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By L. I. Kiss, A. Larouche, V. Dassylva-Raymond

Control of the quenching capacity of the cooling water is of primary importance for maintaining the quality and recovery rate of ingots produced by direct chill casting. Industrially, this can be done using a cylindrical metallic probe undergoing rapid quenching by direct immersion in a reservoir filled with casting water. Such a test rig originally developed at Alcan Arvida Research and development Centre was modified and used to assess the role of key parameters affecting the boiling heat transfer. During the tests, the probe of the instrument undergoes the effects of different heat transfer mechanisms. An experimental study was performed in order to clarify the details of the probe-water heat transfer during rapid quenching. The heat flux along the surface was determined by mathematical modeling using the measured temperature signals, while the corresponding heat transfer regimes like stable and unstable film boiling, nucleate boiling and natural convection were identified by the analysis of high-speed video recordings. Aluminium

Jan 1, 2006

By H. W. Wevers

This paper is the result of an intensive literature search and practical study of the problems experienced by a mining company with the frame cracking of their large-tonnage haulage trucks. It explains the advantages of particular HSLA steels for applications in the welded structures of such equipment. Examples of existing welds in truck frames are analyzed. Modern fatigue models and linear elastic fracture mechanics techniques are explained.

Jan 1, 1978

By J E. Gordon

For many years, it has been known that certain loud noises may, with prolonged exposure, temporarily or permanently damage a person's hearing ability. Pneumatic rock drills, al-though among the offenders, have, until recently, remained unaltered and unrestricted as to noise output. Now, there are drills available with higher rates of penetration and yet with noise levels reduced to those of previous models or less. Use of such drills, when proved to be superior in noise attenuation and of acceptable performance, should be encouraged in order to reduce future hearing losses to a minimum. People Have the Right to Hear P ERHAPS the earliest recognized indication of hearing loss due to industrial noise was the deaf-ness developed by the workmen in boiler factories. Here, the vibration set up in the shells by the riveting hammers gradually deteriorated the workmen's hearing, especially those whose job it was to hold the dollies inside the drum, where the sound is greatly intensified by reflection

Jan 1, 1963

By V. T. Panayotov, M. I. Panayotova

Wastewater from mining and mineral processing activities is often polluted by anion forming metals, such as molybdenum and chromium. Low cost materials, including zeolites, are studied for removing heavy metals from wastewater. It is widely accepted that natural zeolites are not effective in removing metals in anionic form. The paper presents study on use of metal modified natural clinoptilolite to remove Mo (VI) and Cr (VI) ions from model soft wastewater. Modification with Pb, Fe(III), Zn and Ba increases clinoptilolite uptake capacity with respect to Mo(VI) at low pH values of the water subjected to treatment, the efficiency decreasing in the order Pb > Fe(III) > Zn > Ba. Only lead-modified clinoptilolite shows high uptake of Mo(VI) in acidic, neutral and slightly alkaline conditions. Modification with Pb, Ba and Fe(III) increases zeolite uptake capacity with respect to Cr(VI) from neutral water. The effectiveness of Ba-modified zeolite decreases in slightly acidic water. Over 90 % uptake of initially available Cr(VI) is achieved by lead-modified clinoptilolite both under neutral and slightly acidic conditions. Increasing the initial pollutant concentrations increases the removed amount both of Cr(VI) and Mo(VI) for Pb-modified clinoptilolite. The findings could be a basis for using the natural clinoptilolite to remove in consecutive steps: firstly Pb(II) and/or Fe(III) ions and then loaded zeolite to be used for Mo (VI) and/or Cr(VI) removal. The kinetics of Mo(VI) uptake by CL-Ba, CL-Fe(III), CL-Pb, and CL-Zn is best described by the pseudo-first order kinetic equation. The kinetics of Cr(VI) removal by CL-Ba, CL-Fe (II), CL-Fe (III) and CL-Zn is best described by the pseudo-first order kinetic equation. Kinetics of Cr(VI) removal by CL-Pb obeys the equation for the first order irreversible reactions. Finding way to remove anions-pollutants from the mineral processing wastewater will render this industry more environmentally friendly and socially acceptable.

Jan 1, 2016

By H. C. Boydell

Those connected with mining, prospecting, or mining geology in northern Ontario are familiar with the fact that it is a comparatively unusual thing to have assayed a sample for which the assay report shows no gold. Values of 20 cents to 80 cents per ton, or even higher, are extremely common. Whilst contamination by fluxes, faulty manipulation, or a desire, on the part of the assayer, to sugar-coat the pill for the client, may account for 20 to 40 cent values at times, it is un1ikely that they would a1ways do so. Exonerating the assayer from being necessarily at fault, what can be the cause of such a widespread distribution of gold (and silver) in minute quantities- of a dissemination .that, in the writer's experience, and so far as he is? aware, is not met with on a simi1ar scale in other parts of the world? Explanations that suggest themselves are, that the dissemination is due: 1. To a very widespread auriferous minera1ization, post-dating (epigenetic) the formation of the rocks in which it occurs. 2. To a general syngenetic distribution of gold in the volcanic rocks of Keewatin age that form so large a part of the sections of northern Ontario that have been prospected.

Jan 1, 1928

By M. Härting, D. T. Britton, M. Nzikou Mamboukou

"Copper containing different types of nanocomposites have been characterized for nanolabelling and ID. Three types of the rare earth nanoparticles were used for this study, the oxide and the sulphur compound of the Eu and Tb. Characterization techniques uses SEM, and Raman for morphology, chemical composition, and optical characterization respectively. It has been shown that it is possible to include the rare earth particle in a copper matrix without damaging its physical properties. INTRODUCTIONThe development of new materials, often involves the addition of new properties without changing the beneficial properties of the original material (Chen et al., 2009; Khana et al., 2007; Patil et al., 2008). Nanocomposites are nanostructured materials, whose structural elements including clusters, crystallites or molecules, of dimensions ranging between 1 to 100 nm (Moriarty, 2001), or a composite material where one of the phases is a one, two or three dimensionally nanostructured material (Nanotechnology, 2006; Wang, 2001). Nanocomposite materials research is a fast growing area due to the high demand for materials for specialized applications (Edelstein & Cammarata, 1998), such as biolabelling, magnetic storage media, solar energy transformation (Jisen et al., 2004), and resistance welding applications (Bessergenev et al., 1997; Kwon et al.,2006).The properties of the nanocomposite materials depend not only on the properties of their individual parent materials, but also on their morphology and the interfacial characteristics. Thus, significant efforts have been focused on the control of the nanoscale structures via innovative synthesis approaches. Therefore, novel materials of unique properties may be obtained by combining properties from the parent constituents into a single material (Balan, 2006; Garcia et al., 2009). Possible effects of nanocomposites in the original material may include changes in the mechanical properties such as hardness , wear resistance (Rafaja et al., 1987), and electrical properties (Britton et al., 2003). The inclusion process may therefore be used to tailor materials to have particular mechanical, electrical and optical properties (Das et al., 2009). However, to fully understand the nanocomposite, it is necessary to study the fundamental properties of both the host matrix and the inclusions (Li, 2008)."

Jan 1, 2012

Iron control and iron residue management and disposal are significant issues in all zinc production processes. This paper briefly reviews the most important primary zinc production routes and discusses the challenges posed by iron control in each of them. The technologies and strategies that have proven successful in controlling and managing iron are discussed. SNC-Lavalin's experience in designing and commissioning zinc plants provides a unique perspective from which to review this aspect of zinc production.

Jan 1, 2006

By C. A. Pickles, K. Mackowiak, D. Gajonera

"Shake-flask oxidation tests were performed on Red Dog mine waste to study the initial dissolution behaviours of lead, zinc, and iron. The conditions for accelerated acid generation in terms of Eh and pH were determined. Each mineral behaved distinctly, with galena dissolving first, followed by sphalerite, then pyrite, although there was some overlap in behaviour. Iron was not detected in solution until approximately day 40 and was present at low concentrations. The experimental conditions and the theoretical model results indicated the formation of iron oxyhydroxides at low weathering times and jarosite at longer times.RÉSUMÉ Des tests d’oxydation par agitation en flacon ont été effectués sur les déchets miniers de l’exploitation Red Dog afin d’étudier les comportements initiaux de dissolution du plomb, du zinc et du fer. Les conditions entraînant la production accélérée d’acide en termes d’eH (potentiel d’oxydoréduction) et de pH (potentiel d’hydrogène) ont été déterminées. Chaque minerai se comportait différemment ; la galène a été la première à se dissoudre, suivie de la sphalérite, puis de la pyrite, mais un certain chevauchement des comportements a été observé. La présence de fer en solution n’a été détectée qu’après environ 40 jours et ce, à de faibles concentrations. Les conditions expérimentales et les résultats du modèle théorique signalaient la formation d’oxyde-hydroxyde de fer sur de courtes périodes d’altération atmosphérique, et de jarosite sur des périodes plus longues."

Jan 1, 2017

By J. Güntner

A significant portion of Outotec's business relates to the application of fluidized bed for processing a wide range of industrial materials, including gold ore and gold concentrate. As part of the former Lurgi and Boliden organization, our division constructed the first industrial reactor for roasting sulphur-bearing materials in 1950, based on the principles of fluidized bed technology. This process, when combined with efficient heat recovery and off-gas treatment and its conversion to sulphuric acid, became the standard for processing sulphur-bearing ores. In the last 60 years we have delivered more than 265 plants and developed (in addition to the standard fluidized bed solution) variants of the fluidization technology, such as the circulating fluidized bed and the bubbling fluidized bed. This paper describes the different options of the fluidized bed technology for gold roasting reflecting on main process design criteria.

Jan 1, 2011

As land resources decrease, commodity prices increase, and technology evolves, deep sea mining is becoming a viable alternative to meet the increasing demand for minerals. Successful deep sea mining operations are built on sound identification of the resource, proper selection of equipment, a thoughtful production plan, and good project management. These four key activities can be further optimized by analyzing how the spatial variability and uncertainty of the ore body properties impact the final mining operation. To address this problem, IHC Merwede is in the process of developing a risk quantification framework in the context of deep sea mining, which makes use of state of the art geostatistical simulation methods and transfer functions to quantify geological uncertainty and translate it into decision or project risk. The paper introduces the Local Average Subdivision method (LAS) for generating simulated models of the deposit and presents a new extension to incorporate point measurements of geotechnical or ore grade properties. Due to its computational efficiency, the presented method is suitable for simulating largely extended sea floor deposits. The second part of the paper illustrates, through example case studies, the significant benefits of a risk based approach which translates geological uncertainty into financial or operational performance indicators. In particular, the focus is on assessing financial project risk and on the design optimization of the deep sea excavation equipment by analyzing cutting forces, specific energies, and power requirements.

Aug 1, 2013

By J. U. MacEwan

Introduction The equilibrium between copper, zinc, and chlorine may be considered as the simultaneous equilibrium of the two separate chemical reactions of formation of the stable chlorides of copper and zinc at the temperature of the reaction i.e., l440°K. (1,167°C., 2,133°?F.)§ [Zn(g) +Ciz(g) ZnCl2z(g). ... (1) ] [2Cu(l)+Cbi'g) Cu2Cl2(l 1 ....... (21 ] Subtracting, [Zn(g) +Cu2(Clz(l i ZnClz(g) +2Cu!l) ... . (3) ] If this reaction is carried out with a copper-zinc alloy at some constant temperature above the melting point of brass, and at a total pressure of one atmosphere, the equilibrium concentrations obtained will depend on the free energy decrease .of the reaction as written in (3) and on the activities of the various components in. the reaction mixture. If the equilibrium is examined from the point of view of the phase rule, it is a three-component system, and if it exists in two phases (liquid and gas) it will have three degrees of freedom. If the restrictions of constant temperature and pressure are imposed, the degrees of freedom are reduced to one. This means that, in a two-phase system under these conditions, each different alloy phase will be associated with a gas phase of constant composition.

Jan 1, 1951

By J. E. Gill

THE 1938 season was marked by a distinct lull in exploratory activity in the Province of Quebec. Quebec was not unique in this respect, but the condition appears to have been more acute here than in most other parts of the Dominion. Various causes may be suggested to account for this. The general disturbance in political and economic conditions throughout the world has certainly had an adverse influence. Uncertainty induced by changes in the mining laws of Quebec in 1937 contributed. A third cause was the belief, now held by many, that the easily accessible deposits in the main producing belt extending eastward from. the Rouyn district have now all been found and that new discoveries in this field will henceforth come more slowly and more expensively. A fourth is the lack of conspicuous success by companies and individuals who have interested themselves in less accessible areas to the north, notably the Chibougamau district. A fifth, the unattractive appearance, as viewed on published geological maps, of the vast area extending northward to Ungava bay and Hudson strait. A sixth, the attraction of such speculative funds as were available to the Northwest Territories, where spectacular finds were reported in the fall of 1937. Whatever may be the relative importance of these causes, languor in exploration will ultimately be reflected in production returns. This appears, therefore, to be an opportune time to take stock of the general position of the Industry in the Province and to consider ways and means of counter-acting those conditions which are now impeding, or will in the near future impede, its expansion. At the request of the Institute Secretary, Mr. Carlyle, I have prepared a brief summary of accomplishments to date and a discussion of some of the geological aspects of the problem.

Jan 1, 1939

By J. J. Crowder, A. L. Coulson

Ground support is a significant component of underground mining costs. The rehabilitation of failed support, however, is often much more expensive than the initial installation. This paper investigates whether the right type and length of support can be designed correctly the first time, through forward modelling of the support and the mining process. Back analyses demonstrate how high-quality instrumentation and monitoring can help with the estimation of the post-peak (post-failure) rock mass parameters required for a comprehensive analysis. A hybrid modelling approach combines a three-dimensional mine-wide boundary element model with a non-linear finite element model to allow for the failure process in the rock mass. The back analyses demonstrate that, for the case study site, the post-peak Generalized Hoek-Brown value of mr must be reduced significantly in order to properly simulate displacements observed in instrumentation data. High-quality instrumentation data is the key to post-peak rock mass parameter calibration. The procedures outlined in the paper highlight the need for a new hybrid numerical modelling package that can use the influence of three-dimensional mining-induced stresses to predict displacements in, and potential failure of, rock masses surrounding mining infrastructure in order to radically alter strategic and tactical mine design.

Jan 1, 2007

By E. A. Morris

It has been shown that Alberta oil-sands fluid coke can be effectively used to reduce SO2 to elemental sulphur while simultaneously producing sulphur-impregnated activated carbon (SlAC). In the capture of mercury from industrial flue gases, SIAC has proven to be a highly effective adsorbent material. The current research aims at developing an existing SlAC technology to meet the needs of copper smelters for mitigating both mercury and SO2 emissions, while making elemental sulphur as a co-product. The challenge behind this undertaking is that these flue gases generally contain percent levels of 02 and H20 vapour (2-12%). The focus of this study is therefore on the feasibility of reducing SO2 using fluid coke under copper smelter flue gas conditions, as well as the optimisation of SIAC properties for capturing vapour phase mercury. It is hypothesised that mercury capacity is strongly affected by the 02 potential of the activation gas due to changes in surface sulphur types arising from different reduced sulphur species. To verify this, gas chromatography is used to analyse the reaction products while XPS and XANES will be used to describe the nature of sulphur on the SlAC surface. CVAFS analysis of mercury capacity will finalise the hypothesis assessment. Preliminary results indicate that 02 at 5% does not play a significant role in SSA or pore development. As expected, increased residence time contributes to SO2 reduction and elemental S yield.

Jan 1, 2007

By Robert Drummond

Away back in the eighties of the last century, when Sir Charles, then Doctor, Tupper, was not only a prominent but a dominant figure in the political life of Nova Scotia, his opponents brought the railing accusation against him that he was the foremost of egotists because of his frequent use of the personal pronoun. I heard Tupper speak and had no sympathy with the railers, because I could not well see how the pronoun could be dispensed with without laying himself open to a charge of affectation. I shall make reference in what follows to incidents in which I have taken part, and shall be at no pains to dispense with the pronoun, even though thereby I lay my-self open to the charge of being a pupil of the deceased states-man. EVENTS LEADING UP TO THE ORGANIZATION OF THE PROVINCIAL WORKMEN'S ASSOCIATION The Springhill Mining Company began development work at Springhill in the early seventies of last century. So vigorously was the work prosecuted that in 18 7 4 two slopes, the east and the west, were in active operation, with a considerable. output, the east slope on occasional days producing 800 tons. The President of the Company, the late Senator McFarlane, was a Nova Scotian, the other directors were mainly merchants from St. John, N.B. From the first the enterprise was an .astonishing success, due in the greatest part to its geographical position, and in large part to the untiring vigilance of the directors, a majority of whom visited the collieries at short intervals, thereby keeping the manager, much of the time, on tenter hooks.

Jan 1, 1924

By R. V. Tomkins

Introduction In the past fifteen years, bentonite production in the United States has increased very rapidly. From l50,000 tons in l934, it rose to 400,000 tons in l 942 and to a record 920,000 tons in 1948. Occurrences of bentonite ?in western Canada were described in the early part of the century by Ries and Keele (3), Ells (2), Spence (4). and other officer of the Dominion Department of Mines, and, in Saskatchewan, Professor W. G. Worcester (6), of the University of Saskatchewan has explored and carried out tests on deposits of the material at various times during the past thirty years. Nevertheless, Canadian developments have not kept pace with those in the United States. Exact figures for total Canadian production are not released, but it is probably under l0,000 tons annually. There are a great number of uses for bentonite, but in the United States three alone account for 90 per cent of the consumption. These are for drilling gel, foundry sand bond, and oil decolorizer. The tremendous oil exploration programme on the Canadian prairies has increased the possibility of an adequate domestic market for drilling gel. Therefore, in Saskatchewan, our efforts have been directed mainly to the production of a good drilling gel, with a minor part of the project devoted to activation of bentonites for oil decolorizing.

Jan 1, 1952

By John A. Teeter

"A SHORT WHILE AGO I enquired about The Mining Society of Nova Scotia. In all honesty I was apprehensive about addressing such a body if it was highly geared to the technical aspects of discovering and obtaining mineral resources. I was told that this would not be the case. Rather, there would likely be in attendance a broad cross section of people from business, industry and government and from across Canada and the U.S.A. Thus there would be an interest in a free-wheeling discussion of the prospects for industrial development in Cape Breton. Accordingly - being one who hates to miss an opportunity - I intend to exploit the invitation of your executive by being, over the next short while, frankly promotional. I would like to talk about what I consider to be some of the most important attributes of Cape Breton for industrial development and identify some of those prospects. Secondly, I will quickly review some of the things the Cape Breton Development Corporation is doing these days to stimulate some of that industrial development."

Jan 1, 1972

By J. E. Amadi-Echendu, F. Stober, J. Ndlovu, L. R. Nelson

The Polokwane Smelter Complex (PSC) relies on a single 68MW high-intensity six-in-line furnace to smelt a planned 650 000 t/a dry concentrate to produce a platinum group metals (PGM)-bearing matte. As typical of a greenfields venture, considerable attention was paid to the project development and implementation stages of design, engineering, construction and commissioning. Somewhat unusual though, was the role of a dedicated multi-disciplinary "Operational Readiness" and support team, comprising the owners team and specialists from the furnace designer, HATCH, to effect a safe and rapid ramp-up to the design smelter capacity of 68MW. The challenges encountered in developing an effective partnership will be discussed. The modus operandi and roles of the "Operational Readiness" team during the design, procurement, construction and commissioning stages as well as that of the operational support team within the overall ramp-up objective will be presented. The "Operational Readiness" team was responsible for:

Jan 1, 2005

By Michael T. McCaffrey

The wide range of potential feed materials, process steps, and products in metallurgical facilities means that standard equipment might not be available to adequately meet the project technical and economic needs. Custom designed equipment should be considered only after rigorous research precludes purchasing standard equipment. However, the decision to use custom equipment introduces a new element of risk into the project. To manage the risk, custom equipment design should be developed through the same front end loading (FEL) phases as project development. If more than incremental development of custom equipment is required, appropriate test work or pilot trials are required to test key uncertainties. Important activities during custom equipment design include maintaining clearly defined performance objectives, conducting appropriate reviews, carefully crafting commercial and intellectual property agreements with design and fabrication partners, and assembling a multidisciplinary team with sufficient development expertise.

Jan 1, 2015

By W. J. Li, L. Kong, G. L. Li, X. M. Xi, J. Qiu

"A novel hydrothermal method was applied to prepare the precursor of LiMn2O4 using pre-treated electrolytic manganese dioxide (EMD) and lithium hydroxide as the main raw materials. The precursor was subjected to heat treatment between 400 and 900ºC to obtain spinel Li1.05Mn1.95O4 and Li1.035Co0.035Mn1.930O4 positive materials for lithium ion batteries. The structure and morphology of the obtained powder materials were studied in detail by means of X-ray diffraction (XRD) and scanning electron microscope (SEM). It is found that the precursor has an amorphous structure and a high reactivity, which is easily transferred to spinel structure during heat treatment, obtaining a positive material with an uniform structure and good performances. The XRD patterns reveal that single phase spinel Li1.05Mn1.95O4 can be obtained from the precursor after heat treatment at 600°C in air. The final Li-rich Li1.05Mn1.95O4 product obtained showed a well-defined stable spinel structure and distinctive crystal faces with particle size between 200 and 300 nm. The as-prepared Co-doped spinel sample exhibited a excellent electrochemical performance with an initial discharge capacity of 113.0 mAh/g and 93.8% of its original value was retained after 100 charge-discharge cycling at 0.5 C.INTRODUCTIONThe increasing demand for portable electronic devices and hybrid or full electric vehicles is driving the development of cheap, efficient, compact lightweight and environmental friendly rechargeable batteries systems (Chung et al., 2002; Scrosati, 1995). Lithium ion secondary batteries have satisfied this demand to a greater degree than other battery systems. The cathode material plays a critical role in the performance of Li-ion batteries. The high cost and toxicity of cobalt compounds for the cathode material of LiCoO2 has prompted a search for alternative materials. LiMn2O4-based spinels offer a potentially attractive alternative to LiCoO2, due to its abundance, low price, ease of preparation, environmentally friendly characteristics, better thermal stability, and its effortless recycling (Tarascon et al., 1991; Yabuuchi and Ohzuku, 2003; Amatucci et al., 1999; Tsai et al., 2003). Some achievements have been created to meet the requirements (Guo et al., 2010; Kang et al., 2005; Park et al., 2008; Takahashi et al., 2006; Lee et al., 2001; Yoshio et al., 2001; Arumugam et al., 2008). However, the largest obstacle encountered in the practical applications of LiMn2O4 is its fast capacity fading during long term cycling, which is due to Jahn-Teller distortion of the [MnO6] framework, the electrolyte decomposition at high potentials and manganese dissolution into the electrolyte (Fey et al., 2003). The electrochemical performance of LiMn2O4 is also strongly dependent on its morphological properties, such as crystallinity, phase purity, surface area, grain shape and particle size distribution, etc. All these morphological properties are closely related to the material synthetic routines and heat treatment processes (Huang et al., 2000; Myung et al., 2000; Takada et al., 1998)."

Jan 1, 2012