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By J. Bouchard, A. Desbiens, M. Maldonado, R. del Villar

ABSTRACT: Despite many years of practical applications in mineral processing plants, the potential of column flotation has still not been fully exploited. The challenge in measuring some key variables is certainly an important contributing factor to this situation. Reliable online measurement of varibles, such as the froth depth, bias, gas hold-up, frother concentration, bubble surface area flux, and bubble size distribution, provides opportunities for the application of various advanced control strategies and real-time optimization based on an economic criterion. For several years, Université Laval’sLaboratoire d’observation et d’optimisation des procédés researchers have been working on these opportunities. This paper describes the most recent advances and current research trends.

Jan 1, 2011

The New Zealand opportunity NZ?s only significant phosphate deposit 1 million tonnes imported annually - mostly from Morocco US $180/t + $75/t freight

May 1, 2013

By S. K. Dimitrov

?Ellatzite Med? is one of the biggest mining companies in Bulgaria, processing about 12,000,000 t of ore per year. Waste materials left after extraction of copper concentrate are deposited in tailings dam ?Benkovski 2?. The hydraulic structure is built according to the downstream method, through hydrocyclonization where the downstream batter and the body of the wall are formed by the separated coarse sand particles of the separated tailings. In connection with the prolonged concession of Ellatzite Med and the enlarged capacity of Benkovski 2, the tailings dam has expanded on to the surrounding terrain. To guarantee a normal hydrocyclonization and build up of a tailings wall during waste deposition from the ore mill, the technological scheme of the hydraulic transport system of Benkovski 2 has been changed.

Aug 1, 2013

By H. Yoshida, H. Hatta, T. Suzuki

"The effect of the copper and magnesium contents and quenching rate during quenching on the age hardening behavior of 2000 series aluminum alloys was investigated. For the higher copper-containing specimens as conventional alloys, like AA2024, precipitation of the stable phases increased as the quenching rate decreased under the as-quenched conditions. The maximum hardness after the artificial aging of air cooled(AC) specimens was much lower than that of the water quenched(WQ)specimens. On the other hand, for the lower copper-containing specimens, coarse precipitation did not increase even in the case of the AC. The age hardening behaviors of the WQ and AC were very similar such that the maximum hardness and aging rate were almost the same. Many parts of the fine precipitates that increased the hardness were thought to be the GPB zone or fine S’ phase for the WQ and relatively coarse S’ phase for the AC. From the calculated CCT(continuous cooling transformation)diagrams, the lower copper-containing specimens could maintain the copper and magnesium in the solid solution state during the AC, so they could be quenched at a rather slower quenching rate like the AC.INTRODUCTIONThe 2000 series aluminum alloys, containing copper and magnesium as the major chemical components, are some of the well-known heat treatable aluminum alloys. These alloys have a high quenching sensitivity, thus the age hardening ability of these alloys decreases with as low quenching rate. To prevent the decrease of the age hardening ability, quenching is done by a method such as water quenching, which is not very efficient in an industrial situation, because the method requires such large equipment. For these alloys, reducing the quenching sensitivity helps them to be produced in a rather convenient way. For example, 6000 series alloys such as A6063 have low quenching sensitivity, thus they could be quenched by only air cooling just after extrusion and they do not need water quenching. Based on these reasons, investigations of these alloys with high copper and magnesium contents have been conducted in the past to find a way to lower the quenching sensitivity by adding transition elements such as manganese, chromium and zirconium (Kanno, Suzuki, & Itoh, 1986; Suzuki & Itoh, 1986; Kanno, Sakuma, Muromachi, & Watanabe, 1988). However, very few studies have focused on the quenching sensitivity of the lower copper and magnesium containing alloys because of their usage for structural components with high strength, and most of the past studies have used only the fast quenching method like water quenching. On the other hand, from our recent results, there is a possibility to lower the quenching sensitivity of 2000 series alloys with lower alloying elements. In this paper, the effect of the copper and magnesium contents with lower alloying elements and quenching rate, especially in case of slower quenching rate than conventional quenching method, on the age hardening behavior of the 2000 series alloys is investigated by the hardness measurement, structure observation and thermal analysis."

Jan 1, 2018

By D. Furrer, M. Dallaire

The arrival of Image analysis in the last 20 years has changed the world of quantitative metallography. Many standard measurement techniques which were previously manual can now be done with fully automated systems. This reduces subjectivity and operator fatigue and therefore enhances the quality of the statistical results. In many laboratories, Titanium Alloy microstructures continue to be evaluated by traditional methods, where quality of results is subject to operator fatigue and level of experience. Advances in Camera technology have tremendously improved image acquisition. One can often see clearly at 500x what can not be observed at 1000x, allowing for a larger area to be analyzed, without the inconveniences associated with very high magnification objectives. Powerful and versatile Image analysis software combined with a high precision motorized stage gives access to a multitude of applications, which were extremely challenging or impossible until now. Image Analysis tools such as Multilayer Grab, which reconstructs an uneven image into one plane of focus (ex. Observation at high magnification of texture resulting from etching) and Mosaic which builds an image from a number of fields of view (ex. Reconstruction of very large grains at low magnifications) expand even further the power and flexibility of IA systems. This presentation will describe how automated methods are applied to the point count method and grain size measurement. We will show how cameras and software work together to permit quantitative measurements of primary alpha and prior beta microstructures, as well as lamellar alpha plate thickness in titanium alloys.Automated and semi automated quantitative measurements of various Titanium microstrures have been assessed, using the Clemex Vision PE. Examples of the methods and steps used are presented.

Jan 1, 2006

By Jirí Faltus

The paper deals with studying the impact of structural properties and anodizing of surface on the corrosion properties of extruded rods from commercial aluminium alloys: AA6082, AA6262, AA6012, AA2007 and new lead-free aluminium alloys AA6023, AA2015 and AA2111B. Samples were exposed to the corrosive atmosphere NSS, AASS in the chamber by EN ISO 9227. Surface of samples were either in the original state or anodizing by selected mode. The depth of corrosion attack and the form of corrosion attack are evaluated depending on the type of alloy, the metallurgical condition and surface treatment of the samples.

Jan 1, 2015

By Claudio Rocha Rosales

"Peñoles is a mining group with integrated operations in the smelting and refining of non-ferrous metals, and is also a chemicals producer. Peñoles is the world’s foremost producer of refined silver, metallic bismuth and sodium sulphate and is the leading Latin American producer of refined gold, lead and zinc. The Met-Mex Peñoles Zinc Plant commenced operations in 1973 with an annual production capacity of 105,000 t/y. Year after year the production has been increased, and at present, the production capacity is 240,000 t/y. In this paper, the leaching process,particularly the operation of the jarosite circuit is reviewed ,specifying process improvements to treat high iron calcines.INTRODUCTIONThe purpose of the leaching process is to recover the metals, mainly zinc,through a series of extraction stages with sulphuric acid solutions, which progressively increase the zinc recovery. After the series of acidification stages,the solution, which is rich in iron, is sent to the jarosite circuit to separate the zinc from the iron (Garcia & Valdez, 1996).The first step of the leaching process is the neutral leach circuit which produces a zinc sulphate solution that is sent to the purification section for the removal of impurities such as cadmium, cobalt and copper, after this solution is sent to the tankhouse to feed the electrolytic cells."

Jan 1, 2016

By G. J. Arseneau

Mineral resource statements are reported as tonnage and grades. While great care is placed on generating a reliable estimation of grade, the determination of bulk density for resource estimation is often overlooked. Often mineral resource statements are prepared using a simple average value of bulk density. While a simple average estimate of bulk density can be appropriate for some deposit types, an over simplistic estimation of bulk density can result in serious errors in tonnage estimates and consequently to an over or under estimation of metal content. The construction of a reliable bulk density model requires an adequate bulk density database in order to develop a good understanding of the variability of bulk density with grade and geology. A reliable bulk density database is also essential in determining the appropriate modeling technique to minimize the errors in mineral resource statements caused by incorrect bulk density determinations. This paper summarizes bulk density measuring techniques and draws on examples from various deposit types examining the basic principles of bulk density modeling and domain construction for each deposit type. Examples are presented of simple bulk density domains and more complex grade variable bulk density domains with a discussion of best approaches for minimizing errors in density estimation.

Aug 1, 2013

By A. J. Rigby

The wear mechanisms of the tuyere lines of Peirce-Smith and Hoboken converters are a subject of endless debate and speculation. However, there has been an indication that one of the primary factors in the deterioration of tuyere lines is due to the batch operation of the converting process. The cooling of the brick in the tuyere line during out-of-stack times leads to shrinkage of the brick and resultant opening of the joints. Subsequently, on re-entry of the tuyere line into the bath, the joints become penetrated with matte and re- expansion of the brick is prevented. It is thought that this regular cycle of exiting the batch for slag skimming and replenishment of matte and re-entering for further blowing leads to a gradual “ratcheting” of the tuyere brick lining. If no expansion allowance is furnished between the endplate and the endwall of the lining, then the generation of damaging compressive stress is unavoidable. INTRODUCTION It is generally accepted industry-wide that the integrity of a refractory lined vessel is determined by an inextricable combination of refractory brick quality, the caliber of the lining design and installation, and the severity of the process inflicted upon the high wear areas of the vessel lining. Rigby has summarized the concentrated attempt, over the past several years, to optimize the microstructural, chemical, and fracture properties of the refractories used in non-ferrous pyrometallurgical vessels. Furthermore, lining design concepts involving larger and longer brick and the extent and positioning of expansion allowance in the joints have been extensively trialed. All these efforts have provided some, but not startling, improvements. The simple fact is that a vessel lining composed of bricks with an optimized microstructure and chemical inertness must installed with a well-conceived design to decompress the lining stresses that are generated by the batch operation of copper converters. REFRACTORY QUALITY Converting is conducted by injecting air into the molten matte and white metal for the very purpose of generating iron and copper oxide slags. These slags must be contained by a refractory which, by its mineralogical formulation, is optimized for chemical inertness.

Jan 1, 2019

By F. Nava-Alonso, E. Pérez-García, A. Uribe-Salas, J. C. Fuentes-Aceituno, A. A. González-Ibarra, E. N. Castillo-Ventureño

"Precious metals cannot easily be recovered from tellurides by the standard cyanidation process. This work assesses the cyanidation of synthetic samples of precious metals tellurides and explores some alternatives for the leaching of these species (i.e. cyanidation in presence of lead nitrate and thiosulfate leaching). For this purpose, three chemical systems were studied: (1) cyanidation of silver telluride and the effect of lead (II) nitrate addition, (2) cyanidation at high alkalinity and high cyanide concentration of a gold-gold telluride sample containing tellurium and tellurium dioxide, and (3) thiosulfate leaching of silver telluride employing cupric sulfate as oxidant and EDTA as complexing agent for copper. Results showed that standard cyanidation dissolves 10.5% of silver from silver telluride in six hours, while with the addition of 100 mg/L lead increased the silver dissolution up to 100% in the same time. The standard cyanidation of the gold-gold telluride sample dissolves only metallic gold in six hours, while when cyanide concentration and pH were increased, gold and gold telluride were simultaneously dissolved. Finally, thiosulfate leaching dissolves 43.1% of silver from silver telluride in six hours.INTRODUCTION Precious metals tellurides are classified as refractory ores due to the difficulties associated with processing them by the standard cyanidation method. The increasing presence of gold/silver tellurides in some deposits around the world, specifically in Sonora, Mexico, requires new approaches to the cyanidation process, or the development of new leaching techniques. Treatments have been proposed for the recovery of gold and silver from their tellurides, including roasting, preoxidation, cyanidation with lead nitrate, and the use of leaching agents other than cyanide (Zhang, et al., 2010; Ellis and Deschenes, 2016). This work presents preliminary results of three options to recover precious metals from pure tellurides: the cyanidation of gold telluride at high cyanide concentration and high alkalinity, the addition of lead nitrate to the standard cyanidation process, and the use of sodium thiosulfate as leaching reagent."

Jan 1, 2017

By A. Bowles

The process of accumulative roll bonding (ARB) has been applied to wrought magnesium alloy AZ31. Accumulative roll bonding results in severe plastic deformation of sheet material. In AZ31, this process leads to the refinement of the microstructure by dynamic recrystallization. The refinement of the microstructure results in an improvement in mechanical properties with potential for producing materials for superplastic forming. In this work AZ31 was bonded with up to 64 layers and the potential of roll cladding with aluminium was also investigated. The development of microstructure and the mechanical properties are reported here.

Jan 1, 2006

By A. I. Gorshkov, Y. A. Bogdanov, O. Y. Bogdanova

Abstract - Detailed crystal-chemical study of iron and manganese oxides and some other minerals from low-temperature hydrothermal deposits in a newly discovered inactive mound in the TAG hydrothermal field were used to determine the precipitation sequence of mineral phases during lowtemperature processes and their post-sedimentary transformations. Particles of primary sedimentary X-ray amorphous proto-ferrihydrite with high silica content were replaced in situ by nontronite, ferrihydrite, or goethite during alteration. Ferrihydrite is the only proto-hematite phase. The transformation of the iron minerals, related to change in the physicochemical environment, is an important characteristic of low-temperature hydrothermal processes. The occurrence of hydrogenetic Fe vernadite and Mn feroxyhyte in the uppermost part of low-temperature deposits and bottom sediments near the base of the mound is evidence for cessation of low-temperature hydrothermal processes. Among the investigated mineral phases, goethite, nontronite, and hematite are stable in reduced sediments only.

Jan 1, 1999

By T. Lux, H. -J. Krassnig, I. Filzwieser, E. Hecker, R. Degel, A. Filzwieser

Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions for the primary copper production lines as well as for non-ferrous metals starting with the primary smelting of concentrate and ending with the electrolysis. PolyMet Solutions provides the process know-how whereas SMS group supplies the plants and equipment and Mettop the key components. SMS group and Mettop also cooperate in the field of tankhouse technology. Together with Montanwerke Brixlegg AG, Mettop has developed together with a parallel flow technology (METTOP-BRX Technology), allowing a current efficiency of above 98 % at a current density of 420 A/m², which is a milestone in copper electrolysis. For the secondary copper production route, SMS group and PolyMet Solutions developed an innovative refining furnace (PolyRefine) for the smelting and refining of copper scrap. The refined copper is directly charged to the Contirod line to produce copper rods and wires. The innovative cooling solutions of SMS and PolyMet Solutions come into play where furnaces have to stand the highest loads and stresses, for instance in areas of very high temperatures or temperature fluctuations, aggressive exhaust gases and slags, or at critical spots such as taphole areas. Custom-tailored cooling systems for furnace vessels make sure varying loads are compensated in a targeted and effective manner. The solutions include air cooling, spray cooling, cooling technologies with integrated copper elements such as CFM (Composite Furnace Modular) cooling systems, plate and finger coolers. The major innovation in the field of furnace cooling is the ILTEC (Ionic Liquid Cooling) Technology which paves the way for increased plant safety. This revolutionary, patented cooling technology is jointly marketed by Mettop and SMS group. It permits water-free cooling to be implemented and thus makes operation safe wherever it is applied. INTRODUCTION Non-ferrous metals or NF metals are changing the world. There is no modern industrial sector that can do without these valuable metals. Non-ferrous metals find their applications in smartphones, tablets and computers. These materials with their particular properties are the basis of our modern life. The importance of the non-ferrous metals market is reflected by two figures. In 2018, the production of non-ferrous metals was worth more than 237 billion Euros. This contrasts with 255 billion Euros of the value of iron and ferro- alloy production in the same year (International Organizing Comittee for the World Mining Congresses, 2018). Hence, the NF metal industry is almost as important as the iron and steel industry. SMS group is well prepared for this huge market and for growing future challenges. A large contribution here is the new joint venture PolyMet Solutions that was founded by SMS group and Mettop, an Austrian engineering company, with the objective to develop new technical solutions and to enhance customer value. The prices of nearly all metals have come under pressure during the past few years. Therefore, competitive technologies are regarded a crucial factor to achieve success in this critical market situation respectively to stabilize the market position.

Jan 1, 2019

By Ryan W. Siggelkow

Mines today use various methods of mining to extract ore. Because of the dangerous nature of many of these processes, remotely controlled LHD machines are being used to extract the ore from the draw point. The remote control system, although being made safer all the time, has remained virtually unchanged for many years. The basic functionality is an operator switching the machine to remote control, getting out of the cab, walking up a stand, operating remotely, returning to the cab, switching to manual, driving manually, switching to remote, and switching to manual. It seems repetitive, and time consuming, does it not? Networking, convergence, video, voice, and data infrastructures, and other technologies are growing by leaps and bounds in virtually every industry and region, except for mining. From the comfort of the living room couch, a Canadian can play hockey online with full voice conversations over the Internet with someone in Russia in real time. Yet, a mine superintendent must jump through hoops to have a private conversation with the front line supervisor underground. "Is Joe around anywhere?" If Joe hears the message, he will respond. If not, who knows? Maybe he's hurt. Maybe he's not. Where is Joe? Nobody really knows, and that is scary. Today, surface knows that the workers disappeared into the cage at 7:00 a.m. They also know that the workers will probably and hopefully return at 3:00 p.m. Is there not a better way to handle this? With such a complex industry, it seems as if, for the most part, the introduction of new technology into mining has either been overlooked or has been met with some resistance. It is time to step back, look at the process, and see how it can be improved. Key areas of focus will be safety, productivity, dependability, and cost-effectiveness.

Oct 1, 2010

By Norman B. Davis

THE ceramic group of industries is comprised of those engaged in the manufacture of cement, glass, artificial abrasives, whiteware, including earthenware, stoneware, porcelain tableware, porcelain sanitary ware, electrical porcelain, floor and wall tile, porcelain enamel on metals, refractories of all kinds, sewer-pipe and structural clay products, such as terra cotta, brick, and hollow tile. The various sub-divisions of the industry produce a wide range of articles on which we depend for our creature comforts from day to day, perhaps to a greater extent than we generally realize. The industry, in turn, depends on a great number of minerals, and chemical products derived from minerals, and it is the object of this brief paper to present a list of these with notes indicating the particular applications. In order to bring home the importance of the industry to your daily life, stop and consider the many things around you accepted as a matter of course. Cement provides the smooth surfaces of many of our highways, city streets, and sidewalks. It enters into nearly all types of construction, alone or in combination with other clay products. Glass we hardly appreciate because we can see through it so easily, but it is there to serve us in windows, doors, and other light-transmitting structures. Glass is the universal means of transporting liquids and beverages, our beverages are usually served in it, and, with the recent development in fine spun glass textiles, there is a possibility of glass clothing in the future. Chinaware, a general term for table dishes, may be earthenware (not vitrified), semi-porcelain, or bone china, but it is before us three or more times a day ?and we seldom think of the minerals that have made these products possible. Floor tile, wall tile, and other ceramic specialties for interior and exterior use and decoration please the eye and provide sanitary surroundings.

Jan 1, 1938

The 2-4D window shown above is the base startup window which allows you to begin a new project. ??Setting up the project is the first step ??The next step is to setup the properties to be used in this project

Feb 1, 2008

By D. R. Boyle

"The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite _ arsenopyrite _ galena _ Bi-Sb sulfosalts _ chalcopyrite _ tetrahedrite group _ sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was transported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By D. R. Boyle

"Abstract - The Murray Brook precious metal (Au, Ag) gossan deposit is one of nine supergene mineral deposits that have developed over polymetallic massive sulfide deposits in the Bathurst Camp of New Brunswick. Reserves consist of 1.9 Mt of gossan containing 1.53 g/t Au and 65.9 g/t Ag. The supergene zone at Murray Brook consists of six distinct units: a) altered massive sulfide, b) pyrite-quartz sand, c) massive sulfide gossan, d) disseminated sulfide gossan, e) ferruginized wallrock, and f) leached bedrock. The massive sulfide gossan constitutes the main body of economic mineralization and consists of goethite, primary quartz, secondary amorphous silica, K-Fe-Pb-As- Sb-Ag hydrated sulfate and oxide minerals (beudantite, plumbojarosite, jarosite, bindheimite, scorodite), trace cinnabar, and cassiterite of primary origin. The order of stability of sulfide minerals during oxidation was pyrite > arsenopyrite > galena > Bi-Sb sulfosalts > chalcopyrite > tetrahedrite group > sphalerite.Two mass balance techniques (isovolumetric and conservative element) indicate elemental depletion in gossan relative to primary ore in the order: S>Cd=Zn>Cu=Mn>Na=Ca>Fe=Al=V> Mg= K=Se=Hg>Pb>Ti>Ag>Mo=P>Ba; and enrichment in the order Au>As>Sb>Si>Bi. Tin, as cassiterite, is conservative.Mineralogic and paleomagnetic data suggest that the gossan deposit formed under a warm temperate climate throughout the Pliocene. The rate of oxidation and the compositional nature of the ore was significantly influenced by: a) the position of the primary sulfide zone in a downward moving hydrological system, b) primary sulfide composition and zonation that promoted the development of a strong electrochemical oxidation system, and c) pronounced intercalation of carbonate and sphalerite mineralization in sulfide zones, which promoted rapid development of secondary porosity, permeability and downward flow of oxygenated groundwater.During progressive oxidation and physico-chemical erosion of the gossan zone, Au was trans- ported downward in groundwaters, probably as a Auo colloid complex, to be concentrated in the lower horizons of the gossan profile. The precipitation of Au was greatly increased in the pyrite/arsenopyrite zones. Gold concentration was multi-cyclic with continual dissolution and nucleation of the metal until final concentration in the void structures of the gossan. Leaching experiments and microprobe analyses indicate that Au is present in the gossan as submicron composite sols of Au-Ag-silica."

Jan 1, 1995

By K. Lambrych

Hydrometallurgical equipment used to extract and refine copper and other metals is exposed to extremely corrosive chemical environments. These systems must be fabricated from materials that are durable against corrosion, meet exacting mechanical requirements, and perform economically over the life of the mineral processing plant. In several recent large hydromet projects, fiber reinforced plastic (FRP) has been shown to provide equal if not superior durability relative to alternative materials of construction. This paper will compare corrosion performance and cost of plant equipment fabricated with corrosion resistant alloys, rubber lined steel, and FRP made with Epoxy Vinyl Ester thermoset resins. Case histories for FRP piping, storage tanks, extraction vessels, and electrowinning cells combined with laboratory-based corrosion studies will be reviewed to demonstrate how FRP materials are selected for hydrometallurgical equipment. Specific examples from projects such as El Boleo, Long Harbour and others will be used to demonstrate how the versatility of FRP allows for remote fabrication of durable corrosion-resistant large-scale equipment for hydrometallurgical refinement of copper and other metals. INTRODUCTION Fiber reinforced plastic (FRP) began to emerge as a material of construction for corrosion service in many industrial processes in the late 1950s because of its ease of use and overall performance. Corrosion resistant (CR) FRP, as an alternative construction material to alloys, rubber and tile linings, grew steadily in following decades. The aggressive operating conditions associated with hydrometallurgical processes typically require materials of construction that can withstand acids and acid chlorides at temperatures up to 90°C, sometimes higher. Common metallic materials of construction, such as carbon steel, are not compatible with these conditions. High nickel alloys are capable of meeting performance requirements, but often at a high cost. In many cases FRP mining equipment based on epoxy vinyl ester resin (EVER) offers durability, long service life and lower maintenance costs. Through demonstrated performance and decades of case histories, more and more design engineers are confidently specifying FRP as the material of construction for new mineral processing equipment.

Jan 1, 2019

By A. Roca, V. A. Quezada, O. A. Benavente, M. Cruells

The leaching pretreatment of copper ores is widely used in the Chilean mining industry. Agglomeration and acid curing have been identified as the most useful pretreatments. Of these, acid curing was recognized as beneficial in the dissolution of copper minerals, even in sulphides such as chalcopyrite. Extensive acid curing times have an impact on copper extraction, generate a homogeneous acid distribution in the mineral bed and benefit the inhibition of aluminum-silicate minerals (acid consumers). This document describes some of the theoretical background and results regarding the effect of acid curing in a chalcopyrite sample with 74% purity according to Qemscan analysis and a 28.5% of total copper. Leaching tests are carried out at 25, 50 and 70°C, evaluating the effect of a pretreatment on the chalcopyrite dissolution. The original sample and products generated were characterized by X-ray diffraction analysis and Scanning Electron Microscopy (SEM). The performed experiments indicate a direct relation between the effect of curing time and temperature in copper extraction. 92% of copper can be extracted in a leaching at 70°C and with 15 days of curing. Elemental sulfur, jarosite and copper polysulfide (CuS2) have been detected in leaching products. INTRODUCTION The copper extraction from minerals is a technique that has been developed for hundreds of years in the world. In 2017, the largest copper producer was Chile, exported 5.5 million tons (COCHILCO, 2018). However, in order to preserve this production level means overcoming multiple challenges. In the case of the Chilean copper deposits, the average copper grade in 2016 was 0.65%, lower than the 1% declared in 2004 (Consejo Minero, 2018). This is mainly due to the deeper of the deposits reaching sulfide mineral zones, mainly chalcopyrite. Traditionally, these sulfurized zones ore are treated through concentration by flotation and subsequent pyrometallurgical treatments. However, for some copper companies it is complex to process by this alternative, due to the high costs and high rates of water consumption. The mineral resources of these companies are known as "low-grade sulfides" and do not allow, economically, the treatment of these minerals through concentration by flotation. This is how hydrometallurgy becomes an alternative for the treatment of this type of deposits. In addition, several companies have hydrometallurgical plants, which would allow the operational continuity of these plants.

Jan 1, 2019