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By V. Grujic, M. Grujic, D. Salatic

"Two areas are involved in the research work of the comminution process (crushing and grinding). The first one involves the changes of the size class distribution values that are definded by the differential equations in the function of the ore property and working conditions. The second area involves the comminution of the different levels in order to optimize the working parameters and to decrease the operational costs in the grinding process.We have studied, in detail, the possibility of functioning the crusher at the maximal loading, over 4500 kN, ball mills with diameters larger than 5.0 m and semiautogenous mills with diameters larger than 10.0 m.Using the computers, we have achieved the maximal loading range of the crusher, over Fc ? 4500 kN in the crushing process. In the grinding process, using the adequate differential equations in the automation process, we have established the correlation between the pulp mass capacity in the mill, pulp dencity, ore fineness in the pulp and recirculating ore charge.With the appopriate text, equations and graphs, this paper shows the results of our several years research work in the laboratory and in the ore comminution plant of Majdanpek Copper Mine."

Jan 1, 2003

By E. L. Chanturiya

During the mineral processing of pyrites sulphide ores of some deposits of Russia loss of gold with tailings and pyrite concentrates amounts up to 40%~90%. The problem of selective allocation of gold-bearing pyrite is crucial. There are 4 mineralogy-technological groups of pyrite determined in copper-zinc sulphide ores, based on the increase of contents of gold in pyrite. The gold associated with group 4 pyrite contents of 85% the total mass of gold found in the pyrite. The flotation behaviour of the enriched fractions of pyrite (98%), of the allocated from the ore of Gay deposit, were studied essentially in various conditions ?? and the charge of Butyl xanthogenate of potassium (ButX). Some products of selective pyrite flotation were investigated by methods of scanning electronic microscopy, energy-dispersive and X-ray spectral microanalyses, definition of specific resistance and thermoelectric moving force.

Jan 1, 2014

By Genrich A. Denisov

Principles of ecologically friendly geo-technologies construction are formulated on the basis of the works of the leading scientists in the field of rational processing of mineral resources of the Russian Academy of Sciences. One of these concepts is a new direction in rotational disintegration of mineral and technogenic raw material with the purpose of effective subsequent enrichment. A large amount of practical experience has been accumulated in the industry on selective destruction by application of vibrational method on initial material with consideration of its physical-mechanical properties and mineral structure. This method is successfully realised in a conic inertial pulverisation devices constructed by Mekhanobr Institute (St.-Petersburg). A new construction of conical-inertial pulverisation with a modification of disintegration force has been developed recently at Mekhanobr Institute. It allows, in some cases, to increase selectivity of subdivision and to avoid over-disintegration. Advantages of “wet” subdivision methods in conic inertial disintegration devices are proved. The efficiency of such subdivision can be increased due to rational use of the phenomenon of a dislocation-dynamic diffusion. Its advantage is proved by the effect on disintegrated material by frequency-modulated variable electrical fields of low power. It was shown in industrial conditions, that the productivity of the spherical mill can be increased by 10 %, and that it also prevents ecologically harmful surface active substances (SAS) in milling zone and it reduces the dust content in the air. The techniques of tentative estimation of efficiency of various proceedings technogenic materials and their classification are created. The scientific fundaments of rational, ecologically friendly technology of processing and regeneration of various kinds of technogenic raw material are developed. A number of effective technologies on processing of wastes is developed and inculcated in concentration factories and metallurgical factories.

Jan 1, 2003

By John Ralston, Stephen Grano, Yongjun Peng, Daniel Fornasiero

"A specially designed mill which allowed the control of pH throughout grinding was used to study the effect of rgrinding conditions on galena flotation and galena separation from pyrite. The various reactions occurring on the mineral surface were investigated by a range of techniques, including OH- addition to maintain the grinding pH, EDTA extraction, XPS and ToF-SIMS measurements.Galena flotation and galena separation from pyrite were strongly dependent on the metal oxidation species produced on galena and pyrite surfaces under different grinding conditions. Iron oxidation species depressed both galena and pyrite flotation, whilst lead oxidation species activated pyrite but had little effect on galena. Optimum galena flotation and galena selectivity against pyrite were achieved by selecting grinding conditions that enabled lead and iron oxidation production to be controlled."

Jan 1, 2003

By Frank Cappuccitti, Stephen Chryssoulis, Stamen Dimov

Surface organic microanalysis of platinum (Pt) and palladium (Pd) minerals by TOF MS1 is an attractive complement and potential alternative to conventional collector screening methods. Its attractiveness lies on its ability to focus on individual Pt and Pd mineral particulates, therefore providing a more targeted approach. The only requirement is knowledge of the occurrence (mineral composition, grain size and association) of Pt/Pd in the feed sample. This newly developed technique can detect, and identify collectors and quantitate loadings on individual Pt/Pd mineral particulates at plant concentration levels. Using this technology, collector loadings were measured on Pt and Pd metal plates and on PtS2 and PdS particulates which had been exposed together to aqueous solutions of different collectors. Thus, data were obtained on collector selectivity, the effect of sulphur; and of depressants, the latter in combination with TOF-LIMS2 results. Staged rougher tests on North American and UG-2 ores linked Pt/Pd flotation kinetics with collector loadings and ultimately grade/recovery.

Jan 1, 2003

By Takashi Furuyama, Sukeyuki Mori, Takafumi Okuma, Norio Hashiguchi

"In order to achieve a high recovery of particles finer than 10µm, three types of dry Tower Mill (VD-1, KD-1, KD-2 and KD-3) have been developed. These mills differ from each other in the size of the comminuting part, the inside diameter and shape of the classifying part and the system involved in the collecting process. The last version (KD-3) of tower mills in which the comminuting and classifying operations has been separated, can produce particles finer than 10µm from a limestone ore sizing from 420 to 3360µm. In this tower mill, products in comminuting section are blown up and transported into the classifying column, made of an inverted cone on top of a cylinder, before they agglomerate and settle down. Fine particles are deported and recovered in a cyclone with a central spiral ribbon.Previous studies on the grinding efficiency of the tower mill KD-3 have shown how the maximum size of collected products increased with the airflow velocity, disturbing in the same way a smooth regulation of the grinding operation with the tower mill KD-3. A complete knowledge of factors that influence the maximum size of collected products is needed, therefore, to increase the efficiency of the grindingclassifying operation and ensure a better control over the collected products. The present study deals with this issue and, assuming that the structure of the classifying column could be one of these factors, its internal structure was modified (insertion of vertical plates, cone or horizontal nets) before carrying out comminution tests that would establish a relationship between the inward shape of the column and the maximum size of collected products. It was found that the weight of products collected in the cyclone decreases when a cone or some horizontal nets are inserted inside the column. At the same time, the weight of products collected in the column increases. This is due to the fact that coarse particles blown up from the comminution section collide with the base of the cone or the nets and settle down the bottom of the classifying column. Therefore, the cone and some horizontal nets inserted inside a classifying column, have the particularity to stabilize the maximum size of particles (15.1-17.5µm and 8.4-11.3µm) in the cyclone even when the airflow velocity in duct increased. These tools could of great help in the production of particles of definite size to fit for instance the paper industries requirements (production of limestone material sizing - 10µm as paper filler)."

Jan 1, 2003

By Atsushi Shibayama, Toyohisa Fujita, Wan-Tai Yen, Ke-jun Liu

"A gold has been leached with ammonium thiosulfate solution and several leaching conditions have been studied. The leached solution has been recovered by solvent extraction and the optimum conditions have been investigated.SUMMARYIn this investigation, a sponge gold sample (99.92% pure) has been leached with ammonium thiosulfate solution. The effects of CuSO4, (NH4)2S2O3, (NH4)2SO4, NH4OH and retention time on the gold leaching % (extraction %) and thiosulfate oxidation % (consumption %) have been studied. The copper ion acts as a catalyst in gold dissolution. On the other hand, it also accelerates oxidation of thiosulfate (consumption). It was found in this study that the best gold extraction condition was obtained at 43.2 ks with 0.8 – 1.0x103 mol/m3 (NH4)2S2O3, 30 mol/m3 CuSO4, 2.0 – 3.0x103 mol/m3 NH4OH, 0.4 – 0.5x103 mol/m3 (NH4)2SO4, pH 10±0.2 and 150 rpm. The thiosulfate oxidation was about 15% of the initial concentration."

Jan 1, 2003

By Liping Yu Che, Xiaotie Wang, Mingli Cao, Jizu Yongfu Yuan

"It is difficult separating fluorite from Ca, Ba, Si intergrowth minerals than simple from Si, using common reagents such as combination of oleic acid or paraffin soap and water glass, but the finest quality fluorite concentrate whose grade is over 96%F must be required in chemical plant.This paper studies the flotation process of native fluorite from calcite, barite and silicate minerals whose flotation properties is similar to fluorite, using new effective collector H602 and new depressor S602 that is cheaper in cost, and describes the flotation properties. In order to determine optimum flotation separation condition, the effect of pulp pH, pulp temperature, pulp density and the effect of dosage of reagents on flotation were investigated and the flotation result was provided by oleic acid collector and the results of collector H602 were compared with those of collector oleic acid in the test. The test result of ore samples shows that at moderate pulp pH values (10.5-11.5) and other moderate technical conditions, the fluorite mineral can be obtained by new reagents and the rational reagents combination. The conclusion is 98%F of fluorite concentrate can be obtained, using the combination of H602 and S602 and only 5 steps in techniques. The paper discusses the mechanism of the flotation separation of fluorite mineral from intergrowth minerals."

Jan 1, 2003

By Benoit Clermont, Jan Lux

"Magotteaux and Anglo Platinum started a co-operation program with the main aim of establishing the optimum milling configuration measured in terms of throughput, fineness and energy consumption.For this purpose, a fully instrumented pilot milling plant, supplied by Magotteaux (Pty) Ltd, and equipped with a 0.9 x 1.0 m ball mill, was erected at Frank concentrator (Merensky Pt ore). The primary ball mills at Frank concentrator were surveyed in order to set the conditions for the base case. This data was then replicated in the pilot mill under the same configuration. Thereafter, a series of different parameters were varied in order to attempt to optimize the milling system.Only grate versus overflow discharge and open versus closed circuit will be discussed in this paper.It should be noted that this paper does not attempt to give a universal solution as to what milling configuration is optimum in all cases. The conclusions apply for this particular case and probably most others, but it would be advisable to consider each case on its own.CONCLUSION• Overflow versus grate dischargeAn overflow mill has a “pool” of slurry around the toe of the ball charge, which creates a counter lever to the ball charge. This will reduce the absorbed power in the range of 10-15% (depending on the case) and will consequently result in a coarser grind. The tests found a 4% gain in grinding efficiency (Wio) with an overflow mill but this is probably not significant.This lower absorbed power and coarser grind can be counteracted by increasing the ball charge (if below maximum) and/or by increasing the mill volume when removing the grate discharge (a typical grate takes up about 300mm of the mill length).• Open versus closed circuit"

Jan 1, 2003

By Zoran M. Stevic, Mirjana M. Rajcic-Vujasinovic, Zvonimir D. Stankovic

"Huge electrochemical investigations have been performed on Technical faculty in Bor (Serbia) which main goal was the clarification of the copper sulfide minerals behaviour in hydrometallurgic and flotation processes. Modeling of these processes was a part of the effort for better understanding of the reaction mechanisms.The consideration of electrical analog circuit and mathematical model of processes at interfaces copper sulfide/electrolyte (CuS/(CuSO4+H2SO4), Cu2S/H2SO4 and CuFeS2/H2SO4), based on studies of the overvoltage – time transients, will be presented. The transients were obtained using single pulse galvanostatic method and electrochemical cell with standard three electrode assembly. In that goal it was developed an original system for computer measurements that enables the application of several methods for electrochemical investigations (galvanostatic, potentiostatic, cyclic voltammetry, electrochemical impedance spectrometry etc). The system was tested and adjusted using commercial electrochemical equipment made by AMEL, Milano.In the first stage of consideration the different equivalent electrical circuits have been tested by computer programme OrCAD 9.2 in order to identify the circuit with responses equivalent in shape to experimentally obtained ones. In that way it was established a configuration of an analog electrical circuit for investigated electrochemical system. That phase enabled only very rough determination of values of circuit components and their relative ratio.In the second stage the method for determination of all elements of electrical analog circuit is described. It is based on mathematical consideration of a given circuit on one hand, and valves of the overvoltages at selected times, obtained from charging and discharging parts of galvanostatic transients, on the other."

Jan 1, 2003

By Stephen Gay, Dewetia Latti

"When improving a plant a mineral processing engineer would like to know the mineral composition distribution. In order to assess this distribution in particles, as compared to the corresponding distribution in particle sections, a procedure needs to be applied to the observed particle sections. Such a procedure is called a stereological correction. There exists many stereological correction procedures, but one group of such procedures is based on using those stereological equations that do not require making assumptions regarding particle shape or texture. These equations are called geometric probability equations.Davy derived a geometric probability equation to estimate the covariance of mineral composition distributions for particles from both particle sections and linear intercepts. This covariance can be used to measure the variance of the particle composition distribution of each mineral. The equation as presented by Davy requires textural information; however the equation was modified by Gay to be more directly applied to particle sections and linear intercepts. The variance obtained from applying this equation is fundamental to the binary stereological correction procedures developed by Gay and his colleagues; the covariance is fundamental to the multiphase stereological correction.Thus far, validation of both the binary and multiphase stereological correction has been achieved using numerical simulation. This paper shall present results comparing the covariance (and variance) estimates from Gay’s equation with actual three-dimensional information obtained from serially sectioning particles. This involved mounting a set of particles and continuously sectioning all particles uniformly so that the three dimensional structure of the particles could be obtained.The mineralogical data to which the equations described above were applied were derived from two individual size fractions from a hard-rock titanium deposit. The deposit contains a range of minerals and of mineral textures and the two size fractions selected were:"

Jan 1, 2003

By A. F. Raschenko, Y. A. Golodcov, V. V. Elshin

"The autoclave noble metal desorption in apparatuses with a dense stationary sorbent layer is perspective for the technology of sorption gold and silver extraction from solutions and pulps by carbon sorbents. The study of the mechanism and optimization of the autoclave desorption process involve some difficulties. To overcome them it is necessary to use mathematical and quantum-chemical modelling. The given paper deals with a mathematical model for the dynamics of gold and silver desorption from active carbons by alkali solutions based on the physical-chemical notions of the process. The kinetics and the mechanism of the process were investigated using the mathematical model for gold and silver desorption.The calculation of the efficient mass-transfer coefficient (ße) for various initial and intermediate noble metal concentrations in carbon (Cy) made it possible to find that the dependence of ße on Cy in case of gold desoprtion shows a clear extreme character. The value of the initial metal concentration in carbon therewith does not influence the character of the curve the inflection point of which is changed essentially at elevated process temperatures only. The revealed characteristic property, in the author's opinion can only be indicative of the change in the mechanism of gold desorption under autoclave desorption conditions. The assumed [Au(CN)(OH)]- type intermediate that has a higher diffusion coefficient in comparison with the adsorbed complex [Au(CN)2]- can be considered as an intermediate compound in the process of gold desorption."

Jan 1, 2003

By Vladimir I. Ryaboy, Konstantin M. Asonchik

"At flotation of sulfide-barite ores of one of deposits sulfide and barite concentrates are obtained. In sulfide cycle potassium xantogenate as a collector in consumption of 200 g/ton, methylisobutylcarbinol (MIBC) as a foaming agent in consumption of 30 g/ton and also liquid glass are used. In barite cycle tall oil as fatty acid collector in consumption up to 400 g/ton is used.Sulfide concentrate represents mainly gold- and silver-containing pyrite. The contents of gold makes not less than 10 g per ton, silver - not less than 278 g/t. Barite concentrate contains up to 86% of barite.Factory is working in water recirculation conditions. Owing to that in barite cycle fatty acid collector is used, technological water from tailing repository contains fatty acids soap up to 25 mg/l. Before submission into sulfide cycle this water is conditioned with active carbon to delete the main part of fatty acid collector. The active carbon consumption makes 0,4-0,5 kg per 1m3 of water or 1,5-2 kg per ton of ore. The above mentioned consumption of active carbon improves reducing of contents of fatty acid collector from the initial concentration of 25-30 mg/l to 4 mg/l. At concentration 4 mg/l fatty acid collector does not render negative influence on flotation index in sulfide cycle. At the absence of active carbon pollution of sulfide concentrate and its irrevocable lost are observed."

Jan 1, 2003

By Kang N. Zhong, Hui H. Luo, Yunan Phosphate Chemical Co., Yi H. Wei, Yao J. Li, Yu L. Wang

"The three kinds of phosphate ores (igneous, metasedimentary and sedimentary) found in China have great differences in flotation flowsheets and reagents suite because of their crystal structure and mineral composition. The igneous and metasedimentary apatites have good floatability with fatty acid as collector and waterglass, sodium hydroxide or sodium carbonate as conditioners. The sedimentary phosphate is very difficult to beneficiate by direct flotation because of their poor floatabilities and relatively high content of MgO and SiO2, even though the dolomite depressants are used sometimes.The differences in floatability of apatites in China are closely related to their differences in specific surface area. The amount of collector to float apatite increases with the specific surface area. Apatite with lower specific surface area showed good floatability at lower collector concentration. Apatite with a higher specific surface area needed a higher concentration of collector. The content of CO3 2- will affect the specific surface area of apatite by distortion of its crystal structure and consequently affect its floatability.Dolomite can be easily rejected from apatite in a weak acidic medium (pH=5), especially in phosphoric acid medium by reverse flotation. Quartz and siliceous gangue in sedimentary apatite can be removed by direct flotation using fatty acid or by reverse flotation using amine. Amine is not practically applied because sedimentary apatite in China is usually very fine and needs fine grinding, which always results in excessive, very fine, stable and non-flowable foam.Based on the floatability of phosphate ore in China, a two-stage flotation process, direct and reverse flotation (D+R), was developed to beneficiate sedimentary ore. For the Haikou phosphate ore containing 25.11% P2O5, 3.46% MgO and 16.5% SiO2, a concentrate containing 31.84% P2O5, 0.48% MgO and 14.8% SiO2 can be obtained through a continuous D+R test at a recovery of 89%."

Jan 1, 2003

By Yuexin Han, Zehong Wang, Fujia Yu, Wanzhong Yin, Xinchao Wei

Bauxite is the main raw material in alumina and refractory industries. China has plentiful bauxite resources, most of which belong to the diaspore type bauxite with characteristics of high aluminum content, high silicon content and low ratio of alumina and silica (A/S). The resources with A/S 4-7 account for more than 60% of the total resource reserves of bauxite. Therefore improving the A/S through bauxite desilication is the key task of bauxite concentration in China. Normally the grinding fineness of 80-90% - 0.074mm is required in the bauxite flotation process. Thus fine grinding of bauxite ores is necessary, which leads to the high energy consumption. In the meanwhile, bauxite ores are easy to produce slime during grinding processes. The large amount of slime produced in fine grinding greatly worsens the process environment of bauxite flotation, affects the separation performance and results in the loss of metal. Also, fine grinding makes the flotation concentrate difficult to dewater, while the water content in the flotation concentrate must be removed by distillation in the subsequent alumina dissolution process, causing the increase of energy consumption and cost in the production of alumina. In this study, the selective grinding behaviors were examined with Henan Bauxite as feed. Separation of alumina and silica at a coarser grinding fineness was achieved and new route was explored to enhance the desilication in bauxite concentration to improve the A/S of bauxite concentrate.

Jan 1, 2003

By L. A. Vaisberg

"Crushing and grinding are the two most common industrial processes. These processes consume nearly 20 per cent of the entire electric power produced worldwide. This enormous amount of electric power consumed results from the fact that modern crushing and grinding machines employ the processes first introduced by the prehistoric man, namely those of compression, impact, attrition, and cutting. The material thus handled decomposes indiscriminately, and almost completely ignoring the microscopic cracks and other defects of its structure. Apart from the irrational use of the power, the crushing and grinding processes currently in use result in irretrievable loss of useful components or else in a substantial deterioration of the final products obtained, all as a result of incomplete grinding or, reversely, of overgrinding, palletizing, or fracture of particles.The principal type of equipment that has almost universally been used all over the world for more than 150 years for crushing both natural and synthetic minerals comprises unbalanced jaw and cone crushers. The driving element of crushing bodies in these machines is an unbalanced weight, which transfers the crushing body, allowing it to squeeze the material within the eccentricity value only. The maximum reduction ratio achieved by such a drive is 5, which is due to the rigid kinematic arrangement of the crusher, its dynamic unbalance, and the impossibility of increasing the number of impacts on the material being crushed. Moreover, conventional machines cannot cope with super hard materials, and their mechanism is vulnerable to damage by uncrushable objects.On the basis of fundamental research into the theories of solid body and vibration, OAO Mekhanobr- Tekhnika have developed a range of vibrating jaw and cone inertia crushers that make a reduction ratio of 30 feasible in an open-circuit operation with the reduction ratio monitored within a wide range. In these crushers, the eccentric drive is replaced with a vibrating one. In this way the rigid kinematic drive became dynamic, thus allowing pieces of material to be crushed in a thick layer due to the effect of their bumping into each other, and with the amplitude changing automatically. This results in a number of advantages as compared with conventional crushers:"

Jan 1, 2003

By Máximo Pérez, Julio C. Videla, Rosa Dzioba

"This paper reports the hydrometallurgical treatment of gravity concentrates of gold samples and outcrops associated with graphite ores obtained from:• flotation tailings of crystalline graphite minerals• outcrop samples of graphitic rock associated with auriferous minerals and free gold located in the Villa Union district and surrounding areas - La Rioja Province - Argentina.Previous studies of the flotation potential of crystalline graphite minerals failed to consider the presence of noble metals.The samples represent a mineralized zone of crystalline graphite which is distributed in different formations with a NE - SW trend in Maz, Punta Colorada and Las Ramaditas hills, covering an area of about 300 square kilometers."

Jan 1, 2003

By Ponisseril Somasundaran, H-L. Chen, University of Athens, D. R. Nagaraj, Zhonghua Pan, Jing Wang

Gums are often used as depressants for talceous gangue minerals in the flotation of nickel and platinum bearing ores. However, the mechanisms of gum adsorption on talc are not clearly established. In this work, adsorption of guar gum at the talc-solution interface is investigated using spectroscopic and allied techniques. Guar gum adsorption on talc is not affected significantly by changes in solution conditions such as pH and ionic strength. Electrokinetic studies showed that guar gum decreased the negative zeta potential of talc but did not reverse the charge. Fluorescence spectroscopy studies conducted to investigate the role of hydrophobic bonding using pyrene and dansyl probes showed no evidence of the formation of hydrophobic domains at talc-aqueous interface. Urea, a hydrogen bond breaker, reduced the adsorption of guar on talc to the same extent as that for guar/alumina system, in which hydrogen bond plays an important role. All of the above results suggest that one of the main driving forces for guar adsorption on talc is hydrogen bonding rather than electrostatic or hydrophobic force.

Jan 1, 2003

By Richard K. Komarek, Antonios Zavaliangos, Roman T. Dec

"The work in the paper introduces a 2-dimensional finite element model for analyzing particular material processing in a roller press. Two basic roller geometries are considered: (a) smooth rolls (used for milling and compaction) and (b) rolls with cavities, commonly used for briquetting. A model is presented that is suitable to analyze material behavior through all stages of the rolling process: feeding zone, nip region, neutral plane and release section. It can predict pressure, shear stress, slip of the material over the roller surface, material velocity field, failure of the compact during release and the course of other important process variables.MODEL, RESULTS AND CONCLUSIONSAn associated Gurson model was employed as a constitutive model for the material. The calibration of the model was based on experimental results from an instrumented compaction die. Coulomb friction law was used to describe phenomena on the material/roller surface interface. Powder River Basin sub bituminous coal fines with moisture content 9% was used as a model material.Two finite element models have been set up, one for the briquetting roll and one for the “equivalent” flat roll. Approximately 3200 plain strain continuum elements with reduced integration (CPE4R) were used. Lagrangian-Eulerian (ALE) approach in conjunction with judiciously applied remeshing was employed with the commercially-available, dynamic explicit version of ABAQUS finite element code.Comparison of model predictions with experiment shows that there is an agreement in terms of the general trends of experimental values recorded on laboratory roller presses. Gurson model overpredicts stresses at low densities and, as a consequence, overpredicts roll force and roll torque."

Jan 1, 2003

By Sun Chuanyao, Jia Muxin

Generally, if the bond valence (BV) between metal ion and oxygen of the mineral is greater than 0.8, only surface species –Me-O-H or –Me-O exposures on the mineral interface, if the BV is between 0.2-0.8, the metal ion exposures on the interface, and if the BV is less than 0.2 the metal ion dissolves into water. The PZCs of oxide minerals and island silicate minerals are determined by the bond valence of the bond in the mineral crystals, the higher the bond valence the lower the PZC of the mineral. So the PZC sequence of Al2SiO5 minerals is kyanite> andalusite> sillimanite. The general rule for framework silicate minerals is as: The higher the Al content, the lower the PZC of the mineral, when the ratio of Al to Si in the tetrahedron skeleton is below 1:3. The higher the Al content, the higher the PZC of the mineral, when the ratio of Al to Si in the skeleton is between 1:3 and 1:1. The general rule for layer silicate minerals is summarized as: the three-layer silicate minerals have much lower PZCs than that of the two-layer silicate minerals. The threelayer silicate mineral with the octahedron layer occupied by lower charged cations has lower PZC than that of the three-layer silicate mineral with the octahedron layer occupied by higher charged cations. The twolayer silicate mineral with the octahedron layer occupied by lower charged cations has higher PZC than that of the two-layer silicate mineral with the octahedron layer occupied by higher charged cations. The layer silicate mineral with Al substitution in the tetrahedron layer has lower PZC than that of the layer silicate mineral without Al substitution in the tetrahedron layer. Such pyroxene minerals whose M1 is occupied by a trivalence cation and the M2 is occupied by a monovalence cation has lower PZCs than those both M1 and M2 are all occupied by bivalence cations. Such hornblende minerals whose M2 is occupied by a trivalence cation and the M4 is occupied by a monovalence cation has lower PZCs than those both M2 and M4 are all occupied by bivalence cations. There is no Si4+ or 4 coordinated Al3+ exposures on the surface of framework silicate minerals, the metal ions of three layer or chain silicate minerals are compact between tetrahedron layersor chains, they hinder the metal ions to interact with oleate acid radical, the metal ion octahedron layer exposures on the surface of a two layer silicate mineral, but the the oleate acid radical can not attach to a metal ion by replacing a –OH- that connects three metal cations in the same time, So the floatability of such silicate mineral is bad. The metal octahedron chain style of an island silicate mineral affects it floatability, the mineral exposures octahedron chain metals with two dangling bonds in two directions floats better than the mineral exposures octahedron chain metals with two dangling bonds in one direction.

Jan 1, 2003