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By Seong-Taek Lim

Recently, 7xxx aluminum alloys have been evolved into new variants for thick semiproducts which have low amount of 2nd phases and low quench sensitivity. Commercial 7xxx alloys, especially in the thick forgings made of big ingots, often entail microstructural inhomogeneities and concurrent poor mechanical properties due to limited heating ranges and slower quench cooling. In this study, high strength aluminum alloy 7175 and 7050 are adjusted as an attempt to control the equilibrium phases (M-, T- and S-phase) to have optimum microstructure for the thick forging applications. The effects of the relative content of (Zn, Mg, Cu) on the evolutions of the coarse equilibrium phases, hardening response and resultant mechanical properties are investigated. Equilibrium phases (M,T,S) are evolved depending on the constitutional effect, primarily the change of Zn:Mg ratio, and cooling rate following solutionizing. The formation of the T- and S-phases is effectively controlled, and M-phases are homogeneously precipitated in the adjusted (dilute and high Zn:Mg ratio) alloys. It provides extended heating range and lower quench sensitivity than conventional alloys. The attempts ensure the microstructural homogeneity and improved properties, and is expected to be uniquely applicable in 7xxx thick forgings.

Jan 1, 2004

By A. L. Valdivieso

"The correlation obtained by plotting pH of maximum adsorption of dextrin versus the isoelectric point of involved metal hydroxides can be used to predict the depressing effect of dextrin on flotation in ""pure"" sulfide mineral systems. Sulfides are strongly depressed by dextrin whenever their surfaces are coated by the corresponding metal hydroxide. The efficiency of dextrin as a depressant is affected by the adsorption of the sulfhydryl collector. Hydrolyzable cations modify this relationship in flotation of sulfide ores. This type of deviation of the real-life systems from the predictions based on the behavior of the pure systems shows the possible ways that could be followed to further improve the obtained correlations. Advances in Mineral Processing Science and Technology Proceedings of the 48th Annual Conference of Metallurgists ofCIM Sudbury, Ontario, Canada Edited by"

Jan 1, 2009

By A. Hekmat-Ardakan

Conventional hypereutectic Al-Si alloys such as A390 are used principally for the casting of components used in wear applications requiring abrasive resistance such as in engine or compressor blocks. A comprehensive study was undertaken to investigate the potential of improving the mechanical properties of these alloys by the addition of magnesium. A thorough thermodynamic study of the effect of the addition of Mg to the conventional A390 alloy showed that Mg2Si starts to form as a primary phase at 4.2% Mg as well as in the products of the binary and ternary eutectic reactions forming the matrix. Experiments were carried out in producing castings with different cooling and solidification rates of alloys with up to 10% Mg. Mg additions were found to increase the hardness over the as cast alloy due to solid solution strengthening. Also, T6 heat treatment greatly improved the tensile properties of these alloy compositions due to the strengthening effect of the theta-Al2Cu phase. The elongation of these alloys generally decreases marginally with Mg content. The most significant property improvement of the alloys with higher Mg content is the substantial increase in wear resistance. This is attributed to the dispersion of smaller particles of Mg2Si and their coherence with the matrix as compared to the large Si particles in the conventional alloy. A new rheoforming process for A390 is presented that improves the processing of the semi-solid slurry. Structure modification elements were also added to refine the primary and eutectic silicon greatly improving the processing of the semi-solid slurry.

Jan 1, 2011

By Z. Y. Ma, H. Y. Yang

The process of microwave-ultrasound assisted leaching of valuable metals from copper anode slime was proposed in this paper. Design of experiments has been used to study the effect of the main leaching parameters, such as microwave power, ultrasound power and reaction time. The central composite design (CCD) was used to predict the maximum leaching efficiency of copper, tellurium and selenium. The experimental data obtained were fitted to a second-order polynomial equation, and they also were analyzed by analysis of variance (ANOVA). The 3-D response surface plots and the contour plots were applied to determine the optimal conditions. The optimum conditions of microwave-ultrasound assisted leaching process were: microwave power 834W, ultrasonic power 638W and reaction time 403s. Under these conditions, the experimental leaching efficiency of copper, tellurium and selenium were 98.88±0.56% 98.96±0.78% and 98.57±0.67%, respectively, which agreed well with the predicted values.

Jan 1, 2014

By V. ?. Chanturiya, I. Zh. Bunin, M. V. Ryazantseva

"Surface changes in naturally occurring metal sulfides (pyrite, arsenopyrite, sphalerite, chalcopyrite, galena, and molybdenite) due to treatments from high-power electromagnetic pulses (HPEMP) at varying times were studied using X-ray photoelectron spectroscopy. Analysis of the obtained results revealed common patterns and differences in surface transformations. The transformations were found to include two main stages. The first stage was observed at low treatment intensities (up to n ~103 pulses). At this stage, formation and accumulation in the surface layer of the nonstoichiometric sulfide phase, oxides and hydroxides, as well as elemental (polysulfide) sulfur and/or metastable sulfur species (thiosulfate, sulfite) was observed. The second stage (N = 3·103 pulses) is characterized by thermal removal of sulfur species and renewal of the mineral surface (sulfidization).It was found that the chemical changes of the sulfur on the surface layer of pyrite, arsenopyrite, chalcopyrite included accumulation/formation of S0 (Sn 2-) at the first stage of the transformation, followed by its removal. An increase in the surface concentration of elemental sulfur for pyrite and chalcopyrite was 10–12% while arsenopyrite was approximately 5%. A more complicated chemical change was observed for sphalerite and galena, that included formation/accumulation of metastable sulfur species (thiosulfate, sulfate) at the initial stage (up to 103 pulses) and during longer treatment times, the sulphur is reduced back to its initial state (sulfide or disulfide). The increased concentration of S0 sulfur, compared to the original sample, was only 3% in galena and sphalerite.The application of HPEMP treatment to improve flotation selectivity is supported by singlemineral flotation tests. Changes in flotability as a result of HPEMP treatment are principally explained by surface phase changes that resulted in higher adsorption activity."

Jan 1, 2016

By S. D. F. Rocha1, L. Katsarou, G. P. Demopoulos

"Crystalline scorodite (FeAsO4·2H2O) has been pointed out as the most stable compound to immobilize arsenic for disposal due to its good stability performance according to EPA’s TCLP test. However, in anaerobic conditions, arsenic releasing is increased to undesired levels due to scorodite reductive break down, in eh <100 mV at 5.5< pH <7 which causes contamination of groundwater. In this work, the concept of encapsulation by controlled deposition of mineral coatings immune to pH or redox potential variations is presented. Aluminum and calcium phosphates were evaluated as coatings and the release of arsenic from scorodite previously coated with phosphates was substantially decreased when compared to the VALUES (obtained from crude scorodite, both in oxic and anoxic conditions. INTRODUCTIONThe widely acknowledged hazardous properties of arsenic as a soil and natural water contaminant and its adverse health effects when present in drinking water have led to very strict environmental regulations (Mandal & Suzuki, 2002) aiming at the drastic reduction of the presence of arsenic in the effluents of the mining and metallurgical industries.In Canada, the Metal Mining Effluent Regulations (Government of Canada, 2002) dictate that the maximum monthly mean concentration in tailings for arsenic must be lower than 0.5 mg/L. At the same time the new Environmental Protection Agency’s (EPA) standard for drinking water foresees concentrations of arsenic less than 0.01 mg/L, which means that the leachability limit for the industrial waste is set at 1 mg/L arsenic (EPA, 1994; Le Berre et. al, 2007). One of the preoccupations of the mining and metallurgical industries is directed to the elimination of arsenic presence in all its effluents, especially since arsenic is commonly found in many ores mainly in the form of oxides and sulphides. After processing of arsenic-containing ores and concentrates, arsenic can be present either in solid residues and tailings, liquid effluents or in flue dusts. Several of these forms of arsenic waste materials are soluble and therefore may cause the contamination of ground water, if disposed of without further treatment."

Jan 1, 2012

By M. A. Perras, H. A. Kasani, G. Walton

The development of an underground repository for the storage of spent nuclear fuel relies on a multi-barrier system to isolate the used fuel from the environment – ultimately, the biosphere. These barriers include engineered copper and steal canisters, dense bentonite, and the natural rock as well. In order to reduce the potential flow pathway along the excavation induced damage zone, various slots perpendicular to the excavation axis have been proposed. These slots are called cut-off seals and generally are filled with bentonite as it has high swelling potential and very low permeability. Many different geometries have been proposed, but clear guidelines on the selection of the optimum geometry have yet to be developed. In order to assess the optimum geometry, three shapes have been selected for this numerical study, including a trapezoid, a triangle, and a thin rectangular slot. The cut-offs were modelled for a conceptual shaft constructed in the Queenston Formation from Ontario over a stress to strength ratio that has been found at many underground research laboratories. It was found that the excavation of a triangular and thin slot cut-off had the smallest increase in the damage as quantified based on the extensile volumetric strain within the plastic yield zone. Both shapes showed an increase in the damaged zone by 13 cm at a stress to strength ratio of 2.75. The trapezoidal cut-off damage zone increased by 20 cm at the same stress to strength ratio. Further study is required to better define the optimum cut-off shape for wider variety of conditions and other geological formations.

Jan 1, 2020

By Farzaneh Abedini, Narain Hariharan, Lucas C. McFarlane, Nikolas A. Romaniuk, Tiffany Thayne

The use of dewatered mine tailings as backfill material (commonly referred to as ‘paste’ backfill), is the most practiced form of backfill in Canada providing significant environmental benefits by reducing the size of external tailings facilities and improved economics through enhanced resource recovery. Paste backfill operations reuse filtered mine tailings with a cementitious binder and water to create a slurry that is hydraulically transported to refill underground stopes, later forming a structural network of cemented tailings in the mine stopes. Unlike typical structural applications that utilize General Use (GU) Portland cement; modern paste backfill operations maximize strength performance by blending Portland cement with ground granulated blast furnace slag (GGBFS) or other supplementary cementitious materials (SCMs). GGBFS and other SCMs offer key performance benefits and carbon reductions; however, the availability of these SCMs is rapidly dwindling in today’s carbon-constrained economy. This paper examines the development of an alternative binder system that provides similar performance and carbon reduction to that of GGBFS for mine backfill operations. The binder utilizes the chemical reaction between a reactive source of aluminosilicates and available calcium from calcium oxide or calcium hydroxide to replace between 50 to 100% of GGBFS. The performance of the binder is examined with insights into the hydration mechanisms that generate mechanical strength in the cemented paste network. Paste backfill slurries require precise engineering to create a material that maintains flowability during pipeline transport and generates enough strength to meet operational targets once placed in the stopes. Engineering of such slurries requires large amounts of water to be added to the binder-tailings matrix, far exceeding the typical water to binder ratios used in concrete mix designs. This characteristic of paste backfill warrants great emphasis on understanding the hydration mechanisms of the binder used in the paste backfill system. GU cement is typically composed of 50-70% tricalcium silicate and 15-30% dicalcium silicate.  The hydration mechanisms of these compounds consume 4 to 6 units of water to mineralize into calcium silicate hydrate cemented phases that result in compressive strength development. Cementitious aluminate and aluminosilicate phases make up 5-20% of GU cement and aid in secondary performance characteristics such as set time. Certain calcium aluminate hydrate phases such as monocarboaluminate and ettringite mineralize 10 to 32 units of water into their crystalline structure. Hydration products such as ettringite are traditionally avoided in construction applications due to their propensity for volumetric expansion after cement setting, leading to micro-fissures and subsequent strength degradation (known as ‘sulfate attack’). This paper proposes that such hydration products benefit the strength development in paste backfill slurries with the aforementioned characteristics due to their greater potential to mineralize free water. The newly developed calcium aluminosilicate binder is designed to replace 50-100% GGBFS or other SCMs used in paste backfill systems and meet operational strength requirements by providing exceptional hydration characteristics through cementitious reactions. Additionally, the aluminosilicates used have a minimal carbon footprint and a secure supply outlook, thereby allowing mine operators access to a low-carbon binder option throughout the mine’s lifespan.

May 4, 2025

By M. Turek

Cost management in the conditions of increasing competition and unforeseen market turbulence constitutes one of the key areas of the enterprise?s activity. In the last two years the demand for hard coal on the domestic and global market of non-renewable resources has increased significantly. Polish hard coal mining industry, as an industry in the stage of decline, received a chance for rejuvenation. However, one of the most significant conditions of seizing this opportunity is the rationalization of mining costs and improvement of production effectiveness. Due to the significance of this issue, the main objective of the paper is to identify the possibilities of improving the production effectiveness in the hard coal mining industry. In order to meet such an objective, in the first part of the paper we measured effectiveness in the Polish hard coal mines in years 2006- 2011. The research encompassed three out of five mining enterprises operating in the country. Then based on the received results, guidelines concerning the improvement of effectiveness of production were created, taking into consideration infrastructural, technical, economic and organizational determinants. Furthermore, opportunities and threats for improving the production effectiveness, stemming from the external conditions have also been indicated.

Aug 1, 2013

By Junhyun Choi, Allan Gomez-Flores, Chonbuk National University, Siyoung Q. Choi, Gahee Kim, Seungkon Kim

In this study, to confirm the effect of depletion attraction on the flotation, we theoretically and experimentally investigate the effect of the depletion attraction force on flotation. While varying the concentration of the depletion agent (polyethylene glycol), three different systems are studied: pure malachite, pure silica, and a 1:1 mass ratio of malachite and silica binary system. We find that recovery increases significantly as the concentration of the depletion agents increases for all three systems, as the depletion agent facilitates the adsorption of the particle on the bubble surface. However, the recovery suddenly decreases in a certain concentration range, which corresponds to the onset of the decreased surface tension when high concentrations of the depletion agent are used. This non-monotonic overall recovery trend implies the surface adsorption of the depletant on a surface. The decreased surface tension of the air/water interface suggests that the recovery rate is lowered due to the adsorption of the depletion agent to the bubble surface, acting as a polymer brush. Based on our observations, we conclude that the depletion force can greatly improve particle adsorption, as predicted in the accompanying theory paper, while simultaneously the adsorption of the depletion agent on the bubble surface plays an important role because it hinders particle adsorption. We also perform experiments in the presence of a small amount of a collector, sodium oleate. An extremely small amount of the collector leads to the increase in the overall recovery, which eventually reaches nearly 100 percent. Nevertheless, the grade worsens as the depletant provides the force to silica particles as well as target malachite particles.

Jan 1, 2016

By W. Swidzinski

"Zelazny Most" post-flotation copper mine tailings pond is the only place to of storeing wastes for KGHM POLSKA MI EDZ S.A. The flotation tailings is are the main waste stream in copper mining in Poland. Sufficient storage capacity for tailings is crucial for , thus uninterrupted production of copper is crucially related to the possibility of storing wastes in the pond. The pond covers a Its over 14 km2 arca, almost 50 m high dams making this dame this construction one of the largest in the world. The risk assessment of potential damage due to un stable ility loss of dams or environmental contamination, as well as safely constructing damsincrease of dams within the design criteriaprocess, require quick access to a large amount of the monitoring data , which in vast amount have to be monitored, that needs to be analyzed and processed and reported, every day. This In the paper describes the numerical information system "SyZeM" , used for designated to the "Zelazny Most" pond, baseding on the Oracle database and Geographical Information System , to manage the graphical and descriptive data in coherent way., is presented. The main structure of the system, as well as the methodology of storing, processing and reporting the geological, geotechnical, hydrogeological, geophysical, chemical and survey data are shown. The aspects of Optimizing optimal and risk mitigation and safe management of copper wastes and risk mitigation with the help of "SyZeM" are discussed.

Jan 1, 2007

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018

By R. H. Schonewille

One of the many challenges in developing new metallurgical processes is choosing the best option for validating process design parameters and establishing the process operating window. Historically this has been achieved by constructing pilot or demonstration plants of considerable size and complexity, to enable integrated operation of all key process units for a significant duration. While this would appear to be the best option for minimizing technical risk, it is often impractical from a perspective of cost, schedule, resources or bulk sample acquisition. Such an undertaking can even provide a false sense of security, as the optics of running a complete scaled-down version of a commercial plant suggest a high level of process understanding, regardless of the challenges encountered during operation. Xstrata Nickel has undertaken numerous process development and improvement projects over the past 15 years to support green field project development and continuous improvement in existing operations. The approaches used have included; computer simulation, cold flow modeling, construction of pilot test units in third party facilities, commercial plant referencing and the more conventional construction of integrated test plants. Regardless of the strategy employed, the keys to success have included; managing stakeholder expectations, involving the commercial plant design engineers in the planning stage, anticipating subsequent data and sample requirements and most importantly, constructing and operating complex demonstration plants only as a last resort. This paper provides examples of various process development approaches used by Xstrata Nickel and discusses the rationale specific to each project.

Jan 1, 2011

By Andrew Barnes

The adsorption capacity of peat collected from a proposed mine development in northern Sweden has been determined using laboratory column experiments in which peat was irrigated with a simulated (acidic) waste rock dump leachate. The simulated leachate was made using a hydrogen peroxide leach of composite waste rock from the proposed mine development. The waste rock samples were composited in proportion to their predicted extractable tonnage for the mine development in order to generate a more representative leachate solution for the waste rock facility. As expected the test revealed that the peat material shows a very high affinity for attenuation with greater than 70% of Co, 90% of Ni and 95% of Cu removed from influent solutions through the majority of the tests demonstrating the potential benefits in mine water treatment. In contrast, it was found that Fe is initially released from the peat at concentrations up to 100 mg/L and can mean potential problems for the water released depending on the receiving environment. The exact mechanisms for Fe release is uncertain, though it is suspected that ion exchange / competitive desorption is responsible. Inspection of the laboratory results and drainage data from the natural peat wetland receiving drainage during overburden prestriping and mine development at the mine site are comparable, confirm the validity of the experiments, and further emphasize the potential for future use of pre-stripped peat material in managing water quality.

Aug 1, 2013

Waste rock extracted from a mine is typically stored nearby on the surface. Such waste rock piles must be designed to ensure their geotechnical and geochemical stability during the mine operation and after closure. The optimal construction of a pile requires detailed planning. Deposition should involve benches of limited height to control the global slope angle, based on the long term factor of safety. It can also be advantageous to compact the top of each bench and to give the surface an outward inclination to control water flow by limiting infiltration and favoring lateral diversion. When part of the waste rock contains reactive minerals, it is also deemed necessary to use selective placement with the non-reactive portion to prevent direct exposure to natural conditions. The construction must be well documented, and include data from the monitoring program. These and related aspects are presented and discussed in the paper.

Aug 1, 2013

By Eduardo A. Pérez, Alejandro R. Alonso, Rosa María Luna-Sánchez, Gretchen T. Lapidus

Rare earth elements have been widely used in various sectors, from the aerospace and steel industries, to electronic applications, particularly in displays and batteries for portable devices. The high demand for newer and better equipment, such as cell phones, tablets and lap tops, has increased the consumption of the rare earth elements and at the same time the need for its recovery from electronic wastes. For that reason, the recycling of batteries is important, principally the Ni-HM batteries, due to their elevated content of rare earths elements, in addition to the high concentrations of cobalt and nickel. The current processes are based on dissolution in strong acid solutions (sulfuric acid concentrations from 2 to 4 mol/L), and temperatures from 30 to 90°C. In the present work, electrodes from spent Ni-HM batteries were leached using 1 mol/L H2SO4, in the presence of ozone as the oxidant, where recoveries of 96% for La, Ce and Nd were obtained at room temperature. The separation of Ni and Co from the leach solutions was performed using an electrochemical reactor, after which rare earth elements were precipitated, obtaining a mixture of its hydroxides with impurities below 1%, according to EDS analysis.

Jan 1, 2014

By Michael L. Wayman

Native copper is copper which exists in nature in elemental, metallic form, rather than being chemically combined as is the case with the more usual oxides, sulphides, carbonates, etc. Several other metals, including gold, silver and platinum also occur in native form as do, rarely, iron, lead and mercury; a few naturally occurring native metal alloys, notably electrum (gold-silver) and tumbaga {gold-copper or gold-silver-copper) are also known. An analysis of the relative availabilities of native metals as nuggets in a useful size range111 shows native copper to be by far the most abundant of the native metals, exceeding both gold and silver by at least two orders of magnitude. While such an estimate is crude, it serves to illustrate why copper was one of the first metals to have been used by ancient peoples. Native copper is known to occur on all inhabited continents, although its exact occurrence and abundance in ancient times cannot be unambiguously determined because many surface deposits may have been totally exploited and are therefore no longer identifiable. It is clear, however, that native copper does or did occur in all areas inhabited by the early metal-using cultures, for example in the Andes, in Central America and in the Near East. It is remarkable that most of the world&apos;s native copper occurs in the deposits of the Lake Superior region, primarily on the Keweenaw Peninsula of northern Michigan and on Isle Royale, an island in Lake Superior some 50 miles north of the Keweenaw deposits. Canadian deposits of native copper are found in Newfoundland and Labrador, Nova Scotia, Quebec, Ontario, British Columbia, the Yukon and the Northwest Territories (on Victoria Island, Bathurst Inlet and the Coppermine River area). It was to locate the latter deposits that the explorer Samuel Hearne was sent overland from Hudson&apos;s Bay in 1770; they were also surveyed by Sir John Franklin&apos;s expeditions in the 1820s.

Jan 1, 1999

By J. A. MacLellan

"CONSTRUCI'ION OF SHERRITT'S CONCENTRATORSSherritt Gordon is operating two mills north of the 56th parallel, and is presently engaged in building a third. The author was closely involved in the design and construction of all three of these concentrators.The Lynn mill is the oldest of these three concentrators-it is a 4,000 ton per day nickel-copper plant built in 1953. The Fox mill is a 3,000 ton per day copper-zinc concentrator built in 1970. The Ruttan mill will be a 10,000 ton per day copper-zinc plant scheduled to go on line in July 1973.LYNN MILL The Lynn mill including the crushing, concentrating, drying and load out plant is about 69,700 square feet or 17.4 square feet per ton per day. '!his plant was originally built in 1927 at Sherridon, 150 miles south of Lynn Lake, as a 2,000 ton per day copper-zinc plant. In 1952 the plant was moved by tractor train to Lynn Lake. The whole plant was re-oriented within the original perimeter walls as a 2,000 ton per day nickel-copper plant. This plant was expanded to 4,000 tons per day by the addition of t1-Jo rod mills and a 5-1/2 short head crusher in 1959.The Sherridon mill processed its last ore in Sherridon in September 1951 and the first load of nickel concentrate was loaded at Lynn Lake on November 9, 1953 when the railroad arrived at Lynn Lake.The site for the Lynn Lake mill was cleared of overburden in the summer of 1952 and foundations for structural steel and SO!l8 equipment foundations were poured the late summer and fall of 1952 • Steel was erected from January to June 1953. Most of the equipment came in from January to March of 1953 by tractor sleighs. Sane sleighs upset but no equipment was lest through the ice."

Jan 1, 1972

By E. Stansfield

Coal samples are sometimes taken from a wet spot in a mine, or from an open car or pile shortly after rain, and submitted for analysis in a dripping wet condition. Other samples are taken from a dry spot in the mine, or from an open car or pile after a period of dry weather. Comparison of the analyses obtained in the two cases would be absurd, although the samples might be of essentially the same coat apart from the surface moisture on the one. The analyst therefore attempts to reduce all samples to an equal basis by the operation known as air-drying. Air-drying is practised by the chemist for three reasons: (1) To make it possible to grind the coal to powder. (2) To bring the coal sample to a condition in which it will not change in weight rapidly whilst portions are being weighed out for analysis -in other words, to bring it into equilibrium with the air in the laboratory. (3) To determine the water-retaining power of the coal. Any kind of drying is satisfactory for (1); the coal should be dried more or less according to the humidity at the time in the laboratory for (2); whilst it should be always dried to the same extent for (3). In other words, no method can be satisfactory for both (2) and (3). In this paper the only question considered is (3) -that is, air-drying the coal under standard conditions so that strictly comparable results can be obtained for the water content of coals after air-drying. After a sample of wet coal is exposed, it loses moisture until it is in equilibrium with the air at the time: thus the coal will loose distinctly more water in air of 20 per cent relative humidity, for example, than it would in air of 80 per cent.

Jan 1, 1923

By C. M. Acuna, M. Sherrington

In high temperature processes thermodynamic equilibrium is assumed and therefore chemical potential of elements, among the condensed phases, have to be the same. In such situation impurities distribute accordingly and their fractional distributions are affected by the masses of the coexisting phases. It has been claimed Teniente Converters perform quite well for smelting high impurity concentrates, especially in respect to volatilization and/or slagging. Production of high matte grade near white metal composition, requiring moderate oxygen enrichment in the process air, results in a huge mass of gas and therefore a high fraction of impurities report to it. Similarly, by recycling different sources of slag, flue dust or other materials, the mass of the final slag is increased and so do the masses of impurities reporting to the slag. Nevertheless, above a certain level the recycling of smelter byproducts is no longer feasible and the cycle has to be halted, unless higher impurity mattes are accepted. Although the process might be continued during converting and refining, lengthy and expensive measures have to be taken if suitable anode copper for electrolytic refining is to be achieved. In the present study samples of high arsenic matte grade and slag were obtained on a pilot scale. The matte samples, on the order 75%Cu, were equilibrated with slag at varying ratios in magnesia crucibles under CO/C02 atmospheres at 1523 K. After 24 hours equilibrium matte and slag were rapidly solidified and analyzed by copper, sulfur, iron and arsenic. Furthermore, industrial samples of matte and slag, in the order 75%Cu at 1523 K, were obtained via a special quenching sampling device to determine the association of copper and suspension of matte and copper in slag. Based on the results, the distribution coefficient of arsenic between slag and matte was evaluated along with copper species in slag and the fractional distribution of arsenic, in the coexisting phases, was determined as a function of the ratio mass of slag to mass of matte.

Jan 1, 2007