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By A. M. Gaudin

Introduction The discovery of artificial radioactivity, that is, of radioactivity of acorns other than those which are naturally radioactive, has increased vastly the possibility of using radioactivity as an analytical cool. The incomparable value of radioactive atoms, which are commonly termed tracers, arises from the extreme sensitivity of this analytical method. To get an idea of this extreme sensitivity it may be useful co recall that gravimetric analytical methods will not permit the weighing of anything much lighter than one-hundredth of a milligram of material. Under the most favourable circumstances, this represents an uncertainty in the answer of 1016 acorns, or 10,000,000,000,000,000 acorns. Accurate spectrographic methods possibly have a sensitivity 10,000 times greater than this, but the uncertainty is still of the order of 1012 atoms. The tracer permits ascertainment of decay of a single atom so that its sensitivity, without half trying, can be several orders of magnitude greater than that of any other method available co chemists. In addition co the sensitivity of tracers to which reference has just been made, tracers have another property which makes them unique. A radioactive atom is almost exactly like the corresponding non-radioactive acorn m regard to its electronic structure, and therefore in regard to its chemical properties. The nucleus is different, but the nucleus does not participate in chemical reactions. Therefore, a tracer acorn behaves like an ordinary atom until such time as its nucleus undergoes a catastrophic decay. This unique property permits one to use tracer acorns as atomic spies and therefore to follow the behaviour of acorns of a certain kind among their own kind. In other words, the tracer method permits us to study and measure what we call self-diffusion. All of the uses of tracers that have been made depend on the two properties co which reference has been made.

Jan 1, 1949

By J. S. Kirkaldy, W. J. Slater, G. R. Mason

Activation analysis for copper and manganese in 10 mg samples machined from aluminum-base diffusion couples has been used in the study of ternary diffusion in the Al-Cu-Mn system. The accuracy, economy and convenience of the method are considered to be very competitive with other methods for analysis of such small samples. Neutron-activated aluminum-zinc alloys in the range from 10 per cent to 100 per cent zinc have been equilibrated with a known volume and the vapors subsequently condensed and collected. The vapor pressures relative to pure zinc (the thermodynamic activities) have been determined at 550°C' by recording the relative count of /'-rays from zn65 in the collected samples. The method is a sensitive one, although subject to serious obstacles to experimental accuracy.

Jan 1, 1961

By M. H. Cullender

THE determination of the flow characteristics of gas wells depends upon the analysis of pressure data obtained under shut-in conditions and under one or more known flow conditions. These data are commonly referred to as back-pres-sure test data, and I know you are all familiar with the back-pressure equation where, Q rate of flow, Mcfd @ standard conditions C coefficient of the back-pres-sure curve P 1 formation pressure, psia P • sand face flowing pressure, psia P2 (psia)2/1000 n exponent of the back-pres-sure curve Figure 1 is a graphical presentation of the back-pressure equation; the coefficient is the rate of flow at a difference in squared pressures of 1, in this case 2250 Mcfd, and the exponent defines the manner in which the rate of flow changes with a change in the difference in squared pressures. In Figure 1, the exponent of the back-pressure curve is 0.554 which means that for a 10-fold change in the difference in squared pressures, there will be a 3.58-fold (10 raised to the 0.554 power) change in the rate of flow.

Jan 1, 1961

By Aaro E. Aho

Yukon, one of the most potentially accessible, relatively undeveloped, regions of Canada, has major mineral possibilities. The Klondike placer gold fields and the Mayo silver-lead ?district are the sole major producers but large base-metal re-serves have been discovered in re-cent years and important asbestos deposits are now being explored. Several major exploration companies are active in this region despite short seasons, permafrost overburden, remoteness, lack of transportation, and resultant high costs. Pro-posed new roads can be expected to accelerate development. At ?present the major future mineral possibilities are considered to be lead-zinc, copper, aslbestos, silver-lead, gold, and mineral fuels. These and other mineral possibilities are outlined for various geological subdivisions of Yukon. Major favourable metallogenic features of Yukon include complexity of rock types and structures, widening of the Cordillera with cross-trends, and variety and quantity of mineralization found even with limited prospecting. Comparisons with southern 'British Columbia and the U.S. Cordillera suggest that further exploration will result in discovery and development of more major ore deposits and reserves which will eventually revolutionize economy of mining in Yukon. Such mineral resources, with interior petroleum and natural gas possibilities, and ?huge coastal hydroelectric power potential, are the foundations of a much larger future mining industry in Yukon.

Jan 1, 1958

By Ainul Akhtar, Steve Cockcroft, Jixiang Xu, Daan Maijer, Lu Yao

"Nitrogen rich Ti-N inclusions are one of the more difficult inclusions to remove during liquid metal refining of titanium. If present in the final component, they can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading. Understanding the kinetics of dissolution of Ti-N particles during consolidation/melting of titanium can help us better operate and design the melting processes to minimize their occurrence in Premium Quality Titanium production. A numerical model based on finite difference method has been developed to calculate the dissolution of a spherical Ti-N particles in molten titanium. Analytical solutions were used to verify the finite difference code for calculation of concentration profile and the dissolution of spherical solids. Taking into account the limitations in these approaches for the different cases examined, the invariant field approximation showed good agreement with the results from the numerical analysis. Evolution of the size of a spherical Ti-N particle during dissolution was predicted by the numerical model and the particle dissolves in 163 s.INTRODUCTION Properties like low density, high specific strength and excellent corrosion resistance make titanium attractive for a variety of applications. Key characteristics in the processing of titanium and its alloys include its high sensitivity to impurities, especially atmospheric oxygen and nitrogen and its high reactivity in the molten state. Nitrogen rich inclusions Ti-N, also known as Type ? or hard alpha defects, usually have substantially higher hardness and lower ductility than the surrounding material. Because they can act as fatigue initiation sites, Ti-N inclusions can significantly decrease the mechanical performance of titanium and its alloys in applications involving cyclic loading, even in minor amounts (tenth of a percent) (Lampman, 1990; Moiseyev, 2005; Lütjering & Williams, 2007). Ti-N encompasses as a broad range of nitrogen contents from a few wt% up to stoichiometric TiN. The liquidus temperature of Ti-N titanium increases substantially with increasing nitrogen content. Consequently, depending on the concentration of nitrogen, the melting point of Ti-N inclusions can be above bulk liquid metal temperatures during melt processing. Thus, removal of Ti-N defects hinges on dissolution and not melting."

Jan 1, 2017

By D. C. Fraser

Copper occurs invisibly in a geo-logical environment characterized by swampy conditions and an accumulation of forest peat. This swamp, located in southeastern New Brunswick, contains up to ten per cent cop-per (dry weight), in the organic sediments. This occurrence appears unique in that the metal is apparently organically combined in a chelate compound. Unlike the acidic nature of most peat bogs, the pH of the cup-riferous peat is nearly neutral. Analyses of the peat and associated soils have indicated that the bulk of the copper is contained in the organic sediments. It appears that the cop-per distribution is affected by capillarity, evaporation and the growth of frost crystals, and that the copper fixation is effected by organic sequestration resulting in the metal being bound to the nitrogen or oxygen components of the forest peat. While such a fixation mechanism is not definitely established as responsible for the immobilization of the metal, the facts at hand are compatible with

Jan 1, 1961

By D. H. Stonehouse

"ALTHOUGH final statistics are not yet available concerning Nova Scotia' s mineral production for 1958, it is estimated that the value will be slightly lower than that of 1957. In making this statement it is but fair to say that one year ago a reduction in mineral value was also forecast (for 1957 as compared with 1956) and final figures from the Dominion Bureau of Statistics ($68,058,743) indicated, instead, an increase of $2,000,000 over 1956. However, 1958 did bring problems to the industry which would indicate a drop in production value. The estimates figure for 1958 is $64,000,000. COAL Coal production came from 28 mines, 5 less than were operating since 1957. There were 5,269,896 tons of coal produced by 1,978,512 man-days' labour, for a tons per man-shift of 2.66 (0.05 higher than during 1957) or an increase of 1.9 per cent over the 1957 all-time high for this Province. This record has been established as a result of concentrated efforts to mechanize the coal mines of the Province, and it is hoped that it will be bettered during 1959. Collieries which showed some production for 1957 and none for 1958 were the McGregor at Stellarton, the Franklin at Sydney Mines, the MacLellan, the Rose bank No. 2 and the Rose bank No. 3 at Inverness."

Jan 1, 1959

By Dart Wantland

"AbstractThe scope of geophysics in civil engineering and the nature of exploration geophysics are briefly discussed. Engineering problems amenable to geophysical attack are illustrated by specific examples. The various methods available, accuracy of results, and costs are treated. The possibilities of new uses of geophysical techniques are pointed out.IntroductionTHE SCOPE of geophysics in engineering is different than in oil or mining exploration. In civil engineering, geophysics solves specific problems; as for example, what is the depth to bed-rock along the axis of a proposed dam? The area to be surveyed is of limited extent, and the subsurface information .sought is relatively near the surface. The engineering geophysicist is not called upon to investigate geological basins or extensive mineralized areas or to probe for data to thousands of feet in depth. The geophysical tools employed in the three fields are, however, quite similar; the differences are mainly in the objectives.The Natural Geophysical ExplorationThe terms geophysics and geophysical exploration have been used heretofore and will .be employed in what follows. The question is, therefore, What is geophysical exploration?Geophysical exploration is a line of field work where measurements are made at the ground surface with special instruments to get geological subsurface information. Briefly stated, geophysics is a form of exploration that supplements geological work. It is a blend of physics and geology since physical measurements are made •at the surface of the ground that can be interpreted in terms of subsurface conditions."

Jan 1, 1953

By E. Swartzman

"IntroductionGENERALLY, the necessity for mining coals of higher impurity content, the drive for lower costs by intensive mine mechanization, changing market requirements, and the increasing competition of oil and natural gas, have continued to result in an upward rise in coal preparation, and have necessitated a more intensive study of coal preparation problems.Increasing adoption of •continuous mining equipment, for example, is introducing new problems in coal preparation. Limited experimental work in the United States (1) shows that the effect of the continuous miner on size distribution varies with the characteristics of the seam. In some seams, the fines problem is lessened, in others it is greatly aggravated. Generally there is a decrease in the relative amount of the top sizes (plus 2 in.) and a substantial increase in the intermediate sizes (down to about 1/8 in.). Contrary to expected results•, where continuous miners with vertical-moving cutting heads are used, an increase in impurities in the slack sizes does not necessarily occur where draw-slate is taken. This is because the draw-slate tends to be kicked out in lump form. However, if a seam contains bands •and lenses of impurities they are bound to be in the mined product."

Jan 1, 1952

By A M. Goodwin

Detailed stratigraphic studies in the Birch-Uchi Lakes area have shown that the volcanic components are arranged in superimposed sequences, or cycles. Each cycle displays a progression from predominantly mafic effusives below to predominantly felsic extrusives above. Sedimentary rocks are preferentially associated with the felsic extrusives. Two volcanic cycles are represented. The average stratigraphic thickness of the volcanic rocks present is 31,000 feet. The original volcanic pile was probably in the order of 40,000 feet thick. The present lithologic composition is estimated to be: mafic volcanic rocks, 60 per cent; felsic volcanic rocks, 27 per cent; sedimentary rocks, 10 per cent; and others, 3 per cent. Gold occurrences are preferentially distributed with respect to the volcanic succession. Of fifty recorded occurrences, thirty-nine are located in the upper felsic division of the lower volcanic cycle; forty are associated with closely interbanded daciterhyolite pyroclastic rocks, andesitic lavas and siliceous sediments. The gold-bearing quartz veins either lie at the contacts of enclosing lithologic units or occupy cross-cutting fractures in one or more adjacent units.

Jan 1, 1965

By D. H. d Hamly

THE work of Brown and others at Pittsburgh (Brown, Baum, Yant, and Schrenk, 1938)(1) and the success of their light field microprojector (Figure 1), have shown that the microscopy of dust quantitation can be greatly improved. It has been shown that dark-field microprojection of dust spots on konimeter slides is possible (Pullen, 1940), and this paper is a discussion of the new microprojector and a new counting method which is made practical by this instrument. The microscope makes possible the ready determination of the dustiness of mine ventilation air. Reduction of the dust concentration from a dangerous to a safe level involves one or more of the following: reduction of dust production, filtration of the air stream, or dilution with non-dusty air. Each of these raises important engineering problems of time and costs, and trustworthy information on the state of dustiness of the air is required ?both before and after the employment of any method of reduction. Records of this information may be divided into two broad classes concerned with safety: (1) the level of dustiness, and (2) the quantity and kind of dust produced by a machine under a given set of conditions. Though the first requires only one determination for a given time and place, numerous routine records are required to show the continuous safety of the air in an actively producing mine. Though repeated samples are required, highly accurate counts are not needed to show safety or to indicate whether a substantial increase in the non-dusty ventilation air has produced a proportionate decrease in the dustiness of the mixed air. The Devers and Gathercole konimeters have proved satisfactory instruments for this purpose in Ontario.

Jan 1, 1942

By W. J. Bennett

WHEN Dr. Horace Fraser, your President, invited me to speak to you today I advised him in confidence that I was leaving my present positions on April 30th. In the circumstances it seemed to me that this audience might prefer to have as its speaker one who wo.uld J1ave a continuing association with the atomic energy programme. Dr. Fraser was kind enough to suggest that my re-marks might he of special interest to you, since I would be able to sum up my views on the atomic energy programme. I hope that I will not disappoint him or you on that score. I am particularly pleased that my last public appearance in my present positions should be at the Annual Convention of the C.I.M. since, as all of you know, a very important part of my work has been in the mining field. As it happens, my first public address on the subject of atomic energy and its raw material -uranium -was made at your Annual Convention in Montreal in April, 1949. It seems fitting that my final address should also be made at this convention -nine years later.

Jan 1, 1958

By Robin N. Adair

The Halfmile Lake stratiform volcanogenic massive-sulfide deposit consists of pyrrhotiterich breccia-matrix sulfides and pyrite-pyrrhotite-rich layered sulfides that form a laterally continuous sheet stratigraphically underlain by an extensive pyrrhotite-chalcopyrite-quartz stringer zone. Mineralization is hosted by a sequence of felsic pyroclastics and volcanic-derived, fine-grained metasediments. The proportion of volcanic to sedimentary rocks indicates increasing vent proximity from southwest to northeast across the deposit area. Fine- to medium-grained felsic pyroclastics and roughly equal amounts of fine-grained metasediments comprise the stratigraphic footwall to the mineralization. Quartz-feldspar porphyritic bodies cut this sequence and may have provided the heat source for exhalite activity. Felsic tuffs, locally crystal-rich, and lesser amounts of metasedimentary rocks make up the immediate stratigraphic hanging wall. This sequence is stratigraphically overlain and locally interfmgered with mafic volcanics that contain substantial proportions of felsic fragments. Deposition of sulfides post-dated the beginning of felsic volcanism, which places the deposit in the middle of the Lower Tetagouche Group. Compositions of the volcanic rocks range from basalt to rhyolite and exhibit sub-alkaline affinities. Strongly overprinted whole-rock, trace-element, and REE geochemical signatures resulting from mineralizing hydrothermal activity confirm the genetic relationship between the stringer zone and the mineralized sheet. Large-scale D1 folding has overturned the entire sequence. D1 thrust faults and related sheath-like folds have profoundly affected sulfide distribution. D2 is manifested by a penetrative S2 foliation, and D3 is represented by large-scale open folds.

Jan 1, 1992

By F. A. Forward

"IntroductionTHE LYNN LAKE MINE, situated in Manitoba about 150 miles north of Sherridon, has been actively developed by Sherritt Gordon Mines, Limited, during the past seven years, resulting in the establishment of a proven reserve of over 14,000,000 tons of ore containing 1.223 per cent nickel, 0.618 per cent copper, and additional cobalt values. For many years, the Sherritt Gordon Company operated a copper-zinc-gold mine at Sherridon but, as this mine was approaching exhaustion and as it was proposed to use the mining and milling equipment to treat the Lynn Lake ore, a number of unusual problems were faced in transferring plant and operations from the one mine to the other, and particularly in preparing to undertake nickel production.Preliminary investigation showed that the ore could be concentrated by flotation to produce a copper concentrate containing 28 to 30 per cent copper with less than 1 per .cent nickel, and a nickel concentrate containing 11 to 14 per cent nickel, 0.3 to 0.4 per cent cobalt, and less than 2 per cent .copper, with high recovery of the three metals in .the concentrates. It was apparent that, initially, the copper concentrate could be economically smelted and refined in the usual manner. But as the nickel concentrate contained an insignificant amount of precious metals (less than 0.02 oz. per ton) and as .it had a much higher nickel content than comparable concentrates normally produced from sulphide ores, the selection of a treatment process and the location of a plant required careful study."

Jan 1, 1953

By F. Nava-Alonso, E. Pérez-García, A. Uribe-Salas, J. C. Fuentes-Aceituno, A. A. González-Ibarra, E. N. Castillo-Ventureño

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."

Jan 1, 2017

By David Thomas, Charles Harper, Brian Watters

The Star-Waddy Lakes area lies withjn the northeasterly-trending early- to mjd-Proterozoic volcanoseilimentary-pl utoruc belt referred to as the La Range Domllin. In the area investigated the domajn is composed of the Central Metavolcaruc Belt which is bordered by metasedimentary belts of the Crew Lake and MacLean Lake Belts to the northwest and southeast respectively. The boundaries between the Central Metavolcanic Belt and the flanking belts are generally marked by prominent zones of shearing. The volcanosed imentary succession is intruded by a variety of ultramafic to felsic plutons which, on the basis of lithology, field relations and geochronology, can be broadly subdivided into three groups or episodes. These are: a) an 'early' (ea. 1866 Ma), possibly subvolcanic, episode marked by composite intrusions ranging from gabbro-diorite to granite, b) an 'intermediate' (ea. 1854 Ma) plutonic event distinguished by more homogeneous felsic intru ions ; and c) a 'later' (ea. 1835 Ma) event characterized by leucocratic quartz-rich grani te intrusions. The La Range Domain has undergone polyphase deformation with a strongly developed northeast-trending structural grain. Large scale folding is manjfested by large regional sy nforms, arcuate and triangular patterns associated with many of the plutons and by tight to isoclinal folds within the adjacent metasedimentary belts. Inhomogeneous strain characterizes much of the Star-Waddy Lakes area. With strain gradients being typically very steep, zones of high strain consisting of zones of extreme extensional fabrics, discrete shearing, as well as broader zones of cataclasis and structural slicing, are often juxtaposed with areas of relatively minimal deformation . Dilation structures tend to favour these zones of highly contrasting strain. Late, brittle fractures, faults and shear zones are widespread and appear to be particularly important as loci for gold mineralization. Metan1orphic mineral assemblages indicate that upper greenschist to middle amphibolite facies conditions were attained. Geological and geochenucal evidence indicates that the Central Metavolcanic Belt evolved in an island arc environment. Metavolcanic rocks from both the Waddy and Star Lakes areas display similar characteristics on variation diagrams (e.g. AFM and the Jensen cation plot) in that the dominant trend is calc-alkaline with some basic to intermediate types having a mildly tholeiitic character. A few samples from the southern end of Lower Waddy lake display komatiitic to basaltic-komatiitic afl'injties. The relatively immobile minor and trace elements (e.g. Ti , Zr, Nb, Y, Cr) provide reliable characterization of the metavolcanics, particularly of the basalts, which have highly distinctive trace element properties. Geochemical patterns for the basalts are similar to those for modem volcanic arc basalts. Low initial 87Sr/86Sr ratios (0.7017 - 0.7019) are consistent with a subduction-related origin for the volcanics. The major plutons have chemical properties typical of volcanic arc granites and are largely calc-alkaline in character, showing little chemical variation from the volcanics.

Jan 1, 1986

By The Staff

Introduction It is the purpose of this paper to discuss a number of the metallurgical improvements in the technology of copper-nickel ore treatment which have been introduced during recent years in the plants of ?the International Nickel Company of Canada, Limited. In common with other ore treatment processes, the procedure for extracting nickel and copper is changing almost continuous! y. These changes are necessitated by reason of changes in ore grades and characteristics, rising material and labour charges, and the constant drive to maximize metal recovery and to minimize production costs. It is not possible to present a comprehensive list of all the changes made, and only a selected number of the improvements in the milling, smelting, and refining operations are covered. It should be clearly understood that some phases of the procedures described have been pioneered by others in kindred fields and due acknowledgment is given to their foresight and efforts. Articles have been published over the years describing the operations of the International Nickel Company plants and the reader is referred to the Engineering and Mining Journal, Vol. 130, No. 9, November 10th, 1930, and to the Canadian Mining Journal, Vol. 58, No. 11, November, 1937, and Vol. 67, No. 5, May, 1946. Other references are the Transactions of this Institute, 1932, 1938, and 1946; Metals Technology, American Institute of Mining and Metallurgical Engineers, February, 1938, and Canadian Chemistry and Process Industries, April, 1940.

Jan 1, 1948

By J. G. A. Stevenson

"IntroductionDURING the past quarter of a century diamond drilling, in all its phases, has increased in Canada to a very impressive total of more than 10,000,000 feet annually. Since the art of diamond drilling became recognized, some seventy-five years ago, there has been considerable improvement in both equipment and technique. The steam-powered drill rig and the hand-set diamond bit are things of the past.The purpose of this paper is to review some drilling trends •and practices over the past few years. In the preparation of the paper, the author wishes to acknowledge kind assistance of Mr. J. D. Cumming, Dr. C. H. Hitchcock, Mr. Robert H. Quintal, and many others, including staff members of the Longyear organization.Figures provided by the Dominion Bureau of Statistics for the year 1954 show that Canadian production of metallic and non-metallic minerals and structural materials had a value of $1,454.2 million, excluding radioactive products for which figures are not available. Approximately 61 per cent of this valuation comprised production of nickel, copper, gold, coal, asbestos, zinc, lead, and iron. It is certain that diamond drilling played a major role in the discovery and development of the orebodies from which these minerals were obtained.After the surface examination of an ore deposit, diamond drilling will automatically follow, in order to determine structure, grade, and tonnage.Footage drilled by mining companies and contractors on mineral exploration and blast-hole work since 1945, as reported by the Do-minion Bureau of Statistics, is shown in Figure 1."

Jan 1, 1955

By A. McLean, L. Gao, Z. Shi, Y. D. Yang, K. Chattopadhyay, G. F. Zhang

Levitation melting of metals is one of the emerging applications of magnetic and electric fields in liquid metal refining. The varying magnetic field generates induced current inside the metal droplet and leads to the Joule heating effect and Lorentz force against gravity. This contactless process can avoid contamination from the crucible and can be used to produce high-purity materials. Visualization of the levitation melting process is difficult, and thus generally investigated by mathematical modeling. In the present study, a three-dimensional mathematical model of metal levitation was developed using finite element method for proper understanding of the levitation process. The effects of harmonic magnetic field frequency, coils power input, and sample size on levitation nickel droplet were investigated. Temporal evolution of temperature fields were predicted directly though the model. Levitation and balance condition of the droplet were investigated as well.

Jan 1, 2015

By C. Piribauer, E. Feichtenhofer, A. McEneaney

"As part of a major diversification project, RHI AG, through its plant in Drogheda Ireland, has developed a Caustic Calcined Magnesium Oxide (CCM) for use in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry. In the course of the project, the company investigated the chemical and physical properties of a number of different Magnesia’s used in Co & Ni hydrometallurgy applications and has been able to determine the important parameters for a successful Magnesia for this application. A number of live plant trials have confirmed the results of this testwork and the company is now proceeding to produce this product in commercial quantities at Premier Periclase Ltd., the RHI AG plant in Drogheda, Ireland. This paper will outline the development work conducted by the company and highlight the important chemical and physical properties that make a successful CCM. Much of the research was conducted at the RHI Technology Centre in Leoben, Austria. In addition, a number of external laboratory studies were conducted on behalf of RHI AG. The result of this work has allowed the company to develop a Magnesia product with optimised properties for use in the Cobalt and Nickel hydrometallurgical extraction process.INTRODUCTION Premier Periclase is part of RHI AG, a globally operating supplier of refractory products, systems and services, headquartered in Vienna, Austria. The company produces Magnesia from seawater at its plant in Drogheda, Ireland. While the main focus is on production of refractory grade Dead Burned Magnesia for the steel industry, the plant also produces a number of different grades of Caustic Calcined Magnesia as well as Magnesium Hydroxide products. As part of a major project to diversify the company’s product base, the use of CCM in the Cobalt (Co) & Nickel (Ni) hydrometallurgical extraction industry was investigated. One of the company’s highly reactive grades of Caustic Calcined Magnesia was found to be particularly suitable for this application. In an effort to understand what makes a successful Magnesia for hydrometallurgy the chemical and physical properties of different Magnesia’s used in Co & Ni hydrometallurgy were investigated. This paper and conference presentation outlines the findings of this process."

Jan 1, 2017