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By Venkata S. Buddhiraju

Pelletization of iron ores involves balling on a rotating disc to produce wet pellets and induration of wet pellets on a moving grate to produce fired pellets. The quality of pellets produced and the productivity of the pelletization process depend strongly on the characteristics of the feed to the pelletization disc, especially the particle size distribution and the moisture content. The upstream processes involved in the preparation of pelletization feed include grinding, thickening and filtration of the iron ore slurry. The focus of the present work is the closed circuit wet grinding of iron ores. The circuit consists of a primary ball mill, a regrind mill and a hydrocyclone. A population balance model was developed to predict the grinding kinetics and an empirical model was fitted for the separation of fine particles from the coarse particles in the hydrocyclone. Batch grinding kinetics experiments were performed on a laboratory scale ball mill to obtain the ore breakage parameters which were subsequently used for the simulation of the industrial mills. The models were customized for the industrial operations and the effects of different process variables like feed flow rate, water flow rate, etc., on the size distribution of product from the grinding circuit were studied. Additionally, different circuit configurations were simulated to determine operating conditions that could result in the desirable product particle size distribution. The results of simulation were in close agreement with plant observations and the new circuits explored through simulation have helped in identifying potential opportunities for process optimization and control

Sep 1, 2012

By Stephen J. Harker, John Knights, Randolph A. Pax, Glen A. Stewart

"Mineral samples were obtained from different stages of a mineral processing circuit used to extract the copper and gold rich mineralogical phases. The aim of this work is to characterise the quality of the samples at different stages of processing. The samples were taken of the head grade, tailings, cyclone overflow and the final concentrate.Characterisation of the samples was determined using Cu-Ka X-ray powder diffraction and Fe57 Mossbauer spectroscopy. These measurements will be presented and discussed in terms of the enrichment of the ore, showing the removal of magnetite and quartz through the processing, the final concentrate being rich in chalcopyrite and pyrite. This data also shows the utility of Mossbauer spectroscopy to provide mineralogical phase information directly.Mossbauer spectroscopy is a tool to determine the material phases of a sample. It is a nuclear based technique which measures the amount of attenuation of a narrow Doppler shifted source energy as it passes through a sample. The attenuation depends on the amount of resonantly absorbing material in the nuclear radiation path from the source to the detector. Synchronous detection of the doppler shifting velocity and the nuclear radiation count gives a Mossbauer spectrum. By convention, the energy axis of the Mossbauer spectrum is displayed in units of velocity.Figure 1 shows Mossbauer spectra obtained for a sequence of samples throughout a processing plant. These spectra show the removal of magnetite and the concentration of chalcopyrite and pyrite. Optical microscopy results indicated a significant component of bornite not witnessed with Mossbauer spectroscopy. Closer examination showed that optical microscopy assays over estimate the bornite component."

Jan 1, 2003

By Wieslaw Wszolek, Kazimierz Trybalski, Ryszard Tadeusiewicz

"The present work is an attempt of neural networks application to the description of complex technological processes of useful minerals enrichment. Neural networks are among the most convenient tools that have been added recently to the professional toolbox of modelling specialists, and they are particularly useful in realisation of multiple practical tasks, characterised by great complexity and relatively low amount of available a priori knowledge about the nature of the modelled processes. They are successfully applied in a wide variety of problems related to data processing and analysis, their prediction, classification or process control. The object of the study was the technological site for copper ore enrichment by floatation, being a part of technological line in the Ore Enrichment Plant ZG „Polkowice”, KGHM „Polska Miedz” S.A.The main floatation is described by parameters measured by the supervision and control system, which can be grouped with respect to the functions performed for the object:a) input function: aFG - copper contents in the feed material for the main floatation [% Cu]b) control: LFG I - level in the first section of the floatation unit [%], LFG II - level in the second section of the flotation unit [%], LFG III - level in the third section of the floatation unit [%], LFG IV - level in the fourth section of the floatation machine [%]. These quantities compose the five elements long input vector.c) output function: ? - copper contents in the waste from main flotation (final waste) [% Cu]The measurement data, containing the above-mentioned parameters, have been collected during the normal operation of the plant. The data contain momentary values of the parameters, registered every 10 minutes, covering the period of 196 hours of the plant’s operation (1176 measurements for each quantity).For construction of the model used in the study classical multi-layer perceptron-type neural network has been used, with one hidden neuron layer, trained by the error back propagation method."

Jan 1, 2003

By John A. Herbst, Ming Song, Xiangjun Qiu

"It has been known for sometime that as wear occurs in tumbling mills there is an associated change in mill throughput. These changes have traditionally been simplistically, attributed to “mill volume effects”. New high fidelity simulation (HFS) tools (involving DEM, CFD and Breakage models) are now giving new “microscale” insights into the complex interactions that occur between evolving lifter/liner profiles and breakage. An illustration of this analysis is shown in Figure 1 below.Here we see that after a new lining is installed (Region I) the wearing process reduces the liner thickness resulting in a larger power draw and an associated higher throughput until Region II is reached. By this point the lifter height is reduced significantly changing charge motion (less cataracting) the power begins to decline, but the comminution efficiency increases with this type of “calmer” breakage environment therefore the throughput continues to increase. In Region III the lifter is no longer providing the minimum required charge lifting action, the power and the throughput both drop off significantly. In the last two stages the behavior is especially complex because throughput is not linearly related to power since grinding efficiency is changing.The study described here shows that these new HFS tools allow the design of wear part profiles which will maximize mill productivity over the entire life of liner/lifter systems. A simple example of such a design procedure is shown involving the selection of a sinusoidal profile for a 34 ft diameter SAG mill.The paper discusses how the principles exposed in this simple example can be applied to search for an optimal profile in which non-standard modifications are allowed to compensate for throughput or wear shortcomings of standard profiles."

Jan 1, 2003

By Fernando Concha

"Thickening development and innovation in the 20th Century occurred in two decades periods. From 1900 to 1920, Dorr invented the continuous thickener and the first method of thickener design was proposed by Coe & Clevenger. From 1920 to 1940, the operating variables of continuous thickening were discovered by Comings at the University of Illinois. From 1940 to 1960, the first theory of sedimentation was proposed by Kynch and several authors, Talmage and Fitch, Ysioka and Hasset used this theory to develop new thickener design methods. From 1960 to 1980 Shannon and Tory demonstrated that this theory applied exactly for the sedimentation for small rigid spheres in water and Scott showed that it is not valid for flocculated suspensions. From 1970 to 1990 the phenomenological theory of thickening was developed based on the theory of mixtures. Papers by Kos, Bascur, Thacker and Lavelle, Concha and Bascur, Concha and Barrientos, Auzeris, Buscal and White, Landman, White and Buscal show the application of this theory to thickening and Adorjan presented the first thickener design method based on this theory. In 1980s the mathematical analysis and solutions of Kynch’s model for batch and continuous thickeners was obtained by Bustos. The new Century brought solution to the phenomenological thickening model which was applied to thickener design, simulation and control. The method of thickener parameter determination was improved by designing new laboratory and on-line instruments and advanced control strategies was designed and validated in plants. Structural thickener design produced improved feedwells and feed dilution mechanism, stronger raking mechanism and different thickener shapes according to new ambient requirements, such as high rate thickener and paste thickeners that increase the water recovery. New challenges include better flocculation and advanced control strategies."

Jan 1, 2014

By R. Weyhe, B. Friedrich, H. Heegn

"Nickel-metal hydride batteries (Ni-MH) are storers of electrochemical energy, which have a higher specific storage capacity than lead or nickel-cadmium batteries. The demand for Nickel-metal hydride batteries is increasing rapidly since their market launch in the early 1990's. In 1999 the output of cells exceeded 80,000 tons per year (1 billion cells per year). Today there is no suitable and sustainable recycling process to recover nickel, cobalt and rare-earth metals. The discarded batteries are used in the steel industry as alloy material because they contain nickel. Cobalt and rare-earth metals are lost; they are non-recycleable.In a German governmental funded research project, IME Aachen, ACCUREC Mühlheim and UVR-FIA Freiberg are cooperating in processing as well as in creating a feasibility study. The target of this project is the development of a new recycling process for metal recovery from Ni-MH-batteries. The proposed process consists of a combination of mechanical, pyrometallurgical and hydrometallurgical processing steps.After shredding the steel shell, the various fractions of battery materials are carefully separated by mechanical processing. A hammer mill with one rotor with a perforated discharge grid of 20 mm opening, was found to be suitable for crushing the batteries to release the active mass of electrodes for metallurgical processing. The ground material is wet screened at a mesh size of 0.5 mm; thus a fine fraction is obtained with valuable components such as Ni, Co, and RE and an oversized fraction consisting of a mix of iron chips, electrodes grids, plastic chips, paper, and flocculent material of separators. The organic components are avoidable when there is a thermal step at the beginning of processing batteries.The separated fine fraction is smelted in an electric arc furnace. Any pyrometallurgical process relies on a suitable slag system. In this specific case, the process has to allow separation of nickel and cobalt as metal from the rare-earths almost quantitatively, collecting the rare-earths as well as impurities e.g. as oxides. The products are a nickel-cobalt alloy and a slag phase enriched with rare-earth oxides for further treatment to ‘mischmetal’."

Jan 1, 2003

By Zhongxue Li, Cuiping Li, Xiaoyun Hu, Yiqing Zhao, Huaying Wang

"Under the auspices of World Federation of Engineering Organizations’ Committee on Engineering and the Environment (WFEO-CEE) and Society for Mining, Metallurgy and Exploration (SME) Task Force on Sustainability and Mining (TFSM), and aimed at helping raise global understanding on and promote capacity building of risk management, this paper presents a framework and prototype of toolbox or knowledge warehouse for facilitating the application of risk analysis, mitigation and management techniques (RAMT) in the mining and minerals sector. The conception, design and implementation of the intended system of knowledge warehouse of risk analysis, mitigation and management techniques (KWoRAMT) are outlined. The system architecture of KWoRAMT is based on a browser/server (B/S) structured platform with web oriented interfaces and composed of data base, knowledge warehouse, searching mechanisms, and risk assessment methodologies. The knowledge sources for KWoRAMT will come from the TFSM expertise and Internet, including laws and regulations, codes of practice, standards, guidelines and best practices. The functions and outcomes of KWoRAMT consist of guided navigations with web links, categorized risk tools, annotated best practices with cases, and integrated risk approaches and solutions based on typical risk methods. Risk categories include those impacting on mine safety, mine occupational health, and mine community environment throughout the whole of mine life cycle from exploration, construction, and exploitation and processing to post-mining closure. Mining associated hazards will be identified and linked by vulnerability onto risk receptors through pathways. Risk management techniques for assessing impacts and consequences of mining induced hazards will be categorized with their pros and cons or strengths and weaknesses. Best practices and significant cases including experiences and lessons with problems, solutions, and recommendations on how solutions would be derived will be illustrated. Integrated risk approaches based upon typical methods will be developed for alternatives and actions."

Jan 1, 2014

By Ricardo Duque-Soto, Gonzalo Montes-Atenas

The depletion of water resources has posed an enormous challenge to the continuity of many mine sites, particularly those located in arid zones worldwide. In Chile, the use of seawater has been foreseen as one possibility to solve this problem. Nevertheless, the direct use of high ionic strength solutions such as those present in the sea has been found to have some drawbacks. Specifically, rhe extraction of copper from complex ores using high ionic strength solutions such as that of seawater has become one of the most relevant topics in the field of copper hydrometallurgy. This study aims to determine the effect of the degree of salinity on copper extraction kinetics in mixed oxide-sulfide ores. A leach protocol was implemented to study the extraction kinetics, varying the degree of salinity of the medium and the temperature. A thermodynamic model was developed to explain differences in the metal extraction. It was found that the ionic strength impacted positively the copper extraction, probably due to the reduction of the effective concentration in solution due to ionic interactions enhancing the diffusive mass transport of copper ions. This effect is observed to be enhanced when up to an overall salinity values close to 20gpl.

Jan 1, 2014

By Douglas Fuerstenau

"Comminution not only is the major energy cost in mineral processing but it also can limit the grade of ores that can economically be processed. Rittinger first postulated that the energy for comminution is proportional to the new surface produced. Because most of the strain energy needed to initiate and propagate cracks in particles cannot be recovered, researchers reported woefully low comminution efficiencies. Recognizing this, Schoenert proposed that the baseline for assessing comminution efficiency should be the mechanical energy needed to break single particles. After extensive single-particle studies, Schoenert turned to comminuting beds of particle in piston dies. Finding particle-bed comminution to be energy efficient, he had the brilliant conception of making the process continuous, namely his invention of the choke-fed high-pressure roll mill (HPGR). Practical comminution involves masses of particles, which can lead to energy efficiencies far less than that of single-particle breakage. A three-way classification of grinding modes in terms of the mobility of the particle mass provides the necessary insight into the low efficiency of different comminution machines: namely, single-particle breakage, confined particle-bed grinding (HPGR), and loose-bed grinding (ball mill). Examples are given for determining and comparing comminution efficiencies. The size distribution of comminuted products become self-similar, and a single parameter, the median size, can be used to quantify the extent of comminution. The reduction ratio, expressed in terms of the mean size of the feed and product, varies linearly with expended energy and the slope of such plots is a measure of the grindability of the mineral. This approach clearly gives the order of energy efficiency as single-particle > particle-bed > loose-bed comminution. HPGRs are more efficient at low reduction ratios but lose that advantage at higher reduction ratios. Extensive hybrid grinding experiments carried out with our instrumented ball mill and HPGR showed significant energy savings by first comminuting the material in the HPGR and followed by the ball mill. At Cerro Verde an industrial-scale hybrid HPGR/ball mill system is reported to have a 13 percent energy savings over a SAG mill/ball mill system."

Jan 1, 2014

By Camilo Uribe, Williams Calderón, Gonzalo Montes-Atenas

In industrial hydrometallurgical operations, the leaching process is often implemented via heap or dump leaching operations. During the pile up of these massive amounts particles a porous material is then formed. The manner it is constructed is crucial since it will define the permeability and other parameters determining the flowrate of leaching solution across the material. This study aims to estimate how the unsaturated permeability of the staked porous structure confined in a column-like geometry varies with and without particle size segregation. The piling up will be modeled using the Rocky® software. Different disposals of particle size distributions across the column will be simulated and their effect onto the overall column unsaturated permeability will be estimated. It was found that when the belt speed increased, the particle segregation in the column also increased. This condition is expected to improve the permeability of the porous structure in the column, probably due to the smaller compaction of larger particles when they are located at the base of the column and maintain a suitable porosity to permit leaching flowrates relatively high, suggesting better extraction results. The opposite was observed when small particles were preferentially located at the bottom of the column. These results are expected to provide an insight towards what is the best way to construct heaps and dumps.

Jan 1, 2014

By Georg Unland, Thomas Wegner

"Impact crushers are widely used in different industries to crush materials which can vary from soft to hard and from ductile to brittle. However, the sizing of impact crushers is still based rather on empirical than on scientific approaches. Therefore, a test rotor was developed in order to investigate the principles of comminution by impact. Rocks of diabase with different diameters were used to gain the crushing properties with the following results:RESISTANCE AGAINST CRUSHINGLikelihood of BreakageThe likelihood of breakage is a function of the impact velocity and the particle diameter. The likelihood increases with higher velocities and larger diameters. Maximum Crushing ForceThe crushing force is related to the area of projection of the rock. The smaller the particles and the higher the velocities the larger are the maximum related contact forces.Contact TimeThe contact time increases with the rock diameter whereas the influence of the impact velocity is neglectable.Mass Specific Crushing WorkThe mass specific crushing work decreases with the particle diameter and increases with the impact velocity."

Jan 1, 2003

By D. P. Hatfield, G. de Jager

"Recent developments in image analysis techniques and the power of computer hardware have spurred international interest in the potential uses of image analysis techniques in a range of industrial applications. One of these applications is the control of the complex flotation process. Despite years of work, the flotation process is still poorly understood. Current attempts to control flotation cells focus on consistently duplicating the control achieved by human operators.In human control of flotation two of the dominant visual cues are the froth flow speed and the froth stability. These two factors can be measured and inferred respectively from image analysis of video of the froth surface. Two important hydrodynamic variables for control of the flotation process are the air addition rate and the level of the froth pulp interface.The current work focuses on the relationship between froth flow speed and the rate of recovery of concentrate from a flotation cell. Results are presented that show a strong relationship between flow speed and concentrate yield. These results include tests where the conditions in the cell were not changed, as well as tests involving changes to the cell level and air addition rate. Preliminary results are presented which show a correlation between froth stability and froth percent solids.Future developments of the system will include comprehensive froth texture typing, colour space and stability analyses."

Jan 1, 2003

By Paul W. Cleary

"Particle scale simulation of industrial particle flows using DEM (Discrete Element Method) offers the opportunity for better understanding the flow dynamics leading to improvements in equipment design and operation that can potentially lead to large increases in efficiency, throughput or product quality. DEM has been used for modelling many industrial applications, particularly milling. This includes ball and rock motions and power consumption in ball mills, AG and SAG mills, vibrational segregation, flows in rotating drums, operation of dragline excavators and hopper flows. In mineral processing, DEM has been concentrated on mills because of their critical importance. However DEM also offers the opportunity to improve many other parts of mineral processing operations. These areas often do not receive the attention that the key comminution equipment commands, but can become critical when they fail or under-perform. Importantly their assessment/improvement using DEM is often much more feasible because of smaller problem sizes and the absence of poorly understood physics such as breakage. In this paper we describe DEM simulations of four important pieces of non-comminution equipment that are commonly found in or near mineral processing plants (these are shown in Figure 1):"

Jan 1, 2003

By Fu Ping-Hao, J-P Franzidis, Sergio Mauricio Vianna, Ewen Silvester, Emmy V. Manlapig

"Over the last 5 years, an ambitious project has been undertaken at the Julius Kruttschnitt Mineral Research Centre (JKMRC) aiming to isolate, study and, if possible, model the effect of particle size, liberation and collector adsorption density on the floatability of mineral particles. As part of this project, we have conducted highly controlled flotation test-work, combined with state-of-the-art solution and surface analytical techniques such as High Performance Liquid Chromatography (HPLC), Time of Flight Secondary Ion Mass Spectroscopy (TOF-SIMS) and detailed mineralogical analysis to fully characterize the flotation behavior of a natural ore.The flotation tests were undertaken using a high-grade lead-zinc ore from BHP-Billiton's Cannington mine (Australia) in a specially designed continuously operated laboratory scale flotation rig. Solution and adsorbed collector concentrations were measured independently during the course of the flotation tests using HPLC based ex-situ techniques. Liberation studies were performed using the JKMRC Mineral Liberation Analyser (MLA) on selected size intervals of different streams to estimate the specific surface area of galena. These results were used to calculate the collector adsorption density (collector coverage) on galena particles, with the eventual aim of developing a mathematical model describing the relationship between pulp chemistry, feed mineralogy, and floatability of galena particles."

Jan 1, 2003

By Paula Olea, Gonzalo Montes-Atenas

Froth flotation operation is a large tonnage process aiming at selectively separate economically valuable minerals from gangue material. The wellbeing of an industrial froth flotation operation has been historically assessed and understood in terms of many variables known to somehow affect the process performance. Among these variables, air dispersion have been pointed out as key to secure the correct transport of hydrophobic particles to the froth phase and, then, to the concentrate. One of the classic parameters assessed when evaluating the air dispersion in flotation tanks is the superficial gas velocity. Many reports have focused on studying the superficial air velocity profiles across the pulp phase and theories have been based on the fact that the measurements should be performed in the so called "quiescent zone", which is a volumetric region inside a flotation cell of difficult determination. The hypothesis behind this research work is that the reporting of particles to the concentrate would provide a better correlation with the effective air flowrate pattern created in the froth phase. The aim of this study, as a first step towards developing a flotation model fully froth phase-based, is to estimate the effective surface area used in a flotation cell derived from results obtained with a specific setup at laboratory scale. The methodology considers running a thin lateral flotation cell cut at different superficial air velocities, with and without particles. It was found a non-linear correlation between the superficial air flow rate and the characteristic distance between the vertical wall next to the cell lip and the cut point where the foam or froth flowrate almost stops contributing marginally to the overall amount of solid particles transferred to the concentrate. The presence of hydrophobic particles reduced the mobility of the froth phase reducing the characteristic distance.

Jan 1, 2014

By Alejandro Rubio-Lopetegui, Gonzalo Montes-Atenas

The occurrence of Enargite (Cu3AsS4) in hydrometallurgical plants bears a number of challenges. One question lies on how Copper and Arsenic can be selectively extracted from the solid surface structure when immersed in aqueous solution. The leaching of Enargite in ambient conditions has been extensively studied; nevertheless, challenges regarding the process kinetics and surface structures enabling the extraction process remain ill-understood. Prior knowledge indicates that different conditions of pH, Eh, temperature, speciation of the aqueous phase or variations of these parameters defines the overall rate at which metals and other elements will be transferred to the solution. One aspect that the research studies have seldom addressed involves studying the main features of the surface structures formed during the leaching process at the outmost surface atomic layer. Such structures will mediate between the solid bulk and the solution to undertake subsequent stages of leaching process. The aim of this research work is to critically analyze the state of the art of Enargite electrochemistry from the mediator formation-dissolution mechanisms standpoint occurring at the mineral-solution interface. The most probable mediator species reported in the literature were found to be: Arsenolite and Sulfur (acidic media), Covellite (acidic and alkaline media) and Tenorite (alkaline media). As a result of this analysis, it was observed that the surface speciation was not in full agreement with the previous knowledge suggested to explain Enargite leaching reactions and, therefore, modified Eh-pH diagrams are presented. The acquired insights on the surface structures rising from the Enargite-aqueous solution interactions is further revised to provide new experimental protocols towards selectively separating Copper and Arsenic through hydrometallurgical paths.

Jan 1, 2014

By Susanna A. C. Stadler, Chris Aldrich, Jacques J. Eksteen

"Slag foaming occurs in several pyrometallurgical processes. These processes include steelmaking in basic oxygen steelmaking furnaces and electric arc furnaces as well as various non-ferrous operations like sulphide smelting/converting and base metal slag cleaning. Although slag foaming in steelmaking processes has been extensively researched, little attention has been given to slag foaming in non-ferrous operations. Slag foaming phenomena are complex because often the system consists of three or more phases. With this in mind, factors previously identified as influencing slag foaming were investigated. These include the slag basicity, physical properties of the slag, namely viscosity, surface tension and density, the formation of particles due to undercooling of the slag and the FexO concentration in the slag.Slag foaming was investigated in a vertical tube furnace. The different slags were contained in alumina crucibles and bubbling argon gas through the molten slag induced foaming. The foam height was measured by using stainless steel probes and a voltmeter. The conductivity of the slags made it possible to measure the foam height from the position of the probes when the electrical circuit was completed. Slags were foamed at different temperatures to investigate the effect of solid precipitates.The effect of increasing FexO concentration was found to decrease the foam index due to lower viscosities, but higher surface tension depression appears to have led to increased foam index values at high FexO concentrations."

Jan 1, 2003

By Katsunori Okaya, Toshio Inoue

"Movement of mill charge in the centrifugal mill is essentially dissimilar from that in the vibration mill with circular path despite the apparently similar mode in the motion of mill body. This dissimilarity is the reason for the substantial advantage regarding the comminution intensity of the centrifugal mill over the conventional vibration mill accounting approximately to one order of magnitude.Bradley et al. (1983) developed a math model regarding the mill charge as a lump. This model is presented in a simple equation with which motion of the mill charge can be predicted in terms of the parameters describing the specification and the operation of the centrifugal mill. This equation can be used to explain the power draft of the mill as well as the stability of mill operation. More recently, on the other hand, a numerical simulation technology called discrete element method (DEM) has become a vital vehicle for estimating the motion of the grinding media in the mill. The authors developed a mill simulator called ‘Mill Solver’. Mill Solver is designed to simulate various types of mills including centrifugal and vibration mills. The principle of this simulator is to calculate individual kinetic events of interaction of balls in the mill in a minute time interval, hence the mill performance can be constructed for estimation."

Jan 1, 2003

By Ljudmil S. Grigorov, Eric Forssberg, Hanumantha Rao Kota, Robert J. Pugh, Lidia B. Alexandrova

"The effects of mixed collectors on some physicochemical parameters (thin film lifetime, kinetics of expansion of the three-phase contact, equilibrium three-phase contact angle and surface tension) involved in the elementary act of flotation were investigated experimentally.We have used the microscopic thin balance developed by Scheludko et al (1970) to study the stability and interactions within the thin film between the silica surface and air bubble with (i) a long chain C10 amine and (ii) a cationic/anionic surfactant systems consisting of mixtures of a long straight C10 chain amine with long straight chain C8, C10 and C12 sulfonates at 1:1 molar ratio. The experiments were performed at a range of concentrations at pH 6.5. The equilibrium contact angle was measured with a microscope technique using the modified Mingins-Sheludko method (Mingins and Scheludko, 1979). The surface tension was measured by the method of Wilhelmy (Adamson, 1960). It was found that the mixed surfactants caused lower contact angles, lower rates of the thin film rupture and longer film lifetime, compared to the pure amine system."

Jan 1, 2003

By Katarina Theander, Robert J. Pugh

In the flotation process, control of the stability of the froth is extremely critical. In the case where the froth is too stable then mechanical entrainment of particles can occur but in the opposite case, where the froth is too unstable and difficult to skimm-off, then a reduction in recovery can result. In minerals and deinking flotation, commercial fatty acids are used and may act as both both collectors and frothers. However, frequently the fatty acids are mixed with nonionic ethoxylated surfactants to give more effective froth control and increase the flotation performance. It is of interest to note from the surface chemistry literature, that such mixtures may cause synergistic effects in surface activity which may explain changes in bubble size, foaming and carry over of particles. In the present study, we have carried out foaming and drainage experiment with oleic acid and model nonionic surfactants; hexa(ethylene glycol) mono-dodecyl ether, C12E6 and tetra (ethylene glycol) mono-dodecyl ether, C12E4 both in separate and mixed systems. Frothing was carried out in a column, equipped with a series of conductivity electrodes which enabled the water content of the froth to be measured along the length of the column, during various stages of the drainage process. The variation in water content of the froth enabled the process to be characterised by distinct three stages; (a) an entrainment state where the water transfer from the bulk phase to the froth was dominant (b) a steady state when entrainment and drainage are balanced and no water is transferred to or from the froth and (c) the drainage step when drainage predominates and the volume of the bulk phase increases. We also carried out surface tension measurements on the oleic acid/ nonionic systems and related the results to the frothing and drainage performance. From the surface tension data, the adsorption interaction parameter of the mixed systems at the air/solution interface could be calculated and was found to depend on the oleate/ nonionic surfactant ratio. This value was related to the frothing performance and the results indicated a positive interaction parameter for the mixed surfactant systems which could explained the synergistic effects in frothing performance.

Jan 1, 2003