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By R. Hewer

Transition metals have been widely used in medicine throughout history. The medicinal use of metals extends back to the earliest recorded history when the Chinese used gold as treatment for a variety of ailments. The ancient Egyptians used copper to sterilize water and mercury was reportedly used by Hippocrates in 400BC. Thereafter, numerous other metals have been used as treatment throughout the centuries. For example, zinc sulphate was used as an emetic in the 17th century and zinc oxide was used to treat epilepsy in the 18th century. This use of metals, and numerous other instances, which have been well described in Sneader 2008,1 make for interesting reading but largely occurred prior to the advent of rigorous scientific method. Therefore, although there are exemptions, most therapeutic applications of metals prior to the modern age lack scientific grounding and have been found to be mostly ineffective. Of more relevance are metal-based medicines approved by regulatory bodies (i.e. Food and Drug Administration; FDA) that are in current use as therapeutic drugs. There are presently a large number of metal-based drugs that are approved for use by the FDA ranging from over the counter medicines, such as bismuth subsalicylate for gastrointestinal problems, to prescription drugs such as lithium carbonate for the treatment of manic depression. The list of metal-based medicines approved by the FDA not only incorporates base metals but also includes precious metals. Platinum complexes have been found to be potently active against several different types of cancers while gold complexes have shown application as treatment for rheumatoid arthritis (RA). With the well-established foundation that exists for metal-based medicines, it is imperative to continue exploration into new therapeutic areas. The precious metals; gold, ruthenium and platinum, continue to attract scientific interest in the field of biomedicine and have been widely researched. Scientific studies conducted on gold complexes have demonstrated the potential of this metal for the treatment of HIV/AIDS, cancer and malaria. These diseases are also specific health concerns for developing nations; countries where disease has devastating impact. Within South Africa alone, an estimated 5.7 million people are infected with HIV/AIDS,2 approximately 7 000 new cases of malaria are reported annually, and it is projected that 1 in 4 persons will develop cancer. Continuous development of therapeutic drugs to combat these diseases is therefore apriority, and the exploration of gold-based compounds for this purpose is warranted.

Jan 1, 2009

By D. G. Krige

Using a very large number of chip-sample values from a mined-out area of the Hartebeestfontein mine and accepting these as equivalent to borehole values (also areas of 1 km by 1 km as equivalent to 'mines'), the authors apply a series of borehole-valuation procedures to these 'mines', Large undeveloped sections of existing mines are also regarded as the equivalent of such 'mines'. These procedures start with the orthodox arithmetic mean and then introduce additional information in the form of the Iog normal frequency distribution model for Sichel's 't' estimator. Knowledge of the average log-variance within mines leads to the tH estimator. The mean grade of the 'family' of mines to which a new mine belongs is then introduced via regression or elementary kriging. Next, further information on the macro spatial structure of the grade is used, together with the grades of adjacent existing mines in ordinary and simple macro-kriging procedures; finally, via the distribution model, the grade is seen as a function of the logs of the grades and their variances. These are introduced as spatial variables, and both are estimated by macro-Iog normal ordinary and simple kriging procedures with grades and variances from adjacent mines'. Comparisons are also made between macro-kriging on lognormal transformed values versus untransformed values. Conclusions are drawn on the relative importance of the various items of additional information used, on the procedures followed, and on the significance of the advantages gained

Jan 1, 1992

By N. von Stade, G. du Plessis, W. van Niekerk, H. Bosman

Exploration, and other, boreholes are drilled to obtain information about the geological environment. Knowledge of the exact position (dip and direction) of the holes is important to ensure compatibility between the hole and the geological information. Kumba Resources traditionally used mechanical methods to determine the hole characteristics. These are cumbersome and expensive, and as a consequence a new method, the IVEC (Iscor Video Exploration Camera), was developed which utilizes a charged coupled device (CCD) image sensor focused on a three-dimensional compass. This system is rugged, relatively inexpensive and gives real-time results during borehole logging. Keyword: Borehole inclination, deviation, dip and direction, geophysics, exploration.

Sep 1, 2001

By J. Portal

One of the key products produced by the mineral sands industry is the titanium dioxide slag, a process that requires grinding of a coarse product down to a valuable saleable product. Traditional methods have included the vertical roller mill in tandem with dynamic air classifiers and, alternatively, two-stage grinding and crushing through an AG mill in closed circuit with a dynamic classifier and secondary gyradisc crushers. The products produced, commonly known as chloride and sulphate slag, are differentiated by the particle size distribution of the final product. The more valuable chloride slag must, by specification, be a product sized in the range between 850 and 100 microns?the more fines generated in the grinding process, the less higher valuable final chloride slag is produced. This paper will explore a technology that is new to both the mineral sands and to other mineral processing industries. Inter particle communition, or IPC as it is known, has been applied in the cement industry to improve the performance of clinker grinding mills. The principle is to create a process of material on material comminution under high pressure that fractures the material along the grain boundaries rather than breaking it smaller than a gap setting in the crusher. The process is now looked at for the TiO2slag producers because of the potential benefits of energy savings and with a minimal generation of minus 100-micron fines. Discussions will revolve around the design and functionality of the Rhodax® both from a process and maintenance perspective, a typical test regime and results on slag grinding. The development of the flowsheet necessary for the process will be examined, the ancillary equipment required and finally the scale-up from the test to an industrial plant will be investigated. Full-scale results of an operating plant will also be given showing the benefits that can be realized. A promising new flowsheet with fines reintroduction to the Rhodax® crusher will be presented.

Jan 1, 2007

By S. Tu, Y. Yuan, H. Wei, Z. Chen, M. Jia

"To reduce production costs and increase efficiency in ageing coal mines, a system that utilizes two shearers in a fully mechanized longwall working face is proposed. Using theoretical and engineering experience, three issues pertaining to the system were determined: (a) the two-shearer mining technique; (b) matching and modifying the equipment; (c) and coal-cutting task allocation for each shearer. Two mining processes are proposed, with the two shearers travelling in either the same or opposing directions. To avoid breakage of chains and pan extrusion of the armoured face conveyor (AFC), the length of the AFC ‘snake’ was controlled. To ensure continuous cutting and transporting of coal, the cross-sectional dimensions of the AFC were checked and the shearer closer to the head drive was modified. Based on the assumption of equal cutting times for each shearer, the meeting position of the two shearers was obtained by using a theoretical model of mining task allocation. Application of this technique at No. 2 Jining Mine, China, has shown remarkable benefits: daily production capacity was increased by 54% and personnel efficiency was improved by 33 t/d per person. IntroductionAll coal mines aim to increase the unit output of the working face to reduce mining costs and improve the economic efficiency of the operation. To achieve this goal, a production model known as one mining face of the mining area has been adopted by most Chinese coal mines (Hu, Meng, and Zhu, 2008; Zhang, Zhang, and Wang, 2000). Under these conditions, the main technical approaches to maximize the output are increasing the width of the working face (Qu, Xu, and Xue, 2009) and accelerating the advancing speed (Robbins, 2000). In coalfields with shallow seams, the width of a fully mechanized face exceeds 300 m (Ju and Zhu, 2015; Fu, Song, and Xing, 2010); in coalfields with deep seams, the width of the face is usually greater than 240 m (Liu et al., 2016; Li et al., 2013). The term ‘super-long working face’ was proposed to describe working faces with a width of over 240 m (Zhao and Song, 2016; Xu et al, 2007) in China. To support these long working faces with rapid advancing speeds, high-powered mining equipment is required (Kulshreshtha and Parikh, 2001, 2002; Tu et al., 2009; Mishra, Sugla,and Singha, 2013). This is easily achieved in newly built mines, but is not a good choice for ageing mines because of the low return on a high investment on account of the limited remaining resources. It is therefore difficult for ageing mines to significantly increase their unit output with the existing mining equipment. This study focused on this problem: two shearers were applied to a longwall fully mechanized working face (LFMWF) to achieve increased unit output."

Oct 1, 2018

By Wm. Bleloch

SYNOPSIS The feasibility of rejection of nitrogen from stack gas by recycling of top-gas with cold-blast 95 to 98 per cent oxygen is assessed. It is concluded that nitrogen could be removed to a level below 3 per cent of the stack-gas using recycled cleaned cold top-gas and 95 to 98 per cent oxygen produced by a single-column air separation plant with liquid-air reflux instead of liquid nigroten reflux. The partial pressure of carbon monoxide in the stack-gas could be doubled without top pressure and the deposition of carbon and reduction of iron oxides by the stack gas could be markedly increased. It is concluded that rate of stock descent could be doubled compared with present-day practice and an iron make of 4400 kg/m 2 of hearth area/hour may be attainable with a working volume of 129 m2/m hearth diameter by this method. Oxygen consumption is estimated at possibly 280 m2 (0.4 t)/t iron made and carbon consumption at possibly 280 kg/t iron. Power consumption for oxygen including auxiliaries is estimated at 304 kWH/t 100 per cent oxygen as 95 to 98 per cent gas. The air separation cycle due to Schuftan is discussed in some detail, and the components of a 1 600 metric ton/day separation plant are briefly discussed. The paper is a theoretical essay.

By S. Vorberg, B. Fischer, U. Glatzel, R. Völkl, D. Lupton, M. Wenderoth

Owing to their excellent oxidation and corrosion resistance, Pt and its alloys are being used preferentially at elevated temperatures and in aggressive environments. For example, an important application field is the glass industry. Alongside the discovery of new potential application fields, the knowledge of material properties is essential for computer simulations, design configuration, process optimization, research and development or quality assurance purposes. Due to the importance for technical applications high-temperature properties have been investigated for currently available Pt-base alloys with ongoing improvements. For the determination of tensile creep test data up to 3000°C, including precise strain measurement, special experimental equipment has been developed at the University of Applied Sciences Jena, Germany. An overview of the existing and newly obtained mechanical property data on pure Pt, solid-solution strengthened Pt-Rh alloy, oxide dispersion-hardened materials Pt DPH and Pt 10%RhDPH as well as cutting-edge results on Pt-base superalloys hardened by intermetallic precipitates will be presented and discussed. Furthermore, some important application examples for the abovementioned Pt-materials will be given.

Jan 1, 2006

By S. Selmer-Olsen

New trends and developments in the production of ferro-silicon, ferro-manganese and ferro-chrome alloys are discussed, with emphasis on the general trend to the adoption of large production units. Problems which arise, both of a metallurgical and an electrical nature, due to the use of large electric furnaces, are outlined with specific reference to the limitations imposed by the power carrying capacity of Soderberg electrodes, the furnace resistance and the furnace reactance. The implications of combining high resistance within the furnace with good metallurgical operating conditions are illustrated by considering the production of ferro-silicon and ferro-manganese. The possibility of replacing electric furnaces used for ferro-manganese production, by large low shaft blast furnaces using oxygen enriched blast, is mentioned. The continued use of small electric arc furnaces for ferro-chrome production is also mentioned, and is ascribed to lack of ore suitable for treatment in large furnaces. Agglomeration of chromite ores appears to be a possible answer to this problem.

By K, J. MAUNDERS

This paper briefly describes a computerised model of the South African electricity system which has been developed jointly by the Atomic Energy Board and the Electricity Supply Commission. The results of an analysis of this system have been subjected to a fairly extensive sensitivity analysis which reveals that up to the year 1990 between 680 and 700 million tons of coal will be required for electric power generation, together with between 7 000 and 10 000 tons of uranium. This result is fairly insensitive to data variations, but the prediction of a cumulative requirement up to the year 2000, of between 1 300 and 1 800 million tons of coal and 25 000 to 70 000 tons of uranium, proves to be very data-sensitive.

Jan 1, 2014

By R. C. M. van der Spuy

The heavy-minerals plant at the Palabora Mining Company treats 25 to 30 kt of new feed daily. The U3Og value of the ore averages approximately 40 p.p.m. The circuit consists of four stages of upgrading on 68 Reichert cones, fol. lowed by a jig and 30 table decks. The paper describes how feed-distribution problems have been overcome and the methods used for monitoring and controlling the cone performance. The adaptation of a standard jig for the recovery of fine minerals is discussed, and a method of 'table agglomeration, for the recovery of coarse refractory copper sulphide is described. The tables consist of polyurethane-covered fibreglass decks, and their operation is controlled according to measurements of the uranothorianite content of the concentrates and middlings by means of a nuclear scintillation counter. The upgrading ratio of the uranium mineral by gravity concentration is 1000:I, baddeleyite (ZrO.) being recovered as a by product.

Jan 1, 1982

By R. Yi

The determination of the optimum cutoff grade for a surface mine may be very different from that of an underground mine because a selectable mining method may be used in the latter case. A review of research into the theory of cutoff grade is made and then a new method, based on Optimal Control Theory, is presented. This method uses a Hamiltonian function to assist in obtaining the solution. It is shown that the life of a mine can be divided into three parts: a beginning period bf planning before mining; an intermediate period when both an average price and market information are used continually to adjust the cutoff grade; and, a final period when the main consideration is the current market situation.

Jan 1, 1987

By A. Pytlik, W. Masny

"Underground mining is subject to various natural hazards such as seismic events, rockbursts, fire, and gas (methane). In general, an increase in the extraction depth causes an increase in the likelihood of these hazards, especially seismic activity and rockbursts. Dynamic phenomena such as rockbursts and tremors have been recorded on six continents: Europe (Poland, Russia, Czech Republic, Germany, and Slovenia), Asia (India, and China), North and South America (USA, Canada, and Chile), Africa (South Africa), and Australia. To select appropriate mine working supports for such dynamic phenomena, the performance characteristics of such support types must be determined under both static and dynamic load conditions.This article presents information regarding the application of rockbolts in Polish underground hard-coal mines. Dynamic phenomena occurring in the mines from 2004–2013 are also characterized. A methodology developed at the Central Mining Institute (GIG) for the laboratory testing of rockbolts is presented. In this methodology, the bolts are loaded by the direct impact of a free-moving mass (up to 20 000 kg) at speeds of up to 1.2 m/s. The facilities at GIG used to test the support under static and dynamic load conditions are characterized, and the results of laboratory tests on yielding bolts with a nominal capacity of 420 kN are presented. These types of bolts are commonly used for reinforcing steel arches and the surrounding rock mass in Polish coal mines. The results of the laboratory testing of yielding bolts are discussed.IntroductionSeismic events such as rock bumps and tremors occur with great frequency during underground mining. These phenomena have been reported in such countries as Poland, Czech Republic, Germany, France, Slovenia, Russia, India, China, the USA, Canada, Chile, South Africa, and Australia (Brauner, 1991; Potvin, Hudyma, and Jewell, 2000; Kidybin??ski, 2003; Driad-Lebeau et al., 2005; Li, Cai, and Cai, 2007; Whyatt and Loken, 2009; Durrheim and Riemer, 2012; Holub, Rušajova, and Holec?ko, 2011). Descriptions of the dynamic events and their effects in the form of damage to or destruction of supports have been presented in many publications, both for hardrock mines as well as for coal mines (Brauner, 1991; Dubin??ski and Konopko, 2000; Heal, 2010; Heal and Potvin, 2007; Simser, Joughin, and Ortlepp, 2002; Kaiser and Cai, 2012; Cai 2013; Nierobisz, 2013; Mark, 2014; Masny and Prusek, 2015). One of the main goals of the research has been to develop methods, criteria, and guidelines for the selection of an optimal and safe support for mine workings located in areas of rock bumps or tremors. Example of such studies include the Canadian Rockburst Support Handbook (Kaiser, McCreath, and Tannant, 1996), or the principles presented in the literature (Li, 2010; Cai, 2013)."

Jan 1, 2016

By A E. Paterson

General aluminium corrosion charts based on 1100 alloy listing product and temperature have been developed by AFSA, mainly from available sources. The categories of corrosion expectation are fairly wide. As a result the charts are more useful in indicating what is not suited as distinct from what is. The question of how to develop useful information is assessed. Having discarded improbable options one is left with the need to refine the possible. Within each alloy group corrosion potential differs. From an engineering application point of view, the corrosion resisting marine alloys, the 5xxx series show increasing corrosion as the percentage of Magnesium increases. An important issue is that as the welding filler used for 5xxx series is Mg rich (to avoid hot cracking), the filler is likely to show the weakest resistance. In addition, when subjected to fatigue loading, the preference for critical joints is to dress the joint to the level of the base material. Overheating of the weld extends the HAZ zone and weakens the material as Mg moves to the grain boundaries. Indicator chart refinement approaches suited to aluminium use in commercial transport are discussed.

Jan 1, 2006

By Marthie Kotze, Jacolien Wyethe, Bert Van Hege, Richard Bell

Base metal refinery effluent streams may contain low metal concentrations that cannot be recovered by precipitation. Although the concentration is low, the total mass of unrecovered metal can have significant value because of the volumes of effluent generated. This metal may be recovered with high efficiency using selective ion exchange resins. Three process schemes are considered, viz., fixed bed column ion exchange, continuous countercurrent resin-in pulp, and continuous carousel resin-in-pulp. Each of these has different requirements in terms of equipment, resin inventory, capital and operating costs, and different limitations on feed conditions. Bateman and Mintek recently developed a model which allows an upfront economical evaluation of ion exchange options. The model evaluates the capital and operating costs for each process scheme for various base metals. This provides a general guideline for selecting the appropriate process arrangement for a given process stream.

Jan 1, 2005

By B. M. Van Vliet

SYNOPSIS This paper outlines the principles involved in the regeneration of activated carbon for renewed use in the recovery of precious metals or the purification of water. While chemical methods are effective in restoring the activity of spent activated carbon containing only single or defined adsorbates, thermal methods have to be used when the spent carbon is loaded with a heterogeneous mixture of adsorbates such as those normally present in industrial process streams or effluents. The steps involved in thermal regeneration are described, together with the operating conditions that can be controlled to give the required degree of activation. Finally, an account is given of the structural changes that occur in a new or spent activated carbon during thermal treatment.

Jan 1, 1991

By H. M. Dus, D. J. Smith

Resistivity tests indicated that, at temperatures lower than 1450°C, reducing agents alone, as well as burdens consisting of high-carbon ferrochromium and reducing agents, exhibit wide differences in resistivity. These differences are less pronounced at elevated temperatures. The resistivity of a reducing agent and the volume fraction it occupies are important factors controlling the resistivity of burdens of high-carbon ferrochromium. A mathematical model is formulated to describe the dependence of the resistivity of mixtures of conducting and insulating particles on the particle sizes and the volume fraction occupied by the conducting phase. The resistivity of burdens of high-carbon ferrochromium is high if the particle size of the reducing agent is larger than that of the other components of the burden. A number of reducing agents showed small variations in their reactivity towards chromite ore in the solid state. However, with chromite ore in the liquid state, reduction proceeded more rapidly with reducing agents occupying larger volume fractions. During the smelting of manganese ore, high initial rates of reduction were observed for reducing agents that had a high reactivity towards carbon dioxide and a high content of volatile matter, and that occupied a large volume fraction. High liq'uid-state reactivities were observed for reducing agents occupying a large volume fraction and having a Iow degree of graphitization.

Jan 1, 1980

By J. Levin, I. J. Corrans

Wet high-intensity magnetic separation (WHIMS) for the concentration of gold and uranium was tested on many Witwatersrand cyanidation residues, and on some ores and flotation tailings. The results varied, but many indicated recoveries of over 60 per cent of the gold and uranium. The main source of loss is the inefficiency of WHIMS for material of smaller particle size than 20fLm. The recoveries in the continuous tests were lower than those in the batch tests. The continuous tests indicated an operational difficulty that could be experienced in practice, namely the tendency for wood chips and ferromagnetic particles to block the matrix of the separator. It was decided that a solution to the problem lies in the modification of the separator to allow continuous removal of the matrix for cleaning. A system has been developed for this purpose and is being demonstrated on a pilot-plant scale. Promising results were obtained in tests on a process that combines a coarse grind, gravity concentration, and WHIMS. In the gravity-concentration step, considerable recoveries, generally over SO per cent, of high-grade pyrite. were obtained, together with high recoveries of gold and moderate, but possibly important, recoveries of uranium. A simple model describing the operation of the WHIMS machine in terms of the operating parameters is described. This should reduce the amount of empirical test work required for the optimization of operating conditions and should provide a basis for scale-up calculations. The economics of the WHIMS process is discussed.

Jan 1, 1979

By L. S. Belyayeva, A. S. Chumak, N. N. Boyko, A. V. Bondarenko

Analysis of results of many years concerned study of the fire hazard parameters of the material of the mine conveyor belts come in for use at the mines of the Ukraine in 1984-2002 that was carried out in the laboratories of the Scientific-Research Institute of Mine-Rescue Work is adduced in the paper. The basic tendencies on raising the fire safety of the conveyor belts that are retraced in their world production are shown.

Jan 1, 2003

By W. Peters, W. A. H. Poppmeier

An overview is given of the present state of traditional and new steelmaking equipment and techniques, and one of the direct steelmaking methods that are currently being developed is described. In steelmaking processes, coal is used to supplement the energy input and to reduce iron oxides in the slag. Foamy slag practice is discussed, and the most widely used types of ladle recarburizers, their properties, and manufacture are described. It is concluded that the use of carbon sources, mainly for supplementing energy and as reductants, will increase in the future, but that demands on the purity of the materials will probably become more stringent. If hydrogen were manufactured at a competitive cost, it could become an alternative fuel and reductant in the field of iron and steelmaking.

Jan 1, 1993

By D. D. Marsden, L. E. Kun

Although a regulation is in force that all water used underground shall be free of bacterial contamination, in practice it is often very difficult to accomplish this. The standard method of disinfection m South African mines IS treatment with calcium hypochlorite, although liquid sodium hypochlorite is used at a few sites. Primarily because the process depends on human control for the addition of the hypochlorite and the regulation of its now, it is frequently found difficult to disinfect mine water adequately and continuously. In many marine environments, chlorine generated by the electrolysis of seawater in its passage through an electric cell is used for disinfection. The generation procedure is continuous and needs no human control except for occasional checking of the equipment. This paper describes the successful implementation of the process, suitably .modified, .at four underground sites. After severe scaling problems had been overcome, a procedure resulted that chlorinates considerably more effectively than the previous system (dosing with calcium hypochlorite), and that has a lower amortized operating cost.

Jan 1, 1981