Nickel, Copper, and Total Precious Metal Recovery from Twin Metals Minnesota Concentrates Using the CESL Process

"Teck Resources Limited (“Teck”) has developed and extensively tested on a continuous basis the CESL Technology hydrometallurgical process for treating copper and nickel sulphide concentrates, including bulk copper-nickel concentrates. Copper, nickel and cobalt are leached efficiently into solution, utilizing CESL process conditions. Total precious metals including gold, silver, platinum and palladium are recovered from the residue stream via sulphur flotation. This paper describes the CESL Technology testwork on a bulk copper-nickel concentrate derived from Twin Metals Minnesota?s (TMM) deposits within the Duluth complex and evaluates the economic benefits (increased cash flow, increased revenue certainty) and investment criteria (capital cost, payback and cash flow) of incorporating CESL Technology into the staged development of TMM?s deposits.INTRODUCTION Mineral Processing and the Role of Hydromet in the Duluth Complex The Duluth Complex in northern Minnesota, United States (US), represents one of the largest undeveloped accumulations of copper, nickel, gold, and platinum group metals (PGMs) in the world, ranking second in copper and PMs and third in accumulation of nickel. The figure below identifies some of the larger known deposits within the Complex (see Figure 1). Copper, nickel, PM and PGM mineralization within the Duluth Complex is hosted by mafic to ultramafic intrusive rocks that are part of the overall intrusive complex.One of the mineral processing challenges of Cu-Ni-PM-PGM deposits in this Complex is the complicated, polymetallic nature of the mineralization1: copper occurs primarily as chalcopyrite and cubanite with minor occurrence of talnakhite; nickel occurs as pentlandite and refractory nickel oxide/silicates; iron sulphides are present as both pyrrhotite and troilite; and PMs/PGMs occur in both the sulphide matrix as well as discrete minerals. An additional challenge for the Duluth Complex is the ratio between copper and nickel; in most of the identified deposits, copper grade is three to four times greater than the nickel grade, which precludes the production of a simple bulk concentrate due to the lack of a traditional smelting market for a bulk concentrate of this character."