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By K. Matsuura, M. Ohno, T. Tokunaga

"Recently, weight saving of automobiles has been strongly required to solve the global environmental problems. Mg alloys are one of the promising candidates as a new material for automobile components. However, the application of the Mg alloys is limited due to their poor corrosion resistance. In the authors’ preliminary study, an Al/Mg/Al clad sheet was fabricated by hot extrusion and subsequent hot forging. The clad sheet exhibited a high corrosion resistance and excellent super plasticity. More specifically, the elongation of the clad sheet was as high as 550%.Importantly, despite that the elongation of Al itself was only 40%without cladding with Mg, the ductility of Al was greatly improved in the form of the clad sheet. In the present study, in order to clarify the mechanism of the superplastic deformation of the Al part in the clad sheet, the microstructure evolution of the Al during the tensile de formation is investigated. The tensile tests were conducted at a temperature of 573 K and at a strain rateof1.0×10-3s-1. The Al exhibited fiber-type texture at the beginning of the tensile deformation, and brass-type texture after the elongation of 50%.INTRODUCTIONMg alloys have been gaining attention because of their excellent properties e.g. light weight, good recyclability and high electromagnetic shielding. However, their practical applications have been limited due to their poor corrosion resistance. In the authors’ previous study, in order to solve this problem, Al coating on Mg alloy by hot extrusion has been proposed, and the Al-coated Mg alloy plate was fabricated(Tokunaga, Matsuura, &Ohno,2012). The plate was hot-rolled and an Al/Mg/Al clad sheet was fabricated. No cracks or debondings were observed at the Al/Mg interface. The sheet exhibited a high corrosion resistance in a comparable level as pure Al. Also, the sheet exhibited a large and uniform elongation of 550%in a tensile test at a temperature of 573 K and at a strain rate of 1.0×10-3s-1without any breakings or debondings of the Al part(Tokunaga, Matsuura, &Ohno,2014).Mg alloys have been known to exhibit a superplastic characteristic when the grain size is small. However, it is known that the pure Al does not generally exhibit the super plasticity. As mentioned above, the Al-coated Mg alloy sheet exhibited 550% of elongation in the authors’ previous study (Tokunagaet al., 2014). However, the pure Al itself showed only 40% of elongation, while the Mg alloy itself exhibited 800% of elongation. Thus, it has been demonstrated that the pure Al was super plastically elongated when it was bonded with the Mg alloy. Generally, deformation mechanism of the super plasticity of the Mg alloy is known as a grain boundary sliding. On the other hand, the mechanism of the superplastic elongation of the pure Al is still unclear. The purpose of the present study is investigation of the deformation behavior of the Al part in the Al/Mg/Al clad sheet during tensile de formation."

Jan 1, 2018

By Zhou Yanwen, Fudong Wang, Shing Liu

Mixed CrB2 and MoS2 powder (Cr:Mo=1:1 atomic %), without any further process, were used as the targets to be sputtered and deposited onto stainless steel and silicon substrates by pulsed DC power supply. The structures and properties of the CrBMoS films were then analyzed by using SEM, XRD, micro-hardness tester. The SEM morphology of the films showed dense, defect free structure, and the preferred orientations of the films were CrB2 (111) and MoS2 (200) according to XRD spectra. The thicknesses of the films were measured and the relationship between the deposition rates and pulsed factors was determined. The films, with the micro-hardness as high as 19GPa and friction coefficient as low as 0.02, could be considered to be the hard solid lubricant films.

Jan 1, 2015

By T. P. Johnson, A. Vathavooran

"Conventional mining operations can produce a wide range of wastes containing gold and other precious metals but which are less suitable for processing by traditional methods. There are also types of ore that do not fit easily into a traditional processing flowsheet, e.g. because the refractory nature of their minerology or the combination of valuable metals is less suitable for traditional processes. Nevertheless, these potential sources of valuable metals remain unexploited resources that have attracted growing interest in the metals and mining industries over recent years. The challenge is therefore to develop and use alternative processing methods that have the flexibility of operation to cope with a wide variety of material types and tonnages, whilst providing high recoveries for valuable metals. Tetronics’ DC plasma smelting technology achieves industry-leading recovery rates for precious metals from a wide range of input materials and initial precious metal concentrations, whilst generating an inert slag-based material as a by-product (even when starting from a hazardous waste input material), approved within the EU for use in construction applications. This paper describes how this technology can be used as a key part of an overall process for the recovery of precious metals from these interesting materials.INTRODUCTION The extraction of gold from its ores by various forms of cyanide leaching has been practised by the mining industry for over a century (Minerals Council of Australia, 2005) and it remains the primary extraction method in a wide range of mining operations. The ability of cyanide to extract gold efficiently and quickly from lower grade ores without extensive additional processing, coupled with well-known methods to recycle the cyanide for re-use within the process mean it is often both the most economically preferable and environmentally acceptable method for recovering gold. As a result, 88% of all gold produced from mines in the USA in 2014 was recovered via leaching of open heaps or dumps (UGGS, 2016). Nevertheless, there are occasions where certain combinations of mineralogy and other circumstances reduce the effectiveness of cyanidation techniques, so that ever more elaborate additional processing steps are required, with inevitable increases in operating costs (Swash, 1988). In these circumstances, which are likely to be more common in future as ore qualities diminish, other methods of extraction may offer better alternatives. Whilst much less commonly used for Au extraction at present, pyrometallurgical methods are amongst the longest-established of these alternative approaches and merit serious consideration in such cases."

Jan 1, 2017

By N. Afrin

The microstructure and tensile properties of AZ31B-H24 magnesium (Mg) alloy after friction stir welding (FSW) were evaluated. The grain size was observed to increase from approximately 5 µm to about 9 µm after FSW. The obtained Hall-Petch type relationship showed a strong grain size dependence of the hardness values. While the FSW led to about half of the yield strength of the base magnesium alloy, the ultimate tensile strength after FSW could reach about two thirds of that of the base alloy. The hardening capacity of the FSWed samples was about twice of that of the base alloy. The strain hardening exponent of the base alloy was found to be about 0.1 whereas it became larger than 0.3 for the FSWed samples. After yielding the base alloy showed a high initial and almost constant work hardening rate, corresponding to linear hardening stage II, followed by stage III with a decreasing hardening rate. Stage II linear hardening was observed to be absent in the FSWed samples.

Jan 1, 2007

By Peter A. Witt

Highland Valley Copper is a conventional truck-shovel mining and flotation concentrator operation located some 75 kilometres southwest of Kamloops, B.C. (Figure 1). The ore is within a porphyry deposit and is mined at a rate of 135,000 metric tonnes per day from two separate open pits. The nearby mill produces concentrates containing 375 million pounds of copper and 5 million pounds of molybdenum metal yearly. Head grades are roughly 0.40% Cu at a 0.23% Cu equivalent cut-off. The strip ratio currently sits at 0.55:1 with waste quantities made up of separate rock and unconsolidated overburden units. From the mill, concentrates are trucked to nearby Ashcroft and then hauled by rail to ocean port facilities in Vancouver. The mine employs 950 persons and is planned to operate until 2009. The operation is a partnership between three owners: TeckCominco (61.4%), BHP Billiton (33.6%), and Highmont Mining (5%). Management is shared by the two principal owners and directed by an appointed committee.

May 1, 2002

By Peter A. Witt

Highland Valley Copper is a conventional truck-shovel mining and flotation concentrator operation located some 75 kilometres southwest of Kamloops, B.C. (Figure 1). The ore is located within a porphyry copper deposit and is mined at a rate of 135,000 metric tonnes per day from two separate open pits. The nearby mill produces concentrates containing 375 million pounds of copper and 5 million pounds of molybdenum metal yearly. In the Valley pit, head grades are roughly 0.40% Cu at a 0.23% Cu equivalent cut-off. The Valley pit strip ratio currently sits at 0.55:1 with waste quantities made up of separate rock and unconsolidated overburden units. From the mill, concentrates are trucked to nearby Ashcroft and then hauled by rail to ocean port facilities in Vancouver. The mine employs 950 persons and is planned to operate until 2009. The operation is a partnership between TeckCominco with a 63.9% interest, BHP Billiton holding 33.6%, and others 2.5%. Management is shared by the two principal owners and directed by a management committee.

May 1, 2003

By L. Chunpongtong

ABSTRACT Oil sands production occurs on a massive scale, making orebody estimation a challenge. In rainy conditions, operators can have difficulty accessing ore at the mapped location. Without enough inventory as a buffer, the high-cost stockpile is depleted quickly, necessitating the removal of significant amounts of overburden and interburden to meet plant feed requirements. The inventory curve—a plot of ore inventory on a period-by-period basis—plays an important role in selecting an appropriate scheduling scenario. This paper presents a programmable method for creating an inventory definition by using a pit optimization tool.

Jan 1, 2014

By G. W. Neumann

"In order to avoid pollution of water in Flemming Brook and Little River, which drain the area in which the Brunswick No. 12 Mine and Concentrator are located, the company has gone to considerable expense in preparing tailings storage and effluent setting ponds. The attached drawing gives a plan of the six settling ponds together with elevations of the dikes and the effluent weirs.All original dikes for the six ponds were constructed from humus-free clay and rock material, which was obtained, preferentially, by excavating from within the dike area. Run-off water, precipitated on the outside slopes of the dams will drain off without contacting the tailing material. A ditch was made north of the dam site to deflect surface run-off to the east into a branch of Flemming Brook.A secondary dike, made from tailings, has recently been erected on No. 1 and No. 2 tailings pond inside and above the earth-filled dike which serves as a roadway. Run-off from the tailings dikes will be retained inside the ponds by ditching between the roadway and tailings dike into ponds 4 and 6."

Jan 1, 1969

By K. M. Mayhew, G. D. Barr, T. M. McCoy, C. T. Knilans

"Teck Resources Limited (“Teck”) has developed and extensively tested on a continuous basis the CESL Technology hydrometallurgical process for treating copper and nickel sulphide concentrates, including bulk copper-nickel concentrates. Copper, nickel and cobalt are leached efficiently into solution, utilizing CESL process conditions. Total precious metals including gold, silver, platinum and palladium are recovered from the residue stream via sulphur flotation. This paper describes the CESL Technology testwork on a bulk copper-nickel concentrate derived from Twin Metals Minnesota?s (TMM) deposits within the Duluth complex and evaluates the economic benefits (increased cash flow, increased revenue certainty) and investment criteria (capital cost, payback and cash flow) of incorporating CESL Technology into the staged development of TMM?s deposits.INTRODUCTION Mineral Processing and the Role of Hydromet in the Duluth Complex The Duluth Complex in northern Minnesota, United States (US), represents one of the largest undeveloped accumulations of copper, nickel, gold, and platinum group metals (PGMs) in the world, ranking second in copper and PMs and third in accumulation of nickel. The figure below identifies some of the larger known deposits within the Complex (see Figure 1). Copper, nickel, PM and PGM mineralization within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex.One of the mineral processing challenges of Cu-Ni-PM-PGM deposits in this Complex is the complicated, polymetallic nature of the mineralization1: copper occurs primarily as chalcopyrite and cubanite with minor occurrence of talnakhite; nickel occurs as pentlandite and refractory nickel oxide/silicates; iron sulphides are present as both pyrrhotite and troilite; and PMs/PGMs occur in both the sulphide matrix as well as discrete minerals. An additional challenge for the Duluth Complex is the ratio between copper and nickel; in most of the identified deposits, copper grade is three to four times greater than the nickel grade, which precludes the production of a simple bulk concentrate due to the lack of a traditional smelting market for a bulk concentrate of this character."

Jan 1, 2017

By A. McLean, A. Hue, K. Le, Y. D. Yang, P. Wu

While the treatment of relatively inexpensive ferrosilicon alloys is a potential refining route in order to generate solar grade silicon, phosphorus is one of the more difficult impurities to remove by conventional processing. In this project, the use of an electromagnetic levitation technique was used to investigate the dephosphorization of ferrosilicon alloy droplets exposed for various times and temperatures to a hydrogen-argon gas mixture. It was found that approximately 40% of the phosphorus was removed from an 85%Si-15%Fe alloy after 20 minutes exposure at approximately 1673K, to a gas mixture containing 48.5% hydrogen. Further dephosphorization is expected with longer reaction times. The effect of increasing temperature was found to be insignificant, although processing at lower temperatures is not only economically advantageous, it also decreases evaporative silicon losses, thus resulting in a more efficient process.

Jan 1, 2015

By C. Tissot, R. Palmer

"Due to the low concentrations of gold, direct measurement of gold concentration in ore on belt has not been seriously considered to now. Pre-concentration or sorting strategies have largely consisted of particle sorting based on secondary characteristics such as colour, which can be successful in select cases. CSIRO has produced sample measurement results using gamma activation analysis of ~300 gm samples with accuracies of around 30 ppb at best. With this encouragement, a feasibility study into gold ore measurement on belt for the purpose of sorting pods of gold ore has been undertaken. The study described here included, prototype design options with existing industrial Linacs, extensive Monte Carlo modelling of measurement sensitivity and shielding, further sample measurement, a study of the interaction of target measurement accuracy and sorting efficiency, and a rough estimation of potential economic benefit. The projected model sensitivity of around 0.1-0.15 ppm (1 standard deviation) in 10 seconds for 1 ppm average feed result in good bulk sorting performance and intriguing economic potential.INTRODUCTION Pre-concentration or sorting strategies for gold ores have largely consisted of particle sorting based on secondary characteristics such as colour or density, which can be successful in select cases (Klein, 2010). No method is available to measure gold content for sorting in particles or even in bulk on belt, principally due to the low concentrations of gold present. In fact, in many cases it is difficult to do rapid bulk grade measurements of base metal ores with concentrations many orders of magnitude higher. By a fortunate quirk of nature gold is particularly amenable to gamma activation analysis (GAA). CSIRO has performed extensive work in GAA of samples of crushed ore (Tickner, 2017). This has resulted in the Photon AssayTM technique that is currently being commercialised through the CSIRO spinoff company Chrysos. The technique relies on the recent availability of industrial high intensity X-ray sources such as Linacs which are currently being used in industry for security, medical and sterilisation applications. This development has led to CRC ORE funding a feasibility study to determine whether on-belt measurement of gold concentration is possible at a rate and accuracy sufficient to be useful for bulk sorting, where pods of ore are diverted rather than individual rocks. The study in the first instance is based on Monte Carlo modelling that has successfully predicted the performance of the sample based gold measurements. As well as the measurement feasibility consideration was also given to the likely heterogeneity of gold ores and hence the degree to which useful separation could be achieved. This is then tied to a back of the envelope evaluation of the order of magnitude economics of bulk sorting in an example deposit."

Jan 1, 2017

By V. C. Wittchen, T. R. Yu, J. E. Croxall

"The consolidated rockfill at Kidd Creek Mines is a weakly cemented, minus 15 cm aggregate which posed problems for conventional drill/blast drifting methods. Consequently, lateral access to mineable ore adjacent to backfilled areas was gained by drifting around the fill in shattered rock.In mid-1987, Kidd Creek Mines began to investigate means of mechanically excavating drifts in backfill . The results of this investigation led to a trial program using a Dosco MK-2A Roadheader to excavate the required drifts in backfill.The roadheader was tested at Kidd Creek Mines from July to November 1988, in 28-735 X /C to be used as the top access for drilling and blasting 32-74/ ST. During this period, the roadheader excavated 54 m of a 4.3 m by 3. 7 m arched drift in backfill. Cutting rates over the period averaged 0.8 m/cutting hour as projected with a daily high of 2.0 m/cutting hour.Wood-lagged 2-piece steel arches on 1.2 m centres were chosen as ground support for the trial. Shotcrete will be tested in a roadheader drive for its potential to improve productivity by replacing the steel arches.The trial program included evaluations of point-attack picks, two sizes of cutter motor, 20 MPa (3000 psi) water-assisted cutting, cuttings-removal systems, and environmental control devices."

Jan 1, 1990

By Kevin P. Plucknett, Z. Memarrashidi

"In the current work, factors influencing the corrosion mechanisms of TiC and Ti(C,N) based cermets are reviewed. Cermets were typically prepared with 30 vol.% of metal binder, in the form of various in-situ reaction-formed Ni3Al alloys. Commercial WC-Co hardmetals were also examined as baseline materials. The assessment of corrosion involved a variety of electrochemical measurements, including open circuit potential and potentiodynamic polarisation. The corrosion potential and current density were determined, following Tafel extrapolation, allowing estimation of the corrosion rates. Post-corrosion characterisation involved scanning electron microscopy analysis and associated energy dispersive X-ray spectroscopy of the sample surfaces. It is demonstrated that the primary corrosion mechanism for this type of cermet is dissolution of the metallic phase during oxidation attack, and thus this response can be expected to increase with the amount of binder in the cermet, although degradation can be subtly affected by composition (i.e. alloy composition, C:N ratio, impurities in the ceramic phase, etc.) and test procedure (i.e. aerated vs. de-aerated electrolytes). It was observed that addition of N content into the ceramic phase is beneficial to the corrosion characteristics of TiC based cermets, through significant refinement in the grain size of the hard phase. Similarly, elimination of impurities, such as W in selected TiC powders, also improves the corrosion resistance.INTRODUCTION Cermets are prepared using the combination of a hard, high elastic modulus ceramic phase with a ductile, high toughness metallic binder. This pairing of hard and ductile components ensures wide application of cermets in demanding wear environments. These materials are consequently used industrially in both bulk and coating form. The most common example of such a composite system is based on the use of tungsten carbide with a cobalt-based binder (WC-Co), which has been widely examined over the past 80 years. However, while WC-Co has been shown to exhibit an excellent combination of high strength and wear resistance, the corrosion and high temperature properties of this material are relatively poor. In addition, WC-Co possesses a high density (~13–14 g/cm3), which makes it a less desirable option when the component mass is a design factor (i.e. use in aerospace). In particular, the aqueous corrosion response of WC-Co limits its use in wear environments where combined corrosive degradation may occur (i.e. tribo-corrosion scenarios). Alternate cermet systems are therefore being actively developed due to these performance limitations."

Jan 1, 2017

By R. Browner, J. Collard, D. Ibana

The extraction of cobalt from synthetic pressure acid leach solutions of nickel laterite ores by the direct solvent extraction route using ESPLIM is reported. It first explored the use of gaseous ammonia as pH modifier and then the variables that affect the dispersion of the aqueous phase in the organic phase such as ionic strength, viscosity of the phases, initial droplet size, etc. were explored so that phase hold-up and thus extraction can be effectively controlled. The results show that the technique allows better control of phase dispersion circumventing one of the main weaknesses of conventional solvent extraction.

Jan 1, 2005

By Peter C. Jones, Wanda M. Carter, David H. Watkinson

"Abstract - Pyrrhotite, chalcopyrite, and pentlandite are the dominant sulfide minerals in the 740 zone of the Kelly Lake orebody (Inco Ltd.), Copper Cliff Offset, Sudbury. Petrographic and quantitative electron microprobe analyses of minerals, from sulfide assemblages and host quartz diorite, of the 740 deposit have revealed three processes that have affected sulfide mineralization and associated sulfarsenide and platinum-group-mineral (PGM) distribution: magmatic, hydrothermal, and tectonic. Accessory, zoned cobaltite, and gersdorffite occur in sulfides as a result of these three processes, and PGM occur dominantly in hydrothermally remobilized and deformed ores. Where PGM are present in sulfarsenides they provided nuclei for sulfarsenide growth. Solitary PGM are orders of magnitude larger than those PGM found within sulfarsenide minerals. Five varieties of PGM occur, michenerite and sperrylite being the most common, with lesser froodite, hollingworthite, and ruarsite.The effect of a deformation is a localized fabric in the ore, revealed by pyrrhotite and chalcopyrite bands; pentlandite porphyroblasts also partially define the foliation. The deformed ore is also characterized by alteration of the adjacent quartz diorite, which produced an alteration assemblage including almandine garnet, Fe-rich biotite, and chlorite."

Jan 1, 2001

By Jeffrey S. Loen

"The size, morphology, surface texture, per cent mineral inclusions, and bulk chemistry (Ag and trace elements) of placer gold particles vary systematically according to transport distance from source rocks, as indicated by a case study from the Pioneer district in Montana, and data from the literature.Placer gold samples show a rapid decrease in mean and maximum particle length, and a gradual increase in flatness index (F.I. = length + breadth/2 x thickness) from about F.I. = 2 in bedrock deposits, to as much as F.I. = 45 over transport distances of several tens of kilometers. Primary mineral inclusions (mainly quartz, sulfide minerals, and iron oxides) are mostly lost within 10 km to 20 km of fluvial transport; this loss of quartz and trace metals causes a major change in bulk chemistry of placer gold samples. Following the loss of inclusions and the development of flakes, edges of flakes are folded and the mean number of folded edges in a sample increases with distance. When viewed under the electron microscope, surface textures of placer gold particles also become progressively more pitted with distance.Analysis of placer gold particles can be used to help evaluate placer source-area problems (placers with no known hard-rock gold deposits). For example, coarse placer gold containing abundant inclusions indicates a proximal source. On the other hand, an abundance of thin flakes is evidence of a long transport distance and possible reworking from older gravels. Placer gold characteristics can therefore provide information on distance to mineralized source rocks."

Jan 1, 1995

By L. Voisin, E. Díaz, V. Montenegro, W. Kracht

Grinding media is of great concern in the mining industry mainly because its consumption represents an important part of the costs during mineral processing and consequently, of the total mining business OPEX. In addition, grinding media consumption impacts directly on flotation performance through negative contamination by corrosion, affecting the pulp chemical potential, complicating the understanding and control of the process, as galvanic interactions between mineral species also occur. In addition, during the process there is also a physical consumption of the grinding media through erosion and impact. In both cases, mineralogy has an important role because pulp abrasion power, chemical reactivity, rheology, hardness and other variables depend on the minerals contained in the pulp and their interactions. In the present study, a geometallurgical and phenomenological model, which describes the grinding media consumption and its relationship with mineral hardness expressed by Bond Work Index, was obtained based on advanced mineral characterization techniques such as Hylogger3TM, X-ray diffraction, X-ray fluorescence and experimental grinding tests using a laboratory mill applied on Chilean copper pulps. The results obtained show that pH has an important effect on grinding media consumption, because corrosion varies with hydrogen ions availability. Also, mineral hardness depends on mineralogical composition, but textural analysis must be performed to have a better description of this property. Finally, minerals present in a sample define the grinding media consumption mechanism, because a sample with harder minerals and a greater value of Bond Work index is capable of protecting grinding media from impact wear, while a sample with lower hardness but with a big sulfide minerals content would be more aggressive with grinding media because corrosion is more important in this case. The geometallurgical model obtained is capable to relate the grinding time, mineral hardness, content of sulfide minerals and grinding pH to estimate the grinding media consumption.

Jan 1, 2017

By Ian Ewart, Trevor Bergfeldt, Gourab Satapathy, Ajay Patel

"Conventional electrowinning (EW) of nickel from sulfate electrolytes is complicated by several factors including the requirement for a diaphragm cell to separate the anolyte and catholyte and the need to minimize nickel mist emissions. Developed and commercialized by emewCorporation, this novel process electrowins high purity nickel cathode (99.5%) from copper refinery bleed streams using the proprietary emew vortex EW technology. The emew nickel process incorporates high flow rate in an enclosed cylindrical EW cell operating at high current densities that overcomes the challenges of conventional nickel EW and completely eliminates the risk of nickel mist emissions. The tubular cathodes are easily harvested and mitigate the effect of plating stresses inherent in nickel EW. The present paper describes the emew nickel process and its most recent application to copper refinery bleed streams at full-scale.INTRODUCTION To meet the stringent demand of customers, nickel producers are giving prime importance to production of high purity nickel cathodes. The major challenge for refineries is to improve cathode quality and appearance despite fluctuating electrolyte impurity levels. The basis of achieving good quality cathode includes the control of electrolyte impurities and consistency of specific process conditions. The commercial operation of emew nickel technology has been successfully implemented and has demonstrated the ability to produce high quality nickel cathode from refinery bleeds. This paper emphasizes the importance of upstream impurity removal to achieve the required nickel emew feed composition by evaluating the benefits of using selective precipitation as a purification scheme with the aim of improving the overall nickel recovery while ensuring suitable nickel concentration in the advanced electrolyte is achieved. Nickel electrowinning is similar to other electrowinning processes that employ insoluble metal anodes & cathodes. It requires the passage of direct current between two electrodes that are immersed in a conductive, aqueous solution of nickel salts. For the recovery of nickel from solution, the most common methods are electrowinning and hydrogen reduction. Electrowinning usually occurs from sulfate, chloride or mixed sulfate/chloride electrolytes. In sulfate electrolytes, nickel electrowinning cells are normally designed to achieve specific criteria as outlined below (Robinson & Tuppa, 2002):"

Jan 1, 2017

By Zihe Ren, Edouard Asselin, Marcus Tomlinson, Tianbi Zhang, Jing Liu

"Raman spectroscopy is used to quantify the extent of disorder in the carbonaceous matter associated with preg-robbing ores. Previous studies of Goldstrike ores showed that the height and width of the peaks for the “D” (disordered) and “G” (graphite) bands, the so-called “Raman ratio” had a strong correlation to the preg-robbing value (PRV) measured for various ore samples. A brief literature review on Raman spectroscopy as it applies to preg-robbing ores is presented. Further, recent studies, presented here, have shown no correlation between the Raman ratio and the PRV for a wide variety of ores. This suggests that the extent of organic carbon crystal disorder is not the main factor in determining preg-robbing characteristics.INTRODUCTION Preg-robbing may arise from natural carbonaceous materials in the ore. Several mechanisms have been proposed in the past decades including a physical sorption process by the carbonaceous matter, or via the reduction of aurocyanide at the mineral surface (Abotsi & Osseoasare, 1986; Afenya, Osseoasare, & Abotsi, 1983; Tan, Feng, Lukey, & Van Deventer, 2005). Nevertheless, the mechanisms of preg-robbing remain poorly understood. Understanding the nature of the preg-robber is of practical importance for the selection of a suitable treatment process. Fine carbon particles in the ore have been recognized as preg-robbers due to their similarity to the activated carbon used in the carbon in leach (CIL) or carbon in pulp (CIP) processes. Previous research has illustrated that the activated carbon (also referred to as amorphous carbon in some literature) has a much higher absorption ability than pure graphite with high crystallinity (Adams & Burger, 1998). Adams et al (Adams, Swaney, Friedl & Wagner 1996) concluded that carbonaceous matter is largely responsible for the overall preg-robbing capacity of a given ore. However, the mechanism of carbon preg-robbing was still not clear mostly due to the complexity of amorphous carbon and its behavior in different solution matrices, and at different pH and temperature (Adams, 1990, 1993)."

Jan 1, 2017

By N. Hosking, M. Nichols

Aluminum alloys are increasingly used for automotive body construction but are susceptible to filiform corrosion or paint blistering in service. Filiform corrosion resistance of two 6000-series aluminum alloys was investigated in this work. Test panels were produced with full automotive coating layers and scribed parallel and perpendicular to the rolling direction. The corrosion exposure comprised an inoculation step with acidified salt solution followed by a 6-week exposure period at 95% relative humidity and either 25°C or 70°C. Greatest corrosion activity was measured on the alloy with higher copper content, AA6111. Higher temperature exposure led to greatly enhanced corrosion activity for AA6111 compared to the lower temperature exposure. The 70°C exposure also led to greater mean corrosion-affected area measurements for the low copper aluminum alloy, AA6022, but the effect was not as stark as that observed for AA6111. Rolling direction affected the propagation direction, and possibly mechanism, of the corrosion effects. Cross-sectional analysis revealed dense corrosion products within the filament, comprising mostly aluminum and oxygen but with traces of chloride and sulphate. Development of varying filament and blister types on a single test panel and the progression of corrosion underneath a filament into the substrate indicate that several corrosion mechanisms can develop on the test panel, testament to the complexity of the corroding surface developed on an aluminum automotive body panel.

Jan 1, 2015