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By Theo Lehner

The Rönnskär smelter has wide experience in the field of recycling of non-ferrous metals. Today, smelting and refining from primary and secondary raw materials are integrated in a complex flow sheet. Boliden operates a lead flash smelter, a lead refinery, a copper smelter and refinery, a sulphuric acid and sulphur dioxide plant, a slag fuming plant and precious metal plant at its Rönnskär smelter in the North of Sweden. The Business Area Smelter Operations also incorporates Boliden Bergsöe, Sweden's lead-acid battery recycler, and Norzink, Norway, where recycled zinc accounts for more than 20% of it's production. Raw materials for the Rönnskär smelter include concentrates, ashes, slags, metallic scrap, electronic scrap and electric arc furnace (EAF) steel-making dust. This paper briefly describes current operations and illustrates current measures to improve productivity. Limits to recycling as experienced by a non-ferrous smelter are, illustrated. The deportment of critical elements contained in raw materials is also discussed.

Jan 1, 1998

By Xi Yun Yang

Ultrafine (0.1µm) spherical magnetite powder was prepared successfully by hydrothermal reaction of ferrous sulfate and sodium hydroxide with activated pyrite as reducing agent in the temperature range 120-140?. XRD and XPS analyses indicate that pH value and pyrite amount have a direct influence on the composition of the product. Stoichiometric Fe3O4 can be obtained only when pH value is 12 and the molar ratio of pyrite/ferrous sulfate is 1:1.8. The hysteresis loop of Fe3O4 shows a ferromagnetic behavior with a saturation magnetization of 75.2 emu/g and a coercivity of 152Oe.

Jan 1, 2006

By Hideki Yamamoto

A new technology to convert fluoride gas (C2H2F4 ; R-134a) contained in the exhaust gases from semiconductor manufacturing plants and refrigerators directly into a harmless substance have been established, thus, presenting a new concept for the disposal of fluoride gases such as CFCs that are associated with the global warming. Experimental results verify that chemical reactions with metal compounds can take place at substantially lower temperatures of 700- 800K as compared with combustion. treatment temperatures of 1200-1500K. The reaction product is mainly metal fluoride, which chemically is a harmless material. Furthermore, this process is compact, easily controlled, safe and has low running costs. This paper deals with a new chemical reaction method for the harmless disposal of gases effecting the global warming.

Jan 1, 2003

By Hideki Yamamoto

A new technology to convert fluoride gas (C2H2F4 : R-134a) contained in the exhaust gases from semiconductor manufacturing plants and refrigerators directly into a harmless substance have been established, thus, presenting a new concept for the disposal of fluoride gases such as CFCs that are associated with the global warming. Experimental results verify that chemical reactions with metal compounds can take place at substantially lower temperatures of 700- 800K as compared with combustion treatment temperatures of 1200-1500K. The reaction product is mainly metal fluoride, which chemically is a harmless material. Furthermore, this process is compact, easily controlled, safe and has low running costs. This paper deals with a new chemical reaction method for the harmless disposal of gases effecting the global warming.

Jan 1, 2003

By Ravinder N. Reddy

Electrochemical capacitors are charge storage devices. They bridge the gap between dielectric capacitors and batteries in terms of energy and power density. Electrochemical capacitors are classified into two types, electrochemical double layer capacitors (EDLCs) and capacitors based on pseudocapacitance. In EDLC, charge is stored at the interface between electrode and electrolyte. Carbon is considered to be prime electrode material for EDLCs due to its many favorable characteristics. In this study carbon materials are derived from thermal decomposition of catechol- formaldehyde polymers and are studied as electrode material for electrochemical double layer capacitors. Carbon electrode surface is characterized using NOVA 1200 gas sorption analyzer. It is also characterized using XRD and SEM. Carbon electrodewaselectrochemically characterized using cyclic voltammetry (CV). A highest capacitance of 110 F/g was observed in 30 wt% H2SO4.

Jan 1, 2006

By Katja Reinharter

Arsenic can be found in different sulfidic copper concentrates and residues, which for several years have commonly been used in copper metallurgy, as the “arsenic-free” resources are getting rare. Due to the high toxicity the removal of arsenic in the copper smelting process is a very important topic. The typical chemical slag and sulfur attack on the refractory material is getting enhanced by the presence of arsenic. This work deals with post-mortem investigations of a magnesia-chromite brick and castable used in copper smelting furnaces showing an additional and increased chemical attack by arsenic. The knowledge on the wear behaviour is not only based on a detailed chemical and mineralogical characterization, but also on thermochemical FactSageTM calculations, which are carried out on provided post-mortem samples. Post-mortem investigations on used refractory materials represent an important prerequisite for the product development, as well as for special engineered lining concepts to support our customers.

By E. C. T. Chao

Micro-optical and synchrotron radiation-induced X-ray fluorescence (SXRF) techniques have been used to study unoxidized and oxidized samples of Carlintype sedimentar,y rock-hosted disseminated gold ore. In these samples, Where much of the gold is submicroscopic, the SXRF technique, which has a spatial resolution of about 20 ~m and a minimum detection limit (MDL) in the ppm range, is an ideal and necessary tool for precisely locating gold-rich areas in a sample. Gold-rich areas pinpointed by SXRF were later studied in detail by micro-optical methods, principally optical microscopy and scanning electron microscopy with energy-dispersive X-ray analysis (SEM-EDX). In two unoxidized and one oxidized ore samples, SXRF analyses have shown gold to be present predominantly in discrete clay-rich and silicified areas. Gold was not detected by SXRF in association with pyrite or carbonaceous materials. SEM-EDX examination of the gold-bearing areas in the unoxidized samples succeeded in identifying only two free gold particles, 0.2 and 0.5 ~m in size. In the oxidized sample, gold particles appear to be larger (but still submicroscopic) in average size and more evident in micro-optical examination after SXRF location of goldbearing areas. The findings of these studies may help to improve the efficiency of processing and recovery of gold from unoxidized ores.

Jan 1, 1987

By T. Feldmann

Despite the ubiquity of applications for germanium, there is a lack of practically useful solubility data in acidic solutions. Previous studies were done at ambient temperature and only for commonly used acids (H2SO4, HCl). Hence, an investigation of the solubility of GeO2 in different acids was undertaken. Several inorganic and organic acids were studied in the concentration range of 1–11 mol/L and at 23, 40, and 60 °C. In the case of H2SO4 and HCl previous data was confirmed. Lower acidity resulted in a higher solubility for Ge at all tested temperatures. Tests done at 40 and 60 °C and low to moderate acidity levels, gave slightly increased solubility values at higher temperatures compared to 23 °C. This wasn’t the case at higher acidity levels, i.e., the solubility curves at different temperatures converge at high acidity. Lastly, a relationship of water activity and GeO2 solubility in different acid media was established.

By Malti Goel

"The cost-effective capture of carbon dioxide (CO2) from the point sources for its reduction the atmosphere offers many challenges in materials science. Novel CO2 capturing approaches using chemical, physical and biological methods are in the research stage and are aimed to minimize the cost. Appropriate materials development , which can withstand required temperature or pressure as the case may be for CO2 emanating from coal gas or industrial waste gases form the minimum condition. Other requirements are reclyclability of material and cost of separation. Nano-material composites can be more effective in selective capture of CO2 and can offer solutions for large-scale separation process. Nano-porous material catalysis can enhance the reaction rate of CO2 with other chemicals and thus help in capture of CO2 and convert it into value added products. This paper reviews recent industrial scale developments. In the Indian context, R&D priority areas in CO2 capture process development with a focus on energy industry are presented.IntroductionScience of Climate Change is growing at an enormous pace. With the ultimate goal of stabilization of greenhouse gases in the atmosphere, new scientific approaches are being researched worldwide. A shift in policies from low carbon and no carbon energy sources to fossil fuel sources with capture of carbon and its permanent storage is taking place. The process of carbon capture is both energy and materials intensive and the cost of power generation may increase up to 40% when carbon capture and storage (CCS) technology is implemented. Development of cost effective R&D technology therefore remains the greatest challenge before the scientific community."

Jan 1, 2009

By Stanko Nikolic

One of the keys to success in process development is incremental scale-up, allowing for potential problems to be identified and rectified. The ISASMELT™top submerged lance (TSL) process was developed to maturity using this method by Mount Isa Mines, now owned by Glencore. Commercialization only occurred once the process had been proven on each scale and as a result the ISASMELT™ technology now operates successfully around the world. An important parameter in the evolution of the technology has been the furnace campaign life. The initial commercial scale furnaces had minimal water-cooling. Although this led to shorter campaign lives, an extended development program resulted in the achievement of four-year campaign lives, without any water cooling. In tandem to the refractory designs Glencore Technology, supplier of the TSL technology, has progressed cooled copper lining designs for application to both the ISASMELT™ and ISACONVERT™ furnaces allowing for ultimate flexibility in the lining choice. This allows each ISASMELT™ operating site to minimize their overall life-cycle costs by balancing their campaign life with lining costs, energy inputs, and other shutdown requirements.

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from the University of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Farzaneh Sadri

After water leaching of an acid baked REE concentrate, impurities such as Fe, Al, Th, and Cu are removed by neutralization with different reagents such as NaOH, Mg(OH)2, MgCO3, CaO, and CaCO3. Among these chemicals, lime (CaO) and limestone (CaCO3) are the preferred reagents due to their low costs. However, because of calcium sulfate dihydrate (gypsum) precipitation, they are not so common in industry. One of the disadvantages of gypsum precipitation is the adsorption of REE to the precipitates, losing a fraction of REE to gypsum which is hard to recover. In this paper, batch and continuous conditions in the impurity removal process using limestone are investigated and the differences between these two processes are examined. Based on the experiments, REE uptake by gypsum significantly increases in continuous processes, and different gypsum morphologies are observed.

This symposium is dedicated to the lifetime achievements of Professor H.Y. Sohn. It covers the scientific fields, processing routes and investigation techniques in which Prof. Sohn has worked during his career and is based in the equally important three topical areas: Principles, Technologies, and Industrial practice. Professor Sohn was General Chair of the very first TMS Fall Extraction and Processing Symposium in 1983 in San Francisco which led to the Annual such symposia as this International symposium. Furthermore, the theme of that symposium was sulfide smelting, which is also included in this symposium. [ ] Professor Sohn was born in a beautiful dynastic capital Kaesung, Korea on August 21, 1941. He received his B.S. degree in 1962 from Seoul National University, M.Sc. in 1966 from the University of New Brunswick, Fredericton, N.B., Canada, and his Ph.D. degree in 1970 from theUniversity of California at Berkeley all in Chemical Engineering. After working as a Research Associate at the State University of New York at Buffalo and as a Research Engineer at Du Pont?s Engineering Technology Laboratory, Dr. Sohn joined the Department of Metallurgical Engineering at the University of Utah in 1974 and currently holds the ranks of Professor of Metallurgical Engineering and Adjunct Professor of Chemical Engineering.

Jan 1, 2006

By Junji Shibata

Waste solution from the Ni non-electric plating process contains 4.0 kg/m3 Ni, 0.1 kglm3 Fe, 0.0 I kg/m3 Zn, 48 kg/m3 S042-, 98 kg/m3 HP032-and 31 kg/m3 laetic acid as a typical composition. Solvent extraction, cementation, ion exchange resin and precipitation methods are possible to use for the treatment of this kind of solution. In this study, solvent extraction of Ni was investigated using two kinds of extractants to clarify the relation between extraction percent and pH for various extractant mixtures. As Ni ion has an octahedral structure with ligands, the synergistic effect for Ni extraction is considered to take place in solvent extraction using two types of extractants. The investigation of the synergistic effect for Ni extraction was carried out in case of various extractant systems.

Jan 1, 2003

By Minji Jun

Leaching of the surface-coated metals from waste acrylonitrile butadiene styrene plastics (WABSP) has been investigated in the ammoniacal solution. The ammoniacal leaching of WABSP (typically containing 4.1 wt% Cu, 1.3 wt% Ni, 0.03 wt% Cr) efficiently dissolved copper and nickel, leaving unleached chromium as fine particles. The results indicate that the anions of different buffer media for metals leaching follow the order: CO3 2− > Cl− > SO4 2−. A declined leaching with high NH4OH–(NH4)2CO3 ratio (8:1) and a steep rise in extraction with high pulp in solution revealed the influence of anion (CO3 2−) and cation (Cu2+) present in the system. The leaching performed in carbonate solution by maintaining 5.0 M total NH3 concentration as NH4OH–(NH4)2CO3 ratio, 4:1; pulp density, 200 g/L; agitation speed, 400 rpm; temperature, 20 °C and time, 120 min yielded the maximum extraction (>99%) of copper and nickel. The study reveals a plausible recovery of the surface-coated metals from the WABSP without altering the properties of polymer material that can be recycled separatel

By William E. Torres

The Southern Peru Limited smelter, in Ilo, operates two reverberatory furnaces, seven Peirce-Smith converters, one Teniente Converter, two casting wheels and a single contact acid plant. The Teniente Converter was commissioned in August 1995 and was designed to smelt 744 dry metric tons (820 dry short tons) of concentrate per day. The process off-gas is collected in a water-cooled hood, cooled in a spray chamber, and cleaned in a Joy electrostatic precipitator for further treatment in the Acid Plant. This paper presents the current Teniente Converter operating practices and control philosophy. Relevant improvements and modifications to achieve a 379 day campaign without tuyere replacement and a daily average smelting rate of 862 dry metric tons (940 dry short tons) of concentrate are discussed.

Jan 1, 1998

By Pedro A. Netto, Giulio R. Altoé, Sergio N. Monteiro, Ygor M. Moraes, Frederico M. Margem, Gabriel O. Glória

Since environmental issues are becoming more and more important Worldwide. Nowadays, Natural fibers are been used to substitute the synthetic ones. Although PALF fiber is an important natural fiber and its mechanical Properties surpass in various aspects some other lignocelluloses fibers, such few studies have been conducted with the fiber obtained from leaf of PALF plant. In order to better evaluate the mechanical properties and possible applications, this paper aims to improve the elastic modulus of the PALF fiber by Weibull statistics, by evaluating their mechanicals properties and possible applications. The fibers were divided in diameter intervals and the tensile strength and elasticity modulus were measured in each range. The fractured surface was examined using scanning electron microscopy. The results, interpreted by the Weibull statistical method, showed a correlation between the fiber elastic modulus and its diameter.

Jan 1, 2015