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By Derek J. Lennon

Ground conditions in central Glasgow generally comprise loose granular deposits overlying stiffer soils. CFA piling would normally be preferred for urban sites in these ground conditions, but flighting of the superficial deposits has on occasions resulted in building damage. Over the last five years rotary bored piling with vinyl polymer support fluid has proved to be an economic alternative to bentonite slurry. Two case histories in central Glasgow are described in this paper, one for piles founding in granular soils and one for piles founding into bedrock. A comparison is made between the methods required for disposal of the liquid waste from bentonite and vinyl polymer slurries.

Jan 1, 2006

[Secretary's Note.—The following official tables, prepared by the government of the State of Nuevo Leon, and presented to the Institute at the fifth seseion of its Mexican meeting, held at Monterrey, November 26, 1901, present in compact form a general summary of the mineral and metallurgical industry of the State for the preceding calendar year, together with a statement of the railway-shipments of ores from January 1 to October 31, 1901, which, in the absence of direct official mining and metallurgical statistics (not yet available for that year), clearly indicates an increased activity and productiveness of these industries. In other words, the mines are reported to have yielded in 1900 a total product of 83,960,169 kilos of ore; whereas, the railway is reported to have carried, in 10 months of 1901, a total of 108,318,647 kilos of ore. At this rate, the railway-shipments for 1901 mould amount to nearly 130,000,000 kilos. It is, of course, possible that the railwaystatistics include other freight than ores, or that they include duplications, such as would be involved in the record, first of certain ores transported, and afterwards of the " base bullion " produced therefrom. An accurate comparison is therefore impossible ; yet, after making all reasonable allowances for such items as have been named, it seems safe to infer that the mining and metallurgical industry of this State accomplished in 1901 a substantial progress.]

Jan 1, 1902

By Steven D. Botts

The Antamina project, owned by BHP Billiton Plc, Mitsubishi Corporation, Noranda Inc., and Teck Cominco Ltd. , is a $2.3 billion copper/zinc project, located in the Ancash Department in Perú. The project consists of an open pit mine, a 70,000 ton per day concentrator, a 302 Km. long concentrate pipeline, port facilities, a new access road, power line, and town site. The project is designed to produce up to 1.5 million tonnes per year of copper and zinc concentrates over a 23-year project life, and will be the third largest producer of zinc and the seventh largest producer of copper in the world. This mega project is the largest mining investment in the country and, during its construction stage, was the most important construction project worldwide. On May 28th, 2001, Antamina commenced testing operations and four months later, it reached commercial production. Antamina was officially inaugurated on November 14th, 2001 by Peruvian president Alejandro Toledo. The construction stage of the project generated 8,000 direct jobs, with a peak of 10,000 employees, and 30,000 indirect jobs. The permanent workforce consists of approximately 1650 employees, the vast majority of which are Peruvian Nationals; around 30% of whom came from the department of Ancash where the deposit is located. Approximately 5,800 indirect jobs will be generated from the project. Independent sources state that Antamina will increase the Peruvian mining exports by 30% and Peruvian GDP by 1.4% within its first year of full operation in 2002. Since winning the privatization bid for the project in 1996, the company has implemented a successful approach to community development and environmental protection based on sustainable development principals. Throughout the development of the project, a number of initiatives have been undertaken to ensure full involvement of the local populations in community development activities and the company?s environmental program. Due to its size, difficult logistics, cultural considerations and financial aspects, the project has faced a number of unique challenges in the area of environmental protection and management of community interaction. Antamina has been innovative in its approach to these issues, and as a result, has set new standards in Perú for environmental and community management, and sustainable development.

May 1, 2002

By D. Newman

Multiple seam mining is prevalent in Southern Appalachia because economically mineable coal seams are numerous and frequently occur in close vertical proximity. West Virginia, Kentucky, and Virginia have 117, 55, and 40 mineable coal seams respectively. It is extremely rare to have an underground mine that has not been undermined, overmined, or has mining adjacent to it. In many cases the multiple seam mining is concurrent with extraction sequenced in superjacent seams. Because underground mining is focused on recovering the most valuable reserves, mining is rarely practiced from the top seam down, which is the practice most conducive to stability. The combination of room-and-pillar mining methods that include development only, small block, partial retreat, full retreat, and longwall mining produce a wide range of mining geometries and complexity in underlying and overlying seams. In the future, the number of multiple seam operations will increase as reserves are depleted and future mines are, by default, located closer to abandoned mine workings. The improved coal market has transformed many formerally uneconomically mineable seams into attractive reserves. The approaches and methodologies used for multiple seam stability analysis are dictated by the site conditions, including overburden/interburden thickness and lithology, mining geometry, and the mining methods in both the active and abandoned mines. Multiple seam stability analysis using analytical and numerical methods is illustrated by two case histories that reflect close proximity room-and-pillar mining and mining in bump prone situations.

Jan 1, 2007

By Junji Shibata

It is important to recover and reuse the metal values contained in various industrial wastes in a viewpoint of environmental preservation. Most of industrial products are made through the processes to separate impurities in raw materials, solid and liquid wastes being necessarily discharged as industrial wastes. Chemical methods such as solvent extraction, ion exchange and membrane, and physical methods such as heavy media separation, magnetic separation and electrostatic separation are considered as the methods for separation and recovery of the metal values from the wastes. In this paper, some examples of the application of solvent extraction to the treatment of wastes are introduced. The treatment of solid wastes such as Ni-Co alloy scrap, Sm-Co alloy scrap, fly ash and flue dust, and liquid wastes such as plating solution, the rinse water, etching solution and pickling solution are accomplished using solvent extraction technique.

Jan 1, 1996

By Jorge Díaz A

El presente texto revisa los métodos utilizados en las minas de tajo de abierto como son la perforación, disparo y seguridad y así mejorar los standars y el rendimiento futuro en la industria minera. Respecto al primer método empleado, se analizan los factores que afectan el rendimiento de brocas y cómo dicho factores varían, impidiendo la adaptación de prácticas universales de perforación. Asu vez, estos mismos permiten seleccionar el tipo de broca adecuado y mejorar el máximo rendimiento del mismo. En cuanto la voladura y los explosivos, se revisan las variables fundamentales que ejercen una influencia sobre el resultado de un disparo y así realizar un estudio comparativo de los agentes explosivos en uso, tratando de interpretar el mecanismo de la explosión y a la vez aplicarlo a las diferentes formaciones presentes en Cerro. Finalmente, se describe la organización del sistema de seguridad y las obligaciones de este comité en la industria minera.

Aug 20, 1965

By Basson. J., L. R. Nelson, L. A. Cramer

The South African based platinum mines produce the world?s majority of platinum metal that is used in autocatalysts and jewellery. As the platinum market is forecast to grow at healthy rates into the future, the South African producers, Anglo Platinum, Impala, Lonmin and Northam are planning to expand in the next decade. Furthermore a number of smaller producers who are accessing other mineral rights are entering the buoyant market. The South African platinum mines have traditionally exploited the Merensky reef of the Bushveld Igneous Complex (BIC); however, the mining of this reef is reaching depths that require significant vertical shaft systems and costly refrigeration for access to the ore bodies at deeper levels. In the past decade all of the producers have begun to mine the less attractive UG2 reef because of its cheaper mining costs. This UG2 reef contains significant quantities of chromite with typically a chrome-to-iron (Cr/Fe) ratio of 1.35. UG2 ores can contain between 10 and 25% Cr2O3 depending upon the reef width and the selected mining method. It is relatively cheap and easy to extract a portion of the chromite from a platinum concentrator tailings stream at a grade of between 40-42% Cr2O3. However it is only in recent years that some ferrochrome producers have begun to source some of their chromite from the tailings of platinum producers. South Africa is also the world?s largest single producer of ferrochrome and supplies much of the world?s stainless steel producers and thus the growing market for their product. As the traditional sources of high Cr/Fe ratio ores have been depleted at the shallow economic depths and thus have become more expensive sources of chromite, technical developments have improved the ability to use fine chromite economically to make acceptable grades of ferrochrome. Thus UG2 fines are now becoming possible cheap sources of acceptable feed to the ferrochrome industry. The abundance of feedstock for ferrochrome production and the lessening dependence on mined material will impact upon the structure of the ferrochrome business in South Africa. With continued platinum mining from UG2 reefs, South Africa is set to remain highly competitive in the world?s ferrochrome/stainless steel industry.

Jan 1, 2004

By Donelson A. Robertson

Literature was searched and cases of alleged water well damage were investigated. Occurrence of ground water in Appalachia is primarily in low yield, fractured, water table aquifers. Four test sites were chosen based on geographic and geologic diversity. Test wells were drilled at each site and base line data on water quality, static water level, and drawdown characteristics were obtained before surface mining commenced. Blast induced ground vibrations were measured at the surface by the wells at levels up to 5.44 inches per second maximum resultant particle velocity. Measurements made at the bottom wells indicated that vibrations were considerably attenuated at depths of 140 to 160 feet. No direct evidence of change in water quality or well performance was produced by blast vibrations, but removal of downslope support by excavation does cause lateral stress relief which permits the water-bearing fractures to become more open. This additional storage capacity causes the static water level to drop and for well-bore permeability to improve. Static water level recovers if sufficient recharge is available and well performance is improved.

Jan 1, 1980

By Fuzail Siddiqui

"The SIDMIN program aims at filling the mineral processor’s need to know the deportment of ‘minerals of interest’ not just ‘elements of interest’ that pass through the processing plants. Generally, chemistry is used as a tool of routine monitoring on site. Mineralogy, which is relatively much slower, is used more as a tool of research and post mortem investigations and these services are usually provided by a distant facility. The SIDMIN program enables site management to receive chemical and quantitative mineralogical reports on their critical samples daily, simultaneously and affordably.The author developed the SIDMIN program at ZCCM Nchanga Division where it continues to be a powerful tool for monitoring the efficiency of operations. Outlines are given of procedures for quick sample preparation and quantification of significant minerals in process samples. A specimen report is presented, which shows the format of reporting the contributions of individual minerals to metal losses at critical stages of the circuit. It is shown that SIDMIN provides timely information to management, about trends and abrupt changes in the quality of ore, and its processing, in a way never achievable by chemical analyses alone. This greatly helps in resolving the age-old problem of ‘bad ore’ or ‘bad operations’ on a day-by-day basis. For example increase in copper mica in the feed indicates excessive ore dilution during mining. Increased loss of free sulphides was traced to insufficient reagent conditioning time at the Concentrator. Persistent losses of leachable oxides at the Tailings Leach Plant were traced to inadequate leach residence time.SIDMIN is affordable because it can be implemented using basic optical microscopes, minimal quantities of micro-chemical reagents and custom trained site staff who demonstrate good colour perception and an ability to follow laid down procedures consistently."

Jan 1, 2000

By Thomas V. Falkie

In bygone days, the mineral engineer spent most of his/her time on the technical aspects of designing, building, and managing mineral operations. In the last few decades, mostly since the 1960s, increasing amounts of engineering man power and time are spent dealing with federal, state, and local government agencies, laws, and regulations. It is not possible to plan, design, build, or operate mines, mills, smelters, or even office buildings without detailed consideration of government regulations and permitting requirements dealing with environment, worker health and safety, etc. The four chapters of this section provide an overview of the social, legal, political, environmental, and health and safety aspects of mineral enterprise. The section sets the stage for the working engineer/geologist in industry, government, consulting, or academe and points the direction for more detailed study in each of these areas.

Jan 1, 2008

By Robert H. Peters

This report presents a literature review conducted by the U.S. Bureau of Mines. The review summarizes what has been learned from recent empirical studies of the relationship between mine safety and characteristics of miners, mine management, and mining companies. The review is based on literature published in the United States during the period from 1976 to 1988. In addition to summarizing the empirical findings, this report discusses the implications and limitations of these studies, and gives recommendations for improving mine safety. An annotated bibliography section appears in the appendix.

Jan 1, 2009

By Patrick J. Foster

This paper summarises a behavioural safety project undertaken in seven quarries in the UK in order to investigate its applicability as a means of raising the standards of health and safety in the UK quarrying industry. A behavioural safety methodology was developed and trialled at two quarry sites in the UK. During the study the number of unsafe acts and minor accidents had decreased and at one of the quarries there was a 95% reduction in the number of working days lost. It was then introduced at a further five sites of varying sizes and within this focused specifically on lone workers as well as behaviours that affected quality and environmental issues. Positive improvements were noted in most of these operations. The project also looked at the effectiveness of health and safety performance indicators. Here, the common lead and trailing indicators for both safety and health that are commonly used by industry were identified. In consultation with the UK quarrying industry these were then used to identify specific performance measurement criteria that can be used by the quarrying sector to measure performance. Following on from this a quarry specific health and safety management system specification was developed for large and small quarries.

Jan 1, 2008

By T. V. Swaminathan

Monazite sand is normally processed by, the caustic soda route to produce mixed rare earths chloride, thorium hydroxide and trisodium phosphate. Bulk of the mixed rare earths chloride is used for the preparation of FC catalysts. Recently some of the catalyst producers have shown preference to cerium depleted (lanthanum enriched) rare earths chloride rather than the natural rare earths chloride obtained from monazite. Therefore, a process for producing cerium depleted rare earths chloride, cerium p thorium and uranium from Rare earths + thorium hydroxide obtained by treating monazite based on stepwise hydrochloric acid extraction, was developed in our laboratory. The process involves drying of the mixed rare earths-thorium hydroxide cake obtained by monazite-caustic soda process followed by stepwise extraction of the dried cake with hydrochloric acid under specified conditions.

Jan 1, 1989

By D. Blackwell, W. R. Reed, G. Ross, S. Peters, M. Shahan

Dust collectors for roof bolting machines generally use a dry box to collect the roof bolting material. Recently, an underground mining operation converted a dry box dust collector to a wet box dust collector with a unique exception from MSHA for testing purposes. Water is routed to the roof bolter from the main water line of the continuous miner. The wet box utilizes a water spray to wet the incoming material. Testing was conducted comparing the two different collector types. Respirable dust concentrations surrounding the roof bolter with the different collection boxes were similar. The main difference in respirable dust concentrations occurred when cleaning the dust boxes. The average respirable dust concentration during cleaning of the wet box was 0.475 mg/m3, and during the cleaning of the dry box the average respirable dust concentration was 1.188 mg/m3. The silica content of the roof material was high, ranging from 28.9% to 52.7% during this study. The results from this study indicate that using the wet box as a collector reduced exposure to respirable dust up to 60%when cleaning the collector boxes. INTRODUCTION Currently, the dry vacuum dust collection system is the standard dust collector on roof bolters in underground coal mining. It has been proven to be an effective dust control to prevent roof bolter operators’ overexposure to coal mine respirable silica dust during roof bolting operations [Potts eta l, 2011 and Colinet, 2013]. The dry collection system works as follows: drill cuttings are vacuumed into the precleaner. The precleaner dumps oversized material onto the mine floor while undersized material enters the dust box via vacuum airflow produced by a blower. The cuttings entering the dust box are either deposited on the floor of the dust box or into a dust collector bag. The vacuum airflow leaves the dust box through a final filter which removes any small particles from the airflow. Figure 1 shows the internal view of two dry collection system boxes; one that does not use the dust collector bags and another that uses the dust collector bags. Dust collectors that use dust collector bags to contain material inside the dust collector box have been shown to provide better protection to roof bolter operators than dust collectors that do not use the bags [Listak and Beck 2008]. The dry collectors are very efficient at reducing respirable coal mine dust exposure from roof bolting activities. Recently, Blue Mountain Energy’s Deserado underground coal mining operation, outside Rangely, CO, made a modification to the dry collector system to convert it to a wet collector system with a unique exception from the Mine Safety and Health Administration (MSHA) for testing purposes. The wet collector system still uses a vacuum system to pull material from the vertical roof bolt hole, but incorporates a water spray nozzle located inside the dust box to wet the incoming material. The flow through the nozzle ranges from 1.9–7.6 lpm (0.5–2.0 gpm) at 0.69 MPa (100 psi). The conversion to the wet collector system removes the precleaner and the cyclones inside the dust box. The wet material (sludge) then empties through a specialized valve in the bottom of the box. The final filter is still used to prevent respirable dust from leaving the dust box through the exhaust. During operation, the wet collector dust box is opened and hosed clean after roof bolting every place. After every two entries the final filter is changed out. Figure 2 shows the inside of the wet collector box.

Jan 1, 2019

By E. Don Dilling, Wm. F. Hergert, J. W. Pennington, C. E. Wood, M. J. Slendlove, H. A. Doerner

"INTRODUCTION The Bureau of Mines began a study of various methods for producing magnesium metal from magnesite ores in 1936 at Pullman, Wash., with the cooperation of Washington State College. This work included a study of the basic principles involved in the reduction of magnesium oxide by carbon, which soon led to the development of a continuous process. In May 1939, a small pilot plant was operated, which included a small single-phase arc furnace with a hydraulic feed mechanism and an oil-spray device for shock cooling the metal vapor. 5/Subsequently, the Ford Motor. Co., Dearborn, Michigan, began a study of this process on a larger scale. A pilot plant with a nominal capacity of 10 pounds of magnesium metal per hour was constructed and operated intermittently. A larger unit with a nominal capacity of 100 pounds of magnesium per hour was partly constructed when war activities prevented experimental work.In the meantime, the process was greatly improved through continued investigation by the Bureau of Mines at Pullman, and these improvements were successfully tested by continuous operation in a small pilot plant having a normal capacity of 4 pounds an hour."

Aug 1, 1945

By R. C. D. Phillis

The annual mine planning process is one of the most important tactical/operational steps towards achieving strategic goals. These tactical plans are part of a very comprehensive Mineral Resource Management process, with the natural sequel to planning being execution. The execution of an underground hard rock mine plan is a multi-project environment that comprises many development-construction-equipping-stoping single project paths, which are referred to as ?stoping paths?. The uncertainty that typifies execution of projects comes in the form of untimely disruptions to constituent tasks and/or project paths. Annual mining plans also include quantified objectives for occupational health and safety, production, quality, cost, employee morale, environment, and corporate social investment. Such objectives make for a highly complex environment that management must contend with?complex in the sense that all the paths and objectives have interdependent constraints. Furthermore, at the time of this paper, Sections54*and 55**of the MHSA*** put the onus on management to ensure legislative adherence. It stands to reason that planning estimates allow excess capacity?buffers?that cushions the impact of untimely disruptions. This paper concerns the fact that despite all the buffers allowed for, time, scope, and budget creeps impact on mine planning and threaten its successful execution. As a consequence, the paper deals with buffer management, the essence of Critical Chain Project Management (CCPM). Effective buffer management provided strategic (executive level) updates without losing the tactical/operational detail necessary for job card creation, especially where professional skills and experience are in short supply. Indicative bottom-line results showed CCPM to be highly effective.

Jan 1, 2011

By Mike Rylatt

"The BHP Diamonds Inc. and Blackwater Group (Dia Met Minerals Ltd., Charles Fipke and Stewart Blusson) joint venture began production at Canada=s first diamond mine during the last quarter of 1998.Construction of the processing plant began in mid 1997. During the 1998 winter season, the heavy process plant equipment was delivered to the Ekati site, 300 km NE of Yellowknife, by the ice road. Towards mid 1998 the construction activities were complete and commissioning began. The mine officially opened in October 1998.Initial production of 9000 tpd kimberlite will be from the Panda pipe grading 1.09 ct/t at an average value of US$13O/ct.Processing starts with a gyratory crusher reducing the ROM kimberlite to 90% passing 15Omm before further reduction to minus 75mm in a WaterFlush crusher. The crusher product discharges into a 4m diameter x 7m long primary scrubber. After screening, the minus 75 +1 mm kimberlite is conveyed to a 250 ft feed bin ahead of the 1.7 m diameter x 1.1 m wide high pressure grinding roll. The HPGR produces 50% minus lmm in a single pass, the compacted flake product is dis-agglomerated in a secondary scrubber. The scrubber product is screened into a minus 25 +lmm heavy medium separation plant feed and conveyed to a 375t HMS feed bin ahead of two 150 HMS modules. Milled 270D ferrosilicon at a slurry density of 2.6 g/cc and HMS feed are pumped to three 420mm diameter cyclones. Heavy mineral concentrates, approximately 1 % of the plant headfeed, are pneumatically transported to the Recovery plant for final diamond recovery using wet high intensity magnetic separators and high intensity (attrition) milling prior to three stages of x-ray recovery. At full production, Ekati will produce approximately 2 kg/day of diamonds.This paper details the later commissioning phase and the first three months Oof operational activities during the build up to full production at the Ekati processing plant."

Jan 1, 1999

By Larry A. Lien

"A brief summary of the different membrane separation options currently available to the mining industry will be presented and discussed. The processes described involve operating membrane plants on the following applications: pregnant leach solutions (PLS) in the copper and gold industries, fractionation and concentration of metals and acids in refineries, and wastewater treatments to meet state-of-the-art surface discharge criteria.Included is a specific discussion on cost savings resulting from an operating membrane treatment system of nearly 3,500 m3/hr barren water relative to the prior, conventional precipitation practice at a major heap leach gold mine. This Engineered Membrane Separation® (EMS®) plant has produced water for six years that has met all standards for direct discharge into the environment, and captures and returns to the operation valuable minerals and solvents which were not previously being extracted in the Merrill-Crowe process.INTRODUCTIONMembrane technology has been available for more than 35 years, but has been used sparingly in the mining industry. However, recent developments in polymer chemistry, spiral-wound element design and construction, water clarification pretreatment equipment and techniques, and an expanded understanding of membrane fouling and cleaning techniques have dramatically improved the reliability and robustness of membrane-based systems for potential use by the mining industry.In the past 15 years large operating plants have successfully demonstrated the use of this “new” membrane technology to include the separation of pay-metals from large-volume acid and cyanide heap leach mining solutions containing copper, zinc, gold and silver. Moreover, variations on these same membrane technologies are ideally suited to fractionations that add value to processing fluids from refineries, like separating metals from acids or concentrating acids and producing high-quality process fluids."

Jan 1, 2010

By J. Basson, L. R. Nelson, L. A. Cramer

The South African based platinum mines produce the world?s majority of platinum metal that is used in autocatalysts and jewellery. As the platinum market is forecast to grow at healthy rates into the future, the South African producers, Anglo Platinum, Impala, Lonmin and Northam are planning to expand in the next decade. Furthermore a number of smaller producers who are accessing other mineral rights are entering the buoyant market. The South African platinum mines have traditionally exploited the Merensky reef of the Bushveld Igneous Complex (BIC); however, the mining of this reef is reaching depths that require significant vertical shaft systems and costly refrigeration for access to the ore bodies at deeper levels. In the past decade all of the producers have begun to mine the less attractive UG2 reef because of its cheaper mining costs. This UG2 reef contains significant quantities of chromite with typically a chrome-to-iron (Cr/Fe) ratio of 1.35. UG2 ores can contain between 10 and 25% Cr2O3 depending upon the reef width and the selected mining method. It is relatively cheap and easy to extract a portion of the chromite from a platinum concentrator tailings stream at a grade of between 40-42% Cr2O3. However it is only in recent years that some ferrochrome producers have begun to source some of their chromite from the tailings of platinum producers. South Africa is also the world?s largest single producer of ferrochrome and supplies much of the world?s stainless steel producers and thus the growing market for their product. As the traditional sources of high Cr/Fe ratio ores have been depleted at the shallow economic depths and thus have become more expensive sources of chromite, technical developments have improved the ability to use fine chromite economically to make acceptable grades of ferrochrome. Thus UG2 fines are now becoming possible cheap sources of acceptable feed to the ferrochrome industry. The abundance of feedstock for ferrochrome production and the lessening dependence on mined material will impact upon the structure of the ferrochrome business in South Africa. With continued platinum mining from UG2 reefs, South Africa is set to remain highly competitive in the world?s ferrochrome/stainless steel industry.

Jan 1, 2004

By S. Nagamatsu

Alumina supported gold catalyst prepared by spray reaction method (spr) provides gold particle with about 20 nm of diameter. The gold particle size is larger than conventional gold catalysts. However, the spr catalyst shows higher catalytic activity for NO-CO reaction. In the present paper, we have discussed the local structures of spr-Au/Al2O3 catalyst by using Au L3-edge XANES spectra. In order to investigate the local structures of Au-sites, multiple scattering approach to XANES analysis was applied. Calculated Au L3-edge XANES spectra for fcc-Au and Au2O3 were in good agreement with the observed spectra. XANES spectra for spr-Au/Al2O3 were characterized by 4 types of Au sites (bulk, interface, surface and peripheral). In this case, almost all gold sites (> 90 %) are bulk site. The other sites are less than 10 % of gold particle. However, the experimental and the calculated results of Au L3-edge XANES spectra for spr-Au/Al2O3 require about 30 % of gold oxide or hydroxide. Bulk of Al2O3 contains a certain number of gold nano-particles, which was incorporated in the bulk Al2O3 support. In the interface area, gold oxide forms a few layers. This result was also supported by DV-Xa electronic structure calculations. The comparison of the catalytic activities of the spray catalysts and the impregnation catalyst for the NO-CO reactions imply synergy effects between gold nano-particles and alumina support.

Oct 1, 2003