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By Xian Jian Guo, Lei Li, Hua Wang

The distribution and behavior of As, Pb and Zn elements in the copper smelting process were investigated using thermodynamics. The differences between thermodynamics evaluation and practical smelting processes were analyzed. The main factors affecting the distribution of the elements are oxygen enrichment in blowing, copper matte grade and smelting temperature. In general, the distribution ratio of As, Pb and Zn to off gas increases with the smelting temperature and decreases with oxygen enrichment in blowing. Meanwhile, their distributions in matte decreases and that in slag increases with the increase of copper matte grade. There is some gap in distributions between thermodynamics evaluation and practical smelting processes. INTRODUCTION The copper concentrates usually contain a number of minor elements, the control of which in copper smelting processes is often a key to the quality of the anode copper produced and may also have a bearing on the overall economics of the process (Yang et al., 2017). Knowledge of the thermodynamic properties of the minor elements in slag is very important in the control of the slagging reactions (Takeda Y, Ishiwata & Yazawa, 2007). In addition, the environmental contamination caused by the minor elements associated with copper-bearing ores, such as As, Pb and Zn, has become more and more important (Wang, 2004). Arsenic, lead and antimony, which are all carcinogenic metalloid elements, are usually contained in iron-rich wastes, and theirs emissions are considered to be one of the foremost environmental concerns (Wang, 2004). It is important to elucidate the elements distribution of them in the reducing-matte smelting process. The distributions of As, Pb and Zn elements in the copper smelting process are dependent on many factors, including the temperature, raw material composition, reduction atmosphere, concentration level, and slag chemistry etc. (Chen L Z, Xu X, 2016). Generally, these minor elements mainly distribute in phases of gas, copper matte and slag in the smelting process (Shu, Wang, & Qu, 2016). The arsenic exists mainly in the form of sulfo-arsenides in the copper concentrate, and it will decompose and be oxidized in the smelting process (Chen & Lu, 2016). Part of the products, including AsS, AsO, As2 and As2O3, evaporates into the gaseous state, and some other part enters into slag phase in the form of As2O3 and As2O5 (Wang, Guo, & Tian, 2017). Meanwhile, the As2O3 in the slag phase can also be reduced to metallic As and combine with Cu, S, Fe forming Cu3As2, As2S3 and Fe3As2, and then enter into copper matte. During the copper smelting process, about 50% of zinc enters into slag phase in the form of ZnO and 45% exists in the copper matte in the form of ZnS. Little volatizes into the gas phase. Most lead exists in forms of PbS and PbO in the copper concentrate, and it is mainly distributed in copper matte in the smelting process (Zheng & Lin, 2015).

Jan 1, 2019

By A. J. Russell

"This paper investigates why it is critical for a mine to accurately determine thermal rock properties and virgin rock temperatures. Theoretical simulations of deep mining production zones have demonstrated that thermal conductivity (k), virgin rock temperatures and specific heat (cp) significantly impact rock heat predictions which can be the dominant component of a mine’s heat load. Natural variability in these factors showed that realistic errors can have a significant effect on mine heat loads. This can ultimately affect miner safety and introduces risk to the viability and sustainability of a project. INTRODUCTION Accurate heat load determinations are critical to ensure that underground working conditions are maintained within legislated and mine specific parameters to safeguard the safety and productivity of employees. Underpredicting mine heat loads will result in hot underground conditions, which risk the health and safety of employees, reduce the productivity of employees or stop production if legislated temperatures in working areas are exceeded. Overestimating mine heat loads will result in increased capital and operating costs reducing the viability of the project. Over- or under- predicting the heat load for a project will increase the project risk. Heat sources in a mine can broadly be broken into two categories. These two categories are defined by Hemp and Rawlins (2014) as natural and artificial heat sources. Those sources which depend on the size, location and depth of the mining areas are defined as natural heat sources, whereas those heat sources which are a result of the actual mining activities are defined as artificial heat sources. Autocompression, or the conversion of potential energy, to enthalpy is an important consideration when determining the air temperature in the mine and its interaction with natural and artificial heat sources. It is documented by Jones (1985) and Hemp and Rawlins (2014), that the heat flow from rock in deep mines can dominate other heat sources; information from BBE’s archives show that this is between 40% and 60% of the total heat load. They also point out the importance of accurately measuring both the thermal rock properties and virgin rock temperatures (VRTs) for determining and planning the ventilation and refrigeration requirements for a mine. Both of these texts cite multiple methods for calculating the heat-flux and ultimately the heat load for the different working areas in a mine. All of these methods demonstrate that the heat flux and heat load will increase proportionally with increased thermal conductivity (k), specific heat (cp) of the rock or mineral, and VRT depending the area of the mine or mining method."

Jan 1, 2019

By O. A. Ojo, R. G. Ding, M. C. Chaturvedi

In this study, the fusion zone microstructure of tungsten inert gas weld of a directionally solidified NhAl-base alloy was examined by the standard metallographic techniques involving the use of optical, analytical scanning and transmission electron microscopes equipped with energy dispersive spectrometer. Fusion zone cracking was observed to be closely associated with interdendritic secondary solidification microconstituents identified as consisting of y, y' and NiMo (Y) phases. Depression of solidification temperature to the terminal ternary eutectic reaction temperature of the system during cooling is suggested as an important factor contributing to the fusion zone cracking.

Jan 1, 2006

By K. M. Ed

MR. J. C. NICHOLSON: The author has discussed his subject in a very thorough manner. One difficulty is the tendency to regard a 'permitted' explosive as a 'safe' explosive. There is no such article as a safe explosive; any explosive is only as safe as the man who handles it. In making up the primer, the method illustrated in the paper is alright for the ordinary explosive but not so for the sheathed explosive, for the sheathing would be punctured. MR. T. L. McCALL: I fee! quite certain that there would be little, if any, trouble from flame shots or misfires if the author's suggestions were carried out. There is a tendency on the part of the shot-firer to over-shoot, so as to bring clown more coal for the miner, and frequently a shot has not sufficient burden imposed upon it. Shooting one hole may not only lessen the burden on an adjacent hole, but may practically release it altogether, in which case the second hole should be fired with a very small charge, or perhaps it might not be necessary to shoot it at all. While the paper refers to shooting in the coal only, it should be under-stood that the instructions given are equally applicable to brushing shots. I do not wish to bring up any contentious point, but would the author say a word on cushioning with air gaps and on multiple shooting? Single shooting in rock might open up a feeder of gas which could be ignited by the ?second shot.

Jan 1, 1940

By Robert B. Parsons

"The Canadian tax treatment of mining operations outside Canada is not as attractive as the treatment of Canadian operations. Further, the Canadian company that invests abroad a host of complex rules. This month, Tax Notes examines some of the major Canadian tax considerations confronting the Canadian company that wants to invest abroad. IntroductionCanadian-based mining companies are investing abroad more than ever before. These foreign investments trigger a complex set of tax rules that are distinct from the rules that apply to Canadian investments. In most cases, careful tax planning is mandatory if the company's tax liabilities are to be minimized. This article summarizes the main tax considerations that need to be taken into account with respect to a mining investment outside Canada.Branch Versus SubsidiaryOne of the first questions that arises in connection with a prospective foreign investment is ""Should we invest directly (that is, in a branch operation), or should we invest through a foreign subsidiary?"". In the case of a branch operation, the Canadian company owns and operates the business directly - that is, the foreign business assets are part of the Canadian legal entity. In the case of a foreign subsidiary, the foreign business operation is owned and managed by that subsidiary. The tax treatment of a branch and a subsidiary can be quite different."

Jan 1, 1994

By Forrest A. Kerr

Northern British Columbia is a term which probably conveys to various individuals quite different meanings. To the average person it signifies an area of indefinite size and indefinite position which may start at Prince Rupert, Stewart, or somewhere else, and end at Alaska or .the Yukon. Many people, in their conception, fail to encompass in their mind's eye that vast tract of land lying ~o the east of the panhandle of Alaska. Few realize that the area north of an east-west line through Stewart represents more than one-third of the Province and is, of course, the part most appropriately designated as northern British Columbia. This section, more especially the northernmost 100,000 square miles, from political, geographic, and economic viewpoints stands isolated perhaps more than any other part of British Columbia. Unlike the rest of the Province, it has no coast line, being cut off from the Pacific ocean by a narrow strip of Alaska. It is bounded on the north by the Yukon, and on the east by Alberta. In the south this northernmost 100,000 square miles is limited by a divide of rugged mountainous country separating the drainage basins of the Stikine and Liard rivers from those to the south.

Jan 1, 1929

By Abdurrahman Tosun

It is very important for after blasting processes that muck pile fragmentation is predicted and controlled during blasting. Therefore, a significant research effort has been devoted to the development of mathematical equations that predict the value of average muck pile fragmentation. The specific charge parameter used in all of these equations is determined as the ratio of the total mass of explosives used to break a volume of rock. The length of blast surface and the row number of the blasthole are ignored in the calculation of the specific charge. However, in a blasting operation, blasthole geometry may result in additional material being impacted by a blasthole. This is due to effect shares of in both end sides of blastholes and the back region of blasting surface. In this study, a total of 14 blast tests, 8 at the first quarry and 6 at the second quarry of the Bati Anadolu (Western Anatolia) Cement Factory, were performed. In each study area blast tests were designed in the same direction continuously to provide stable structural properties of the rock. Therefore muck pile fragmentation depended on only specific charge values for each blast tests. Specific charge values were calculated according to both an average blasthole and also the total volume of material occurred as a result of blasting for each blast tests. During loading until the end of blasted material the front, the back, the arm off and the bucket off pump hydraulic pressure values occurred in hydraulic pistons of the loader were determined with a lot of data received for each blast tests. After that the relationships between specific charges values obtained according to two different methods and hydraulic pressure values of the loader were established with two correlations. The relationships between specific charges values obtained according to the total volume of material occurred as a result of blasting and hydraulic pressure values of the loader occurred as the best results especially the blasting operations that have the total length of blasting surfaces are short.

Aug 1, 2013

By F. Andrieux

"Extruded aluminum profiles are increasingly used for lightweight vehicle construction. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles, not only the stress state but also the orientation influenced both the deformation and damage behavior. For the material characterization smooth tensile tests were performed in six orientations, both stress-strain curves and r-values were registered. Moreover notched tensile and shear-tension tests were performed in three directions. Finally punch specimens were tested to investigate biaxial loading. Digital image correlation (DIC) analyses were performed to determine local strain values such as critical values at failure. Numerical investigations were conducted with the strain based damage model GISSMO, which is well suited and widely applied for crash simulation. For a strain based failure model the choice of the deformation model is crucial. Deformation models with increasing complexity were investigated to find the best compromise over all experiments. It was found that there is still a great requirement on development of a material model which describes the orientation dependence of the hardening behavior over all stress states in order to be able to use a strain based failure model reliably.INTRODUCTION Weight reduction is an important step for less energy consumption and as a consequence aluminium is increasingly used in automotive parts. An important field of application is the well-established aluminium extrusion which allows the realisation of quite complex shapes of profiles required for an innovative lightweight design with integrated functions. Typical applications are chassis parts, bumpers, crash elements, air bags, etc. Especially the Al–Mg–Si medium strength alloys of the 6000 series can be easily extruded to form complex profiles and prevail for extrusion. Since fracture strains of aluminum profiles are relatively low, damage modeling is crucial for reliable crash simulation. For aluminum profiles not only the influence of the stress state but also the orientation with respect to the extrusion direction have an influence on both the deformation and damage behavior and need to be characterized. The effect of orientation on deformation behavior has been intensively investigated in the last decades and material models haves been proposed (e.g. Barlat & Lian, 1989; Barlat, Lege, & Brem, 1991; Barlat et al., 2003) to describe accurately anisotropic behavior. However it can be noticed that the parameters of anisotropic material models often rely on the yield stress in different directions, which means that the effect of strain hardening is not automatically accounted for. The accuracy of the models at large deformation is not guaranteed and has to be verified. In contrast to deformation models both the characterisation and the modeling of anisotropic damage behavior are not systematically studied. Isotropic failure models based on a critical strain as function of stress triaxiality (ratio of the hydrostatic stress to von Mises equivalent stress) are widely used for crash application (e.g., Bai & Wierzbicki, 2010; Sun, Andrieux & Feucht, 2009; Sun et al., 2013). The mechanisms of failure are manifold and not fully understood; to develop an anisotropic failure model it is mandatory to also have experimental data in different orientations for loading scenarios other than uniaxial tension, e. g. shear, biaxial tension, which implies an extensive experiment plan. This makes the development of failure models more challenging than deformation models for which it is possible to develop a reasonable anisotropic model using the framework of yield function and calibrate the material parameters based on results of tensile tests in different directions. Moreover the development of deformation and failure models are intricate as the variables governing the damage evolution are predicted by the def"

Jan 1, 2018

By Robert B. Parsons

"Two recent decisions by the Canadian courts could reduce the taxes paid by many profitable mines in Canada. At a time when the mining sector is hurting from an ever increasing tax burden and soft prices, the results of two cases are welcome news. Mining companies are well advised to check prior years' tax returns in the context of these developments. IntroductionSince 1976, the income tax legislation has provided a reduced rate of tax for taxpayers engaged in the mining of mineral resources, through the mechanism of the ""resource allowance"". The deduction given for the resource allowance effectively reduces the federal rate of tax by one quarter on resource profits. In general terms, ""resource profits"" are defined to include a taxpayer's income from: the production and processing in Canada of ore to any stage that is not beyond the prime metal stage (or the pellet stage or its equivalent in the case of iron ore); and, royalties computed with reference to the amount of value of production from mining operations in Canada.In computing income from these sources, the taxpayer must deduct expenses that may reasonably be regarded as applicable to those sources, with the exception of expenditures for Canadian exploration and development or financing costs.As a result of the mechanics of the calculation of the resource allowance, one quickly realizes that the lower the expenses deducted from the resource profits, the higher the resource profits and consequently the higher the 25% resource allowance. The impact of the recent court cases is to narrow the range of expenses which are required to be deducted in the determination of the resource profits.The two cases are outlined below."

Jan 1, 1991

By W. Mirihange

Considerable mechanical property decline is always observed at the Heat Affected Zone (HAZ) of AA 5083, This occurred as a result of the thermal effect on the hardened material, It is highly beneficial to have a prospective metallurgical procedure to overcome this decline of properties. Therefore, experiments were set to evaluate the effectiveness of a quick post weld heat treatment process with the AA 5083, Optimum results were obtained at 473K and with approximately 600 seconds time, The interplay between the time, temperature and mechanical properties are possible to explain by the Lifshitz-Slyozov-Wagner (LSW) theory and by considering the composition of the material.

Jan 1, 2005

By W. R. McQuarry, M. E. Wilson

"The structural relations of the ore deposits of the Staclacona mine are of considerable interest, for they not only illustrate the effect of a change in competence of the wall-rock, but also the effect of either the convergence together of two faults, or a change in the clip of a fault, or both of these factors, on ore deposition.The mine is in claim M.L. 1818 near the eastern end of Pelletier lake and lies about 2 miles south of the town of Rouyn. The Company was organized in 1926 to explore claims in Rouyn, Dufresnoy, and Beauchastel townships, but attention was directed mainly to those in Rouyn. Underground work began in 1928 with the sinking of the main shaft to a depth of 300 feet. Except for 1930 and 1931, the mine has been in operation continuously since that time. Production, which began in 1936, up to the end of 1946 has amounted to 1,381,422 tons of ore from which gold and silver having a total value of $7,861,860 were recovered. The average grade of the ore milled in 1946 was $6.68.GEOLOGYThe rocks in which the Stadacona ore deposits occur are mainly volcanics of the (Keewatin) Abitibi series intruded here and there by numerous dykes, sills, or masses of diorite. Single dykes of olivine diabase and lamprophyre are also present in the property and are intersected in the mine workings. The volcanic rocks are part of a wide belt of northward dipping lavas and pyroclastic rocks, having a thickness of over 16,000 feet, that extend from the east-west trending belt of Timiskaming sediments on the south northward to the Horne Creek fault and form the south limb of a large syncline. The volcanic rocks within the property consist of numerous, east-west trending, northward dipping flows of andesite and a few flows of rhyolite interbedded with rhyolite ruff and agglomerate. The angle of dip throughout most of the property is 60° to 80°N., but in the main cross-cut on the 850- and 975-foot levels stratification in rhyolite tuff was noted dipping 35°N. The tuff at this point lies above an intrusive mass of diorite and it is probable that the change in dip results from the way in which the tuff and agglomerate have been thrust aside by the intrusive."

Jan 1, 1954

By P. Turcotte, E. Karampinos

"Construction of underground excavations in squeezing ground conditions faces several technical challenges that can result in delays in production and high costs due to rehabilitation. A review of the behaviour of drifts under squeezing ground conditions was undertaken at the LaRonde mine. In particular it focused on implemented strategies to control the observed large deformations. The mine experiences a large range of squeezing ground conditions, mostly driven by the presence of foliation and high stresses. This results in large deformations over one meter in radius. A comprehensive ground control strategy has been implemented with the aim to manage, rather than arresting drift closure. The evolution and effectiveness of the employed support strategy are discussed based on documented field observations. In complement to the field implementation numerical models are used to provide further insight on the observed squeezing conditions.INTRODUCTIONThe development of underground excavations under squeezing ground conditions is usually associated with excessive rehabilitation and significant failure of ground support due to large deformations. Cost research case studies have concentrated on squeezing ground conditions in tunnelling. An overview of the methods used for the identification and quantification of squeezing and the numerical methods for the simulation of these conditions in tunnelling has been provided by Barla (2002). Numerous support systems that can manage ground deformation are available for civil engineering tunnelling. Nevertheless, the use of these systems in mining would result in high support cost and production delays. Mining operations have higher development rates and shorter service life. This study focuses on the behaviour of underground excavations under squeezing ground conditions in hard rock mining.In a mining context, the magnitude of deformation is usually higher than in civil engineering tunnelling as there is a higher tolerance for operation purposes. Potvin and Hadjigeorgiou (2008) noted that in mining, squeezing is encountered when the total displacement of an excavation reaches at least tens of centimeters over the life expectancy of a supported drive and is associated with considerable damage to the ground support."

Jan 1, 2015

By C. M. Acuna, M. Sherrington

In high temperature processes thermodynamic equilibrium is assumed and therefore chemical potential of elements, among the condensed phases, have to be the same. In such situation impurities distribute accordingly and their fractional distributions are affected by the masses of the coexisting phases. It has been claimed Teniente Converters perform quite well for smelting high impurity concentrates, especially in respect to volatilization and/or slagging. Production of high matte grade near white metal composition, requiring moderate oxygen enrichment in the process air, results in a huge mass of gas and therefore a high fraction of impurities report to it. Similarly, by recycling different sources of slag, flue dust or other materials, the mass of the final slag is increased and so do the masses of impurities reporting to the slag. Nevertheless, above a certain level the recycling of smelter byproducts is no longer feasible and the cycle has to be halted, unless higher impurity mattes are accepted. Although the process might be continued during converting and refining, lengthy and expensive measures have to be taken if suitable anode copper for electrolytic refining is to be achieved. In the present study samples of high arsenic matte grade and slag were obtained on a pilot scale. The matte samples, on the order 75%Cu, were equilibrated with slag at varying ratios in magnesia crucibles under CO/C02 atmospheres at 1523 K. After 24 hours equilibrium matte and slag were rapidly solidified and analyzed by copper, sulfur, iron and arsenic. Furthermore, industrial samples of matte and slag, in the order 75%Cu at 1523 K, were obtained via a special quenching sampling device to determine the association of copper and suspension of matte and copper in slag. Based on the results, the distribution coefficient of arsenic between slag and matte was evaluated along with copper species in slag and the fractional distribution of arsenic, in the coexisting phases, was determined as a function of the ratio mass of slag to mass of matte.

Jan 1, 2007

By E. R. Landry

This paper reviews the current state of electric furnace technology, with emphasis on some of the more recent developments. A large section of the paper is devoted to the use of increasingly high power inputs by arc furnace operators. Operating practices are then covered, including some of the newer techniques which have been tried.

Jan 1, 1967

By L. Tapia

The main disturbance for stability in primary grinding using SAG mills is related to continuous changes in the ore being fed to the plant, such as size and hardness. Searching for stability is the first step to accomplish, before trying to maximize the mill throughput. The time variability in the characteristics of the ore being fed from the mine to the plant must be known or inferred to perform adaptive changes in the grinding process control. In day to day operation, such information is not available in real time. Transport times and inventories between the mine and the plant complicate the situation. Under this scenario, Minera Los Pelambres implemented a grinding optimization strategy, based on the real time analysis of certain process variables, such as ore size, mill current consumption, pebble generation and throughput. As a result, both grindability and stability indexes are inferred. This is equivalent to inferring the ore characteristics by knowing its effect on the grinding behavior. These two indexes permit control of the SAG mill total charge level and hence, allow optimization of throughput by means of an expert control system.

Jan 1, 2007

By L. Torres, C. S. R. Rondestvedt, M. Bustos

In February 2010, Teck’s newest Concentrator at Mina Carmen de Andacollo (CDA), Andacollo, Chile was commissioned. The Concentrator is a single line configuration, comprising of one 36 ft diameter x 20 ft long SAG mill driven by an 18,000 hp gearless drive. The SAG mill feeds two ball mills each 25 ft in diameter x 40.5 ft long, each driven by a total of 19,000 hp through dual pinion drives. A series of four phases will be reviewed from operational readiness, mechanical completion, commissioning, and ramp-up. Also, now after 6 months of operation, this paper will review the significant steps taken during ramp-up enabling the announcement of commercial production, in October 2010.

Jan 1, 2012

By O. Hall

DISCUSSION AT QUEBEC MEETING MR. A. V. CORLETT: With drill holes radiating from a common point, is loading carried to the collars, and do you undertake to distribute the powder evenly? MR. R. V. PORRITT: When the collars of the holes, particularly the diamond-drill holes, are close together, two out of three holes are loaded only to within six or seven feet of the collars, and the intervening holes are loaded close to the collars. When the collars are farther apart, the holes are loaded close to the collars. No spacers are used, and the holes are filled solid with powder, this applying particularly to the diamond-drill holes, except, of course, where the collars are close together and some holes are not loaded close to the collars. MR. J. G. L. McCREA: I would like to enquire in respect to the various efforts made to reduce the cost of diamond drilling to the lowest point, what is. the relative cost of the solid bit to the standard bit? It would seem that the solid bit has the higher cost. MR. PORRITT: The non-coring or solid bit gives a slightly lower diamond cost than the coring bit. With the coring bit, the greatest diamond loss is on the inside stones, apparently due partly to vibration, but mainly to the core blocking against these stones. This condition, of course, does not apply with the non-coring bit. Our experience is that the non-coring bit, which drills out a much greater area, has a diamond consumption slightly less than the coring bit. The non-coring bit is sturdier, and is far less liable to damage in starting holes and in drilling through cracked or broken ground.

Jan 1, 1939

By Ben Cottrell

In this paper technical drilling is referred to as the process of collecting engineering and metallurgical parameters for subsequent mine design considerations. Throughout the development of a mineral exploration property there are various opportunities to ?piggy-back? technical drilling onto the routine exploration drilling process, helping to reduce future costs and delays associated with re-drilling and missing information. This article is written from the engineers and metallurgists point of view, to outline some best practices for exploration borehole planning and technical data collection requirements.

Aug 1, 2013

By K. Ohto, B. B. Acihikari, H. Kawakita, M. Gurung, S. Alam

Two kinds of adsorbents were prepared from persimmon tannin extract to investigate their adsorption behavior of metal ions from hydrochloric acid solution; one was prepared by treating with concentrated sulfuric acid while another was prepared by immobilizing functional groups of quaternary amine. The former adsorbed only gold(III) and its maximum adsorption capacities was evaluated as high as 1510 g/kg while the latter adsorbed not only gold(III) but also palladium(II) and platinum(IV), the maximum adsorption capacities of which were evaluated as 820, 89 and 101 g/kg, respectively. For both adsorbents, practical adsorption of base metals was not observed.

Jan 1, 2011

By J. W. Coetzee, H. E. Deist

Carbon-in-pulp (CIP) and Carbon-in-leach (CIL) processes are used extensively in the gold mining sector to recover aurocyanide from solution. This paper discusses the modelling of these operations, using various simplifying assumptions, in order to simulate the effect of changing operating conditions on the dynamics of the system. It is assumed that the adsorption and leaching rates are a function of concentration difference between the source phase and recipient phase. The simulation was set up using Matlab's Simulink interface. Plant variables are solved using a medium scale Newtonian search algorithm in Matlab, where the differences between the actual and predicted plant outputs are minimized on a continuous time-line.

Jan 1, 2005