Search Documents

By Hämäläinen M., O. Hyvärinen, E. Jääskeläinen

HydroCopperTM is a new hydrometallurgical process for the treatment of copper sulphide concentrates, which has been developed by Outokumpu. The process includes chloride leaching of copper concentrate, solution purification and precipitation of copper(I) oxide, an intermediate product, which is reduced and cast into copper products. The reduction can be carried out by pyrometallurgical methods or hydrometallurgically in an autoclave. This paper discusses the thermodynamic and kinetic aspects of the hydrogen reduction of copper(I) oxide in an autoclave. The results of the laboratory tests are presented and discussed. Finally, the autoclave method is compared with other options.

Jan 1, 2004

By Hiwa Salimi, Foley. Stephen R, Loghman Moradi

Common water-miscible organic solvents including DMSO, DMF, methanol, ethanol, acetone and THF in combination with HCl and low concentrations of H2O2 were investigated for dissolution of gold. THF showed the best result demonstrating that gold powder could be completely dissolved in 1.5 hours in 1.0 mol/L HCl and 0.2 mol/L H2O2. No complete gold dissolution was observed for the rest of solvents even after 24 hours. The rate of gold dissolution was measured by dissolving gold wire in THF/HCl/H2O2 mixture. The rate of gold dissolution in optimised condition was 75 g m-2 h-1 at room temperature and significantly increased to 590 g m-2 h-1 by raising the temperature up to 60 oC. Although a THF/HCl/H2O2 mixture showed a slower dissolution rate in comparison with aqua regia, however the applied conditions are considerably milder which is highly promising for gold leaching in an industrial scale.

Jan 1, 2015

By P. E. Davidson

The management of solid waste is known to be a large and increasing problem in high-population areas throughout the world. It is not necessary here to add further definition to the nature and magnitude of the problem. Instead, it is the purpose of this paper to describe a new process, called the Andco-Torrax System, which will be of use in converting municipal solid waste into useful energy forms and a granulated slag by-product. The paper includes a description of the first commercial plant for the process.

Jan 1, 1977

By F. Nava-Alonso, E. Pérez-García, A. Uribe-Salas, J. C. Fuentes-Aceituno, A. A. González-Ibarra, E. N. Castillo-Ventureño

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."

Jan 1, 2017

By O. A. Ojo, E. Anisimov, A. K. Khan

Electro-spark deposition (ESD) has recently generated a great deal of interest in processing aerospace materials. This is due to its potential for joining and repairing difficult-to-weld precipitation strengthened nickel-based superalloys without having problems of welding cracking that often plaque these materials. The short duration of current pulses involved in the process combined with the intermittent contact results in extremely rapid thermal cycle that produces nearly no heat affected zone in the substrate material. The microstructure of electro-spark deposited superalloy was meticulously studied in this work by scanning electron microscopy (SEM) and analytical transmission electron microscopy (TEM). The results show that in contrast to general assumption, the extreme rapid cooling rates involved in the ESD process did not produce partition-less solidification that is devoid of second phase microconstituents in the material. The secondary microconstituents were found formed along the intercellular regions of the solidification microstructure. The nature of these particles and the possible implication of their formation on mechanical properties of ESD processed material are reported and discussed.

Jan 1, 2015

By R. C. A. Thurston

Introduction A mechanical spring has been .defined by Wahl ( 1) as 'an elastic body whose ?primary function is? to deflect or distort under load, and which recovers its original shape when released after being distorted'. Most material bodies are elastic to some extent ? and will deform under load, but they are seldom regarded as springs since this is not their primary function. The principal applications of springs are the absorption of energy and the mitigation of shock, the support cf moving masses or the isolation of vibration, and the provision or measurement of definite loads or torques. A large number of spring types have been developed to serve these purposes and to meet the different operational requirements; they range from the large semi-elliptic leaf suspension spring to the delicate watch hairspring. The springs of most importance in machine design, however, are the helical round-wire compression or tension types. They are made in a wide variety of sizes and are used in tremendous quantities, mainly because of their low cost, their compactness, and their relatively high efficiency. Their field of application is as broad as that of machine design itself, but the bulk of production is almost certainly for suspension systems of vehicles such as automobiles, freight and passenger cars, and mine cars, and it is with the last of these applications that this paper is primarily concerned.

Jan 1, 1951

By R. L. Stanton

"The present contribution is complementary with a preceding one on the field association of the conform-able ""pyritic"" deposits. It considers the more important features of their mineralogical constitution and their microtextures, re-examines the present interpretations of these, and of-fer-some alternative explanations. The term ""pyritic"" for these de-posits is m many cases a misnomer, as two quite distinct ore types are inuolve. One is a banded pyritic sphalerite-galena-chalcopyrite ore (for which the term '•pyritic"" is in-deed quite suitable), while the other is non-banded and is composed essentially of pyrrhotite and chalcopyrite. In addition to these constitutional differences, each is distinctive in general appearance and texture. The occurrence of two such consistent but clearly distinguishable ore types is attributed -rather than to difference in source material and pressure-temperature conditions of deposition -to the contribution of similar source material to dissimilarly oxygenated environments of sedimentation. Textures in the banded ores generally thought to be indicative of replacement or of high-temperature exsolution are explained by slow, law-temperature segregation in situ during compaction, folding, and regional metamorphism."

Jan 1, 1960

By Yun-Soo Lee, Su-Hyeon Kim, Hyoung-Wook Kim, Joon-Hyeon Cha

A7075 aluminum alloys have high strengths but poor corrosion resistance. In order to improve the corrosion resistance, a clad sheet is suggested, that is the A7075 alloy sheet bonded to A1XXX or A6XXX aluminum alloy sheets which are surface layers with good corrosion resistance. Mechanical properties of the clad sheets are determined by the combination of the component layer sheets, and thermomechanical treatment should be precisely designed when the strengthening methods of the core and the surface alloys are quite different. In the present study, three-layered A6022/A7075/A6022 clad sheets were fabricated by roll bonding process. Simplified processes incorporating a twin roll casting were also suggested in order to reduce the processing cost. Several temper methods composed of rolling, annealing, solution treatment, and aging were suggested in order to optimize the mechanical properties of the sheets. The strengths of the clad sheets were compared with the bare A7075 and bare A6022 sheets.

Jan 1, 2015

By J. G. Debanne

MOST company-employed petroleum engineers have in their accounting departments punch-card computers that can perform engineering calculations thirty to three hundred times faster than desk calculators, or they can rent such machines from Computing Service centres. These machines not only eliminate the drudgery of desk calculation but also the risks of human errors. The I.B.M. t 604 punch-card computer of Texaco's accounting department in Calgary has been used for oil and gas property evaluations, curve fitting by least squares, statistical core analysis studies, unsteady-state water in-flux studies, phase equilibrium performance prediction of oil reservoirs, gravity segregation calculations, etc.

Jan 1, 1958

By E. C. Keeley

THE property of Buffalo Ankerite Gold Mines, Limited, is in Delora township, Porcupine area, Ontario. The southwestern part of the property is ground formerly owned by Marbuan Gold Mines, Limited, which was acquired by Buffalo Ankerite in January, 1936. Until 1938, the Ankerite (or North) mine and the Marbuan (or South) mine continued as separate operations, each developed through a surface shaft and winze to the 1050 level and each having its own mill. This meant high hoisting costs, which, in 1936 and 1937, amounted to 36 cents per ton. In 1938, the underground workings of the two mines were connected on the 1050 level, and ore from both mines was hoisted at the main, or No. 2, shaft of the North mine, location of which is shown in Figure l. This shaft was discontinued at a depth of 1150 feet because, owing to the soft nature of the talc (serpentine) rock in which it was sunk, it had to be concreted throughout, and also because of its great distance--1,100 feet and 1,400 feet, respectively-from the North and South orebodies.

Jan 1, 1945

By P. C. Santos-Munguía, F. Nava-Alonso, O. Alonso-González

"The gold recovery of a Mexican cyanidation plant, in Sonora, has been decreasing due to the increasing presence of gold tellurides. This work presents the results of different processes aimed to recover the remaining gold from the cyanidation tailings of the operation. The cyanidation in the mine is performed at 0.1 g/L NaCN and pH = 10.3, adjusted with lime. The treatments studied in the laboratory with these tailings were: cyanidation at higher cyanide concentration than that used in the plant, cyanidation with oxygen injection, cyanidation with oxygen and lead nitrate addition, and thiourea leaching. The results obtained with each of these treatments are presented and discussed with the final objective of proposing a method to recover the gold associated with tellurium.INTRODUCTION It has been demonstrated that gold telluride is refractory to the conventional cyanidation process and, for this reason, some alternative methods to recover precious metals from tellurides have been proposed. (Zhang et al., 2010). These include cyanidation with modified conditions or the use of non-cyanide leaching agents. This work presents the gold leaching results of tests performed with a sample of cyanidation tailings obtained from a Mexican deposit containing telluride species. The mine exploits a mesothermal deposit with a molar Te/Au ratio of 1, containing also lead, molybdenum, bismuth and tungsten. Gold is recovered from the ore by standard cyanidation, however, lately the gold recovery has decreased, likely due to the tellurium content of the ore. The sample used in this work was the cyanidation tailings of this deposit. It was treated in the plant by cyanide heap leaching (0.1 g/L NaCN, pH = 10.3 adjusted with lime). Some gold remained after the cyanidation and it was thought that this gold was associated with tellurium. The objective of this work was the recovery of the remaining gold from the tailings by an alternative process."

Jan 1, 2017

By Technische Universität Braunschweig, K. Saksl, J. Furste, P. Eschenbacher, F. Brunke, D. Wolter, M. Kohnke, C. Siemers, J. Kiese, M. Schlemminger

"In general, titanium alloys combine outstanding mechanical properties with corrosion resistance and biocompatibility and are, therefore, used in many challenging applications. Nevertheless, for special products, well-tailored properties are required which might not be achievable by a specific design so that new or modified alloys are needed. In this overview paper, alloy development strategies performed at the Institute for Materials of the Technische Universitat Braunschweig are discussed at different examples, namely, (1) oxidation-resistant, microstructural-stabilized and cold-workable alloys for exhaust applications, (2) aluminum- and vanadium-free, medium-strength and cold-workable alloys for implants and osteosynthesis applications and (3) free-machining alloys by the addition of particles with low melting points for non-safety critical light-weight constructions to replace heavier steels, e.g. in automotive applications. A special focus is set on the alloy development techniques and the analyses carried out to achieve well-balanced properties by the optimization of the alloy compositions. INTRODUCTIONTitanium belongs to the allotropic metals and can therefore exist in two different equilibrium lattice modifications. Pure titanium crystallizes at 1668°C in a body centered cubic (bcc) structure called ?- titanium which at 882°C transforms to a hexagonal close packed structure (hcp), the a-titanium. A martensitic ?-to-a-transformation is possible at large cooling rates. This thermally induced hexagonal martensite is called the a'-phase. The transformation temperature named ?-transus-temperature (T ?) can be influenced by alloying elements (Peters & Leyens, 2002).For titanium alloy production typical alloying elements are aluminum (Al) and oxygen (O), both a-stabilizers shifting the ?-transus temperature to higher temperatures, whereas tin (Sn) and zirconium (Zr) only show a limited influence on the ?-transus temperature. The ?-stabilizing elements are subdivided into two groups: Niobium (Nb), molybdenum (Mo) and vanadium (V) stabilize the ?-phase between the melting point and room temperature and are therefore called isomorphous -stabilizers. Elements like copper (Cu), iron (Fe) or silicon (Si) also stabilize the ?-phase to lower temperatures but undergo a eutectoid reaction during cooling. ?-titanium then dissociates to a-titanium and an intermetallic compound. Consequently, these elements are called eutectoid ?-stabilizers (Boyer, Welsh & Collings, 1994)."

Jan 1, 2016

By James B. Templeton

"IntroductionWith the steady rise of the cost of coal and freight, the time is now ripe for an investigation into the feasibility of using the heat pump for heating purposes in fairly remote industrial areas.The gold mines of northern Ontario seemed to be a most likely place for the application of the heat pump.It was decided that the first step in the investigation would be to determine what economic advantage was to be gained by using the heat pump and thereby determining whether a further and more detailed research programme was warranted.If we can use the heat pump with economic advantage, we can reduce our mining costs and make a worthwhile contribution to our national economy by reducing the import of U. S. coal.The investigation was conducted under the auspices of the Nipissing Fellowship and directed by Professor R. E. Barrett of the Department of Mining Engineering, University of Toronto.With the able guidance of Mr. C. S. Gibson, of the Mines Accident Prevention Association of Ontario, the author visited the following mines: Mcintyre-Porcupine, Delnite, Dome, Lake Shore, Wright-Hargreaves, Kirkland Lake, Macassa, and Kerr Adcliso11.In all cases, the management and technical personnel of these mines were most co-operative and helpful in supplying information and ideas.It should be emphasized at the outset that the design and operation of the heat pump itself is by no means complicated or even new. The reason we hear so much about it today is because there have been improvements in compressors, motors, and heat exchangers in the past few years, and because fuel and freight rates have risen to such a point that, in some cases, the heat pump now has an economic advantage over other methods of heating."

Jan 1, 1950

By J. E. Reeves, J H. Morgan

Certain non-metallic minerals are used widely as fillers in the manufacture of many Canadian products. The first part of this paper deals in a general way with deposits of such minerals and their mining, with the concentration and preparation of the minerals for market, with specifications of the consumers, and with methods of control of the products to meet the specifications. The second part of the paper de-scribes talc as a specific example of mineral filler. Its production and uses in Canada and the possibility of producing higher grades of talc are discussed. Some suggestions are made for meeting the needs for mineral fillers as Canada's industry expands. RELATIVELY few people are sufficiently aware of the vast and important role that is being played in our everyday lives by mineral fillers. Many kinds of paints, papers and plastics, to mention three major classes of industrial products, are literally loaded

Jan 1, 1961

By Y. Serres

In the past, conventional reflection seismic techniques were not very successful when applied to typical mining exploration: they lacked resolution in the shallow range or were not cost effective. By combining a light earth tamper source, special geophones and field procedures, a stacking process of the returning seismic events using a microprocessor system, and a sophisticated sequence of adapted digital data processing, Mini-Sosie achieves high resolution in the 100-ft to 4000-ft range. Additional advantages result from the very quiet nature of the source and flexibility of the system. Although Mini-Sosie might be used in the refraction mode, or for well velocity logging, it has found its main applications with the reflection technique.

Jan 1, 1978

By J. W. Thomson, H. J. Lloyd, R. J. Taylor

"THE HOLLINGER MINE has been producing gold and by-product silver almost continuously for forty-eight years. The value of current production is $10,000,000 annually from one million tons of ore. Its management •has, particularly over the past decade, increasingly . concerned itself with the problem of profitable operation in a time of steadily rising costs and a fixed price of gold. At one period in the life of the mine, before World War II, production resulted in yearly profit margins that were stable and relatively thick. In winning gold from a series of inconsistent vertical ore lenses, operating management was much better protected than it is today against a general rise in cost or dip in grade of ore. The tissue-like thinness of present-day margins demand more careful handling. A sharp rise in costs, if protracted, could easily rip the tissue to shreds and close down the business. The counter-measure of raising grade and gutting the mine would bring on the end perhaps more rapidly, without having contributed much to the recovery of our national re-sources, nor to community welfare. The alternative is to keep costs under control."

Jan 1, 1960

By Roberto Pena, Cristhian Morales, Darwin Morales, Veronica Cambiaso

"This article makes evident the shortcomings of the current operation of oxygen pipes as well as the damages they cause and why they cause them. When focusing on the causes and effects of these drawbacks, it was possible to develop a new family of thermal lances that could pierce a taphole with the precision of a drill but with the capacity to complete the whole operation. Although efforts have been made to replace oxygen pipes since they are annoying, dangerous and inefficient, nobody had worked to improve the way the traditional oxygen pipe taps/perforates the furnaces and reactors tapholes. In fact, developments made in drills and robotic arms, have failed to replace the oxygen pipe, which despite their negative side effects have been used for more than a century. Observation and theory were key to radically transform this humble tool into a dependable and efficient support in the operation. A good news that it is worthwhile to share for the benefit of all of us, passionate about the world of pyro metallurgy.INTRODUCTION Normally, reports and papers prepared for conventions, symposia or other technical events related to metallurgy aim to relevant topics in the operational field, probably because in them lay the scale economies every company pursues. We intend to give relevance to a matter normally disregarded in operations, but that unmistakably vital: if the furnace or reactor cannot be bled, the pyrometallurgical process will not be completed. Besides, if the tapping task is difficult or is long delayed, the availability of the furnace will be reduced. Consequently, there will be a waste of energy and workers will be exposed to dangerous levels of radiation as well as to work overload and physical injuries Apart from these basic effects, in tapping operations where oxygen pipes are used, we can see serious damages in the smelting furnace, especially in the taphole components such as refractory bricks, taphole jackets and water cooled plates. This paper intends to show that taking care of the tapping task can significantly upgrade not only to the tapping operation itself, but also the whole plant productivity."

Jan 1, 2017

By J. G. Trowell, D. T. Magee

"IntroductionMANITOBA'S first recoverable oil was from the California Standard Daly 15-18 well in Lsd. 15, Sec. 18, Twp. 10, Range 27, W.P.M., completed early in 1951. This well also gave the first indications of commercial production in the Williston basin, which is centred in North Dakota and extends into southeastern Saskatchewan and southwestern Manitoba. Subsequent drilling in the Manitoba portion of the basin has revealed the presence of oil in more or less commercial quantities at various points in an area approximately four townships in width and eleven townships in length.Although completions are becoming fairlly widespread in the area,, the greatest activity is in the Virden district, with the focal point in the Daly field, approximately eight miles west •of Virden. This paper will deal with the various techniques used in the Daly field, where •completion problems have •been unusually troublesome. Techniques evolved there have already been used with success at other points in southwestern Manitoba.Daly FieldGeneralTo date, all production has been from the Mississippian limestone, which is encountered •at depths ranging from 2,300 to 2,500 feet. Pay thickness is •of the order of 100 feet. Core analyses indicate average porosity .of about 9 per cent but permeabilities, for the most part, are extremely low."

Jan 1, 1953

By B. K. Choi, G. E. Kim, S. Noh, T. K. Kim

Oxide dispersion strengthened (ODS) steel has been developed as the most prospective core structural material for next-generation nuclear systems because of its excellent high strength and irradiation resistance. In ODS steel, finely dispersed nano-oxide particles with a high number density in the homogeneous grains can be very attractive to achieve superior mechanical properties at high temperatures, and these favorable microstructures can be significantly changed using process parameters during the mechanical alloying procedures. In this study, the effects of mechanical alloying times on the microstructure of 10Cr-1Mo ODS martensitic steel were investigated. Pre-alloyed powders with Y2O3 powder were mechanically alloyed for various milling times using a high energy horizontal ball-mill apparatus (model: symoloyer CM20). Powder properties such as the mean particle size, size distribution, and crystallite size were evaluated. Uniaxial hot pressing was employed to consolidate the milled powders. The results of a microstructural observation after the MA and UHP processes indicated that the homogeneity of the martensitic structures was considerably increased with the longer milling time. It is thus concluded that the mechanical properties of the ODS martensitic steel are greatly dependent on the mechanical alloying times.

Jan 1, 2015

By John F. Dougherty

Recently, there has been much debate as to the relevance of reporting financial results using the conventional accounting systems, which is based on historical costs, during a period of rapid inflation. In the following paragraphs , the symptoms, if not the causes, of inflation, its detrimental effect on the financial soundness of business in general and the financial reporting changes being advocated to overcome perceived weaknesses in the present financial reporting system in accounting for the effects of inflation will be reviewed. Finally, a course of action as a sound approach to the financial reporting problem will be recommended.

Jan 1, 1978