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By Yongjie Bu, Wei Sun, Zhiyong Gao, Yuehua Hu, Hongbiao Tao, Runqing Liu, Central South University

"The flotation behavior of O-isopropyl-N-ethyl thionocarbamate (IPETC) and pH for chalcopyrite and galena was studied through pure mineral test, adsorption quantity determination, solution chemistry calculation and Materials Studio simulation. The results show that the recovery differential value of chalcopyrite and galena is about 20% when pH of the pulp 9.5 and IPETC is 7×10-4 mol/L, the flotability differences of the two minerals is significant. There is competitive adsorption between OH? and IPETC on mineral surfaces, it lead to galena flotability is lower than chalcopyrite flotability. IPETC can remove the hydration layer on mineral surface and adsorb on active sites for collector adsorption, minerals have a better hydrophobicity.INTRODUCTIONCopper and lead are two of the most widely used metals in industrial and living, their applications include building construction, various metal alloys, heat and electricity, machine manufacturing (Zhang et al., 2014). Chalcopyrite and galena are the major source of copper and lead, normally they associated with each other. With the growing use of these resources, high grade and dissemination large particle sizes minerals are less and less, the use of low grade and complex dissemination minerals have to be paid more attention (Chen, Ye, & Li, 2010; Liu, Sun, Hu, & Wang, 2009). As the special properties and complex composition of copper-lead sulfide ore, flotation separation of chalcopyrite from galena effective is a research emphasis and difficulty point in mineral processing (Bruckard, Sparrow, & Woodcock, 2011).In the separation process of chalcopyrite and galena, it is rather important to choose effective collector (Huang, Wang, & Liu, 2014). Enlarging and using the two mineral flotability will be a good basis and start in flotation (Reyes-Bozo et al., 2014). Qin et al. (2013) made a great deal of research on flotation separation of copper/lead concentrate, collector O-isopropyl-N-ethyl thionocarbamate (IPETC), butyl xanthate (BX) and ammonium dibutyl dithiophosphate (ADTP) were investigated, BX and ADTP floated both chalcopyrite and galena well, specific adsorption appeared in the surface of mineral, the problem was the collectors were not selective enough, however IPETC showed better selective."

Jan 1, 2016

By A. C. Halferdahl

The Granby ores may be divided into three groups or classes. The No. I ore is a heavy pyrite, chalcopyrite, pyrrhotite, sulphide carrying some free silica, and calcite. No. 2 ore carries the same general group of sulphides as does No. 1, but in a lesser amount. The gangue is an altered greenstone. No. 3 ore has a smaller amount of sulphides than either of the others. Analyses of these ores is as follows: Cu. Si02 Fe. CaO S. Al 203 MgO No. I. Per Cent. 1.8 17.5 33.0 5.7 34.5 2.3 1.3 No. 2 Per cent. 2. 0 35. 6 23. 9 4. 3 I .5. 0 9. 2 6 .. 0 No. 3, Per cent. 1 . 5 40. 9 21 . 7 3. 0 I 1 . 3 11 . 0 5 . 4 The sulphide minerals in No. 2 and No. 3 ores occur largely in bands in the gangue, and for these portions comparatively coarse grinding serves to release the gangue. Drill cores show a certain dissemination of sulphides in portions of the rock, so that grinding to 5 per cent. + 65 mesh with 65 per cent.-200 mesh liberates the sulphide minerals very completely. The association of the sulphides is fundamental. The pyrite was probably deposited first and was followed by a portion of the chalcopyrite, or these two portions of the sulphide minerals were deposited together.

Jan 1, 1924

By J. C. Loretto, H. A. Simons

The paper discusses how, in the routine testing of ores, insufficient communication between the laboratory and the design personnel can lead to misunderstanding or misinterpretation of test results and consequent design errors. A number of examples are given together with suggested modified interpretations and the resulting dollar savings indicated by these new interpretations.

Jan 1, 1972

By David J. Kerr, Robert Mason

"From1927 to1989, the Hornemineproduced53.7 Mt of ore grading 6.1 g/t Au and 2.2% Cu from two large volcanogenic massive sulphide deposits composed primarily of pyrrhotite, pyrite and chalcopyrite. The ore bodies were hosted by a package of chlorite-sericitealtered epiclastic rhyolite tuffs which were deposited in a narrow palaeo-graben located on the flank of a major felsic volcanic centre. M ineralizingfluids percolated upward through the permeable footwall rocks and were further focussed along syn-volcanic, graben-bounding faults. Sulphides were deposited by a process of sub-seafloor replacement of the rhyolite tuffs.Gold-copper-(zinc) mineralization, including ore zones mined between 1985 and 1989 as the REMNOR ore zones, is present throughout the 900 m of felsic volcanic stratigraphy at the Horne. All the deposits were formed by syn-volcanic hydrothermal processes active during felsic volcanism. There is no evidence to indicate that any economic gold mineralization was introduced by a post-volcanic hydrothermal episode.RESUMEDe 1927 a1989, /amineHorneaproduit53.7 Mt de minerai avec une teneur de 6.1 g/t Au et 2.2% Cu provenant de deux grands amas de sulfures massifs volcanogeniques comprenant esentiellement de la pyrrhotite, de la pyrite et de /a chalcopyrite. Ces gites font partie d'une séquence de tufs rhyolitiques epiclastiques chloritises et sericitises qui ont ere déposes dans un paleo-graben étroit situe sur le flanc d' unimportant centre vo/caniquefelsique.Lesfluides mineralises ont circule de bas en haut a travers /es roches perméables sous-jacentes; ils ont été également canalises par les failles syn-volcaniques en bordure du graben. Les sulfures se sont déposes par remplacement des tufs rhyolitiques immédiatement et sous /e plancher océanique.Les zones minéralisées en or et cuivre (±zinc) - y compris celles qui ont ere exploitees au cours de l’opération Remnor (1985-1989) - se retrouvent, sans discontinuité, à travers les roches volcaniques felsiques dont l' epaisseur atteint 900 m. Ces gites se sont formes par le biais d' un processus hydrothermal qui ag issait pendant le volcanisme felsique. II n'y a aucune évidence de minéralisation aurifère d'importance économique qui soit postérieure a l' activité hydrothermale syn-volcanique."

Jan 1, 1990

By Antonius Prayoga

PT Smelting adopted the Mitsubishi Continuous Technology for its copper smelter plant which has been operating since 1998. Through a series of expansion projects, the plant annual production capacity increased gradually from 200,000 to 300,000 tons of copper. There were no significant modifications for the smelter to reach the 50% additional capacity. It was mostly achieved by intensifying the operation of the furnaces by increasing the oxygen content in the furnaces blowing air. Intensive smelting furnace operation caused shorter campaign life of some furnace refractory, especially the melt zone wall on furnace outlet. During each furnace relining, which is done once every two years, severe wall erosion was found. The worst condition occurred in 2007 when the smelting furnace experienced a melt leak through the eroded wall beneath the bath-line coolers. During the 2008 furnace relining, a modification was performed by installing vertical coolers behind the melt zone wall. Additional vertical coolers were installed during the 2012 furnace relining to extend the coverage area. The modification improved melt zone wall integrity significantly by keeping them safely within the two year campaign life. Recently a modeling study was done to estimate the influences of molten waves on furnace wall erosion. The aim of the study was to predict the impact of blowing parameters, such as blowing air velocity, on the melt wave character and wall erosion.

Jan 1, 2015

By R. P. Zahn

The need for quantitative mineralogical data to characterize ore types before they are processed is becoming increasingly necessary. Mineralogical data (modal abundances, grain size, liberation/locking characteristics, mineral textures and associations) can provide invaluable information to facilitate the identification of metallurgical issues that may arise during processing of a particular ore. This paper will discuss the use of QEMSCAN analysis in conjunction with bench scale flotation test work to determine metallurgical characteristics for several ore types that will be fed to the Morenci concentrator upon commencement.

Jan 1, 2007

By W G. Forbes

SOME 20 years ago, upon finishing second year at the University of Manitoba, I was faced with the choice of whether I wanted to be a geologist or a chemist. Accordingly, I sought out Professor Brownell, Head of the Department of Geology, to ask him what a geologist did. His reply contained the statement that following graduation one went out into the field in northern Canada for 5 to 15 years to reduce to practice what had been learned at university. To a young man, very socially conscious, even one year, let alone 5 to 10, in a small mining community sounded like being banished to a monastery in the Himalayas and thus I turned to chemistry. Moving to the present, last month I asked a geologist, and then a mining engineer, what does the fresh graduate in their field do these days? The reply was: usually serve an apprenticeship for an indeterminate period either underground or in the field learning the job.

Jan 1, 1965

By The Hollinger Mill Staff

MR. E. L. Longmore (l), in presenting this paper at the Annual General Meeting, suggested that it was neither desirable nor necessary to read any but the briefest portion of the paper. He wished to emphasize that the scale of the milling operations at the Hollinger not only provided several units in continuous operation to ensure that the test work was being carried on under normal conditions, but also provided a large and competent staff to supervise such an extensive experiment and to criticize intelligently the recorded results. He wished to acknowledge the enthusiastic co-operation of the group of assistants whose excellent work was responsible for the confidence with which the conclusions could be presented. The following data were given as a supplement to the published paper. Following conclusion of the test work described in the paper, the size of the balls fed to the mill was changed from 3-in. diameter to 2Yz-in. Within a short time, a gradual rise in the tonnage rate took place and, as no other condition had been changed, the increased tonnage was credited to the changed character of the ball load. At present, the average daily tonnage for the mill with low discharge is 1,507 tons, an increase of 77 tons over the 1,430 tons ground when feeding a 3-in. ball. A similar increase in tonnage should be credited to the high-discharge test, if the 2;Y2-in. ball had been used at that time. This would raise the 1,117 tons ground at that time to a new figure of 1,177 tons. From a study made to determine those factors influencing the rate of pulp flow through the low-discharge mill, it became evident that the ball screen used on the high-discharge mill must have been restricting the flow through the mill, although this was not recognized at the time. Accord-ingly, it was decided to repeat the high-discharge run. Additional length was added to the 21-in. ring grizzly originally used, and the length of the reverse spiral was increased. The end of the grizzly was left open so that, if necessary, excess pulp might flow out. A coarse mesh 3 ft. by 3 ft. flat screen was provided to catch stray balls.

Jan 1, 1937

By Charles Tkaczuk

Key issues ? Process control is a corporate function implemented locally. ? Security and documentation is mandatory requiring standard practices. ? Publish and communicate activities (do not re-invent the wheel). ? Payback metric system for all projects. ? Partnering with vendors based on experience, expertise and joint R&D. ? Focus on phased process control projects and distribution of costs. ? Integration of services and functions. ? Application of global standards. ? Big picture application thinking.

Apr 1, 2005

By H. C. Gunning

Introduction Considerable attention has of late been attracted to the area surrounding Nimpkish lake, on northern Vancouver island, by the discovery of important rich copper deposits. In less than two years some 200 mineral claims have been staked in a small area, and at least two groups have very promising surface showings. During the summer of 1929, the writer spent one month investigating the general geology and mineral deposits of the region, and, although no detailed work has as yet been done in the field or in the laboratory, the importance of the mineral discoveries and the lack of geological information available to the public warrants a preliminary paper on the district. The district is, from a mining viewpoint, very accessible. Boats from Vancouver call at Englewood, in Beaver cove, four times a week. From Englewood, a first-class logging railway, operated by the Wood, .English Company, extends to the northeast corner of Nimpkish lake. The fifteen-mile trip from the north to the south end of the lake is made by boat, two tugs being maintained by the logging company. The whole trip from Englewood can easily be made in one day. The known mineral deposits lie immediately east of the southern part of the lake, four miles or less from the shore. A fair trail, four miles ? long, leads from the lake to the Nimpkish Copper group. Apart from this trail and an old logging railway grade which follows the east side of Klaanch river for several miles, no trails exist on the southeast side of the lake.

Jan 1, 1930

By J. S. DeLury

Introduction The problems of metallogenesis are largely related to those concerning the origin of igneous rocks, which, in turn, are involved with the question of crustal mechanics. Many ore-bodies are genetically related to associated intrusive and there is an equally close association apparent between igneous intrusion and crustal deformation. The problem of ore-deposition is concerned, therefore, with the fundamental problems of geology. For a long time speculations regarding crustal movements rested largely on the contraction theory and its associated conceptions. Vertical movements were considered to be all important and horizontal movements secondary to them. Magmas were pictured as rising more or less vertically in the crust and were believed to form in vertically disposed magma-chambers or reservoirs. The principle of magmatic differentiation seemed to offer the best explanation of the origin and association of diverse rock types and it seemed also to require the existence of quiescent magma-chambers for the admittedly slow process of differentiation. Accumulating evidence of the importance of horizontal movement in the crust, has, along with other considerations, discredited the contraction hypothesis and many of the inferences that go with it. The same evidence may require some change in the prevailing conception of the origin of the various types of igneous rock and of the mechanics of intrusion. Geologists are now at sea concerning some of the vital and fundamental problems of the crust, and the field is open for speculation. The writer is developing a hypothesis which seems to permit an explanation and? a correlation of earth structures and phenomena. If it rests on a firm foundation, the hypothesis, because it is fundamental, is certain to have a profound bearing on the problems of economic geology. It is for this reason that an outline of the hypothesis is offered at this time. Only a few of its economic bearings are foreseen at this time and these will be indicated.

Jan 1, 1932

By A. S. Dawson

"IntroductionTHE PURPOSE of this paper is to describe the results of a preliminary investigation of a method thought to be useful in interpreting geological structures in un-metamorphosed sedimentary rocks. The writer is not aware of the method having been described or investigated previously, although no thorough search of the literature has been made.The method to •be described is based on the assumption that, in argillaceous sedimentary rocks, certain ceramic properties are diagnostic for certain beds within areas of variable limits.Two ceramic properties• have been investigated: pyrometric cone equivalent (P.C.E.), and bloating characteristics of shales. The enquiry has been directed toward testing the usefulness of these properties in determining the following:A -The correlation of shale beds and, by inference, of coal seams, sandstone beds, or other such structures associated with them.B.-The location of contacts between marine and non-marine shales where lithological, palaeontological, or other evidence is lacking.Limitations of time and facilities have prevented a thorough investigation of this problem. The results given in the present paper are preliminary only. It is hoped, however, that they will occasion discussion or even lead to more thorough investigation of the method by individuals or organizations.There are, admittedly, various limitations to the proposed method. It is thought to show some promise when used in conjunction with the well-known and established methods used in stratigraphic correlation and, more particularly, when the conventional methods are not applicable."

Jan 1, 1952

By K. E. Waters, N. Brodusch, R. Gauvin, H. Demers

"Rare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. The characterization of the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores are needed to find the optimal industrial process to extract the ores containing the rare earths. Rare earth-bearing minerals contain many elements with the M-and L-lines overlap, requiring a high degree of resolution, pushing the boundaries of scanning electron microscopy quantitative analysis. Enhanced microscopy at a high spatial resolution with improved x-ray quantitative analysis enables the accurate determination of the distribution of the desired rare earths in various mineral phases. INTRODUCTIONRare earth elements are becoming increasingly in demand, due to their prevalence in both renewable energy devices and high-end electronics. From batteries (lanthanum and cerium), to magnets (dysprosium and neodymium) and lighting (yttrium), the rare earth elements are crucial to the advancement of technology, and to energy saving devices (Crow, 2011). The goal of this project is to characterize the composition, morphology and volume fraction of the various phases that have valuable rare earths in the ores in order to estimate the economical VALUES (of the ores and to find the optimal industrial process to extract the ores containing the rare earths. High spatial resolution imaging and x-ray microanalysis are needed to reach this goal. In this work, the results obtained with a cold-field-emission scanning electron microscope (FE-SEM) and a silicon drift detector (SDD) energy dispersive spectrometry (EDS) detector at low accelerating voltage are compared to experimental conditions typically used with electron probe microanalysis (EPMA) instrument.With this improvement, a detailed scientific analysis of the composition of these, and other, ores will become possible with a SEM/EDS system. This will help to better understand how such ores were formed, hence assisting in finding them, and to better understand how to process them in preparation for high end industrial applications, namely through mineral processing."

Jan 1, 2012

By I. Southern, S. Kelebek

"Smelting furnace bricks contain significant quantity of base metals trapped in refractory material. A series of flotation tests were carried out on samples of old bricks from Sudbury area to examine upgrading behaviour for recycling purposes. Depending on the grind size used nickel recoveries varied from 60 to 90.6% with corresponding grades of 20% and 14.7%Ni. There is a trade-off between nickel and copper. The nickel has responded well to fine grinding, however, the copper recovery suffered from it. Mineralogical characteristics and flotation behaviour of the brick material are discussed in reference to those from the primary ore. INTRODUCTIONMineral processing is well recognized as a mature technology not only for the mining industry, but also for the environmental industry for the purpose of remediation and recycling. Materials available for recycling are usually the products of many years ago. There are multiple stake holders in this area. In general, when the processing results in a product that can be reused or sold, the company carrying out the remediation makes a profit, while the regulators and the public are pleased due to a cleaner environment. From these points of view, there have been many papers published over the years on various mineral processing techniques applied to separation of many different materials including from mining and metallurgical industries (Wilson et al., 1994; Tsunekawa et al., 2005; Saikia et al., 2012).Flotation may be viewed as the backbone of the mining and metallurgical industry since its invention for separation of solids from one another almost a century ago. It is capable of recovering a variety of finely divided different solids following their liberation from each other. Its versatility and highly competitive nature in terms of cost per tonne of material processed, accounts for its occasional uses in the environment engineering area. In the mining industry, flotation is the standard method used for the sulphide ores. It can be applied as a bulk flotation and/or differential flotation. Bulk flotation, which refers to co-flotation of several components from their source, is most suitable for environmental cleanup objectives. Desulphurisation of various plant tailings is a typical example of this (Benzazzoua et al., 2000)."

Jan 1, 2012

By F. A. McLean

Given a promising claim and the required financial backing to develop it, the first problem that confronts the mine operator is usually the selection of the necessary compressed air plant. The size and type of drive are questions that naturally follow, the former being determined largely by the amount of money available and the speed with which it is desired to carry on the programme of development. The type of drive, such as electric motor, steam or oil-engine, depends on local conditions and has an important bearing on the cost of operations. ns. Few prospective mine operators are fortunate enough to locate claims within the service radius of electric power-lines, although this is more likely to happen nowadays than formerly. In the majority of cases, however, some other form of prime mover is necessary. When wood or coal are available at moderate cost, a small steam-driven plant is usually chosen. Such plants are often arranged so that they can be converted to electric-drive should future developments at any time make this desirable. Many plants of this type are installed in northern Ontario mines. When wood or coal are costly or difficult to transport, oil-engine driven mining plants have many advantages in their favor, and are now quite commonly used. Oil in some locali-ties is considerably cheaper than wood or coal, and is much easier to transport over bad roads.

Jan 1, 1924

By Sherwin F. Kelly

With the progressive exhaustion of ore deposits easily discovered by surface prospecting, the attention of scientists is being turned more and more to the employment of mechanical means for the location of ore bodies whose outcrops are not visible. The dip needle, the Eotvos Torsion balance, and various methods of electrical prospecting are illustrative of the modem tendency. Interest in the possibility of applying electricity to the solution of many of the prospector's problems dates much farther back than is usually realized. The first person to notice an abnormal intensity of electrical activity in the region of certain ore bodies was an Englishman, R. W. Fox, who experimented on the Cornwall copper and tin veins about 1830. Dr. Barus, in the United States, carried the early experiments a step further in his work on the deposits of Eureka, Nevada, about 1880. He made the very definite suggestion that the phenomena noticed would be of material aid to the prospector. Not until Professor Schlumberger, of the Ecole des Mines, Paris, took up the matter, shortly before the war, was any definite effort made to put electrical prospecting on a commercial basis. His work resulted in the establishment of sound principles and practicable field technique, for two distinct methods of prospecting.

Jan 1, 1924

By W. M. Tupper

Municipal governments recognize the importance of aggregates in the local economy and the need to manage this resource in the interest of the public good. They have encountered problems with regulating the industry and the dichotomy between the urban need and the rural source. They have suffered from a lack of financial benefit, an adequate aggregate inventory, provincial strategy, economic information and public understanding. A provincial strategy for ensuring the availability of aggregate supplies to developing areas of the Province is essential. The Province should also be responsible for licensing, research, technical expertise on rehabilitation, public education and financial assistance. Upper-tier municipalities (regions or counties) should assume responsibility for resource management, including resource availability, demand characteristics, truck routing, phasing of resource development and sequential land-use planning. Area municipalities (towns and townships) can best determine the social and environmental impact of a specific aggregate development proposal and should therefore have the primary responsibility for the location of new pits and quarries. They should also have the authority to supplement provincial regulations concerning operating standards and the phasing and standards of site rehabilitation.

Jan 1, 1978

By M. Aushouri, S. H. Mansouri, N. Aminizadeh

A thermo-chemical model of the Peirce-Smith copper converter in blowing the copper stage has been developed to predict the molten temperature. The key assumption of the model was that white metal and gas phases in the converter were in thermal and chemical equilibrium. In this model, the chemical reaction of white metal and oxygen was accomplished completely. So long as sulfur existed in the bath, the generation of Cu2O was frozen. The reaction rate was considered to be constant and controlled by the reacted sulfur. The converter temperature was calculated by heat balances over time. The model was validated by a detailed comparison with measured industrial data. A good agreement was obtained. The converter temperature depended on process parameters such as oxygen efficiency, molten emissivity and oxygen enrichment.

Jan 1, 2007

By Kyeong Woo Chung, Ho-Sung Yoon, Jyothi Rajesh Kumar, Chul-Joo Kim, Sung-Don Kim

The aim of the present study is to investigate the extraction, separation and recovery of the indivisible metals of dysprosium and neodymium from permanent magnets scrap leach liquor solutions with meaningful recovery. The present experimental development focused on dysprosium separation from neodymium and recovery by suitable mineral acids. Fundamental studies of the effect of time, pH and extractant concentration on the metal separation were conducted followed by proposal of a mechanism for extraction. Process development included generation of McCabe-Thiele diagrams and counter current extraction (CCE) studies. After loaded organic generation from the CCE process, this was followed by scrubbing studies as well final recovery of dysprosium.

Jan 1, 2014

"Cobalt refining at Vale Canada (previously known as Inco) has been associated with Ni production. Because certain compounds of both metals carry risks for adverse health endpoints by inhalation exposure, it is critical to understand the aerosol concentrations of specific substances and the metallurgical processes through which they enter the air. Vale Canada has therefore decided to describe the histories of its Ni-related operations and to report industrial hygiene measurements when available. This paper describes electrolytic Co operations carried out at Port Colborne, Ontario (1954–1966), and provides aerosol measurements (1995–2008) for current Co electrowinning operations.RÉSUMÉ L’affinage du cobalt chez Vale Canada (anciennement Inco) a été associé à la production de nickel. Puisque certains composés de ces deux métaux comportent des risques d’effets néfastes pour la santé par exposition à l’inhalation, il est essentiel de comprendre les concentrations en aérosol des substances spécifiques ainsi que les procédés métallurgiques par lesquels ils entrent dans l’air. Vale Canada a donc décidé de décrire les historiques de ses opérations liées au nickel et de divulguer les mesures d’hygiène industrielle lorsqu’elles sont disponibles. Le présent article décrit les opérations électrolytiques effectuées sur le Co à Port Colborne, Ontario (1954–1966), et fournit des mesures de la teneur en aérosol (1995–2008) pour l’extraction électrolytique actuelle du Co."

Jan 1, 2015