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By Tim C. Webb

For almost 350 years, industrial rocks and minerals have been produced, used locally and exported from New Brunswick to markets throughout the world. Up until the early 1960s, commodities like grindstone, building stone, gypsum, and limestone served as the foundation of the province's non-fuel mining industry. The importance and high level of activity surrounding industrial rock and mineral development in New Brunswick is reflected in a multimillion dollar industry generating substantial revenue and providing a valuable service to its people. New Brunswick's varied geology is reflected not only by the diversity of industrial rock and mineral resources presently under development but also in several promising exploration and potential development opportunities. The province also hosts several industrial rock and mineral processing facilities, each with established technologies ensuring high-quality products and each with sufficient flexibility to supply customized products for various specialized niche markets. With the imminent availability of natural gas to parts of the province, the prospects for additional value-added processing and re-examination of known, yet presently undeveloped deposits, appear excellent. These variables coupled with the province's advantageous geographical location, highlighting tidewater access to global markets and within one day's trucking distance to a regional market of several million people, guarantee prompt delivery of high-quality products at competitive prices.

Jan 1, 2001

By L. Paulino, R. A. Camilli, J. Yamamoto, J. C. Araujo

The first paper presented on this work [1], showed how bath ratio was increased from 78% to over 95% using a structured approach to reduce bath chemistry variability. This update will illustrate the steps taken and update the results presented earlier, showing the effects of long power interruptions and several load reductions as well as load increase during the period from 1999 to 2005. Current efficiency was affected by such processes upset; however, bath ratio in range (±0.05) is still higher than 90%, even after an increment of more than 6 kA. This review will explain each of the steps taken to reach stability in this critical smelting parameter.

Jan 1, 2006

By S. F. Featherby

"This paper traces briefly the historical development of coal handling systems to meet the needs of a rapidly developing thermal power generation technology. The wide range of operating requirements is demonstrated by comparing and contrasting the Wabamun GS of Calgary Power Ltd. and a typical modern Ontario-Hydro thermal plant. The problems of safe storage of large tonnages of coal in stockpiles are discussed, together with recommendations for stockpile management. The development of coal bunkers and their management is discussed in detail, together with future trends in the industry."

Jan 1, 1966

By J. A. Cox, R. S. Mattson

"One of the main problems encountered in employing sublevel caving is the inherent high dilution factor. The operating results at Granduc illustrate that this dilution can be closely controlled and satisfactory recoveries achieved, in base metal ores grading less than 2.0% copper equivalent, by using an assay grade control system based on the fundamental draw characteristics. The history of draw control procedures employed since the start of operations provides an effective comparison between this system and one based mainly on tonnage. The transverse and longitudinal sublevel caving mining methods are described and it is shown how improvements in design layout, operating practice and draw control in narrow complex ore zones (12-foot minimum width) have raised the operating performance of the longitudinal system to a satisfactory level."

Jan 1, 1973

By Eric J. Grimsey, Don C. Ibana, David E. Grimsey

The segregation process as applied to nickel laterite ores involves the formation of gaseous nickel and iron chlorides which are subsequently reduced to form ferronickel on the surface of a solid carbon reductant. A fundamental study of the process has been carried out using limonite, nontronite and garnierite ores. The study highlighted the significant impacts that ore mineralogy and carbon addition have on the amount of nickel which is segregated rather than retained within the ore due to in-situ reduction. These important aspects affecting nickel recovery and the success of the process are discussed in this paper.

Jan 1, 2017

By R. Guimarães, L. Silva, J. Milboume

The São Bento concentrator was built by Gencor in 1985 to treat refractory gold-bearing flotation concentrate. The plant was the first commercial application of pressure oxidation for refractory gold ore following about a year after the first use of pressure oxidation on a whole ore at Homestake's McLaughlin operation in California. Ore from the Sao Bento mine is remarkably consistent in gold grade and arsenic and sulphide concentration as is typical in banded iron formations (BIF) (l). Gold content is approximately 9 g/t with approximately 30 - 40% free milling. The balance is associated with arsenopyrite and pyrrhotite. An expansion of both process facility and mine was undertaken between 1996 and 1998, raising the treatment capacity from 32,000 t/mo to 45,000 t/mo.

Jan 1, 2004

By C. W. Hancher, B. D. Patton, W. W. Pitt

"There are a number of nitrate-containing wastewater sources, as concentrated as 30 wt % NO3 and as large as 2000 m3/day, in the nuclear fuel cycle. The biological reduction of nitrate in waste water to gaseous nitrogen, accompanied by the oxidation of a nutrient carbon source to gaseous carbon dioxide, is an ecologically sound and cost-effective method of nitrate waste disposal. These nitrate-containing wastewater sources can be successfully biologically denitrified to meet discharge standards in the range of 10 to 20 g N(NO3-)/m3 by the use of a fluidized bed bioreactor. The denitrification bacteria are a mixed culture derived from garden soil; the major strain is Pseudomonas. In the fluidized-bed bioreactor, the bacteria are allowed to attach to 0.25- to 0.50-mm-diam. coal fluidization particles, which are then fluidized by the upward flow of influent wastewater. Maintaining the bacteria-to-coal weight ratio at approximately 1:10 results in a bioreactor bacteria loading of greater than 20,000 g/m3,This paper describes the results of a bio denitrification R&D program based on the use of fluidized bioreactors capable of operating at nitrate levels of up to 7000 g/m3 and achieving denitrification rates as high as 80 g N(N03-) per day per litre of empty bioreactor volume. IntroductionThe discharge of wastewater containing nitrate at concentrations greater than stipulated by the Environmental Protection Agency (EPA) creates an environmental hazard and constitutes a civil and/ or criminal legal liability.(I.2) At present, we have three options: (1) recycle and reuse of nitrate streams the total economic and technical balance should be Closely examined; (2) use of an alternative acid, which may pose an entirely different set of problems ; or (3) disposal of nonreusable nitrate sources by an environmentally acceptable procedure."

Jan 1, 1980

By D. R. Spink, G. L. Rempel, C. O. Gomez Bueno

"A morphological and chemical study of the Great Canadian Oil Sands Ltd. (GCOS) fly ash has been carried out. Extensive scanning electron microscopy, as well as light microscopy, showed that the GCOS fly ash consists of two fractions, one composed of unburnt or partially burnt irregular-shaped carbon particles and an ash fraction composed of transparent and opaque, often coloured, glassy spherical particles-some of them cenospheres (hollow spheres) and the others plerospheres (hollow spheres packed with smaller spheres). Microcrystals (0.1 to 0.3 um long) growing on the inner and outer surfaces of some of the spheres were also noted and found to contain more Fe, Ti, Ni and V than the spheres.The carbon-free GCOS fly ash particle size follows a lognormal distribution, with a geometric median particle size (by count) of3.8um and a geometric standard deviation of 1.84. IntroductionCanada's current energy situation strongly suggests that oil from the Alberta tar sands deposits will probably be recovered more extensively in the future. Today's commercially proven technology to recover oil from the Athabasca tar sands, as practised by Great Canadian Oil Sands Ltd. (GCOS), involves two major operations, namely: separation of the bitumen from the sand and upgrading of the bitumen to refinery oil; the production of significant amounts of petroleum coke and sulphur during the bitumen upgrading process. The bulk of the petroleum coke is burnt in boilers to fulfill the energy requirements of the entire operation. The boiler ash, which contains appreciable amounts of metals, such as vanadium, nickel, titanium, iron, aluminum and other elements, is collected in the boiler hoppers and cyclones of the petroleum coke-fired steam generation plants. Thus, as well as representing a petroleum resource, the tar sands represent a resource for vanadium and possibly other metals providing that metal recovery processes can be developed."

Jan 1, 1980

By G. Armand, A. Noiret, D. Seyedi, J. Morel

"Clay formations in their natural state exhibit very favorable confining conditions for repository of radioactive waste because they generally have a very low hydraulic conductivity, small molecular diffusion and significant retention capacity for radionuclides. Nevertheless, one concern regarding the hydromechanical behavior around drifts in such claystone is the associated pore pressure field disturbance during excavation works. In the short term, the very low permeability leads to an almost “undrained” condition, meaning that the stress change due to face advance will create volumetric strains leading to an increase or decrease of pore pressure. If the effective stresses reach the failure level, the induced damage around these excavations might change the favorable properties of such formations. To demonstrate the feasibility of a reversible deep geological disposal of high-level and intermediate-level long-lived radioactive waste (HLW, IL-LLW) in the Callovo-Oxfordian claystone (COX) formation, the French national radioactive waste management agency (Andra) started in 2000 to build the Meuse Haute-Marne underground research laboratory (M/HM URL). The present paper illustrates observed pore pressure changes during excavation of drifts (˜5 m diameter), of micro tunnels (˜0.7 m diameter) and a borehole (˜0.15 m diameter). All these openings are parallel to the major horizontal stress at the main level of the M/HM URL. In drifts parallel to the major stress (i.e., when the initial stress field in the drift section is quasi-isotropic) an important increase followed by a drop of pore pressure is observed in the horizontal plane at the drift wall. These observations emphasize the impact of the in situ stress state and rate of excavation on the pore pressure and provide important insight of the hydro mechanical behavior of the COX claystone and the relationship between pore pressure and excavation induced fractures zone."

Jan 1, 2015

By I. J. Burgess, B. C. Barlow

"The electrodissolution of nickel pellets with different controlled electrical variables was investigated in an effort to mitigate plating residue in Watts bath based electroplating cells. During galvanostatic dissolution at 0.4 A dm-2, the anode potential was seen to oscillate between passive and pitting potentials. In-situ microscopy and ex-situ characterization has shown that lacy-pit formation and large, partially perforated, pit covers form during the potential decay from pitting potentials. In general, covered pitting at low current density shows increased plating residue. Using potential pulses is one way to maintain greater control over surface pitting by creating a higher density of pit nuclei while at the same time controlling their growth. Pits generated from a series potential pulses were examined ex situ for a range of pulse times and stages of pit growth were identified. An alternative method of anode dissolution was devised using potential pulses and duty cycles that allowed average current densities comparable to industrial plating conditions to be achieved. By restricting the time at pitting potentials to 0.05 s, plating residue was reduced more than six-fold in comparison to an equivalent galvanostatic experiment run at a comparable current density.INTRODUCTIONIn typical galvanostatic (direct current) nickel electroplating cells employing soluble anodes, some amount of plating residue is produced which consists of metallic nickel and impurities that detach from the bulk in the form of small fines. Significant buildup of residue requires plating operations be halted and the anode assembly cleaned of residue before operation can resume. While variables in the refining process have been shown to affect plating residue, more precise control of electrochemical variables may provide an attractive route to mitigation of residue."

Jan 1, 2016

By Philippe Ribagnac, Bruno Courtaud, Jean-Marie Lambert, Valérie Weigel

Mabounié is a polymetallic deposit in Gabon containing niobium (1.2 wt.%), tantalum (0.03 wt.%), rare earth elements (REE) (1.4 wt.%) and uranium (0.03 wt.%) that are mostly carried by pyrochlore minerals. The classical route for niobium recovery is a pyrometallurgical process that consists of pyrochlore flotation, dephosphorization of the niobium concentrate and aluminothermy to obtain ferro-niobium. Pyrochlore concentrates can also be treated by a hydrometallurgical process with a mixture of sulfuric and hydrofluoric acid leaching followed by solvent extraction to separate niobium and tantalum. However, the first process does not allow recovering REE and the second one is not environmentally friendly because of the use of HF. ERAMET is looking for new opportunities on strategic metals market and has recently developed a hydrometallurgical process for the recovery of all these metals based on a sulfuric acid treatment of the ore (Donati, Courtaud, & Weigel, 2014). As for most of the oxidized ore processes, the major impurity is iron (~30 wt.%). Thus, in this hydrometallurgical process, the question arises of the elimination and stabilization of the iron as residue. The iron in solution is ferrous; goethite precipitation seems the most adapted crystalline form. Lab and pilot tests have shown kinetics of precipitation of 6 g.L-1.h-1 at pH 4.5. To reduce the salt discharge, sodium-jarosite form is more adapted, but at pH 2, 95°C only 30% of iron is precipitated in 5 hours, compared to 100% in goethite form at the same time and pH 2, 80°C. Different ways of oxidation were tested, air, pure O2, activated carbon, without drastic effect. The more efficient was ozone use, at room temperature; the kinetics of oxidation is five time faster than the other ways with 30% of sodium removed from the solution.

Jan 1, 2016

Shafts are the most important workings in the underground mines. Their technical state to a large extent determines the safety and efficiency of mining operations. However, in many cases periodically performed inspections show unsatisfactory technical state of the shaft lining (local defects, cracks, cavities, losses of the outer surface of the lining or, in case of the bricks, losses of the masonry). The most common cause of these types of damage is progressive deterioration of the lining material, impact of aggressive mine waters, impact of mining operations, deformation of the lining due to the rock mass saturation, seismic activity or periodic freezing of the lining in the upper part of a shaft. The paper presents legal requirements associated with the use of mine shafts in Polish coal mines as well as the ways and range of their control. Furthermore, examples of typical damage to shaft lining and ways to repair it, such as additional bolting, filling cavities or a wire mesh and shotcrete installation, are shown. In the final part, the paper presents a short example of a shaft, in which damage to the lining was one of the main causes of the shaft's failure. Due to the damage to the shaft lining, at the depth of approx. 65.0 m, the shaft was spontaneously filled with overburdened soil material. It resulted in a large crater to come to the surface, which, in turn, caused damage to the buildings and facilities present in the impact zone. On the surface the diameter of the crater was approx. 60.0 m, its depth approx. 11 m and the estimated volume was of about 30,000 m³. The disaster also caused disturbance in the ventilation of two neighbouring mines and the increase in methane hazard. Given the size of the crater, the measures to eliminate consequences of the catastrophe were undertaken in several stages.

Aug 1, 2013

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By James F. Allan

"The Kipawa yttrium-zirconium prospect is located about 150 km south of Noranda, Quebec. Yttrium-zirconium mineralization occurs in an elongate, regionally metamorphosed and deformed peralkaline complex in the Grenville terrain. The mineralized zone, as defined by =.0.10% Y2O3, is 1300 m long and 10 m to 30 m wide. Zirconium content typically ranges from 0.50 to 1.20% ZrO2, The mineralized zone strikes northwest and dips 20 degrees to 35 degrees to the southwest. It occurs at the structural base of the peralkaline complex in syenite gneiss and calc-silicate rocks and is conformable with both the footwall contact of the complex, and the layering and gneissosity in the enclosing rocks. Minerals of economic interest are eudialyte (sodium-zirconium silicate), mosandrite (sodium-titanium silicate), britholite (calcium-silica phosphate), and a few other uncommon zirconium and titanium silicate minerals.The highest and most continuous yttrium grades occur in the upper part of the syenite gneiss unit in areas containing eudialyte, mosandrite and minor britholite. Yttrium also occurs in britholite in calc-silicate rocks and in mosandrite in syenitic rocks in the lower part of the syenite gneiss unit. Both the yttrium-bearing minerals and yttrium grades are erratic in the lower part of the unit. Zirconium is generally more uniformly distributed than yttrium. A peralkaline granite gneiss phase of the complex intrudes the syenite gneiss and possibly truncates it, and the mineralization, near the southern boundary of the mineralized zone.The mineralized zone is coincident with a radiometric anomaly and discontinuous yttrium and zirconium soil anomalies.More drilling and metallurgical studies will be required to determine the economic viability of the yttrium and zirconium mineralization at Kipawa."

Jan 1, 1992

By Gilles Carrière

"The Suffield mine is situated five miles southwest of the city of Sherbrooke, in the Eastern Townships of Quebec. lt is the property of Suffield Metals Corporation Limited, a wholly owned subsidiary of Ascot Metals Corporation Limited.The old Suffield or Griffith mine had been worked intermittently from 1863 to 1906, without ever producing much ore. In 1951, diamond drilling done by Ascot Metals proved over one million tons of ore in three new bodies. The average grade of this ore was 0·018 ounces of gold per ton, 2-40 ounces of silver, l ·28 per cent copper, 0·59 per cent lead, and 6-45 per cent zinc. Since then the mine has been active, producing between 300 and 700 tons daily. More recent exploration has found continuations of the ore zones.General GeologyThe ore of the Suffield mine is found in porphyritic rhyolites of the Sherbrooke group (Silurian), at or close to its contact with sediments of the Beauceville group (Ordovician). The contact shows pronounced folds as well as irregularities due to erosion of the sediments prior to the outpour-ing of the lavas. On surface the general strike is north, and the dip is steeply east.The footwall sediments consist of interbedded black graphitic slates and. dark-coloured chloritic quartzite, overlain in many places by a thin bed of magnetite-hearing quartzite.The rhyolite host rock is a light grey rock, containing very abundant quartz and feldspar phenocrysts in a microcrystalline matrix of the same minerals. Some sericite is always present, especially in the vicinity of the ore zones, where the rock shows a pronounced schistosity.Several narrow basic dykes, with an easterly strike and vertical dip, cut all other formations. Most are lamprophyres, of either the monchiquite or camptonite type, but one has been identified as a diabase."

Jan 1, 1949

By J. W. G. Hannon

FOLLOWING the experimental work of Denny, Robson, and Irwin, and the clinical investigation by Crombie and Blaisdell, an investigation of aluminium therapy was begun at Washington, Pa., which is situated in a very large industrial section of the State. Some of the men to be studied were from plants manufacturing silica brick, refractories used in steel and glass manufacturing, and semi-porcelain table-ware; others were workers in foundries, sand blasters, and men engaged in the quarrying of ganister rock. This group of workmen gave an opportunity to study the effects of aluminium on various types of silicosis which differed somewhat from that found in hard-rock miners. EXPOSURE In their occupations, the men studied were exposed to silica dust concentrations ranging from 17 to 97 per cent free silica. In the silica brick industries, the unfired product averages 96 per cent silica in the form of quartz, whereas the fired brick contains 50 to 62 per cent cristobalite plus 17 to 30 per cent tridymite, forms of silica that, on account of their higher solubility, are more toxic than quartz. The operational dust counts in the plants varied from 15 to 9,500 particles per c.c., and the median particle size from the aerial samples was 1.0 micron for the green product and 2.0 microns for the fired product. The length of exposure varied with the occupation as well as with the individual plant, but disabling silicosis could be produced in less than four years in certain exposures. The average time needed to produce radiological silicosis in those susceptible to this disease was eight years. Some of the men in our series of cases have been treated as long as fifteen years after exposure had ceased, and have improved under treatment.

Jan 1, 1944

By The Staff

Introduction It is the purpose of this paper to discuss a number of the metallurgical improvements in the technology of copper-nickel ore treatment which have been introduced during recent years in the plants of ?the International Nickel Company of Canada, Limited. In common with other ore treatment processes, the procedure for extracting nickel and copper is changing almost continuous! y. These changes are necessitated by reason of changes in ore grades and characteristics, rising material and labour charges, and the constant drive to maximize metal recovery and to minimize production costs. It is not possible to present a comprehensive list of all the changes made, and only a selected number of the improvements in the milling, smelting, and refining operations are covered. It should be clearly understood that some phases of the procedures described have been pioneered by others in kindred fields and due acknowledgment is given to their foresight and efforts. Articles have been published over the years describing the operations of the International Nickel Company plants and the reader is referred to the Engineering and Mining Journal, Vol. 130, No. 9, November 10th, 1930, and to the Canadian Mining Journal, Vol. 58, No. 11, November, 1937, and Vol. 67, No. 5, May, 1946. Other references are the Transactions of this Institute, 1932, 1938, and 1946; Metals Technology, American Institute of Mining and Metallurgical Engineers, February, 1938, and Canadian Chemistry and Process Industries, April, 1940.

Jan 1, 1948

By B. K. Choi, G. E. Kim, S. Noh, T. K. Kim

Oxide dispersion strengthened (ODS) steel has been developed as the most prospective core structural material for next-generation nuclear systems because of its excellent high strength and irradiation resistance. In ODS steel, finely dispersed nano-oxide particles with a high number density in the homogeneous grains can be very attractive to achieve superior mechanical properties at high temperatures, and these favorable microstructures can be significantly changed using process parameters during the mechanical alloying procedures. In this study, the effects of mechanical alloying times on the microstructure of 10Cr-1Mo ODS martensitic steel were investigated. Pre-alloyed powders with Y2O3 powder were mechanically alloyed for various milling times using a high energy horizontal ball-mill apparatus (model: symoloyer CM20). Powder properties such as the mean particle size, size distribution, and crystallite size were evaluated. Uniaxial hot pressing was employed to consolidate the milled powders. The results of a microstructural observation after the MA and UHP processes indicated that the homogeneity of the martensitic structures was considerably increased with the longer milling time. It is thus concluded that the mechanical properties of the ODS martensitic steel are greatly dependent on the mechanical alloying times.

Jan 1, 2015

By S. Kashani-Nejad

The kinetics of the thermal decomposition of samples of Mg2(OH)3Cl.2H2O that were obtained by a novel leaching technique applied to a commercial magnesium electrolysis feed were investigated under ambient atmosphere. Thermogravimetric (TG) Analysis showed that decomposition of Mg2(OH)3Cl.2H2O exhibited a single intermediate stage wherein crystalline water was lost at roughly 108 °C. Conversion of the resulting Mg2(OH)3Cl to MgO, HCl and 1120 occurred at temperatures above 398 °C. Thermal decomposition of anhydrous Mg2(OH)3Cl was seen to be consist of two stages. Both stages exhibit first order kinetics with respect to the weight percent of Mg2(OH)3Cl remaining in the sample. However, the rates of decomposition in the two stages were significantly different. Detailed analysis of the kinetic data suggested that the rate of decomposition of Mg2(OH)3C1 was controlled by the rate of removal of the gases released. The change in decomposition rate during the course of the experiments was explained by HCI being released in stage 1 and followed by release of H2O in stage 2.

Jan 1, 2004

By J. E. Gill

Discovered in 1952, the deposits have been explored by diamond drilling on and near a group of islands in lake Nipissing and from under-ground workings. The ore mineral is a uranian pyrochlore. It occurs in breccia zones in association with calcite, apatite, a?cmite, feldsiiars, biotite, magnetite, sulphides, and fluorite in varying amounts. The pyrochlore concentrations occur in a steeply-dipping gneiss series with some crystalline limestone. Trends indicate a ring structure 114 miles in diameter. The main ore zone shows evidence of repeated brecciation and a succession of replacements .giving rise to a complex of rock types. Pegmatite and lamprophyre dykes cut the ore as do calcite-fluorite veins and later faults with small displacements. Columbium and uranium occur al-most exclusively in pyrochlore, but the proportions vary. There is no tantalum and only small amounts of titanium.

Jan 1, 1957