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By Y. Miron

Previous studies at the Bureau of Mines outlined the hazards of ammonium nitrate-fuel oil (AN-FO) mixtures in the presence of pyrite-bearing ores. The recent trend in the mining industry to strengthen AN-FO by the addition of aluminum metal raised the question regarding the effect of aluminum in AN-FO in the presence of pyrite-bearing ore. Laboratory work, similar to that done previously, demonstrated that the temperature of a self-sustaining reaction in the presence of AN-FO ore-aluminum is not lower than that for a comparable AN-FO-ore mixture. However, as might be expected from known thermochemical data, once initiated, the resulting reactions between AN-FO, aluminum, and pyrite are much more vigorous than those observed for AN-FO and pyrites alone. The temperature required to produce a self-sustained reaction for the combinations tested in this study is 250°±20° F while in the previous Bureau study, reactions were noted, in some instances, at 150° F. The different pyritic ores may be the cause of this variation.

Jan 1, 1976

By D. P. Schlick

The German experience in dealing with the health hazard of respirable dust in underground mines is reported from first-hand observation in this Bureau of Mines paper. The report covers-- 1. The control of dust by water infusion, water spraying, and ventilation. 2. The sampling devices (tyndalloscope , konimeter , and BAT-I) and methods used to determine the dust concentrations in mines. 3. The systems of classifying hazardous and safe dust levels in mines. 4. The research facilities devoted to theoretical and applied work on mine dust and pneumoconiotic disease. Tile major research projects on dust and disease now underway in West Germany are outlined in an appendix.

Jan 1, 1970

By S. R. Zimmerley

[In the course of a flotation investi~ntion, a siliceous gold ore was ground ir, R 'ball mill to ~inils 300-mesh. It mas found that the small mount of zlus 300-~esh mnterial had a go12 assw approximately twice that of the oricinal ors, md thst this oversize ~roduct also contained much abra?.ed iron. >!oreover, the gold assay of the abraded iron, which was separated ma~etic-dl:;, wno ei::ht tiaes tkat of the ore. These facts sug,~estsd th~t sone r3laticnshin existed between the abnormally high .gold content and the preseace of abrade4 iron. It was ciecided, therefore, to investl~ate furtkor ths acsoclation of the ;old nith the iron abraded from the balls durir-g grincing. As a nrelininary ex?rr>hent, a samy?le of siliceous gold ore 786 grolznd for 1-1/2 hours i;l 3 ball mill and the nuln was divided into two products electri~mag-etically. The racult s follow: ]

Jan 1, 1937

By W. H. Coghill, F. D. DeVaney

"Introduction Numerous investigators have studied grinding. Each has contributed his bit to a literature that is difficult to correlate. Too many of the results have been transformed into curves with no many ""inflection points"" and ""counterflexures"" that they obscure the issue.Some of the investigators have neglected the very essence of the problem, namely, the power and the amount of material to which a known amount of work was applied. The purpose of this paper is to show the ease with which results can be interpreted when these quantities are duly recognized. Some grinding tests will be given for illustration.Grinding studies are of two kinds: (1) Study of the character of the ore and (2) study of the performance of the machines. Several ores may be crushed by a given machine, or several machines may be used on a given ore. The illustrations given in this report cover both objectives.Grindability Characteristics When the ores are being studied the information sought is grindability characteristics (grain-size distribution) and the grindability (work required to produce new surface) of a group of ores.When the study is of the machines, several machines are used for a given ore or given types of ores, and the grinding performances of the machines are compared by a grain-size study.Table 1 gives the grindability characteristics and grindability of six substances, one of which is coal. The substances are arranged from left to right in progressing order of tons per horsepower-hour. Curves and graphs are not needed for elucidation. The secret of the ease of interpretation is the order mentioned and the similarity of the sizing analyses. Power records must be complete in grinding studies.The grinding device was a ball, plunger, and mortar called the drop weight.' It may be used to advantage when the amount of material to be tested is too small for the orthodox machines.The upper part of table 1 shows the grindability characteristics by the cumulative-sizing analyses. Note how closely the percentage weights agree for a given sieve size. The lower part shows the grindability in terms defined elsewhere. The present paper should be read in conjunction with that paper."

Jun 1, 1934

By John M. Gomes

Two molten salt systems were evaluated as electrolytes for the repetitive recovery of tungsten from tungsten oxide (W03) made by calcining commercial-grade ammonium paratungstate. Using a sodium chloride-sodium fluoride-potassium aluminum tetrafluoride electrolyte at 800° C, 1 pound of 99.8 percent tungsten was recovered for each 2.7 kilowatt-hours of energy consumed. The metal contained 1,100 ppm carbon, was in dendritic masses of spherical grains, and had an apparent bulk density of 5.41 g/cm3. T ngsten of 99.9 percent purity was won from a sodium pyrophosphate-sodium tetraborate-sodium chloride electrolyte at 1,000° C; 6.0 kilowatt-hours of energy was consumed for each pound of metal recovered. The metal contained 120 ppm carbon, was in dendritic masses of hexagonal acicular crystals, and had an apparent bulk density of 7.25 g/cm . Each metallic impurity--aluminum, calcium, copper, iron, nickel, and silicon--in the two tungsten products was 16 ppm or less.

Jan 1, 1966

By R. M. Santmyers

Of the sand and miscellaneous silica produced in the United States , ordinary sand and gravel are , of course , the most important, at least as regards volume of output . The building- construction industry absorbs approximately 75 per cent of the total value of all quartz and silica , as shown in Table 2 of Quartz and Silica, Part I, under "General summary . " Because of their unusual physical properties tripoli and diatomite find extremely wide uses in industry, and as the commercial deposits of these ninerals , especially tripoli , are scattered, large quantities enter into interstate commerce . Whereas ordinary sand and gravel are bulky commodities , these specialties have a fairly high unit value and hence can be transported relatively long distances .

Aug 1, 1931

By N. S. Dalal, Xianglin Shi

"Electron spin resonance (ESR) measurements provide direct evidence for the involvement of Cr(V) in the reduction of Cr(VI)· by NAD(P)H. Addition of hydrogen peroxide (H2 O 2) to NAD(P)H-Cr(VI) reaction mixtures suppresses the Cr(V) signal and generates hydroxyl (·OH) radicals (as detected via spin trapping), suggesting that Cr(V) reacts with H2O 2 to generate the ·OH radicals. Reaction between H2O 2 and a Cr(V)·glutathione complex, and between H2O 2 and several Cr(V)-carboxylato complexes also produces ·OH radicals. These results suggest that Cr(V) complexes catalyze the generation of ·OH radicals from H2O 2, and that ·OH radicals might play a significant role in the mechanism of Cr(VI) cytotoxicity. KEY WORDS: ESR. spin trapping, Cr(VI) reduction, Cr(V), hydrogen peroxide, free radicals.INTRODUCTIONThis communication reports an ESR spin trapping detection of hydroxyl ( OH) radicals.in reactions between some Cr(V) complexes containing biologically important ligands and hydrogen peroxide (H2O 2 ). This work was undertaken because while the reduction of Cr(VI) to lower oxidation states has been suggested as a key step in the mechanism of Cr(VI) toxicity, the reaction· mechanism is not yet clear. 1 Mutagencity has been well documented for Cr(VI) via various bacterial assays, while Cr(III) has been shown not to be mutagenic.2 • 3 Since it has been reported that compounds containing Cr(VI) do not react with isolated DNA,4 the reduction of Cr(VI) by other cellular constituents has been thought to be important in the mechanism of Cr(VI) induced DNA alteration.1·4 • 5 For cellular systems earlier studies include those on the reduction of C~(VI) by microsomes,6-8 rat liver DT-diaphorase,9 and aldehyde oxidase. 10 Regarding the reduction mechanism, Jennette used ESR spectroscopy to show that a long-lived Cr(V) complex is formed as an intermediate in the microsomal reduction of Cr(VI) in the presence of NADPH.8 She postulated that Cr(V) is the ""ultimate"" carcinogenic form of chromium compounds. This conclusion has led to many further investigations of the formation of Cr(V) in the reduction of Cr(VI) under biologically relevant conditions.11 - 19 More recently, however, it has been suggested that oxygen-derived radicals generated during the Cr(VI) reduction are the species responsible for the DNA alteration.20.2• To the best of our knowledge, however, no information is available on the generation of such radicals in the reduction of Cr(VI) under biologically relevant conditions, except some preliminary results on the glutathionyl (GS·) radical formation in the reduction of Cr(VI) by glutathione (GSH). 11 - 19 We, therefore, undertook a systematic investigation of the reaction of Cr(VI) with NAD(P)H, GSH, ix-hydroxycarboxylic acids, and H2O 2 • NADPH was chosen as a model reductant because of its ubiquitous existence inside the cells, its critical role in the enzymatic Cr(VI) reduction,1·6-9 its representation of important cellular Cr(VI) reductants, and its ability to reduce other metal ions.22 GSH was chosen as another model Cr(VI) reductant because GSH also exists inside cells, it represents another important category of cellular Cr(VI) reductants, the thiols, and it also plays an important role in the Cr(VI) toxicity .1• 1 ""- 19.i3.i4 For further clarification, we also studied the reaction of Cr(VI) with several '1'.-hydroxycarboxylic acids in the presence of H2O 2 since these acids are definitively known to reduce Cr(VJ) to form stable, isolable Cr(V).25 .2 6 The results obtained indicate that Cr(V) complexes, produced in the reduction of Cr(VJ) by cellular reductants, react with H2 O 2 to generate ·OH radicals, which might be the initiators of primary events in Cr(VI) carcinogenicity."

Jan 1, 1990

By E. G. Davis

The Bureau of Mines made laboratory-scale experiments to examine the technical possibilities of reclaiming manganese from slags produced by oxygen lancing of high-manganese pig iron. Ferromanganese was added to molten pig iron to yield a 4-to 5-percent manganese hot metal, which simulated a product obtainable from the blast furnace. This was injected with oxygen to reduce the metal to 1 percent or less manganese and form a slag containing about 40 percent manganese. The molten slag was water-quenched, treated with H2SO4) roasted at 660° C, and water-leached to give soluble manganese and iron sulfates. The sulfates were precipitated as hydroxides, converted to the oxide form, and smelted to produce a standard ferromanganese containing 74.6 percent Mn and 0.01 percent P. As an alternate method of manganese recovery, a manganese cell feed was prepared from the leach solutions and electrolytic manganese was produced. Direct smelting of the high-manganese slag resulted in 74.2 ferromanganese meeting ASTM specifications except for phosphorus content. The high phosphorus content of the metal and high slag-to-metal ratio obtained made this approach unattractive.

Jan 1, 1966

By James A. Browning

Conventional flame channelling operates continuously at over 120 db --flame-drill channelling at a maximum of 95 db. The latter process was developed under this program. Individual drill holes are spaced to leave narrow rock webs. Sound and dust passing from the hole are effectively treated by a muffler and water injection.

Jan 1, 1980

By Robert C. Ellman

Stockpiles containing 2.3 million tons of lignite constructed in the period 1948-56 in conjunction with the construction of Garrison Dam on the Missouri River demonstrate successful stable long-term storage of lignite. Uniform and thorough compaction of each of the I-foot-thick layers by which the piles were constructed produced a bulk density of 70 Ib/cu ft. Air penetration into the stockpiles was restricted to a degree that prevents spontaneous heating or deterioration of the stored lignite, A continuing record of observations beginning with stockpiling operations in 1948 has been accumulated, This includes periodic fuel analysis, analysis of pile gases, and measurement of pile temperatures on the first large stock-pile, pile 5. This report describes the stockpiling method, the changes in heating value, pile gas composition, and pile temperature and summarizes observations from 1953 to 1964, Data accumulated attest to the stability of the stored lignite. The variation of the average heating value of periodic pile-depth samples is only 160 Btu/lb (11,990 to 11,830) on the moisture" and ash-free (maf) basis during almost 10 years of storage. Temperature levels of the pile interior are progressively decreasing. At pile surface, cyclic variations occur with the season. The only problem encountered with the large stockpiles is wind and water erosion of the pile surface. The partially successful control measures used are described.

Jan 1, 1967

By G. R. Strimbeck

The Federal Bureau of Mines has been developing processes for producing synthesis gas directly from coal, oxygen, and superheated steam. An atmospheric-pressure pilot plant was constructed and operated to: 1. Determine the operability of the plant for gasifying coals of different ranks under various operating conditions. Listed in decreasing order of rank, these coals included a Pennsylvania anthracite, a bituminous A coal from the Sewickley bed, West Virginia, and a subbituminous C coal mined in the Lake de Smet region of Wyoming. 2. Determine the effect of varying operating conditions on: (a) Standard cubic feet (std.c.f.) of oxygen and pounds of coal of different rank required to make M std.c.f. of product gas (carbon monoxide plus hydrogen); (b) carbon gasified, percent; (c) exit-gas temperature, degrees F.; and (d) heat loss, B.t.u. per pound coal. 3. Compare the gasification characteristics, indicated in item 2, of coals of different rank: Bituminous A, anthracite, and subbiturninous C. 4. Determine the concentration of dust in the gases produced and the efficiency of dust removal, and investigate the relation between the sulfur content in the coals gasified and the gases produced.

Jan 1, 1960

By Robert Lee Stahl

Comprehensive field tests were made by the Federal Bureau of Hines at the Conda open pit mine near Soda Springs, Idaho, to determine whether surface geophysical techniques could be used to detect and delineate faults in phosphate deposits. The tests included seismic refraction, magnetometry, electrical resistivity, and airborne photography. Of the several geophysical techniques tested in the field, horizontal resistivity profiling was the most effective method for diagnosing faults. The method is quick, inexpensive, accurate, and can be easily used by mining company personnel to detect and delineate faults.

Jan 1, 1975

By C. M. Romanowitz

This report deals with the factors which should be considered in evaluating a placer deposit and selecting a dredging system for mineral recovery. Overall dredging feasibility and the design of dredging systems are reviewed. Excavation methods, each with its advantages and disadvantages, are compared. Direct operating costs, both original and updated, of gold dredges with bucket capacities of 6 to 18 cubic feet are included. Costs vary with digging depth, changes in environmental conditions, and physical characteristics of the placer, all of which affect excavation rate and recovery. The costs, updated with appropriate indexes, should be used only as guidelines to evaluate potential dredging projects with similar characteristics. The relation of direct dredging costs to annual production is graphically illustrated by a family of curved envelopes that span dredge sizes from 2-112 to 18 cubic feet. A curve fitted to the data expresses the relation of direct costs to annual production for 151 dredge-years.

Jan 1, 1970

By Wilbert J. Huff

The Explosives Division of the United States Bureau of Mines makes certain laboratory and field investigations that deal with explosions, explosives, ignition, and combustion, together with many related problems, such as the cause and prevention of fires, and certain fundamental scientific questions bearing upon the determination of the chemical and physical mechanisms underlying some of the important phenomena encountered. Its work on explosives has been particularly directed toward determination of the chemical and physical characteristics of explosives designed for use in coal mines and in a more limited way to those used in metal mines, tunnels, quarries, and other engineering operations. This testing is handled by two units of the Explosives Division, as follows:

Jan 1, 1937

By Robert Bottge

When a company develops a mineral property in a remote area of Alaska, it must consider how best to house its personnel. This Bureau of Mines report examines the economics of two options: company towns and company camps. The price required to maintain a 15% discounted-cash-flow rate of return (DCFROR) was derived for hypothetical 1,000-st/d cut-and-fill mines and 50,000-st/d open-pit mines located in three different regions of the State, One set of hypothetical mines utilizes a townsite; the other utilizes a relatively new concept, a fly-in camp or commuting operation, in which two shifts of employees operate the mine and all associated facilities for 1 week before being replaced by a second crew. The study shows that operating costs were higher for mines employing the commuting option than for mines having a company town because of the additional wages paid for overtime hours; however, the price required to obtain a 15% DCFROR for the single-product copper concentrate, f.0.b. the mill site, was significantly lower owing to the lower investment costs for the camp-type operation. The economic advantage for those mines utilizing the camp increases from south to north and from the coast toward the interior.

Jan 1, 1986

By Cleo G. Rall

The value of brine analyses in the study of petroleum-engineering problems was recognized early in the history of petroleum. The Bureau of Mines before 1928 had indicated in several reports.3/ ways in which analyses might be used. Because of the confusion resulting from attempts to correlate the work of different chemists using greatly varying methods of analysis and systems of computation and expression of results, a paper presenting the methods used by the Bureau of Mines was prepared and published in 1928. This system of determining the characteristic constituents of oil-field waters and of calculating and reporting results has been widely adopted by the petroleum industry. The earliest and most obvious use of water analyses is determination of the source of water infiltrating into petroleum and natural-gas wells. For this purpose it is necessary that an analysis of the connate water of the formation from which the oil is produced be available and that an analysis of the contaminated water be made. By comparing these analyses with those of connate waters from formations higher in the structure, the formation from which the infiltrating water comes may be identified.

Jan 1, 1953

By R. E. Peterson

Scrap iron is partially oxidized at elevated temperatures in the selective oxidation process to produce iron oxide and a dense residual metal of high purity. Investigation of the process was confined to converting automobile hulks into useful products. In one test series, compressed, sheared automobile scrap was processed at 1,000° C in a 36-foot-long rotary kiln at feed rates ranging from 300 to 1,200 lb/hr. Less fuel was required to maintain the temperature at the higher feed rates because of the heat generated from the burning of the combustibles and the oxidation of the iron. The bulk density of the residual metal exceeded 75 pounds per cubic foot. In an attempt to lower the quantity of contaminants in the residual metal, another test was designed using automobile hulks which had been prepared by ripping, a low-cost method of scrap fragmentation. Before oxidizing the ripped scrap approximately 62 percent of the total copper was removed in a tumbling, screening, magnetic separation and hand-sorting system. Cast iron made from the residual metal obtained by selective oxidation contained 0.15 percent copper; iron oxide scale obtained from the kiln averaged 0.13 percent copper. Pellets made from the scale demonstrated compressive strengths necessary for blast furnace reduction; lead and zinc were removed by volatilization when the induration was performed in a reducing atmosphere.

Jan 1, 1972

By R. W. Van Dolah, N. E. Hanna, F. C. Gibson

Measures that were taken to eliminate noise resulting from explosives work at the Bureau of Mines facility at Bruceton , Pa . , are described . A method for monitoring sound transmission characteristics of the atmosphere and control of the explosives testing is presented as a noise control measure that offered partial relief during the period in which the modifications were made . Design details of the replacement gallery , used for permissibility testing of explosives , and the modifications of four types of bombproofs are given . Operation of the closed facilities are completely satisfactory , and the noise problem has been entirely eliminated .

Jan 1, 1964

[1.1. The provisions of this code are minimum provisions and are designed to minimize hazards to life and property in and about underground coal mines where electrical equipment and circuits installed used. They indicate the Steps necessary in the selection, installation, operation, inspection, and maintenance of electrical equipment and circuits to obtain proper safeguards in reducing electric shock, fire, explosion and other hazards. Surface as well as underground installations were considered in formulating the code and, unless otherwise stated, each provision applies equal to both underground and surface installations. This code does not apply to buildings and installations not directly connected with mining operations, nor does apply to strip-mining operations.]

Jan 1, 1952

By G. R. Hopkins

Although many small refineries were dismantled in 1934 the total number of plants, including a few under construction, increased from 604 at the beginning of the year to a new high of 638 on January 1, 1935. The capacity also reached a new record, the total of 4,072,400 barrels of crude oil daily being about 45,000 barrels higher than the previous high of January 1, 1932. The number of refineries increased materially in 1933, following construction in east Texas and the building of many small plants in the Rocky Mountain district and elsewhere. Most of the new plants of 1933 were built to provide an outlet for crude or because the ratio between crude oil and gasoline prices appeared conducive to profits However, low gasoline prices and increased costs in 1934 dispelled the hopes for profits; many plants were shut down, and some were dismantled. The number of operating plants declined from 454 on January 1, 1934, to 435 on January 1, 1935, but the number of inactive plants increased from 137 to a new high of 196 during the same period. As indicated above, new construction was at a minimum in 1934, and on January 1, 1935, only 7 plants were being built.

Jan 1, 1935