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By T. Bednarski, T. McCallum, L. Moya, L. Nsenga, B. Mbao

The accumulation of solids in solvent extraction (SX) circuits can cause problems with the physical and economic performance of the operation. These solids are responsible for the formation of crud, a solid stabilized emulsion containing organic, aqueous, air, and fine solid particles. The build-up of crud in SX settlers can limit SX operation throughput, require plant downtime, lead to higher organic losses, or result in higher aqueous in organic entrainment (all of which can have a significant, negative economic impact). Current practices for crud management are typically reactive. Crud is physically removed after it has been allowed to build to excessive levels in the circuit and processed mechanically using centrifuges or filtration. A new proactive solution has been developed to prevent crud formation and build-up. Low ppm dosage of an additive, ACORGA® CR60, into the pregnant leach solution (PLS) has resulted in reduced crud formation in pilot and commercial scale for a variety of PLS streams. This paper will review results from operations in North America and Africa, covering heap leach, concentrate leach, and agitated leach feeds. INTRODUCTION Crud formation and build-up in solvent extraction (SX) circuits has been a long time topic discussed and claimed to be crucial to the whole hydrometallurgical process (Liu, et al, 2006). Crud formation is present in all SX systems be it copper, uranium, zinc, etc., and Ritcey (1980) defined crud as a stabilized emulsion containing organic, aqueous, and fine solid particles. The ore type and feed composition is a major determining factor of crud formation and typically contains Si, Al, Fe, P, and sulfates (Ritcey, 1980). It typically builds at the interface between the organic and aqueous, but can also be observed as floating crud on the surface of the settler, or bottom crud, which is common to find in circuits treating agitated leach feeds such as in Africa. As crud formation has been unavoidable, many of the current crud management techniques are reactive, allowing crud to form and build in SX circuits. Once it does, it is removed and treated via different mechanical techniques, typically through some type of filtration or three-phase centrifuge, to remove the solids and recover the organic phase trapped within the emulsion (Ritcey, 1980). Automated pumping systems have also been designed and are frequently used in North American operations. The time and capital required to react to crud formation can be an overwhelming aspect to SX operation.

Jan 1, 2019

By T. J. Wells

THE blast furnace is the base of the steel industry, since there is no commercially practical way of converting iron ore directly into steel. In three hundred years, the blast furnace has developed from a small unit using charcoal as fuel and producing about one ton of iron in twenty-four hours to a furnace making upwards of 1,500 tons a day. The principle of the blast furnace is briefly this: A descending column of stock, consisting of ore, fuel, and flux, is met by an ascending stream of gases, consisting in part of gases formed by the combustion of the fuel and in part of pre-heated air which is blown into the lower part of the furnace. The flux combines with the impurities in the ore and the ash in the fuel to form slag, which is drawn off as liquid.

Jan 1, 1943

By Arsenio Enriquez, Adrian Deneys, Ryan Walton, Jenny Esker

NOx emissions at the Rio-Tinto Kennecott Copper (RTKC) smelter, near Salt Lake City, Utah, are regulated to a compliance emission limit at the Main Stack of 15.9 kg/hr on an annual rolling average. The paper discusses RTKC efforts and improvements, particularly related to the anode furnace operations, since the Smelter modernization in 1995 to comply with the air quality approval limit. This includes replacement of gaseous ammonia to Steam-Gas Refining (SGR) system during the copper reduction stage, upgrade anode furnace oxygen-fuel burner from Praxair’s Stabilized Jet (S-J) to Jet Lance (J-L) technology, development and implementation of operational best practices and continuing to investigate and evaluate NOx control technology and strategy in the industry. In early 2016, changes to Praxair J-L Burner technology on both anode furnaces, utilizing wider lance spacing, was adopted and further improved NOx emission levels well below the compliance limit. INTRODUCTION Since the establishment of the Clear Air Act in 1970, the Environmental Protection Agency (EPA) has been regulating emissions of nitrogen oxides (NOx) to reduce impact on public health and the environment (USEPA, CAA, USEPA, NAAQS). As a requirement of the Clean Air Act, the EPA evaluates the standards for NOx and criteria pollutants on a periodic basis and as a result, standards have been revised and ultimately reduced over time (USEPA, CAA, USEPA, NAAQS, UDAQ, SIP). To remain competitive with changing regulations and in conjunction with Rio Tinto environmental standards for continuous improvement, the RTKC smelter has been motivated to research and implement NOx control strategies. NOx health and environment impacts NOx refers to a group of seven compounds including the most common, nitrogen dioxide (NO2). (USEPA, NO2). The EPA enforces both short-term (1-hr average) and long-term (annual average) standards for NO2 to protect against associated respiratory system impacts. Short-term exposure of elevated NO2 concentrations can aggravate respiratory diseases and lead to symptoms such as coughing, wheezing or difficulty breathing while longer exposures may contribute to the development of asthma and potentially increase susceptibility to respiratory infections. (USEPA, NO2) Additionally, NOx is necessary in the formation of ozone and particulate matter less than 2.5 microns (PM2.5). Ozone concentrations can negatively impact lung function and in some cases, contribute to chronic obstructive pulmonary disease. (USEPA, Ozone) The particles associated with PM2.5 can reduce lung capacity and aggravate heart conditions. (USEPA, PM2.5) For all NOx related pollutants, children and the elderly are generally at greater risk for the health effects. (USEPA, NO2, USEPA, Ozone, USEPA, PM2.5)

Jan 1, 2019

This paper states how alloy and welding advances have made possible the rapid development of the use of aluminum in the construction of equipment for earth moving and off -highway rock hauling. The main details are given regarding the construction and field testing carried out on an aluminum prototype body. The test results of strain gauge readings are analysed, and a description is given of how these have been applied in subsequent designs. The increase in the number of aluminum units put into the various types of service in Canada, as well as the problems encountered, is described, and the experience gained from five years of field service is discussed in some detail. An assessment is also made of the durability of the e units. The economics of using aluminum, together with the current development position, are reviewed, and predictions are made for considerable future increases in the use of aluminum units in open-pit and off-highway operations.

Jan 1, 1964

By I. Donohue, M. Pearson, E. Barrette

"This paper presents the technique and benefits of the finite element approach for designing the refractory lining in pressure oxidation autoclaves. One-dimensional equations are used to develop an initial refractory design. ANSYS Parametric Design Language (APDL) scripts are then used to build and analyse a more accurate three-dimensional finite element model to verify the refractory thickness, determine weld overlay requirements, and assess mechanical stability. The APDL scripts provide a cost effective means to quickly evaluate various boundary conditions and multiple designs to determine the optimal lining configuration and nozzle layout.INTRODUCTIONNew ore processing facilities demand increased capacity, requiring hydrometallurgy processes that have larger reactor vessels operating at higher pressure and temperature. Many pressure hydrometallurgy operations require vessels with an impermeable membrane and one or more courses of refractory or ceramic brick. The membrane provides corrosion protection for the vessel shell and the brick provides thermal protection for the membrane. Designing a refractory lining with an economic service life as a thermal barrier requires the refractory to be erosion resistant, chemically compatible with the process fluid, and mechanically stable. A fundamental understanding of the factors affecting the lining system is essential as designs move further away from the industry’s experience base.During basic engineering the refractory lining design is developed using one dimensional cylindrical conduction equations for heat transfer and classical hoop stress-strain relationships for determining mechanical stability. The results of the thermal calculations specify the refractory thickness that should prevent the membrane temperature from exceeding the design limit. Mechanical stability of the lining is determined by examining the sensitivity of lining stability with respect to various parameters. There are three criteria that must be satisfied to conclude mechanical lining stability:"

Jan 1, 2012

By Narasimha Mangadoddy, Teja Reddy Vakamalla

"Vertical hydrocyclones are very common in most of the comminution circuits. Inclined cyclones are also found for specific mineral processing applications. In this work, Computational Fluid Dynamics (CFD) technique and experiments are used to find the reasons behind the inclinations effect on hydrocyclone performance characteristics. The water and silica slurry experiments are conducted with 75 mm hydrocyclone at different inclined positions (0-600) to the vertical plane. Corresponding two-phase numerical simulations are performed with Volume of Fluid (VOF) model coupled with Large Eddy Simulation (LES) turbulence model. Multiphase simulations are carried out with Algebraic Slip Mixture model modified with lift, drag forces and Newtonian rheology model corrected with fines for various feed solids concentration. A raise in the under flow solids percentage, cut diameter and a reduction in the water split is observed with the inclination. Electrical Resistance Tomography (ERT) and High Speed Video (HSV) data is used to cross validate the inclined cyclone’s CFD air-core and solids concentration data. Predicted efficiency curves are found in a close agreement with experiments for all the inclinations. Comparison of experimental and predicted flow data clearly follows trend with the literature. Key words: Hydrocyclone, CFD, ERT, inclination, water splitINTRODUCTIONHydrocyclones are devices used to separate or classify particles based on particle size difference in the water medium. Their usage is very wide in chemical, petroleum, mineral and bio industries due to its structural simplicity, high throughput, small volume, low cost and maintenance. Cyclone mainly consists of a cylindrical section followed by a conical section attached to a single feed inlet and two product outlets named vortex finder and spigot. It works on the principle of centrifugal sedimentation. The slurry is fed tangentially to the hydrocyclone, in which larger particles are moved towards the wall and separated by centrifugal forces to the underflow. Smaller size particles follow liquid due to drag forces to the overflow. With its simple structure, the flow behavior inside the hydrocyclone is quite complex. Vertical cyclones are common in practice in most of the comminution circuits. Horizontal cyclones can be found in extreme cases which are for installation convenience rather than for process reasons. Inclined cyclones are also present for specific mineral processing applications. In coal preparation plants, dense medium cyclones are operated near to horizontal inclination of 20 degrees to allow large spigot sizes for sinks removal, self-drain of contents during shutdown. In the phosphate removal, dense medium cyclones are inclined with an angle between 0-90 degrees for better separation of ore and tailings (Liu Feng et al., 2006). Even in the clusters, hydrocyclones are mounted with an inclination around the feed distributor for uniform distribution of slurry and under flow collection. It is believed in mineral processing industry that inclined cyclones would fetch the benefit in number of ways while classifying the material by size. Gravity influences the cyclone performance through the air core size and position variations in large cyclones. It also favours the cyclone operation at coarser cut points without varying any other design and operating parameters. Minimizing fines misplacement to underflow can be achieved with inclination."

Jan 1, 2016

By A. Villanueva

The effect of High Pressure Grinding Rolls (HPGR), as a preceding stage to a conventional ball mill circuit at PT Freeport Indonesia?s C1/C2 concentrators, has been studied in terms of downstream grinding efficiency and circuit performance. When milling the product from the HPGR, mill capacity increased by 21% for the same product grind size, when compared to processing similar ore from a conventional crushing circuit. This achievement is a result of several reasons, among them: reduction in feed size (F80), fines generation beyond the proportional reduction in F80, reduction in ore hardness induced by HPGR comminution mechanism, optimization of the recycle system of the HPGR and ball string optimization in the ball mill circuit given the new feed to the mill.

Jan 1, 2012

By K. C. Corin, Z. G. Song, J. Y. Liu, M. W. Zhang, State Key Laboratory of Mineral Processing-BGRIMM, J. G. Wiese

"In the present study effect of grinding media on flotation of two mineral systems have been investigated, viz. sulphide minerals (including a pure chalcopyrite and pyrite mineral, and two different base metal sulphide ores), and oxide minerals (quartz, hematite and cassiterite). It was shown that mild steel media milling produced lower recoveries in the case of chalcopyrite and pyrite, as compared to the case of milling using ceramic media. For oxide minerals, the effects of using mild steel media as opposed to ceramic media were not as significant as was for the sulphides, although, after mild steel milling, at acidic pHs their recoveries were significantly reduced. For two base metal sulphide ores, viz. Nkomati and Dexing ores, the differences resulting from different milling media , although marginal, were opposite for each of these ores.For oxide minerals XPS showed that oxides and hydroxides of iron (e.g. FeOOH) adsorbed on the surfaces of the minerals. In the case of the Nkomati ore, adding Fe2+ or F3+ ions after milling with chrome steel media resulted in reduced talc (gangue) recovery, but increased water recovery and reduced concentrate grades. Further investigations are currently in progress to examine the Fe ions effect on the talc surfaces and froth properties.INTRODUCTIONGrinding of ores is necessary to liberate the valuable minerals from its gangues to allow for their selective recovery during mineral processing such as flotation. The grinding process inevitably involves contact of the ores with the surface of the grinding device and the grinding media. Accompanied by grinding, several phenomena can occur including the grinding medium wear, formation of precipitated species on the ore surfaces, chemical reaction, galvanic effects, changes in the Eh of solution, etc. There is a considerable body of literature on the differences observed in the flotation of various ores after milling using various grinding media. Laboratory studies have used balls or rods made from mild steel, ceramic, stainless steel or chrome steel to investigate the effects of different grinding media on mineral flotation. It is found that the interactions between the ore and the grinding environment can affect flotation separation of sulphide (Wei and Sandenbergh, 2007; Bruckard, 2011), oxide (He et al., 2014) and carbonate minerals (Song, 2009 and 2010). For example, mild steel milling produces relatively high concentrations of Fe ions in the pulp, affecting the recoveries of minerals compared to the case of ceramic media. On the other hand, the stainless steel media or chrome media are reported to be beneficial to the recovery of sulphides, when compared to the cases of using mild or carbon steel media (Rey and Formanek, 1960; Peng et al., 2003a,b; Huang and Grano, 2006; Bruckard, 2011). It is not clear, however, whether these Fe ions may affect the surface properties of the minerals involved or the general pulp/froth behaviour and hence their floatability. In addition, in the study of an low-S PGE ore carried out by Miettunen et al. (2012), forged media grinding in the CO2 atmosphere led to the highest Pt and Pd grades and recoveries, but the high chrome grinding media gave lower flotation recoveries than those using the forged media."

Jan 1, 2016

By S. Masambi, S. M. Bradshaw, C. Dorfling

The presence of iron in base metal leach solutions complicates nickel and copper recovery processes. Leach solutions are commonly purified by precipitating iron as hematite, jarosite or goethite. Fast oxidation of ferrous to ferric is an important step to remove iron by precipitation at low pH values. This study reviews the ferrous oxidation mechanism and reaction rates in chloride media using molecular oxygen. This work contributes to the development of a better understanding of iron precipitation processing steps, which continues to be an important matter in hydrometallurgy. The specific objectives were to investigate (1) the effect of key process variables (acid concentration, copper concentration, and temperature) on the rate and extent of ferrous oxidation by dissolved oxygen and (2) the oxidation mechanism by varying chloride and hydrogen ion concentrations separately. Batch oxidation tests were performed using synthetic chloride solutions containing 45 g/L Fe and 3 g/L Ni at 50 and 80°C, dissolved Cu concentrations (0.3 to 3 g/L) and HCl concentrations (2 to 4.6 M). Regression analysis indicated that the significance of the effect of different variables on the extent of oxidation achieved after five hours decreased in the following order: HCl concentration > Cu concentration > temperature. Increasing the HCl concentration from 4 M to 4.6 M caused the degree of oxidation achieved after two hours to increase from 58.3% to 98.1%. The catalytic effect of dissolved copper on ferrous oxidation was more significant at low acid concentrations. Experimental data suggest that rapid oxidation of ferrous is possible at high HCl concentrations for two main reasons. First, the formation of ferrous chloride complexes allows ferrous oxidation to proceed without the formation of superoxide as an intermediate product (the rate limiting step in dilute acid solutions). Second, the formation of ferric chloride complexes stabilises the oxidation product.

Jan 1, 2016

By R. W. Thompkins

In order to evaluate the impact of air quality control on mine design, a few examples are given of cases in wh.ich ventilation has affected the economics of the total design problem. Principles for the drainage of gas contaminants are shown, and the contamination control problems created by differential pressures in complicated booster fan installations are discussed. The paper also deals with the use of advanced mathematics for solving some of the ventilation problems likely to be encountered.

Jan 1, 1967

By Kéiko H. Hattori, Neil T. Pettigrew

"Abstract- The Legris Lake Complex is a northeast-trending, 7.3 km long by 3.5 km wide, maficultramafic intrusive complex located in the western Wabigoon Subprovince of the Archean Superior Province. It is one of a series of mafic-ultramafic igneous complexes, the most notable of which is the Lac des Iles Complex, host to Canada’s only producing Pd mine with reserves of 93.5 Mt grading 1.53 g/t Pd as of December 2001 (North American Palladium Ltd., Annual Report 2001). Cu-Ni- PGE mineralization was first discovered in the Legris Lake Complex by a local prospector late in 1999. Shortly thereafter, the property was jointly optioned by Avalon Ventures Ltd. and Starcore Resources Ltd., who continue to discover significant Cu-Ni-PGE mineralization.One of the most notable features of the Legris Lake Complex is the occurrence of extensive brecciation caused by multiple injections of volatile-rich magma. The Cu-Ni-PGE mineralization is hosted by leucogabbro within a 2 km long by 600 m wide, highly brecciated area in the northwestern area of the Complex. The mineralized rocks contain disseminated to blebby sulfides (1 to 5 vol.%), comprising chalcopyrite + pyrite ± pyrrhotite + millerite ± pentlandite, typically surrounded by epidote. The majority of the Cu-Ni-PGE mineralization displays low ratios of Pt/Pd (~0.20) and high ratios of Cu/Ni (~2.9), which are similar to those of the Lac des Iles and the River Valley mafic-ultramafic complexes. The lithologies in Legris Lake Complex bear similarities to the heterolithic gabbro of the Twilight and Roby Zone deposits at the nearby Lac des Iles mine. However, the mineralization at Legris Lake, which is restricted to leucogabbro overlying unmineralized clinopyroxenite, is similar to that of stratiform deposits such as the Stillwater and Munni Munni complexes. The mineralization at Legris Lake is best explained by the late-stage, immiscible separation of a sulfide melt from volatile-rich parental magmas and the subsequent minor redistribution of metals by deuteric fluids."

Jan 1, 2001

By P. Tarassoff

Extractive metallurgy is concerned with the winning of metals from their ores and concentrates. It is therefore not unexpected that extractive metallurgy in Canada has always been closely linked with mining. The discovery and exploitation of new orebodies has provided the impetus for the building of many of our smelters and refineries - past and present - and for the development of new metal extraction processes. The purpose of this paper is to provide a brief overview of those early metallurgical developments, and to highlight the continuing expansion and diversification of the Canadian metallurgical industry.

Jan 1, 1999

By Sepulvedam Jaime E., Levi Guzmán Rivera

"Grinding media consumption rates and their dependence on key operating conditions in semiautogenous grinding mills is analyzed on the basis of a detailed mathematical model recently developed by Moly-Cop´s specialists which describes and takes into account the three primary media consumption mechanisms, namely: abrasion/corrosion, surface spalling and impact ball breakage. The influence of key mill operating conditions – such as ball filling, discharge grate opening, mill speed, lifter profile, and ball quality – on their corresponding grinding media consumption rates is explored via a variety of model simulations, discussing in every case the independent contribution of each of the indicated consumption mechanisms to the estimated total ball consumption rate.INTRODUCTIONA thorough understanding of the independent contribution of each grinding media wear mechanism is extremely important, especially in semi-autogenous grinding (SAG) operations where macrowear (spalling) and ball breakage cannot be ignored or neglected. The high impact conditions imposed in modern SAG milling environments has created serious challenges for grinding media manufacturers since their products must be able to perform with minimal breakage and surface spalling.GRINDING MEDIA WEAR MECHANISMFor SAG milling operations, at least 3 different mechanisms have been identified as the main contributors to the observed overall grinding media consumption, here referred to as: abrasion / corrosion, ball breakage and surface spalling.Wear by Abrasion/CorrosionThe abrasive/corrosive wear mechanism has been discussed in depth in previous publications (Benavente Hector, 2007; Guzman Levi, 2014; Sepulveda and Morrow, 2014). The most widely accepted approach to mathematically characterize the consumption (wear) kinetics of grinding media in rotary tumbling mills is known as the Linear Wear Theory (Prentice, 1943; Norquist, 1950; Sepulveda, 2004) which claims that—at each instant 't' after a grinding body enters the mill load—the rate at which the body loses weight is directly proportional to its surface area exposed."

Jan 1, 2016

By John C. Leighton, C. O. Brawner, Doug Stewart

"Despite the availability of established, sophisticated methods for planning and designing stable slopes in rock, comparatively little attention is usually paid to the problems of carrying out the excavation. Blasting should be carefully planned to obtain optimum fragmentation as well as steep, stable working and final pit walls. The principal difficulty facing a blast designer is the lack of prior information about the many critical blasting characteristics of the rock mass. The common practise of trial-and-error lasting will eventually lead to a suitable program, but must be repeated time after time in variable geology. This frequently results in many blast-damaged slopes. Recent research indicates that monitoring drill performance will yield a Rock Quality Index which correlates to a Powder Factor value. The drilling can provide a continual supply of data, reflecting changes in the rock mass which enables the selection of an economical powder factor.IntroductionWhen planning to excavate a large-scale rock slope, engineer s will generally spend considerable effort to produce a safe, feasible and economical design. Much time will usually be spent on the field map ping, 'structural geologic studies, surface and subsurface hydrology, determination of strengths and effective friction angles of discontinuities, and finally checking stability with the aid of mathematical and analytical models. If the rock cut is to be along a transportation corridor, the prime justification for this time and effort is to produce a clean, stable slope which will be safe for those travelling or working beneath it. For the walls of an open-pit mine, there is the additional economic incentive to maintain the steepest stable slope angle for the minimum stripping ratio (Stewart and Kennedy)."

Jan 1, 1982

By W. L. Ott, C. L. Lewis

"AbstractA technique is described for preparation of palladium sponge and for spectrochemical analysis of the metal in this form. The precision and accuracy of the method are discussed. Analyses are compared with previous spectrochemical analyses of palladium in the black form. Good agreement was found in the two sets •of results and it is concluded that they are more reliable than wet chemical .analyses of the same material.IntroductionFOR SEVERAL YEARS the problem of platinum metal analysis by spectrochemical methods has been under investigation at the Spedtrographic Laboratory, Department of Geological Sciences, Queen's University. The problem, briefly -stated, is as follows: Samples of platinum, palladium,-rhodium, ruthenium, and iridium are received as fine metal powders, called sponge. Direct spectrographic analysis of this material has not been found satisfactory due to its heterogeneity •as regards contaminant metals, which may be present up to a total of one per •cent or more. Further-more, spectrographic standards are difficult to obtain and difficult to prepare accurately by adding weighed portions of contaminant metals to the sponge. The fact that •contaminant metals in original samples are probably alloyed with the major constituent is a further difficulty since complete fusion of these refractory metals proved impractical in the present case as a means of standard preparation. It •has, therefore, been found most satisfactory to dissolve the metals, prepare standards by addition of solutions of contaminant metals, and to reduce both standards and samples to a homogeneous form. A previous paper, by Hawley, Wark, Lewis and Ott (2) dealt with a method for spectrochemical analysis of platinum and palladium in their black form. Since completion of research on the black technique, the possibility of analyzing palladium accurately in its sponge form has• been investigated."

Jan 1, 1953

By R. T. Erskine

"The No. 6 orebody is located 6 miles from the main op.eration of Brunswick Mining and Smelting Corporation Limited and includes open-pit and primary gyratory crushing facilities. Ore is transferred by truck to the secondary crushing facility at the main plant. About 3,500 tons of ore per day are crushed to minus % in. and ground to 68 per cent minus 400 mesh in rod and ball mills for flotation feed. Conditioning and aeration precede rougher flotation, and four stages of cleaning bring concentrates to a grade of 42 per cent Pb + Zn + Cu. Middling products are reground and refloated in a secondary flotation circuit, producing a cleaner feed and a final tails product. Primary bulk concentrate is treated with sulphur dioxide and steam-heated to l 70°F and the majority of the gangue is floated off, leaving a product that assays 57 per cent combined Pb + Zn + Cu and is suitable for marketing. This material is thickened, filtered, dried and loaded into railway cars for shipment to the smelter. Reagent use on flotation is conventional, with many compromises in dosage required to maintain the recovery of lead and zinc in the most advantageous proportions. Many refinements in the flowsheet have been made since start-up in 1966, and more may be made as laboratory and plant testwork indicate possible improvements."

Jan 1, 1971

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

By E A. Mitchell

In the fall of 1961, Cominco dis-carded its long-established system of feeding the lead blast furnaces by narrow-gauge tram and V-cars, and installed an elevated monorail bucket system. This system automatically loads buckets of sinter, along with the correct proportion of coke, and delivers them to any of several designated furnaces. Direct labour usage has been reduced by nine men per day; improved coke proportioning has been achieved; and a major safety hazard has been eliminated. Introduction I N THE fall months of l 961. the system of feeding the lead blast furnaces at the Trail, B.C., smelter of The Consolidated Mining and Smelting Company of Canada Limited was altered from the tradition-al narrow-gauge railway and V-car method to one employing mono-rail carriers. The change was in keeping with a recent trend at Trail to replace narrow-gauge tramming with alternative methods of materials handling. In the case of the blast furnace feeding, the

Jan 1, 1963

By W G. Brese

The attention of the world is being focused on the spectacular rise of elemental sulphur production in Alberta. In the short space of a decade, production has increased from less than 10,000 long tons, in 1952, to al-most 1,000,000 long tons in 1962. Moreover, 1963 sulphur production is expected to rise by 50 per cent to approximately 1,500,000 long tons, and further increases are forecast for ensuing years. The reason for this dramatic in-crease in elemental sulphur production, particularly in the last year or two, is that Alberta elemental sulphur is recovered in association with the production of sour natural gas. When very large volumes of natural gas began moving to U.S. markets in the latter part of 1961, the resultant increase in sour gas production led to a marked increase in the production of sulphur. Consequently, Canada, mainly on the strength of sulphur produced in Alberta, will soon become the second largest producer of sulphur in the Free World

Jan 1, 1963

By H. C. M. Gordon

IN every co al mine the hazard of fire in the underground workings is always present. This is a natural condition, because the mineral wrought and the supports normally used are themselves combustible and because underground fires may originate in many ways. The main causes of such fires are: (1) Open lights igniting gas, wood, or the coal itself. (2) Explosives igniting gas or coal. (3) Spontaneous combustion. (4) Electric sparks or short circuits igniting gas, wood, or coal. (5) Frictional heat igniting wood, coal, or oily material. (6) Explosions of gas or coal dust igniting wood or coal. The relative importance of these causes, and others less frequently met with, varies from district to district and depends to a great extent on the equipment and supplies used, on the training and discipline maintained among the workmen, and on the liability of the coal to heat spontaneously. It follows, therefore, that open lights should not be used and that, wherever there is the least possibility of methane being encountered, only locked safety lamps of an approved type should be allowed underground. It follows, also, that only 'permitted' explosives should be used and that the it use should be confined to conditions under which they are ?permitted?. Similarly, electric equipment should be of an approved type and all such stationary equipment should be housed in well-ventilated fireproof rooms. Such rooms, as well as entries to stables and oil houses, should be provided with doors which can be easily and tightly closed and which should be constructed of fireproof material.

Jan 1, 1937