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By K. Gum, W. C. Hirt, D. A. Rice

Selective flocculation was used to produce a superclean zinc concentrate by minimizing silica contamination. Research was carried out on a flotation concentrate from the Jersey Miniere Zinc Company (JMZ) in Gordonsville, TN. The material was first dispersed with sodium silicate and then causticized tapioca starch was used to selectively flocculate the sphalerite, leaving the silica in suspension. This technique has been applied commercially to iron ore beneficiation but never to zinc processing. The feed material assayed 0.45% SiO2. The use of 0.56 kg/ t (1.13 lb/st) sodium silicate and 0.070 kg/t (0.141 lb/st) causticized tapioca starch resulted in a 98.2% zinc recovery and produced a purified zinc concentrate assaying 66.0% Zn and 0.24% silica. The target level for silica contamination in JMZ zinc concentrates is currently 0.30% Si02. This work demonstrated that selective flocculation is a potential method for cleaning flotation concentrates, particularly where low silica products are required.

Jan 1, 1995

By Mahmut Altiner

Magnesium is listed as a key critical raw material in a report by the European Commission that evaluated raw materials based on supply risk versus economic importance [1]. It has extraordinary properties, such as nontoxicity, inertness, high melting point, stability, low weight, chemical resistance, electrical insulation, optical transparency, corrosion-resistant behavior and refractory nature. It is widely used in the areas of agriculture; the environment, for antibacterial and water-purification purposes; electronics; automotive; drug delivery; ceramics; construction, as filler in brick; and concrete production, in the forms of magnesium oxychloride and magnesium oxysulfate. Magnesium oxide (MgO) particles can be produced through the calcination of magnesite ore at different calcination conditions depending on the desired quality of the product, classified as fused (2,800 °C), dead-burned (>1,400 °C), hard-burned (1,000–1,400 °C), or light-burned MgO (700–1,000 °C) [2]. However, the global availability of magnesite ore is limited.

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbonate gangue from sedimentary apatites (francolite) in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to benepciate a high- MgO siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for car- bonate removal and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the MgO was rejected in the froth. The phosphate flotation stage produced concentrates analyzing about 31% P2O5 0.7% ? 5 MgO, and 4% insol. The overall P2O5 recovery In the two stages was about 85%

Jan 1, 1991

By C. E. Jordan

The Tuscaloosa Metallurgy Research Center of the Bureau of Mines, U.S. Department of the Interior, is investigating the recovery of phosphate from beneficiation slime, as part of the Bureau's efforts to conserve mineral resources through increased use of wastes. Phosphate equivalent to about two-fifths of U.S. production is discarded annually in the wastes. Exploratory flotation tests on the plus 5-um fraction of a slime sample showed promise for a classification-flotation technique. Onsite classification tests at six phosphate washing plants were conducted with a two-stage hydro cyclone system designed to recover the plus 5-um material. The cyclone underflows contained 8.3 to 19.1 percent P2O5, and the recovery of the plus 5-um PZOS values ranged from 81 to 95 percent. The percent P2O5 recovery from the total slimes ranged from 38 to 47 percent. Batch-flotation studies are currently being conducted.

Jan 1, 1978

The paper describes a practical methodology based on numerical modelling for the prediction of progressive failure of underground mine stopes with cable bolt support. A case study of the 40-761 stope at Kidd Creek Mine, Timmins, Ontario is presented. The stope was mined by blasthole open stoping in 1986 as a lead stope within a mining block between 36-1 and 38-2 levels. Initially designed to peak at 38-2 level, the stope back caved upwards approximately 40m towards 36-1 level. Cable bolts were installed above the stope from 36-1 level after caving had begun. The stope eventually stopped to cave when the falling rock mass encountered a sufficiently high cable density. The paper provides details of the geomechanical data and modelling results of the case study. Numerical modelling is carried out using a finite element package known as e-z tools which has, among other things, a special cable/rockbolt simulation capability.

Jan 1, 1994

By Fathi Habashi

CRYSTALLIZATION from aqueous solution is a simple and old method for the recovery of metal values from leach solution. Practically all the methods for the recovery of aluminum from clay are based on the crystallization of an aluminum salt from the leach solution. Differences in solubilities may be used to advantage for separating two metals from the same leach solution. The classical method of Marignac (1866), which makes use of the difference in solubilities of K2TaF7 and K2NbOF5 to separate niobium from tantalum, has been used successfully in the manufacture of these metals (Fig. 10-1). The slurry containing the metal oxides is dissolved in 70 % hydrofluoric acid, diluted, and heated near boiling. A potassium salt is added in sufficient quantity to form the complex fluorides of the niobium and tantalum present. The solution is filtered and allowed to cool. At room temperature most of the tantalum salt crystallizes out while the niobium remains in solution.

Jan 1, 1970

By J. G. Henning, R. Edrissi

This paper describes a practical methodology, based on numerical modeling, for the prediction of progressive failure of underground-mine stopes having cable-bolt support. A case study of the 40-761 scope at the Kidd Creek mine, Timmins, Ontario, Canada is presented. Scope 40-761 was mined by blast hole open sloping in 1986 and was a lead scope within a mining block located between levels 36-1 and 38-2. Initially designed to peak at level 38-2, the scope back caved upwards =40 m towards level 36-1. After caving began, cable bolts were installed above the stope from level 36-1. The stope eventually stopped caving when the falling rock mass encountered a sufficiently high cable density. This paper provides details of the geomechanical data and modeling results of the case study. Numerical modeling of cable bolts around the mine stoke was carried out using a finite-element modeling software. The software, known as e-z tools, was developed by the first author.

Jan 1, 1996

By I. H. Warren

The high temperature lubricant molybdenite, MoS2, is usually produced by a complex sequence of processes involving mineral dressing of molybdenite concentrates followed by leaching with hydrofluoric acid to remove abrasive impurities such as silica (1). Many attempts have been made, mostly by techniques involving, direct fusion of molybdenum compounds with sulphur, to produce synthetic molybdenite. However, apart from some experiments of geochemical interest (2) in which aqueous solutions of sodium sulphomolybdate, Nat MoS4, were decomposed under pressure at temperatures between 300°C and 700°C, no attempts to produce the mineral by hydrometallurgical procedures have been reported. Since molybdenite is nominally a compound of tetravalent molybdenum with sulphur, and the most common state of molybdenum is +6, production of molybdenite is likely to involve reduction and sulphidization. The present study, therefore, describes the reduction, with hydrogen and carbon monoxide, of molybdenum in the hexavalent state in alkaline aqueous solutions containing sulphide ion. In these

Jan 1, 1972

By J. A. Bleeck

A discourse on the relationship between industrial minerals and paper production, concentrating on high grade, ultra fine ground calcium carbonate (mean particle size less than 2 microns) and precipitated calcium carbonate. The scope of the paper encompasses four basic areas relevant to the topic: 1. A tutorial overview of the papermaking process with an examination of various industrial mineral components in that process; 2. A discussion of basic technological topics pertinent to the utilization of carbonate in paper with emphasis on the relative aspect. Of natural ground calcium carbonate (GCC) and synthetic precipitated calcium carbonate (PCC); 3. An overview of paper and carbonate market, in both the United State, and Europe with emphasis on (a) current status and future growth trend. Of such market., and (b) discussion of the major influences on growth and development of such market.; and 4. Identification and discussion regarding the principal producers in calcium carbonate markets serving the paper indu.try in Europe and North America.

Jan 1, 1993

By V. Rajaram

A mine fire or roof collapse may necessitate the reversal of main fans to isolate the fire or provide an escapeway. Hence, to assist the mine operator in estimating the flow and pressure during reversal, Engineers International Inc. conducted a laboratory and field study of the reverse performance characteristics of main mine fans. Laboratory tests were performed using a 2.4-m (96-in.) diam vane axial fan to establish the forward and reverse performance characteristics under controlled conditions. Subse¬quently, a field test was conducted in a Colorado oil shale mine during which two 2-m (79-in.) diam fans were reversed. The data obtained indicate that reverse performance characteristics depend on the blade angle and the hub-to-tip ratio. The quantity in the reverse mode ranged from 30% to 65% less than in the forward mode, and the static pressure was directly proportional to the square of the quantity.

Jan 1, 1987

By J. Hanna

The University of Alabama Mineral Resources Institute (MRI) has developed a unique process for selective fatty acid flotation of carbon-ate gangue from sedimentary apatites "francolite" in the pH range of 4-6 without collector conditioning of the pulp. The process, which does not require an apatite depressant, was modified to beneficiate a high Mgo siliceous phosphate matrix from south Florida. The modified process includes two flotation stages, one for carbonate removal, as mentioned above, and the other for phosphate recovery from the siliceous gangue. The selective flotation separation of the carbonate and phosphate, from siliceous constituents of the matrix at various pH levels and collector dosages are discussed. In the carbonate flotation stage, about 70% of the Mgo was rejected in the froth and the phosphate flotation stage produced concentrates analyzing about 31% P2O5,0.7% HgO and 4% insol. The overall P2O5 recovery in the two stages is about 85%.

Jan 1, 1989

By R. A. Jankowski

The US Bureau of Mines (USBM) conducted a series of laboratory tests to investigate the effectiveness of using a flooded-bed scrubber with exhaust ventilation in deep-cut faces. An experimental test program to determine the impact on respirable dust levels resulting from changes in face airflow, curtain-setback distance, operator positioning and operating parameters of the external spray system on the miner was completed. Gravimetric sampling was conducted in the immediate return and at three sampling locations on the off-curtain side of the entry. Statistically significant differences in dust levels, on the order of 0.5 to 1.2 mg/m3, were observed between specific sampling locations and changes in several test parameters. Dust sampling results indicated that a flooded-bed scrubber and exhaust ventilation can be a viable dust-control system for extracting deep cuts up to 12.2 m (40 ft) in length. The impact on methane was not evaluated.

Jan 1, 1998

By Kenneth J. Leib, Laurie Wirt, M. Alisa Mast

Chemical-constituent loads were determined for an alpine stream in southwestern Colorado that is affected by natural acid drainage from weathering of hydrothermally-altered rock and from acidic metal-rich discharge from abandoned mines. Base-flow loads were compared to storm-related loads using a tracer-dilution approach. A rainstom occurred during the tracer injection, providing the opportunity to measure metal loads before, during, and after storm runoff. Chemical-constituent loads during the storm increased by 1 to 2 orders of magnitude relative to base-flow conditions. The increase in loads was related to two distinct periods; (1) a flush of higher concentrations that occurred soon after rainfall began, and (2) the peak of storm runoff. The initial flush-having no measurable change in discharge--contained the highest loads of trace metals and dissolved iron. The chemical character of peak runoff was distinctly different, as evidenced by the highest loads of total and dissolved major elements and total iron.

Jan 1, 2000

By R. Stanevich

Studies by the National Institute for Occupational Safety and Health (NIOSH) and the Bureau of Mines (BOM) have demonstrated that: (1) 90% of diesel particulate is less than one (1) micrometer in aerodynamic diameter; (2) more than 90% of the respirable mass in electric coal mines was greater than one (1) micrometer in aerodynamic diameter; and (3) in coal mines using diesel equipment, average diesel concentrations can represent up to 53% of the MRE respirable coal dust standard. For mines approaching the 2 mg/m3 standard, compliance may be easier to attain by controls directed at diesel exhaust particulate as opposed to coal dust control. First, however, a Simple instrument is needed to measure diesel exhaust particulate concentrations. This paper describes such a sampler, its construction, and use. While results from this sampler are primarily utilized to identify control areas, NIOSH is also using the sampler for estimating worker exposures in epidemiologic studies.

Jan 1, 1988

By John Matthews

During 1982 and 1983, it became increasingly clear that North River No. 1 Mine would have to buy a set of replacement longwall shields. Despite extensive efforts to make improvements, the shields that were in place at that time were incapable of holding the roof. North River Energy had limited experience in specifying and acquiring longwall roof supports, but a great deal of experience with our conditions and needs. We there- fore compiled a shield evaluation method that uniquely responded to our situation. The resulting system emphasized teamwork among operating, maintenance and engineering personnel. The charge from management was threefold: select shields to support maximum expected loads, optimize face operations, and pay attention to detail. Final selection was made objectively, based on all available information. We chose a 5516 KN (620 tons) support with a minimum yield load density of 760 KN/m2 (7.9 tons/ft2). This paper reviews our process of specification, design, prototype testing, and fabrication, and offers some relevant suggestions.

Jan 1, 1986

By V. Nasri, P. Jarast, M. Bakhshi

The Montreal metro Blue Line Extension toward the northeast consists of the construction of five new underground stations. The project includes 6 kilometers of the tunnel which will be constructed using a Tunnel Boring Machine (TBM). In line with the commitment to integrating sustainability best practices, Envision verification is pursued this project. The Envision reference framework was developed to cover all the sustainable development aspects of an infrastructure project and each phase of its life cycle (planning, design, construction, operations and maintenance, and end-of-life). As a part of this endeavor, low-carbon concrete and shotcrete mixtures are proposed for the linings of TBM and SEM tunnels as well as stations and auxiliary structures. The CO2 emission of the low-carbon concrete and shotcrete mixtures were compared with their typical mixtures and the total CO2 emissions reduction related to the tunnel lining is determined. The study is of strategic significance for achieving emission reduction in the tunnel industry.

Jun 13, 2023

By Raoul Fernandez, Bernard Catalano, Guillaume Roux

The Thaumasia Joint-Venture, composed of Bouygues Travaux Publics, Soletanche- Bachy and Bessac, completed the construction of the underground section of line 2 of the Nice tramway, which comprised a 3.2 km twin track tunnel and four underground stations, in a particularly complex urban and geotechnical context. The density of the surface structures, as well as the presence of many historic buildings on its route made the construction of the tunnel even more sensitive, with a settlement threshold of Half an Inch. The joint venture faced a complex subsoil, varying from one extreme to another from highly plastic clay layers to fibrous peat and to cobbles with very high permeability, with artesian ground water, and with unforeseen anthropogenic obstacles in the tunnel section Due to the diversity of the problems encountered and their variability over short distances, the construction of the underground section of the Nice tramway, in its very sensitive urban context, undeniably constituted an unprecedented challenge.

Jun 13, 2023

By L. A. Arrington-Webb

Forty-four states produced clay products during 1994 for a total value of $1.6 billion. This was a 3% increase in total tonnage and a 7% increase in value from 1993. Kaolin Domestic production of kaolin during 1994 was estimated to be 9.3 Mt (10.2 million st), according to the US Bureau of Mines (USBM). Georgia remained the leading producer with 7.5 Mt (8.2 million st), followed by South Carolina with 535 kt (589,000 st). Kaolin used as a paper coating or filler pigment accounted for 51% of domestic consumption. Other uses included grogs (14%), fiberglass (5%) and plastics (4%). A reclassification by an Alabama producer of fire clay to kaolin accounts for the introduction of kaolin used in grogs. This also accounts for the apparent decrease in the use of kaolin in paper from 60% in 1993. However, the actual amount of kaolin used in paper was the same.

Jan 1, 1995

By J. W. Cash

The mineralogy and textures of cyclone dust, sludge, and occasional build-ups in the American Iron and Steel Institute (AISI) direct iron making pilot plant at Universal, Pennsylvania have been studied by reflected light, transmitted light, and cathodoluminescence microscopy, and phase compositions have been determined by SEM-EDS. The cyclone dust consists of particles of carbon, metallic iron, sulfur-bearing iron, and wustite. Measurements of particles in the sludge indicate that 69% are less than 2.5 µm across, 21 % are 2.5-5 µm, and 10% are larger than 5 µm. Mineralogically the sludge particles are mainly carbon and metallic iron, with minor wustite and sulfur-bearing iron. Build-ups that sporadically develop in the furnace consist of olivine, hercynite spinel, metallic iron, wustite, pyrrhotite, pseudobrookite, akermanite-ferroakermanite and gehlenite. The microtextures shown by the build-ups indicate that much of that material has precipitated at the build-up loci. This study has been supported by AISI and the U.S. Department of Energy.

Jan 1, 1995

By Jack S. Watson, Rasika Nimkar, Robert M. Counce, BRADLEY BENNETT, Patrick Zhang

This study level process design represents an economically viable method for extracting thorium dioxide and other rare earth elements from monazite ore. This paper incorporates results from the 2019 capstone project from the honors Design Internship in Green Engineering in Chemical and Biomolecular Engineering. In this activity, senior students in Chemical Engineering at the University of Tennessee (UT) focused on the development and study of a process for the recovery of thorium dioxide and P2O5 from monazite. While not mandated, the process offers rare earth oxides as attractive byproducts. The project focused on recovery of byproducts rather than the creation or addition to waste streams. Additionally, (1) the process economics relied heavily on recovery of rare earth byproducts, (2) thoriumhandling portions of the process could be effectively segregated from rare earth and phosphate handling portions of the process, and (3) thorium and uranium content of waste streams should be carefully managed and eliminated where possible.

May 29, 2020