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By Wilhelm Flesch

THE object of development work in the field of gasification is to find a process by which all' fuels, regardless of their individual properties, can be gasified economically. This paper describes the development of the Winkler process. The economy of the gasification process depends not only on the degree of the gasification effect but also, to a decisive extent, on the costs of fuel, production, and installations. Fig 1 shows the relation between fuel costs and gasification efficiency for various types of fuels. Since the fuel cost in the gasification of coke amounts to two thirds of the price of gas, and the thermal unit in brown coal costs only one third of what it costs in coke, it is easily seen how profitably cheap fuels can be gasified, especially if these fuels require minimum preparation and gasification is done in the vicinity of the mines. These possibilities were a great advantage of the Winkler generators, which were installed 20 years ago in the central German brown-coal fields and, at that time, were without rival for the gasification of finely divided fuels. In the Winkler generator (Fig 2), crushed and ground solid fuels were, for the first time, successfully gasified with oxygen and steam on an industrial scale. Unlike the usual processes formerly employed on an industrial scale, this gasification, which proceeds continuously in the glowing, seething fuel bed, makes only extremely low demands on the fuel. The fuel no longer has to be in lumps and abrasion-resistant, but must be capable of reaction and must be fed into the generator in a grain size of 0 to 8 mm. Brown coal or bituminous coal, or their low-temperature cokes, can be gasified in the Winkler generator. Large plants using fuels are operating on an industrial scale in Europe and in Japan. Table 1 shows the results obtained by gasifying these, fuels in Winkler generators. The thermal efficiency of gasification, which is the relation between the calorific value obtained in the gas produced and that of the fuel consumed, gives no indication of the quantity of steam generated in gasification. The generation of steam in the waste-heat boiler of the Winkler generator adequately-covers the steam consumed in gasification. To obtain effective gasification in the Winkler process, combustible mate-

Jan 1, 1953

By Harold C. Price

Prior to Sept. 1, 1928, there had never been constructed what might be termed a long pipe line with electric-welded field joints. A year later more than 2500 miles of electric-welded lines had been completed which varied in diameter from 6 to 20 in., and in length from 50 to 700 miles. This paper discusses methods used on five lines with a total length of about 750 miles. The welding equipment used for the firing line or rolling welds, was 300-amp. generators driven with six-cylinder gasoline engines, and for the bell-hole or tie-in welds, 200-amp. generators driven by four-cylinder gasoline engines. A welding gang consisted of a foreman, 6 to 12 firing-line welders and 2 to 4 bell-hole welders, a mechanic and a tractor driver. Coupons about 1/4 in. thick were frequently cut from completed welds, which showed a cross-section of the weld and an indication of its size and penetration. For tests of tensile strength complete welds were cut out. The tensile strength of 52 welds cut from 420 miles of 12-in. line averaged 50,870 Ib. per square inch. The following results give a fair average of the number of welds made per man per day: on 157 miles of 8-in. line both firing-line and hell-hole welds averaged 15.3—the firing-line average was 21; on 39 miles of 10-in. line the firing-line average was 19.9; on 50 miles of 6-in. line, with unfavorable weather, the average was 17.7; on 424 miles of 12-in. line most of which was welded during the spring, 10.3, and with good weather the average rose to 13 welds per day. The average time for making a complete weld on 12-in. pipe 0.313 in. thick was found to be 30 min. for the rolling weld and 45 min. for tie-in welds. A comparison of costs between electric and gas welding shows that the cost of labor for electric welding is 25 per cent. more than gas, generating cost 61 per cent. less than gas, welding wire 40 per cent. less than gas, and supervision and overhead the same. Estimating 50 per cent, annual depreciation on electric welding equipment, and no depreciation

Jan 1, 1930

THE Institute of Metals Division opened its series of meetings by a session* on lead, R. S. Dean be-ing in the chair and G. 0. Hiers acting as vice-chairman. A large and representative audience listened to the papers in the abstract and contributed an inter-esting and fruitful discussion. The main points of these papers and discussion are given below: In the absence of Carl E. Swartz, the summary and conclusions of his paper, "A Study of the Lead-Tin-Cadmium System with Reference to Their Use as Solders," were read. Swartz investigated a number of alloys in the lead-tin-cadmium system and prepared a diagram representing the solidification ranges of these alloys. He also made tensile strength tests of joints made with these alloys, and compared these with joints made with ordinary lead-tin solder. The tests showed solders containing cadmium were equally strong as the lead-tin series and that the cadmium alloys were suit-able in other respects for use as solders. In general, solders of the composition near to the ternary lead-tin-cadmium eutectic appeared to be the best for most soldering work although compositions widely differing are desirable for special purposes. The lead-tin-cad-mium solders are finding a market particularly in the fields requiring lower solidification temperatures than common solders. Mr. Darby opened the discussion and asked whether it was a fact that the lead-tin-cadmium solders were more useful than ordinary solders on galvanized and tin-plated sheet. C. Smith said he thought it to be a fact that galvanized sheet was more easily soldered by the lead-tin-cadmium solders than common lead-tin-solder. Continuing, Mr. Smith showed lantern slides of his own investigation of the thermal diagram and recommended the 70 per cent lead, 20 per cent cadmium, and 10 per cent tin for general employment. He thought the author did not differentiate between wetting and alloying and pointed out that wetting was more a ques-tion of the flux than the metal. In some cases a definite alloy was formed by soldering and in some no evidences of alloying were found. Illustrating the former case he showed slides and demonstrated that failures always took place longitudinal with the brittle compound alloy and transversely across the solder itself.

Jan 3, 1928

By C. E. Birchenall, H. M. Schadel

THE purpose of this study was to measure the vapor pressure of silver as the first step in the determination of activities in silver alloys and to test the limitations of the method adopted. In order to work at low pressures, below 2x10-2 mm of mercury, the orifice effusion technique was employed. To shorten the time of collection of silver from the atomic beam, radioactive silver (Ag110) was used as a tracer. The rate of effusion of a monatomic vapor from an "ideal" orifice, where the thickness of the orifice edge is negligible compared with the orifice diameter, can be readily calculated from the kinetic theory of gases, G = vM a p/v2pRT where G is the weight of material effusing from the orifice per unit time; p is the vapor pressure at oven temperature, T; R is the gas constant; M is the molecular weight of the vapor; and a is the orifice area. Consolidating constants and expressing as the weight of material effusing from the orifice in a period of time, t, (5.83)(10-2) (vM) (a) (t) (p)/vT where GT is total weight of monatomic vapor effused (g); M is molecular weight of the effusing tracer vapor; a is orifice area (cm2); t is time of effusion (sec); p is vapor pressure of effusing material (mm of Hg); and T is oven temperature (OK). The vapor effuses from the orifice in a hemispherical pattern, and the intensity of the beam in any direction is given by the cosine distribution law.' Considering this, the weight of effused material can be calculated from the amount of material passing through a circular collimator intersecting the beam. If such a collimator is in a plane parallel to the plane of the orifice and with center on the normal to the orifice center, GT = G?/1-cos2? = G?/sin2? where G? is the weight of effused material passing through the collimator, and 0 is one half the apex angle of the cone defined by the collimator circumference and the orifice center. Reducing eq 3 to the more directly measurable quantities of orifice to collimator distance, d, and collimator diameter, D, the expression becomes,

Jan 1, 1951

By B. D. Cullity

Gold and beryllium form an intermediate phase composed of the two metals in equal atomic proportions and having the formula AuBe. According to Winkler,' this phase probably exists in two modifications: beta, stable below about 600°C, and alpha, stable between 600°C and the melting point, about 740°C. Only the low-temperature beta form will be considered in this paper. Experimental Procedure The gold used had a fineness of 999.75 to 999.85, balance mainly silver, and the beryllium purity was better than 99.8 pct. AuBe was prepared by melting the constituents in a beryllia crucible in an evacuated induction furnace. After melting and thorough mixing, the alloy was allowed to solidify in the crucible. No difficulty was encountered in obtaining a homogeneous ingot. Both chemical analysis and microscopic examination of the ingot showed that the alloy was essentially one phase, containing 50 at. pct gold. The alloy was quite brittle and powder samples could easily be prepared by grinding in an agate mortar. The X-ray diffraction patterns were made with CuK-alpha radiation in a Debye-Scherrer powder camera 57.3 mm in diameter. The film was placed unsym-metrically in the camera in order to afford a basis for film-shrinkage corrections. A sample homogenized at 500°C gave the same diffraction pattern as a sample taken from the as-melted ingot. General Results The diffraction pattern of AuBe was readily indexed on the basis of a simple cubic lattice with ao = 4.659 + 0.001kX. If the unit cell is assumed to contain four AuBe "molecules," the calculated X-ray density is 13.46 grams per cc as compared with the measured density of 13.55 gm per cc. The only missing reflections in the diffraction pattern are (100) and (220) (see Table I). Since these missing reflections are not those characteristic of body or face centering, the lattice of AuBe must be simple cubic. To locate the positions of the atoms within the unit cell, two possibilities had to be considered: I. The structure was disordered and there were eight positions to be filled by an LCaverage" gold-beryllium atom. That the structure was disordered seemed unlikely since the lattice parameter did not vary with composition in alloys containing sornewhat more and somewhat less than so at' pet gold, indicating a fixed composition for AuBe.

Jan 1, 1947

By George C. Ference

Sulfur is the 13th most common element in the earth's crust, constituting approximately 0.05% of the total. It occurs naturally in its elemental form, as metallic sulfides, nonmetallic sulfates, and as combined or free sulfur in natural gas, crude oil, and coal. COMMERCIAL SOURCES Most of the sulfur that is consumed is converted into sulfuric acid before use; therefore, it is not necessary to recover sulfur solely in its elemental form. Processes for recovery are peculiar- to the types of reserves being processed. The major commercial processes as well as the general geographic locations where the appropriate reserves occur are listed in the following. It should be noted that the sulfur values may be recovered as the primary product, as a coproduct with other materials, or as a byproduct. Elemental Sulfur 1) Frasch mining is used for subterranean deposits of elemental sulfur around the Gulf Coast areas of the United States and Mexico. Generally, but not exclusively, such deposits are located in salt dome structure. 2) Autoclaving, flotation, or solvent extraction of surface deposits of elemental sulfur is practiced throughout the world. 3) Extraction and conversion of hydrogen sulfide from sour natural gas into elemental sulfur is done principally in Canada, France, and the United States. 4) Conversion of metallic sulfides from pyrites into elemental sulfur is done via the Outokumpu process in Finland. 5) Catalytic cracking and hydrocracking of sulfur-bearing crude oils to produce elemental sulfur is done worldwide. Desulfurization of refined petroleum products also yields elemental sulfur. 6) Recovery of elemental sulfur from sulfur-bearing oil sands (Athabasca tar sands) has been initiated in Canada. 7) As of this writing (1970), a plant has been constructed for the thermal decomposition of gypsum to produce elemental sulfur in the United States. Sulfuric Acid Sulfur values in the form of sulfuric acid are recovered via: 1) Recovery from smelter gases throughout the world. 2) Roasting of pyrites throughout the world with iron sinters as a byproduct. 3) Roasting of anhydrite with cement as a coproduct, primarily in Europe. 4) Processes currently are being developed for recovery of sulfuric acid from combustion gases resulting from the burning of high-sulfur-content fuel. Other Sulfur values also are recovered from waste products which normally occur in highly industrialized areas. Some examples are: coke-oven gases, sludge sulfuric acid, and pickling liquors (ferrous sulfate).

Jan 1, 1976

By B. D. Cullity

Gold and beryllium form an intermediate phase composed of the two metals in equal atomic proportions and having the formula AuBe. According to Winkler,' this phase probably exists in two modifications: beta, stable below about 600°C, and alpha, stable between 600°C and the melting point, about 740°C. Only the low-temperature beta form will be considered in this paper. Experimental Procedure The gold used had a fineness of 999.75 to 999.85, balance mainly silver, and the beryllium purity was better than 99.8 pct. AuBe was prepared by melting the constituents in a beryllia crucible in an evacuated induction furnace. After melting and thorough mixing, the alloy was allowed to solidify in the crucible. No difficulty was encountered in obtaining a homogeneous ingot. Both chemical analysis and microscopic examination of the ingot showed that the alloy was essentially one phase, containing 50 at. pct gold. The alloy was quite brittle and powder samples could easily be prepared by grinding in an agate mortar. The X-ray diffraction patterns were made with CuK-alpha radiation in a Debye-Scherrer powder camera 57.3 mm in diameter. The film was placed unsym-metrically in the camera in order to afford a basis for film-shrinkage corrections. A sample homogenized at 500°C gave the same diffraction pattern as a sample taken from the as-melted ingot. General Results The diffraction pattern of AuBe was readily indexed on the basis of a simple cubic lattice with ao = 4.659 + 0.001kX. If the unit cell is assumed to contain four AuBe "molecules," the calculated X-ray density is 13.46 grams per cc as compared with the measured density of 13.55 gm per cc. The only missing reflections in the diffraction pattern are (100) and (220) (see Table I). Since these missing reflections are not those characteristic of body or face centering, the lattice of AuBe must be simple cubic. To locate the positions of the atoms within the unit cell, two possibilities had to be considered: I. The structure was disordered and there were eight positions to be filled by an LCaverage" gold-beryllium atom. That the structure was disordered seemed unlikely since the lattice parameter did not vary with composition in alloys containing sornewhat more and somewhat less than so at' pet gold, indicating a fixed composition for AuBe.

Jan 1, 1947

By E. L. Anderson, J. R. Long, R. S. Dean, F. S. Wartman

Titanium has been estimated to comprise about 0.65 per cent of the earth's crust and ranks fourth in abundance among the metallic elements suitable for engineering uses. In spite of this, applications of titanium for structural purposes have not as yet been developed. Its commercial exploitation has been largely confined to the chemical industries and the production of paints and pigments; no doubt because of the difficulties that lie in the way of preparing the pure ductile metal. Published reports, however, indicate that ductile titanium can be prepared and possesses some unique properties. This, together with the occurrence in this country of several important titaniferous deposits, has led the Bureau of Mines to investigate processes for the production of metallic titanium, methods required for its fabrication, and the properties that may be produced in this interesting metal. Methods of Preparing Metallic Titanium Many early investigators claimed to have isolated metallic titanium; but in the light of present knowledge, it seems that they really had produced various mixtures of carbides and nitrides that have a metallic appearance but are brittle, hard, and unworkable. The first metallic titanium pure enough to be malleable when cold was produced by Hunter1 in the early part of the twentieth century. Kroll,~ van Arkel,~ and Fast,4 subsequently confirmed the facts that pure titanium is a. ductile metal and that small amounts of impurities were responsible for previous reports of brittleness. When heated, titanium reacts chemically with various gases, such as hydrogen, oxygen and nitrogen; if the volume of gas thus absorbed is too great, the metal becomes brittle and unworkable. The principal difficulty in making ductile titanium is prevention of such contamination, and the success of a given process may be judged by the completeness with which it solves this difficulty in a practical manner. Of the gases mentioned, hydrogen is the least objectionable, since its absorption by the metal is completely reversible and, although dimensional changes occur and absorption of hydrogen embrittles the metal, the gas may be removed readily by heating in a high vacuum for a short time. On the other hand, the absorption of oxygen or nitrogen results in the formation of permanent solid solutions of the oxide and nitride, which cannot be decomposed by the strongest reducing agentsz with sufticient completeness to restore the inherent ductility of the metal. Because of

Jan 1, 1946

By J. B. Tyrrell

A short time ago I paid a visit to the alluvial gold fields on the tributaries of the Chaudiere River in Beauce County, Quebec, in company with A. 0. Dufresne, late manager of the Champs d'or Rigaud-Veaudreuil, and now assistant to the Superintendent of Mines of the Province of Quebec. As the conditions under which the gold occurs in this district are not very generally known, and present some interesting features, a brief description of these conditions, and a consideration of the causes which gave rise to them, may be of interest to other mining engineers. During the latter half of last century the country was visited by many mining engineers and geologists, and many references to it may be found in the reports of the Geological Survey of Canada between 1848 and 1911. The most important of these are by J. A. Dresser and J. Keele and the late Robert Chalmers. The Department of Colonization and Mines of the Province of Quebec also published a report with map on the district by J. Obalski. From the earliest times the valley of the Chaudiere River formed one of the main avenues of approach to the St. Lawrence in the vicinity of Quebec from the country to the south as far as the seaboard of the States of Maine and Massachusetts. The Indians had a well-known trail along the banks of the stream, and armed troops and foraging parties constantly moved backward and forward along it between Quebec and New England in those insecure times before the ceding of Canada to Great Britain. Even yet the natural advantages of this old military route are recognized, and the government of the Province of Quebec has now under construction along it a magnificent highway from Quebec to the International Boundary Line, which is to form part of a through highway from that city to Boston. The land along the valley is naturally well suited for agriculture, and about the end of the eighteenth and the beginning of the nineteenth centuries farmers began to go back from the St. Lawrence, and to occupy the higher lands along the upper portions of the Chaudiere Valley. This settlement has gone on until now the country is peopled with a prosperous agricultural population.

Jan 1, 1915

By J. R. Long, E. L. Anderson, R. S. Dean, F. S. Wartman

Titanium has been estimated to comprise about 0.65 per cent of the earth's crust and ranks fourth in abundance among the metallic elements suitable for engineering uses. In spite of this, applications of titanium for structural purposes have not as yet been developed. Its commercial exploitation has been largely confined to the chemical industries and the production of paints and pigments; no doubt because of the difficulties that lie in the way of preparing the pure ductile metal. Published reports, however, indicate that ductile titanium can be prepared and possesses some unique properties. This, together with the occurrence in this country of several important titaniferous deposits, has led the Bureau of Mines to investigate processes for the production of metallic titanium, methods required for its fabrication, and the properties that may be produced in this interesting metal. Methods of Preparing Metallic Titanium Many early investigators claimed to have isolated metallic titanium; but in the light of present knowledge, it seems that they really had produced various mixtures of carbides and nitrides that have a metallic appearance but are brittle, hard, and unworkable. The first metallic titanium pure enough to be malleable when cold was produced by Hunter1 in the early part of the twentieth century. Kroll,~ van Arkel,~ and Fast,4 subsequently confirmed the facts that pure titanium is a. ductile metal and that small amounts of impurities were responsible for previous reports of brittleness. When heated, titanium reacts chemically with various gases, such as hydrogen, oxygen and nitrogen; if the volume of gas thus absorbed is too great, the metal becomes brittle and unworkable. The principal difficulty in making ductile titanium is prevention of such contamination, and the success of a given process may be judged by the completeness with which it solves this difficulty in a practical manner. Of the gases mentioned, hydrogen is the least objectionable, since its absorption by the metal is completely reversible and, although dimensional changes occur and absorption of hydrogen embrittles the metal, the gas may be removed readily by heating in a high vacuum for a short time. On the other hand, the absorption of oxygen or nitrogen results in the formation of permanent solid solutions of the oxide and nitride, which cannot be decomposed by the strongest reducing agentsz with sufticient completeness to restore the inherent ductility of the metal. Because of

Jan 1, 1946

By J. T. Berling, J. B. Conway

MANY studies have been devoted to the correlation of low-cycle fatigue behavior. Several of these have also been concerned with the identification of an effective approach to the prediction of low-cycle fatigue behavior from short-term tensile data. Perhaps the first such approach was that reported by coffin1 in the form: where is the plastic strain range, Nf is the number of cycles to failure, and c is a constant characteristic of a material. In this analysis by Coffin it was reasoned that in a short-term tensile test the value of Nf could be considered as equal to a , in which case the value of c is interpreted as the tensile ductility, f, measured in such a test. If, therefore, the Coffin equation is assumed to be applicable to a given material, it is a simple matter to predict the low-cycle fatigue behavior. Once the tensile ductility is known, this point is located at Nf = 1/4 on a log-log plot of vs Nf and a line is drawn through this point with a slope of to yield a prediction for the fatigue life. Actually, while this equation is quite useful it is not generally applicable, for experiment has shown that the value of —$ does not reflect the relationship between and Nf for all materials or even for a given material over all temperature ranges. An equation similar to the Coffin equation was prepared almost simultaneously by Manson.2 This expression had the form: In this case the exponent on Nf was not assigned any particular numerical value in accord with the various values of this exponent which had been observed for different materials and at different test conditions. Because of this characteristic it will be recognized that little use can be made of this expression in predicting low-cycle fatigue results. A fairly effective expression for use in predicting fatigue behavior was proposed by Manson3 based on a study of numerous sets of experimental results. This relation (Method of Universal Slopes) makes use of modulus of elasticity, ultimate strength, and tensile ductility, and assumes an exponent on Nf equal to 0.6 in representing the plastic strain range contribution to total strain range. While this equation of Man-Son does not yield completely accurate results it must be recognized as being the best means available at

Jan 1, 1970

By Martin T. Broome

INTRODUCTION The Luanshya Mine is situated in the southern part of the Zambian Copperbelt. The copper ore deposit is stratiform, and is preserved in a synclinorium known as the Roan/ Muliashi basin. Roan shaft (formally called No.14 shaft) is located at the eastern end of the syncline and is theoldest of the presently operating hoisting shafts, being sunk during the 1930's. It presently hoists some 45 per- cent of the total Luanshya Mine production. A cross-section through the shaft is shown in figure 1. The ore formation on the south limb is unmined on this section because until recently it was believed that such mining might cause damage to the shaft. This paper examines the influences of adjacent mining on this so-called 'shaft pillar', and describes the mechanics of subsidence of the pillar itself. GEOLOGY AND STRUCTURE Figure 1 shows the general form of folding in the vicinity of Roan shaft. The north and south limbs of the main syncline approach parallelism, with the bottom of the trough fairly smoothly rounded. The axis of the - trough plunges to the west-north-west at 6° - l0°. A brief summary of the major lithologies present in the Roan basin is given in table 1, however, the performance of the overall structure during progressive mining of the ore horizon is controlled by the following features in addition to the mining method. Intraformational Contacts These are characteristically weak in most geological environments. The BC/RL7 contact is an unconformity between moderately weak quartz-biotite schists below (unconfined compressive strength 40 - 80 MN/M 2), and strong quartzites above (U .C .S. 170-200 MN/M2) Subsequent formations are conformable, and planes of weakness are generally the result of contrasting lithology (see below). Weak Interbeds The Rt7, RL6, RL5, RL3 and RU2 horizons consist predominantly of quartzitic rocks, i.e. conglomerates, quartzites and argillites, and as such are generally strong and considered suitable for the positioning of development. Between these however, lie two much weaker dolomitic horizons, the RL4 and RU1. The Rt4 is the main hangingwall aquifer, and must be drained prior to mining. Drainage results in an extremely weak, blocky cavernous horizon which usually requires support if exposed by development. Similarly, the RU1 formation is comprised mainly of dolomites and dolomitic arqillites which are weak and cavernous. In the eastern part of the Roan/

Jan 1, 1981

The Ashanti mine is located in the Gold Coast region of West Africa in Ghana, where gold is found over a wide area of about 105,000 sq km (40,000 sq miles). Ashanti has been the most productive of all the lode mines and has been one of the world's notable gold producers for over 50 years. The mine is located at Obuasi, 113 km (70 miles) north and east of Tarkwa, which is 80 km (50 miles) inland from the coast. The Ashanti lode is worked on 300 m (1,000 ft) of strike length over a width of 12 m (40 ft), and by 1934 it had attained a depth of 700 m (2, 300 ft). The lode is in pre-Cambrian granite intruding a system- of shists, phyllites, etc., containing fragments of the wall rock with quartz, carbonates, sericite and small amounts of pyrite, arsenopyrite, sphalerite, galena, and gold. The shattered quartz fractures carry sulfides and gold, most of which are invisible. (William Harvey Emmons, "Gold Deposits of the World," McGraw -Hill, 1937.) Because the mill treats an ore composed of refractory sulfides - chiefly arsenopyrite and fine free gold - the flowsheet reflects the complex ore characteristics. Plane tables are used in the grinding, circuit for free gold recovery. After roasting the sulfide flotation concentrates, additional free gold is recovered from the calcines with a rotary belt concentrator and the two concentrates are combined for feed to the amalgamation pans, with the resulting gold amalgam being retorted. Following four-stage crushing to minus 9. 5 mm (318 in.) with two stages of grinding, the cyclone overflow is floated for sulfide recovery. The flotation concentrate is roasted with the calcine reground and roughly cyanided to scalp out the gold readily dissolved in one of two cyanidation circuits. The cyanide residue joins the thickened flotation tailing for cyanidation in a complete CCD circuit using filters. The gold precipitates are calcined before melting in pot-type furnaces. The tonnage to the mill of 3,175 mtpd (3,500 s tpd) with a content of over 14.7 g per mt (0.43 oz per st) places the Ashanti production as one of the top producers in the world; and with its past long life, the total production rates it as one of the world's great mines.

Jan 1, 1981

By Porter W. Shimer

As is well known, cast-iron borings are a mixture of small particles of iron with more or less of finely divided graphite, separated from thc surfaces of these small particles during the process of boring. The amount of graphite thus mechanically mixed is, in all cases, quite large enough to cause serious difficulty when the problem is to obtain an average sample of a given lot of borings for carbon determination. This difficulty arises from the necessity of obtaining a uniform mixture of the heavy and comparatively coarse borings with the finely divided and light graphite, and of removing a sample for analysis without disturbing the uniformity of this mixture. It was first sought to overcome this difficulty by having the horings made very fine, so that they might have more nearly the size of the particles of graphite. It was not practicable, however, to secure this uniformity of size, since much of the graphite is in the form of the finest dust. At all events, the duplicate determinations of rarbon in these fine borings, made with every precaution by combustion in oxygen, frequently showed differences too large to be accounted for in arty other way than by imperfect sampling. Very coarse borings were also tried with the idea that the graphite separated from these large and heavy pieces would perhaps be inappreciable ; but it was found that quite enough was separated to vitiate the results. Various methods of mixing were tried, both in the bottle and on glazed paper ; but in all these mixtures it mas found that duplicate samples seldom colitained the same proportion of the mechanically mixed graphite; and when they did, there could be no certainty that it was the true proportion. All this was shown many times over by the failure of duplicates to agree closely, the differencheing sometimes so much as 0.20 per cent. It was finally clear that nothing was to be hoped from these methods. Even if we could secure a perfect mixture containing in every part its due proportion of graphite, it would run a great risk of being destroyed the moment a spatula was inserted to remove a sample: for the least agitation causes some of the graphite to fall through between the coarser borings.

Jan 1, 1886

By W. Rostoker

A STUDY of the titanium-oxygen system' involved an associated series of measurements of the lattice parameters of the a and TiO phases. The results permit some interesting deductions which are herein reported. A comprehensive survey of the physical PI-operties of the phases in this alloy system has been made by Ehrlich.2 However, only impure titanium was available at that time, so that some revision of his measurements is to be expected. The lattice parameters were calculated from the high angle lines of Debye-Scherrer patterns taken in a 14 cm camera and using filtered CuKa radiation. The specimens were prepared largely by crushing and screening of lump samples which had been quenched from elevated temperatures. Only in the case of low oxygen contents was it necessary to resort to filing and annealing. The results of the lattice parameter studies are graphically presented in Figs. 1 and 2. It will be seen that oxygen produces a pronounced distortion of the c parameter of the a phase (hexagonal close-packed). The trend is in general agreement with Ehrlich's work, although the divergence of actual parameter values strongly suggests that his titanium was very impure. It will be noted that the a phase of titanium can tolerate the unusually high saturation solubility of about 34 atomic pct 0. By virtue of this unique effect, it is possible to make a calculation of the effective atomic diameter of oxygen when dissolved in a lattice with metallic bonding. This has not been possible before. Ehrlich's2 density measurements demonstrated that oxygen occupies interstitial positions in the a lattice and the trend of the lattice parameters would certainly support this. In a hexagonal close-packed unit cell the largest interstitial positions lie at (2/3, 1/3, 1/4) and (2/3, 1/3, 3/4). Accordingly, if both of these positions were occupied, the ratio of titanium to oxygen would be 1:1. The extrapolated c parameter may be taken as between 4.93 and 4.99?. The a parameter appears to reach a constant value of 2.955? at low oxygen contents. The distance of the center of a titanium atom site from the [vc2/16+a2/3-1.448] Then the atomic diameter of the oxygen atom is represented by the function: where the radius of the titanium atom is 1.448A,

Jan 1, 1953

By Lester Guttman

THE connection between short-range order and thermodynamic activities in binary solid solutions has been pointed out by Birchenall1 who calculated approximate values of the energy of interaction of Zn and Cu and of the degree of short-range order in alpha-brass at one composition and two temperatures. The purpose of this note is to call attention to a somewhat more accurate theory than that used by Birchenall and to extend the calculations to a wider range of temperatures and compositions as a means of testing its applicability. This is an example of the well-known general method of comparing measured thermo-dynamic functions of a system with those calculated from a microscopic model by means of statistical mechanics. In this case, mathematical approximations must be used which make difficult any decision about the validity of the model. Birchenall's statistical method resembles closely that called by Fowler and Guggenheim2 the "quasi-chemical" method which has been shown to lead in certain cases to results identical with those obtained by the method of Bethe.3 The quasi-chemical method has been extended by Takagi4 to give general formulae for the free energy of binary solid solutions based on several lattices at all compositions and temperatures. Specifically, he treats the four systems typified by: I. ß-brass; 2. a- brass; 3. AuCu3; 4. AuCu. When the temperature is so high that no long-range order exists, these formulae reduce to the same form for all lattice types, namely: [ ] Here the symbols have the following meanings: [F-Helmholtz free energy E-energy S-entropy k-the gas constant per molecule z-coordination number, (e.g. 12 in. a-brass). N-total number of atoms c-atomic fraction of A] VAA, VBB, VAB-energy per bond of the corresponding bonds log means log, throughout The superscript 0 denotes the thermo- dynamic function in the standard state, which has been chosen to be pure A or B with the same crystal structure as the solid solution. The quantity x is the ratio of the number of A-A bonds to the total number and for minimum F satisfies the equilibrium condition [ ] The free energy may also be written in terms of µA and µB, the chemical potentials or partial free energies per atom:

Jan 1, 1948

By J. J. Frawley, W. J. Childs

PREVIOUS studies have shown that if a supercooled liquid metal was perturbed by vibration the probability of nucleation is is During a recent investi- gation to determine quantitatively the amount of energy needed to cause nucleation in a given supercooled liquid specimen, it was found that at low-energy values in the megacycle range, below the threshold energy value for cavitation, the amount of dynamic supercooling was greater than the amount of static supercooling. That is, if a specimen had a given amount of thermal supercooling under static conditions, its thermal supercooling could be increased by the addition of low-energy sound waves. The material used in this investigation was high-purity bismuth. This material was chosen because of its low melting point and the high degree of supercooling which could be easily obtained. The sound gener- ator employed in this work was a commercially built Sperry ultrasonic testing unit. This unit was equipped with a barium titanate crystal as a piezoelectric transducer. These sound waves were transmitted to the supercooled melt by a Pyrex rod, as shown in Fig. 1. The transducer was coupled to this Pyrex rod wave carrier by motor oil. The Pyrex wave carrier was approximately 1.5 ft long to prevent damage to the transducer by heat. The diameter of the Pyrex wave carrier appears to be critical. In the initial tests a wave carrier of 0.5 in. in diam was employed. However, the sound waves had no effect on the amount of dynamic supercooling. When the diameter of the wave carrier was increased to approximately the inside diameter of the Pyrex crucible, the sound waves were more effective. Approximately 200 g of metal was melted under a stannous chloride flux in a 30-ml beaker by induction heating. The temperature was recorded by a Pyrex-encapsulated chromel-alumel thermocoule which was placed in the beaker after the bismuth melted. The Pyrex wave carrier was immersed slightly below the surface of the liquid bismuth and the specimen was reheated to about 500°C. It was observed that the amount of supercooling depends on the amount of superheating the specimen receives; therefore, for meaningful results the amount of superheating was the same for all heating cycles. The specimen was allowed to cool in air and the change in temperature was continuously monitored with a potentiometric strip-chart recorder.

Jan 1, 1969

By A. Andreas

New Mexico, after several years as the sixth ranking oil-producing state, was surpassed by Illinois and for 1939 ranks seventh in the United States. Oil production for 1939 was 36,746,840 bbl. Production for 1938 was 35,510,176 bbl., a gain of 0.033 per cent. Production for the year would have been greater had there been a pipe-line outlet for the Vacuum field. The complete shutdown during the latter part of August covering a period of 15 days meant a production loss of over 1,500,000 bbl. of oil. Daily production allowable as set by the Oil Conservation Commission has followed very closely the recommendations of the Bureau of Mines. It has been found that the recommended allowables as quoted by the Bureau of Mines do not always reflect the actual demand, as there is a considerable lag hetween the recommended amounts and the current demands. During the year the various operating companies have done considerable remedial work in setting packers to reduce the gas-oil ratios in the various fields. Six new fields were discovered in New Mexico during 1939; three in Lea County, two in Eddy County and one in Chaves County. In the early part of 1939 a committee composed of the various engineers and geologists recommended subdividing the old Artesia area into various producing pools. This division was accepted, therefore the total number of producing fields in New Mexico is considerably greater than the number of fields in 1938, but does not represent new fields discovered during the year. The southeastern area continues to he the largest producer of oil. During the year 2,716,551 bbl. were produced in Eddy County and 33,690,996 bbl. in Lea County. Total production ill the northwestern part of the state, which includes San ,Juan and McKinley Counties, was 338,293 bbl. At the beginning of the year the daily average nonmarginal well allowable for Lea County was 48 bbl. At the close of the year it was 49 bbl. The daily average production for the year was 97,313 bbl. During the year, 659 wells were drilled in the state, of which 565 were producing oil wells, 15 gas wells, 6 carbon dioxide gas wells and 73 dry holes. Summarized at meeting; manuscript received at the office of the Institute March 18, 1940. * State Geologist, member of New Mexico Oil Conservation Commission, Santa Fe, New Mexico.

Jan 1, 1940

By A. Andreas

New Mexico, after several years as the sixth ranking oil-producing state, was surpassed by Illinois and for 1939 ranks seventh in the United States. Oil production for 1939 was 36,746,840 bbl. Production for 1938 was 35,510,176 bbl., a gain of 0.033 per cent. Production for the year would have been greater had there been a pipe-line outlet for the Vacuum field. The complete shutdown during the latter part of August covering a period of 15 days meant a production loss of over 1,500,000 bbl. of oil. Daily production allowable as set by the Oil Conservation Commission has followed very closely the recommendations of the Bureau of Mines. It has been found that the recommended allowables as quoted by the Bureau of Mines do not always reflect the actual demand, as there is a considerable lag hetween the recommended amounts and the current demands. During the year the various operating companies have done considerable remedial work in setting packers to reduce the gas-oil ratios in the various fields. Six new fields were discovered in New Mexico during 1939; three in Lea County, two in Eddy County and one in Chaves County. In the early part of 1939 a committee composed of the various engineers and geologists recommended subdividing the old Artesia area into various producing pools. This division was accepted, therefore the total number of producing fields in New Mexico is considerably greater than the number of fields in 1938, but does not represent new fields discovered during the year. The southeastern area continues to he the largest producer of oil. During the year 2,716,551 bbl. were produced in Eddy County and 33,690,996 bbl. in Lea County. Total production ill the northwestern part of the state, which includes San ,Juan and McKinley Counties, was 338,293 bbl. At the beginning of the year the daily average nonmarginal well allowable for Lea County was 48 bbl. At the close of the year it was 49 bbl. The daily average production for the year was 97,313 bbl. During the year, 659 wells were drilled in the state, of which 565 were producing oil wells, 15 gas wells, 6 carbon dioxide gas wells and 73 dry holes. Summarized at meeting; manuscript received at the office of the Institute March 18, 1940. * State Geologist, member of New Mexico Oil Conservation Commission, Santa Fe, New Mexico.

Jan 1, 1940

Discussion of the paper of E. C. HARDER, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin No. 94, October, 1914, pp. 2573 to 2586. I. C. WHITE, Morgantown, W. Va.-I have seen some of the great iron-ore deposits described in this paper. -One of these in the State of Minas Geraes appears to be an immense mountain of iron ore about 2,000 ft. in height. All over its surface from bottom to top may be seen large masses of rich iron ore, varying in weight from a few pounds to several tons, and from all that one can judge without exploitation, the quantity of available ore is certainly very large in this particular mountain. Whether it will prove a mere surface deposit or shell, like the famous Iron Mountain of Missouri, is for future exploration to determine. The question of transportation is the main factor in determining the availability for exportation of these Brazilian iron ores. There is no coal in Brazil that can be manufactured into coke without expensive previous treatment, since the best of the raw coal in the States of Rio Grande do Sul, Santa Catharina, and Parana, contains about 35 per cent. of ash, of which about 6 per cent. is sulphur, and coal of this composition cannot be utilized in iron smelting without purification. When I was chief of the Brazilian Coal Commission in 1904 to 1906, I had a cargo of this coal shipped to Balk, Germany, and treated in the great coal-testing plant of the Humboldt Engineering Works, located just across the Rhine from Cologne. It was found that by crushing and washing the Brazilian coal, it yielded 33 per cent. of briquetting coal, containing only 10 to 12 per cent. of ash (of which 1 per cent. was sulphur), and 42 per cent. of slack coal, with 25 per cent. of ash and low in sulphur, so that about 33 per cent. of the Brazilian coal could be converted into coke of fair quality, as shown by the following average of three analyses, using air-dried coal, of briquets made from the Barro Branco coal bed, State of Santa Catharina: Moisture 1.56 Volatile matter 31.66 Fixed carbon 56.73 Ash : 10.05 Total 100.00 Sulphur 1.34 Phosphorus 0.003 B.t.u 13,395

Jan 4, 1915