the presence of forged steel, highchrome iron and stainless steel as the grinding media. The investigated flotation feed contained 36 g/t (ppm) of silver and 1.86 % of copper. Several flotation tests were conducted using fixed amount of frother and a mixture of sodium ethyl and isobutyl xanthates as the collector at three different doses of 75, 100 and 125 g/t. A comparison of the obtained results confirmed that the application of grinding media with different chemical compositions influenced the electrochemical properties of the suspension and recovery of silver and copper in the final concentrate. The highest values of redox potential were observed for the stainless steel as the grinding medium. Moreover, in the presence of this type of grinding media, regardless of the collector dosage, the best silver upgrading was observed. For the forged and high-chrome iron media, the recovery of silver depended on the collector dosage. It is indicated that higher levels of the redox potential, together with smaller amount of iron released from the grinding medium, improve the flotation of the silver-bearing mineral compounds from the copper sulfide ore.

Jan 1, 2016

By R. C. Gilmore, J. F. Brune

"Pulverized limestone rock dust used in United States underground coal mines to prevent and suppress coal dust explosions must easily disperse by forces of a methane or coal dust explosion. Moisture in the mine environment causes caking of the dust. Colorado School of Mines researchers performed dispersibility tests in a full-size explosion test drift. Tests included conventional, hydrophobized, and rock dust approved for German mines. Conventional and German standard rock dust products partially agglomerate, which may not be effective in suppressing a coal dust explosion, while hydrophobic rock dust retains better dispersibility.INTRODUCTIONA coal dust explosion devastated the Upper Big Branch mine in 2010 resulting in the death of 29 miners, the worst mining accident in the United States since 1972. The explosion propagated through approximately 65 km of active mine workings, but was extinguished in areas that had been properly rock dusted (Page, 2011). Researchers have long studied and established the ability of inert limestone rock dust to suppress coal dust explosions, see Richmond et al. (1975), Cybulski (1975), and Sapko et al. (2000).To be effective, rock dust must contribute to a total inert content of > 80% by weight and 100% of rock dust particles must pass through an 850 µm sieve, while 70% of the rock dust must be finer than 74 µm. This is established in US regulations 30 CFR §75.2. Dry rock dust is a nuisance that prevents mining work downwind from rock dusting activities. To overcome this problem, dust manufacturers have proposed applying the rock dust as a wet slurry or foam. After drying, manufacturers expected the slurry or foam-applied dust to have the same explosion suppression capabilities as dry-applied rock dust.Researchers at the Colorado School of Mines (CSM) designed and built a full-scale, underground Explosion Test Facility (ETF) at the CSM Edgar Experimental Mine in Idaho Springs, Colorado about 20 miles west of the CSM Golden, Colorado campus. To disperse the different rock dust products, researchers produced an air pressure pulse using a mesh array of PETN detonation cord. This method is simpler, more reproducible and safer than other methods considered, including methane-air explosions and a compressed air cannon. The detonation cord blasts produce a wind velocity of 30 to 50 m/s, the minimum velocity at which coal dust explosions can propagate, based on research by Nagy (1981) and Cybulski (1975)."

Jan 1, 2019

By K. B. Chaudhurl

The thermodynamics of the reactions taking place are examined with the aid of equilibrium diagrams for the Pb-O-S system. Based on investigations of chemical, mineralogical and differential-thermo analyses of intermediate products of different desulphuration degrees, an attempt is made to explain the mechanisms of the reactions in the smelting shaft of the KIVCET furnace. The differences between this and other direct lead smelting processes are demonstrated by these thermodynamic and kinetic considerations. Proceeding from these results, the practicability of direct lead smelting processes is discussed with reference to the composition of the primary feed materials to be processed. This comparison also considers the behaviour of minor metals, the products obtained and their characteristics in respect to further treatment. For assessing the operating costs, the over-all energy consumption is considered taking into account various price relations between electric energy and fuels/reductants. Based on the peculiarities of the various processes, an attempt is made to compare the necessary means of meeting the pollution control requirements. The paper concludes with reference to the criteria and problems involved in comparable evaluations.

Jan 1, 1978

By C. Schmidt, M. Kohnk, C. Siemers, J. Kiese

The application of conventional titanium alloys is limited to 550°C due to their poor oxidation resistance. In addition, severe grain growth is observed in single-phase titanium alloys in long-term runs at elevated temperature leading to a degradation of their mechanical properties. In exhaust applications in automotive or aerospace engineering, products are often manufactured by cold-deformation like deep-drawing or rolling which is normally difficult in oxidation-resistant titanium alloys due to the presence of titanium-silicides. Therefore, in the current study, titanium alloys based on CP Titanium Grade 1S (soft grade) were developed showing (1) improved oxidation resistance due to a concerted addition of silicon, iron and niobium, (2) microstructure stability by the precipitation of hafnium-silicides mainly on the grain boundaries and (3) good cold-deformation properties. The industrial production route was developed so that the new class of Ti-Si-Fe-Nb-Hf-alloys is now ready for application in exhaust systems of planes or cars at minimum 800°C.

Jan 1, 2015

By G. Armand, G. Arnold, A. Giraud, C. Auvray

The knowledge and understanding of the mechanical behavior of claystone is of critical importance in the aim of nuclear wastes storage. In this study, specimens of Callovo-Oxfordian claystone (COx) have been obtained from the ANDRA underground research laboratory in Meuse/Haute-Marne (France). This claystone is composed of carbonate inclusions (10-50µm) embedded in an argillaceous matrix (representing expanding clay minerals, such as smectites). The matrix itself is also multiphase and composed of clay aggregates of 1µm-size carbonate and quartz inclusions. This multiphase microstructure leads to a high heterogeneity witch was analysed through nanoindentation test grids. Moreover, the mechanical behavior of the claystone matrix is highly sensitive to humidity and temperature. The nanoindentation tests were performed in a climatic (i.e. temperature and humidity controlled) chamber at relative humidity levels from 50% to 98% and at two temperatures: 20°C and 60°C. In a first step, the curves of indentation were analysed using the commonly used Oliver and Pharr’s approach. Other wellknown parameters as the creep factor were also extracted. In a second step, Fisher-Cripps model (Fischer- Cripps, 2004) and Vandamme and Ulm model (Vandamme & Ulm, 2006) were used to identify viscoelastic properties. A statistical analysis is used in order to extract mechanical characteristics of the different phases. Hardness and elastic modulus decrease drastically with saturation (above 80% humidity) and to a lesser extend with temperature.

Jan 1, 2015

By C. J. Edmonds, R. Bland, W. C. Ferguson, R. Whitehead

"In 1969, the Environmental Science Division of James F. MacLaren Limited received authorization from The International Nickel Company of Canada, Limited to carry out a water quality monitoring program in the Lake Shebandowan region of Ontario, where a new base metal mining and milling complex was expected to go into operation in 1972. The objective of the program is to establish base-line water quality characteristics. Fully realizing their corporate responsibility to minimize the effects of the proposed activities on the environment, Inco decided that it would be desirable to establish a program by which any change in the quality of environmental waters will be detected before detrimental conditions ensue, permitting prompt corrective measures to be taken. The program has been in progress for over two years. The waters are sampled and analyzed four to six times per year. Sampling stations are located in Lake Shebandowan and on the adjacent Gold Creek - Matawin River system. On-site analyses and measurements are made of flow, dissolved oxygen, temperature and pH. Samples also are collected for later analysis in the laboratory. These samples are analyzed for a wide range of chemical and biological characteristics. The paper discusses the extent of the sampling program, the techniques utilized and the value of such programs in maintaining the quality of the environment."

Jan 1, 1973