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By K. L. Gabby

Selective removal of mercury from cyanide leaching solutions while retaining silver has been a long-standing problem, due to the chemical similarity of mercury and silver. In order to be practical, a mercury removal process needs to be both highly selective and use inexpensive materials. This paper reports the use of zinc sulfide (ZnS) as a precipitant for mercury. The mercury cyanide complex (Hg(CN)4 2-) undergoes a replacement reaction with the zinc sulfide, forming insoluble HgS, while the silver cyanide complex (Ag(CN)2 -) remains in solution. Under appropriate conditions, the separation of mercury from silver is nearly quantitative, with close to 100% removal of mercury, while nearly none of the silver is precipitated.

By KAGAN BENZESIK, OMUR CAN ODABAS, SELCUK KAN, Onuralp Yucel

In this study, domestic molybdenum disulfide (MoS2) concentrate was roasted in a chamber furnace and then in a rotary kiln. The behavior of the roasting process was examined in both furnaces, and which type of furnace is more advantageous to use in mass production was investigated. It is theoretically possible to roast in a chamber furnace, but a major problem was observed when the amount of concentrate was increased in the chamber-furnace experiments. The problem was solved by using a rotary kiln. This study improves the understanding of the roasting of  MoS2 concentrate and presents a different perspective to the industry, showing that rotary kilns can also be used for roasting.

By D. S. McAllister, P. M. Rice, M. E. Fowler

The Westside Light Rail Project, a major 19.3-km (12-mile) extension of Portland, Oregon's light rail system, includes 4.6 km (2.8 miles) of twin 5.8-m (19-ft) diameter running tunnels, a binocular type station which, at 80 m (260 ft) below the ground surface, will be the deepest mass transit station in North America, two 9.4-m (31-ft) diameter station access shafts, and a 5.2-m (17¬ft) diameter ventilation shaft. The tunnels are being excavated by TBM and conventional rock, soft ground, and mixed-face methods. Geologic conditions, alignment, underground opening design, excavation method selection, and payment provisions for excavation and initial ground support are discussed.

Jan 1, 1995

By Kurt M. Larson

Future haulage cost projections led Foster Yeoman Limited into developing a fully mobile crushing and conveying system at its Torr Works quarry in Somerset, England. The purpose-built system has an effective throughput of 2,500 tonnes/hour and features an Orenstein and Koppel (O & K) manufactured walking frame, a Fuller-Traylor type 54 X 74 TC gyratory crusher, and unique mobile conveyor modules designed and manufactured by Foster Yeoman. Used in a single-bench operation in this 6 million-tonne per annum limestone aggregate quarry, the system is fed at the production face by 2 Caterpillar 992C loading shovels. The entire system is moved on a daily basis following production face locations.

Jan 1, 1986

By A. Davis

Pit lake chemistry depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock versus oxidizable sulfide content, and the alkalinity of recharging ground water. In this paper, we assess the geochemistry of 11 existing pit lakes, ranging from the acidic Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington Pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits with the long-term pit lake chemistry lying on a geochemical continuum between end members consisting of influent calcium bicarbonate ground water, and naturally occurring sulfate-rich evaporite playa lakes.

Jan 1, 1996

By Raphael Mourad, Colin R. Phillips

Investigation of the traps in LiF:Mg, a multi-peak phosphor, was carried out using simple phosphorescence decay analysis. Half lives at room temperature of the trapping centres (peaks -lb, -la, -1, 0, 1, 2, 3a and 3) in the phosphor after irradiation with [a] radiation were found to be 3 s, 5 s, 28 s, 4 min, 15 min, 1 h, 6 h and 2 d respectively. Justification for the method of analysis is pro- vided and the results of measurements compared with published data. The effects of pre-annealing at 400°C for 1 h and 80°C for 24 h on the trapping configuration and on the trapping efficiencies were also studied.

Jan 1, 1981

By A. W. Wensel

The adsorption behavior of sodium oleate on brucite, Mg (OH)2, has been studied by Fourier transform infrared spectroscopy. Both internal reflection and diffuse reflection (DRIFT) methods were used to characterize the adsorbed oleate on brucite. DRIFT measurements were shown to be quantitative, and an equilibrium adsorption isotherm was obtained. The conformational behavior of the adsorbed oleate was investigated as a function of adsorption density. It was found that at sub-monolayer coverage the alkyl chains of the adsorbed oleate had more ?gauche? character than at multi-layer coverages. Also, DRIFT spectra revealed that the adsorbed species were magnesium dioleate. For internal reflection measurements single crystals of MgO were hydrolyzed to form a thin Mg (OH)2 layer.

Jan 1, 1994

By G. Belardi, N. Sheau, P. Plescia, F. Veglio

A study was conducted to assess a new wet gravity-separation machine, identified as the Multi-Gravity Separator(MGS). Chromite fines, obained from an Albanian chromite and olivine ore and containing 23% Cr2O3 and 18% SiO2, were used in the study. The first step was to determine the influence of various operating parameters. The study indicated that the most important variables for the MGS are rotational speed, tilt angle and shake amplitude. The best treatment conditions for the ore were then identified by investigating a series of circuits designed to produce a marketable product. In open circuit, a concentrate containing 50% CI-203 was obtained with a recovery of 72%.

Jan 1, 1996

By Kalyan Saikia

An integrated statistical-geostatistical modelling of gold exploration data of Gurahar Pahar prospect of Mahakoshal greenstone belt in Central India has been attempted. Statistical modelling of gold accumulation and width reveal a positively skewed 2-parameter lognormal distribution fit with an estimate of mean gold as 0.84 gram/tonne. Geostatistical modelling provided a spherical semi-variogram function fit with mean kriged estimate and mean kriging variance of gold as 0.76 gram/tonne and 0.23 (gram/tonne)2 -respectively. Ore inventory and grade-tonnage relationships for a selected part provided an estimate of 3,36,000 tomes of ore with an average gold of 0.76 gram/tonne at 0.5 gram/tonne cutoff grade.

Jan 1, 2002

By Kenneth R. Miller

Surface mine equipment operators in the Campbell County region of Wyoming's Powder River Basin have found new ways of solving old problems. Technology, experience, competitive pressures and an increasing grasp of economies of scale have driven mine operators, equipment manufacturers and suppliers to specialization of applications. In economic terms, today's coal price of $4.95/t ($4.50/st) equates to $2.53/t ($2.30/st) in 1980 terms - an incomprehensible value at that time. This article describes some examples of change and adaptation made by Powder River Basin coal operators in overburden stripping equipment and techniques. It focuses on the evolution of the design and use draglines, shovels, trucks, scrapers and dozers.

Jan 1, 1998

By Jay A. Bowden

In April of 1990, Homestake Mining Company began a 5,100 m (16,700 ft.) exploration drift from the Homestake Mine in Lead, South Dakota. The drift starts from the mine's 6800 level, nearly 2,100 m below the surface, and extends north to further explore occurrences of gold discovered by surface drilling. Access to the North Drift for men and materials and for disposal of waste rock is limited to the Homestake Mine's #6 Winze, which serves as the major production shaft for the deep levels of the mine. This paper will discuss the successes and challenges encountered while managing a tunneling project 2,100 m below the surface and from an active mine.

Jan 1, 1993

By H. Y. Sohn, M. Pérez-Tello, J. Löttiger

An investigation of the oxidation reactions of two industrial copper mattes was performed using dflerential scanning calorimetry (DSC) and thermogravimetric analysis (TGA) at heating rates of 20°C and 8°C/min, respectively. The temperature of incipient reaction, the total exothermic and endothermic heats of reaction and the weight change during the oxidation process were measured as functions of the oxygen concentration in the oxidizing gas, matte grade and matte particle size. The temperatures of incipient reaction measured from the DSC experiments were found to increase monotonically with all three input variables. TGA experiments showed that Cu2O and CuO CuSO4 are formed before the complete oxidation of Cu2S to CuO.

Jan 1, 2000

By Dirk van Zyl

Three conditions are required for a risk to be realized: (1) a source of risk (i.e., hazard) must exists (2) some process must take place which will lead to the exposure of people, animals, and/or the environment to the hazard: and (3) as a result of the expense, undesirable effects are produced on the people, animals, and/or the environment. A comprehensive risk assessment addresses all three of the conditions through the following four steps: (1) risk source (hazard) characterization, (2) exposure assessment, (3) dose-response assessment, and (4) risk estimation. Although the terminology may differ, the overall approach of financial, public health, and environmental risk assessments is the same (National Science Foundation, 1985).

Jan 1, 1988

By Jr. Smith

Industrial minerals are just other rocks, except for the unique characteristics that make them useful in an industrial process. There is not a ready market for this type mineral and one or more uses must be developed to sustain production. The name "olivine" is a generic term used to indicate a group of orthosilicate minerals in a solid solution series, with forsterite (Mg2SiO4) and fayalite (Fe2SiO4) as endpoints. Since neither is found alone in nature, the mineral is always a combination of the two. The commercial deposits are high in magnesium and on the high end of the melting scale in the series. The name comes from the olive-green color.

Jan 1, 1992

By Li Honggui, Liu Maosheng, Zhao Zhongwei, Sun Peimci, Li Yunjiao

Leaching of Shizhuyuan low-grade refractory tungsten ore was carried out in a mechanically activating reactor. The effect of experimental parameters-temperature, amount of Na2C03, addition of NaOH, ratio of liquid to solid and leaching time - on the recovery of WO3 was studied. The WO3 recovery up to 96.99% have been achieved when the tungsten ore was digested by soda not more than three times the stoichiometric amount at 185-195°C for 1 .O-2.0 hours. Iso-extraction countour diagrams were drawn to illustrate the effect of various parameters on leaching. The WO3 recovery could be expected to increase 10-15% compared to that of conventional soda autoclave process.

Jan 1, 1995

By P. Zhang

Phosphate mining in Florida generates approximately 100,000 tons/day of phosphatic clays (slime). This waste slime not only creates one of the most difficult disposal problems in the mining industry, but also causes tremendous loss of P2O5. About 20-30% of the phosphate mined end up in phosphatic clays. Recovering the phosphate from this waste is difficult for two main reasons: 1) the slime is extremely fine in size, and 2) clay minerals account for almost half of the material. A half dozen dispersants were evaluated for keeping the clay minerals suspended for subsequent separation from non-clay minerals by either settling or cycloning. The separation efficiency and economics are discussed.

Jan 1, 1998

By Roe-Hoan Yoon, Kaiwu Huang

Derjaguin and Dukhin [1] were the first to develop a first-principle flotation model by considering the role of surface forces in bubble-particle interactions. According to the model, the ζ-potentials of particles constitute the energy barriers, E12, for particle (1)-bubble (2) interactions, which corroborates well with the observation that flotation recoveries reach maxima under conditions of zero-zeta potentials. In the present work, a series of surface force measurements were conducted for the quartz-dodecylamine hydrochloride (DAH) flotation system, for which detailed studies had been conducted by D.W. Fuerstenau [2], including the measurements of zeta-potentials, contact angles and collector adsorption as a function of pH.

At present the feasibility of developing underground facilities for the storage of a number of products including toxic waste, oil, nuclear waste and low pressure gas is under investigation in e number of countries. A possible method of storage is in large excavations, Preliminary ventilation design work has identified that the climatic conditions encountered within these large excavations are a limiting ventilation pollutant within the ventilation system. This paper examines the design of a variety of sizes of excavation from a ventilation viewpoint. The main phases of an excavations lifetime can be divided into four main phases, these being construction, civil and mechanical fitting, storage, full and sealed. The paper details ventilation design options for the first two phases of e vaults lifetime, giving climatic simulations to assess the likely climatic conditions within the excavations for e number of facility depths. The options for climatic control are given and analyzed by means of climatic simulations techniques. l. INTRODUCTION The feasibility of developing underground facilities for the storage of a number of products is under investigation at present in a number of countries. This paper details a possible design for such a facility where the product is to be stored in large underground excavations. A facility layout has been designed with the aim of allowing concurrent construction and storage operations. Thus from a ventilation perspective the facility consists of two circuits , a construction ventilation circuit and a product ventilation circuit both of which are served by an intake and a return surface connection The construction and storage circuits are considered as independent of each other , any interaction in the form of leakage must be from the construction to the storage circuit. From the facility design a ventilation network was developed to assess the ventilation requirements of the facility. In analyzing the pollutant loads for the construction circuit two pollutants were recognised to be critical to the ventilation design , these being diesel exhaust fumes and heat end humidity. In this paper ventilation design options for the construction and civil and mechanical fitting phases of the excavations are analyzed by means of climatic simulation and options for climatic control within the vaults are outlined . 2. FACILITY DESIGN A schematic diagram of a facility design is illustrated in Figure 1. There would be two distinct ventilation circuits , one to service the construction operations and the second to serve the storage operations which occur concurrently with construction , the circuits are separated by ventilation bulkheads . Access to the facility for intake air is provided by two drifts, one to serve each circuit. Two shafts act as returns to surface. The facility consists of two distinct zones for the storage of two types of product. One type is to be stored in smell linear excavations. The second zone is for the storage of a second product in larger excavations. The maximum cross-sectional area and perimeter for the smell linear excavations are 456.25 m2 and 83.2 m, while for the larger excavations they are 440.1 m2 and 86.4 m. Excavation construction consists of three phases: 1. Initial pilot tunnel development between main intake and return to provide through flow ventilation. 2. Enlargement to produce the required finished cross-section. 3. Civil and mechanical engineering work to fit out the excavation ready for storage. It is proposed to excavate the excavations using drill and blest methods utilising diesel equipment. Spoil is to be transported to surface by a conveyor belt system. At any one time the maximum number of working places requiring ventilation will consist of ; 3 storage sites, 2 excavations under construction, 2 excavations undergoing civil and mechanical fitting. [ ]

Jan 1, 1993

By C. I. Wilmot

FMC's Paradise Peak Mine was discovered in July 1983. The deposit at discovery contained 11,340 ,000 tonnes (12,500,000 tons) of ore grading 3.71 glt (0.108 oz/ton) Au and 120 glt (3.5 oz/ton) Ag. A feasibility study was completed by Davy McKee in May 1984, with detailed engineering starting in June 1984. Construction of the facility started on January 2, 1985 with plant start-up taking place on April 14, 1986, two and one half months ahead of schedule and more than 10% under budget. This paper describes the status of the operation approximately 1-1/2 years after start-up including revisions and additions to equipment and process.

Jan 1, 1988

By Andy Davis

The evolution of pit lake water quality depends on the lithology and hydrologic characteristics of the ultimate pit surface, the availability of buffering capacity in the wall rock vs. oxidizable sulfide content, the alkalinity of recharging groundwater and the evapoconcentrative characteristics of the system. This paper assesses the geochemistry of 11 existing pit lakes, ranging from the acid Red Hill and Berkeley pit lakes (pH 2.6 to 2.8) to the alkaline Yerington pit lake (pH 8.45). Predicted pit lake chemistry is similar to that in existing pits, with long-term chemistry lying on a geochemical continuum between end members that consist of influent calcium bicarbonate groundwater and naturally occurring sulfate-rich evaporate playa lakes.

Jan 1, 1997