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By M. Maccagni, J. Nielsen

"Engitec developed the EZINEX® Technology some years ago to recover zinc from oxidized secondary sources. This process works at neutral pH and can take into solution any kind of metal, but iron is rejected and remains in the leach residue. Engitec has also developed the FLUOBORATE System, which is able to recover lead and copper from relevant concentrates. Some iron is leached into solution, but it is controlled through a solution purification bleed treatment. In this paper, we present the two above mentioned technologies. They are very different with regards to the chemical environments and the methods used to control the build-up of iron in solution, but both systems are suitable to treat iron bearing feeds.INTRODUCTIONIn the design of hydrometallurgical processes, the most important issues are the water balance, the filtration and the control of impurities. This is particularly important when the process includes an electrowinning unit. Iron has been one of the most problematic elements to remove, especially in acidic environments.Engitec Technologies has developed several hydrometallurgical processes divided in two different electrolyte lines: the Fluoborate Technology for the recovery of lead and copper from primary and secondary sources and the Ammonium Chloride System based on a chloride electrolyte for the recovery of different non-ferrous metals, among which zinc and lead are the most important. In both cases, iron is present in the feed and needs to be eliminated from the solution. It is not a problem for the quality of the metal produced, but when present in solution, it consumes the basic electrolyte reducing its free concentration which is very important both for both the leaching and electrowinning unit operations. Both process systems are very peculiar, the fluoborate case being much more intriguing."

Jan 1, 2016

By Stuart St. Clair

EARLY in 1936, when the American Petroleum Institute issued -J "American Petroleum Industry," which was a survey of the current position of the petroleum industry, and its future outlook, and the figures for petroleum requirements .for 1950 and 1960 were widely publicized by the several oil journals, the impression was given that the petroleum- industry must be nearing maturity and would by 1950 have passed the high' point of its obligations to business progress in the United States.`' Let -us look at the figures which might conduce, this thought. Referring to p. 32 of the report, the total indicated crude-oil requirements in 1940 are 1,099,000,000 bbl-; for 1950, the peak, 1,109,800,000 bbl.; for 1960 a decline to 1,071,020,000 bbl. This downward trend, then established, is probably expected to continue. And this in the face of a crude production in 1935 of 993,942,000 bbl., 38,858,000 bbl.

Jan 1, 1936

By Wilson Acchar

The accelerated growth of urbanization processes and current environmental concerns brought to light the existing enormous quantity of construction and demolition waste (C&DW). Considering the frequent lack of adequate landfill areas available for the disposal of these materials, their use in the manufacture of ceramic products has been attracting a growing interest from researchers and is becoming common practice, with the consequent relief in public administration concerns for the C&DW appropriate management. This work describes the study of clay-based products added with C&DW collected directly from the construction industry. Samples containing up to 50 wt.% C&DW were uniaxially pressed and sintered in air in an electric furnace (950-1150 °C, 1 hour). Sintered test pieces were characterized by X-ray diffraction, apparent density, open porosity and flexural strength. The results showed that up to 50 wt.% C&DW can be added to the clay material, with no degradation in the final product properties.

Jan 1, 2009

By Richard Peaker, Jens Lichter, Alexander V. Potapov

The recent combination of Computational Fluid Dynamics (CFD) and Discrete Element Modeling (DEM) can provide considerable insight into the performance of flotation cells. One area of interest from a fundamental equipment design perspective has been the influence of flotation cell size and the inflow rate on the metallurgical performance of the cell. One of the specific design objectives when increasing the size of flotation cells, or increasing the feed flow to the flotation cell, is to ensure that the feed stream flowing into the cell does not have an opportunity to bypass the mechanism. This paper describes the initial modeling efforts to quantify the inter-relationship of cell size, inflow rates, and feed and discharge box placement, on the retention time distribution of solids in the flotation cell, and the fraction of particles that bypass the mechanism on a size by size basis.

Jan 1, 2007

By J. J. Carlson

Studies were carried out to determine whether filtration rate changes observed in an iron ore concentrator were due to variations in particle shape. It was confirmed that ores mined from different locations differed in filtration rates by as much as 60%. However, when image analysis was used to quantify the shapes of the individual particles in the filtration feed, it was found that the particle shapes showed almost no variation, and the shapes did not correlate with the filtration rate. It was also determined that the filtration rate variations were not caused by changes in particle size distribution. These results suggest that the differences in filtration rate are due to factors other than size and shape, such as surface chemistry.

Jan 1, 2008

Although bismuth mineralization is spread widely through the Lachlan Fold Belt in New South Wales, broad grouping of the various deposits can be effected on the basis of geographical and geological (age and type of associated rocks) affinities. As a result, significant concentrations of bismuth can be recognized in the Mid-Western granites, Cobar-type ore, the Yass Silurian acid volcanic belt, and the Albury, Bega, Braidwoodand Bathurst districts.In these deposits bismuth generally occurs in minor amounts associated with molybdenite, wolframite, scheelite, cassiterite, chalcopyrite, galena, magnetite, pyrite, arsenopyrite, and native gold. From this group of minerals three broadly defined associations can be recognized.I. Bi-Sn-W-Mo2. Bi-Au( -Te)3. Bi-Pb-Cu(-Au)There may be some interchangeability of these metals, as instanced by occasional Bi-Cu-W-Mo mirleralization, but pyrite and/ or arsenopyrite are usually prominent in all associations.The first two of these associations occur mainly in the form of narrow quartz veins rarely averaging more than O· 3 per cent Bi, although there is often a marked enrichment in ferruginous material in the oxidized zone.Most of these veins occur within or adjacent to granitic rocks of varying ages (principally Silurian or Devonian), although Bi-Au mineralization tends to be related to more basic igneous activity than the Bi-Sn-W-Mo association.The latter is also occasionally developed in pipes, usually coarse-grained and richer in bismuth (as at Whipstick, the principal mine in New South Wales with a production of 343 tonnes of the metal), or in lower grade, but probably larger tonnage skarn deposits. The bismuth-base metal association occurs mainly in Silurian acid volcanic sequences and may also form low grade but large tonnage deposits, such as is possibly developed at Cobar.

Jan 1, 1973

By Jean-Sébastien Lambert, Serge Roberge

"At the end of 2014, Holcim Canada (Demix Aggregates Division) considered the possibility of drillingand blasting a big volume of rock in order to expose a high-quality limestone bench in one of their urbanarea quarries in Laval, Quebec (Canada). The project includes many challenges and has thus been qualified as a high-risk operation."

Jan 1, 2016

Talvivaara deposits, Kuusilampi and Kolmisoppi, comprise one of the largest sulfide nickel resources in the world with 642 Mt in Measured and Indicated Resource categories. TalvivaaraÆs preferred extraction technology is bioheapleaching, which is already widely used for other metals, notably copper and gold. The company has demonstrated the viability of bioheapleaching technology for the extraction of nickel using the Talvivaara ore. The leaching process is heat generating and therefore suitable for the subarctic climatic conditions. The planned annual metal production is 33 000 t of nickel, 60 000 t of zinc, 10 000 t of copper and 1200 t of cobalt. Talvivaara deposits are well-suited for open pit mining due to a thin overburden, favourable resource geometry and a low waste to ore ratio. The ore is relatively low-grade, but well suited to bioheapleaching due to its high sulfide content. Bioheapleaching is a process whereby metals are leached from ore as a result of bacterial action. The bacteria used in the Talvivaara bioheapleaching process are endemic to the area and therefore well adjusted to the prevailing environmental conditions. The solution is collected at the bottom of the heaps and either re-circulated through the heap or fed to metal recovery. In metal recovery, nickel, copper, zinc and cobalt are precipitated from the pregnant leach solution and filtered to produce saleable metal products. After the metals are removed, the solution is further purified and returned to irrigate the heaps. Mining, bioheapleaching and metal recovery techniques for the Talvivaara mine have been tested in a 17 000 t on-site demonstration trial during 2005 and 2006. Subsequent construction of the mine started in 2007 and commercial production in the fourth quarter of 2008.

Jan 1, 2009

By Madgwick J. C

A novel, microaerobic, heterotrophic microbial leaching system for manganese dioxide is described. Mixed natural microflora were enriched by addition of sugars and crude plant nutrItIOnal supplements. Between 84 and 104 mg MnH was solubilized per gram sugar at I per cent (w/v) concentrations for fructose and galactose in the presence of 0.03 per cent w/v dried microalgae (a Chlamydomonas species). Some 42 per cent soluble manganese was dissolved by microbial action on MnO, (3 per cent (w/v) pulp density) using a 10 per cent (w/v) molasses growth substrate.

Jan 1, 1983

By J Guo, K Williams, J Y. Guo, A W. Roberts, M Jones, B Chen

Numerical simulations using the discrete element method (DEM) were carried out to investigate the flow patterns and stress field redistribution at the hopper and feeder interface. The influences of different filling heights, belt speeds and clearances between the hopper bottom and feeder surface on feeder loads were studied. Meanwhile, experiments were conducted by utilising wedged plane-flow hoppers with different configurations and horizontal feeders with various clearances. The simulation results were compared with theoretical values and experimental measurements. In terms of the cases presented in this study, simulation results reveal good agreements with experimental observations regarding the flow pattern. Being similar to the theoretical values, the simulations provide close predictions on vertical feeder loads for steady flow states, but they may show significant overestimations for initial states. Additionally, suggestions are given for relevant simulation parameters based on the comparisons shown in this investigation.CITATION:Guo, J, Roberts, A W, Williams, K, Jones, M, Chen, B and Guo, Y J, 2017. Simulation investigation of flow patterns and feeder loads at hopper/feeder interface, in Proceedings Iron Ore 2017, pp 173–182 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 24, 2017

By W. H. Dickinson

The performance of seven antiscalants spanning a range of chemistries was evaluated for control of calcium carbonate (CaCO3) formation in gold processing applications. Three preferred chemistries were identified which provided up to 100 percent inhibition in static jar tests when applied at 30 ppm dosage. The three products were further evaluated using a model carbon extraction circuit developed for this application. The test circuit enabled direct measurement of calcium carbonate formed on the carbon from a supersaturated solution under dynamic conditions. The antiscalants lowered CaCO3 buildup on the columns by 15 - 26 percent compared to untreated controls. Impact of the antiscalants on the rate and extent of gold loading onto a carbon adsorbent was evaluated in laboratory carbon-in-pulp (CIP) studies. The antiscalants generated a 25 - 35% increase in gold loading at gold extraction efficiencies up to 65%. On-site testing at a gold processing facility demonstrated that 10 ppm of the preferred antiscalant was able to fully suppressCaCO3formation in thickener overflow water.

Feb 27, 2013

By J. T. Nel

The establishment of a pilot plant for the continuous production of titania pigment and nano-titania is discussed. The plant was designed, constructed and operated on the Necsa site. The TiO2 production capacity is 7?10 kg.h-1 by the reaction of TiCl4 and O2at>1000°C. Liquid TiCl4 is sprayed under pressure into a plasma reactor where it evaporates and reacts with O2 to form TiO2. Process optimization has allowed for continuous production without any clogging or blockages. The primary advantage of the plasma-assisted process is the possibility to recover and recycle the chlorine values in high yield as Cl2 for use in the manufacture of TiCl4. The HCl formed in most conventional fossil-fuelled processes makes Cl2 recovery and recycling much more difficult. Particle size distribution analysis of the fine, white product revealed a d50= 125 nm. The raw product consisted of 60% rutile that could be increased to 80?100% rutile by post-annealing. The specific surface area (SSA) of the pigment was 8?20 m2?g-1(BET). According to the CIE colour index the ?whiteness? (L*>95) of the plasma-produced pigment was better than that of several commercially available pigments. The particle size could be manipulated by controlling the TiCl4 feed rate, gas flowrates, and the particle quench rate and residence time. Nano-sized TiO2 powders with a particles size (d50) as small as 50 nm were also successfully produced in this way.

Jan 1, 2010

By A. B. Desai

The construction of 1144 nos. of piles, each 1.5 m diameter, bored-cast-in-situ type and varying in depths from 6.5 to 23m, has been completed as foundation for 26 piers of 548 m long aqueduct across Orsang river to carry 1128 m3 water of Narmada Main Canal of the Sardar Sarovar Project in Gujarat. These piles are socketed 1.5 m into foundation grade rockmass. The portal system of 44 nos. of piles and pile cap at the top for each pier is analyzed considering the portal fixed at bottom of piles. The borings for pile shaft were done deploying reverse mud circulation rigs and also by conventional chiseling and bailing operations. Besides vertical loading tests and lateral loading test on piles, dynamic tests such as low strain integrity testing on 290 piles and high strain pile testing on 17 piles were also conducted. The results indicated that (a) the settlement/ displacement are much less than the prescribed limits (b) good quality of concrete (c) piles are firmly socketed and (d) piles have adequate structural capacity to withstand the design load.

Jan 1, 1996

By D. Fukahori, K. Sugawara, A. Sato

X-ray Computed Tomography (CT) is a nondestructive imaging technique, and its efficiency is widely recognized. In the present paper, X-ray CT is successfully applied for the visualization of water permeation process in rock. A new experimental technique using a tracer, which mainly consists of Potassium Iodide (KI), is proposed, together with the analysis method of the velocity field. The permeation process and the velocity field in rock are concretely visualized and analyzed by considering the conservation of mass of the tracers. La tomographie calculée aux rayons X est une technique de la prise d'images non-destructive et son efficacité est largement reconnue. Dans le présent exposé, la tomographie calculée aux rayons X Radio est appliquée avec succès à la visualisation du procédé de perméation de l'eau dans la roche. Une nouvelle technique expérimentale, se servant d'un identificateur principalement constitué d'iodure de potassium (KI), est proposée avec la méthode de l'analyse du champ des vitesse. Le procédé de perméation et le champ des vitesse dans la roche sont visualisés concrètement et analysés en considérant la conservation de masse des identificateurs. Röntgen-Computer-Tomografie (CT) ist eine nicht-destruktive Bildverarbeitungstechnik, deren Effizienz weit anerkannt ist. In der vorliegenden Arbeit wird Röntgen-CT erfolgreich für die visuelle Darstellung des Wasser-Durchdringungsvorgangs im Fels eingesetzt. Eine neue experimentelle Technit mit einem Tracer, der hauptsächlich aus Kaliumiodid (KI) besteht, wird vorgeschlagen, zusammen mit der Analysemethode des Geschwindigkeitsfelds. Der Durchdringungsprozess und das Geschwindigkeitsfeld im Fels werden konkret visualisiert und analysiert, wobei die Bewahrung der Masse des Tracers berücksichtigt wird.

Jan 1, 2003

The purpose of this report is to describe the work accomplished by Mine Safety Appliances Company under Contract No. H0110845. This contract required the design, installation and testing of a permissible mine surveillance and communication system for the USBM Bruceton experimental mine facility. While much of the design and operational detail of this system can be drawn from the instruction manuals delivered with the equipment, some of it will be repeated here in Volume I for the sake of clarity, but the principal objective will be to report on overall system and subsystem performance and to suggest design alternatives for future consideration. Details of the overall system design will be found in Volume II of this report.

Jan 1, 1973

By Eugene H. Skinner

This Bureau of Mines report describes the fieldwork and subsequent analysis to determine physical properties, stress distribution, and several aspects of rock behavior as a necessary evaluation for a typical mine opening. All work was done at a test site on the 3300 level, Crescent mine, Coeur d'Alene mining district, Idaho. Free field stress beyond the influence of the opening was also determined. Conventional overcore technique with the three-component borehole deformation gage developed by the Bureau of Mines was used in three drill holes. Three field verification tests were performed using a gage newly developed by the Spokane Mining Research Center in an approach herein termed "initial deformation method." Use of this method validated that aspect of overcore theory which predicts that similar deformation effect occurs in the wall rock around the perimeter of an opening in rock under stress. Also described are all drilling procedures and performances. Physical property determinations were made on rock samples obtained from the three overcore drill holes. Twelve physical properties with a total of [532] values were obtained at various drill hole orientations and depths. Exhaustive statistical tests were utilized in the analysis of these physical properties. Further elaborated are statistical inferences based on these analyses. Extensive analysis and interpretation of Crescent mine geology are also described.

Jan 1, 1974

By A. G. Pasamehmetoglu, N. Bolukbasi, O. Koncagul

A study has been undertaken to establish the relationships between the O&K wedge test cutting resistances and the geotechnical parameters of rock materials in the context of bucket-wheel excavator operation. Prediction equations were formed to estimate the cutting resistance from the geotechnical parameters by multiple regression analysis. The cone indentor index, uniaxial compressive strength and Shore hardness parameters have been found to be the most significant predictors

Sep 1, 1991

By A. R. Dover

The Richmond-San Rafael Bridge is a 6.92 kilometer (4.3 mile) long major toll bridge span that crosses the northern San Francisco Bay in a highly seismically active region. Tutor-Saliba / Koch / Tidewater JV was contracted by Caltrans to conduct a comprehensive seismic retrofit. The JV provided geotechnical planning and quality control services as described herein, under normal oversight by Caltrans. Part of the robust foundation retrofit design included the installation of 26 new, large diameter piles, including eleven 3.81 m (12.5 ft) diameter, cast-in-drilled-hole (CIDH) marine piles that were drilled 9.15 m (30 ft) into the bedrock beneath the Bay, where the water depth ranged up to about 21.3 m (70 ft). These reinforced concrete-filled composite piles have a steel shell permanent casing from the bridge substructure pile cap through the water column and 30.5 to 39.6 meters (100 ft to 130 ft) of marine sediments to the top of rock. This paper discusses construction, inspection (ranging from the QA employed in the planning of the CIDH pile installation methods and equipment to the actual construction inspection required for the routine installation of the shafts), problems that were encountered during construction, and the solutions that were developed and implemented. Inspection, particularly with the usual difficulties in the marine environment, coupled with the difficult and complex bedrock conditions was particularly challenging, and ranged from non-destructive testing to "in-water, inshell" diver inspection. Similarly, the complexities of dealing with both the steel casing "riser" and the associated drilled shaft (rock socket) portion of these composite foundation elements created some unusual issues. The paper also presents important lessons learned from the project.

Jan 1, 2008

By David B. George

Kennecott Utah Copper adopted Outokumpu Flash Smelting and Kennecott-Outokumpu Flash Converting in 1995, a process based on granulating high grade copper matte. While nickel mattes and very small quantities of copper matte had been commercially granulated for years, no large scale copper matte granulation system had been built. This paper summarizes the history and benefits of copper matte granulation, the Kennecott design basis, the successful operation for over 10 years and potential problems inherent in some matte granulation approaches.

Jan 1, 2006

By Roger A. Archabal, Omar A. Conte, Gustavo Langoni

This international case study focuses on the rigorous geotechnical interaction and results of a soil improvement program utilized to mitigate consolidation settlements of over 1.5 m [5.0 ft]. The extreme settlement results from very deep, nearly normally consolidated clay and the required high floor loading of a new Logistics Park near Bogota, Colombia. The general subsurface conditions consist of very soft clay extending to depths beyond the 50 m [164.0 ft] explored. A required 1.2 m [3.9 ft] thick fill combined with high floor loads resulted in an applied areal load of approximately 7 ton/m2 [1300 psf] (equivalent to about 4.5m [15.0 ft] of fill). Langan recommended performing a test section to validate the initial consolidation settlement calculations and evaluate possible optimization of the prefabricated vertical drain (PVD) spacing and length. The test section sizing was designed to accurately represent the stresses at depth of the future structures. Extreme settlements of over 1.5 m [5.0 ft] in the center and large differential settlements of over 0.6 m [2.0 ft] were measured between the center and corners of the test section over a relatively short test time. Discussion on the methodology, instrumentation, measured results and future optimization are presented. The recommended soil improvement varied from the standard approaches typically utilized in the area. PROJECT LOCATION AND DESCRIPTION The project site is immediately north-northwest of the city of Bogota in the Bogota Valley. The site is bordered with, and has historically been, farming land bordered to the south by the El Rosal-Bogotá highway. The overall site encompasses about 570,000 m2 [141.0 acres] of gross area and about 484,000 m2 [119.6 acres] of net buildable area. The warehouse complex will consist of 10 very large warehouses with footprints ranging from about 15,000 m2 [3.7 acres] to 30,000 m2 [7.4 acres]. The total building area is about 210,000 m2 [51.9 acres] with most of the remaining areas being paved principal drives, truck parking or administrative parking. The topography of the site is relatively flat and close to final grade in roadway areas. However, the warehouse floors will be raised about 1.2 m [3.9 ft] (equivalent to about 2 t/m2 [370 psf] considering engineered fill) to allow for truck docking. In addition, the design floor loads are heavy and estimated to be up to 5 t/m2 [930 psf] and equivalent to about 2.5m [8.2 ft] of fill. Geotechnical conditions at the site are very weak at depths of 50 meters [165 ft] or more, with soft compressible clays comprising the majority of the soil profile. The Bogota Valley is composed in some areas of very deep alluvial deposits. These deposits have been classified as an important challenge and limitation to the development of high/heavy structures such as the project in question for many years (Orozco, 2006). Soft clay deposits have been encountered even beyond depths of 100 meters [328 ft] in some regions of the Bogota Valley (Sanz, 1994). Extreme settlements can be expected if extensive and high permanent loads (above preconsolidation stress levels) are supported in these thick alluvial deposits.

Jan 1, 2018