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"The mining industry uses many types of mineral and metallurgical plants to produce saleable product from ore mined. Plant design history has left current operations with a mixture of manual operation and various forms of automated process controls. Consequently, we typically see high variability in the continuous operations together with a shortfall in the attainment of full capacity, or higher utilisation of consumables.At a level of best practice, ‘Operational Performance Excellence’ focuses on process control, using automation and control systems to deliver process optimisation. This more sophisticated delivery is a great deal more difficult than the first stage of equipment selection / installation. It includes the appropriate selection of the right instrumentation, control system, key process knowledge, individuals with a solid control engineering background / experience, and the essential backing / support of the operations management team together leading to higher value delivery. Robust solutions can be realised, considerably minimising process variation, thus leading to process optimisation. This approach results in an easier, efficient and safer process while providing considerable returns for the plant owners.How variable are your processes, and do you maintain optimised process performance with dedicated resources, modern instrumentation, ‘best practice’ control systems and performance monitoring tools? In this paper, these questions and their possible answers are discussed."

Jan 1, 2014

PERSPECTIVE ?Natural resources exploration, extraction and beneficiation is complex and challenging: ?Input costs rising, complexity increasing, rising stakeholder management needs, regulatory compliance issue, etc. ?With increasing costs and complexity of managing operations are we simply getting less bang for our buck?

May 1, 2013

By Z. Xiao, A. R. Laplante

"The recovery of gold by gravity from grinding circuits differs from virtually all other gravity recovery approaches in that stage (or unit) recoveries are low, typically 1 to 5%, but overall recoveries are generally in the 25 to 60% range, because individual gold particles are presented many times to the primary recovery unit. Full-scale recovery is difficult to predict from benchscale tests. Further, maximizing metallurgical recovery is generally not the primary objective, because of the more efficient downstream recovery circuit (flotation or cyanidation). In this paper, a new concept, the gravity recovery effort, is presented to assist in the design and optimization of gold gravity circuits. It is defined as the product of the circulating load treated by the primary gravity unit, the recovery of this unit, and the gold room recovery. Predicted gold recovery is linked to the recovery effort, the size distribution of gravity recoverable gold (GRG), the dimensionless retention time in the mill and the partition curve of GRG. A case study of economic optimization of the gravity recovery effort is presented. INTRODUCTIONPredicting gold gravity recovery from grinding circuits has always been a hit-and-miss exercise. The problem can be traced to the highly variable gravity recoverable gold (GRG) content of ores, high GRG circulating load, fraction of the circulating load treated, and performance of primary gravity recovery and gold room. Typical values, highs and lows are shown in Table 1."

Jan 1, 2001

By S. Chung

Mining in highly stressed ground conditions has been an increasing challenge at the Brunswick mine. Over the past 30 years, two large regional pillars were established on the 1000 m Level to support the ground for safe extraction of the surrounding ore. The South Regional Pillar contains about 5 Mt of ore and the North Regional Pillar has about 3 Mt of ore. In the fall of 2000, mining activities were suspended following a series of ground movements around the South Regional Pillar along weak geological structures. After extensive geotechnical investigations, a decision was made to carry out a mass de-stress blast in the West Ore Zone (WOZ) to cut the principal stress across an area of 135 m along strike and 86 m high. At the end of July 2001, the WOZ mass blast was successfully initiated. Following this success, the mine decided to take a similar approach to de-stressing the North Regional Pillar (NRP). The final mass blast was taken in early February 2003. Advanced blasting technologies, including state-of-the-art electronic detonators and blast simulation, played an important role in achieving the successful blasts. The high precision of delay timing and long delay duration of the electronic detonators ensured accurate and reliable initiations of over 800 blastholes in the WOZ mass blast. Orica’s DMC_Blast (Distinct Motion Code) simulation code was used to study different blasting blocks for the desired timing in the initiation sequence. This paper describes the process of applying electronic detonators in complex blasts, and discusses how blast simulation results were interpreted to guide engineering design of the mass blasts.

Jan 1, 2005

By C. Gosselin, G. M. Payenzo, C. Bazin, M. Desnoyers, G. Chevalier

"ArcelorMittal Mines Canada operates hydraulic classifiers to reduce the silica content of an iron oxide concentrate from 4.5% to less than 1.2% SiO2. Sampling campaigns were conducted to develop a preliminary model for the hydraulic classifier. Results show that iron oxide and quartz are respectively concentrated in the coarse and fine size fractions of the classifier feed. The mineral partition curves in the classifier and the size distribution of the minerals in the feed are used to simulate the classifier operation in order to identify the source of variability observed in the daily plant production data. Results indicate that most of the variation is probably caused by unsteady operating conditions of the classifiers.INTRODUCTION Hydraulic classifiers are a class of gravity separation devices (Wills, 1992) used to classify particles according to their size and specific gravity. Hydraulic classifiers also known as density separators (Hearn, 2002) combine hindered settling and upward flow of water to selectively entrain light particles to an overflow stream. Denser particles settle to an underflow stream. Hydraulic classifiers are used for various purposes ranging from cleaning of coal (Das, Sarkar, & Mehrotra, 2009), recovery of chromite from plant tailings (Kumar, Tripathy, & Rao, 2009) to upgrading iron oxide concentrate (Hearn, 2002). ArcelorMittal Mines Canada operates several hydraulic classifiers to upgrade an iron oxide concentrate by removing fine quartz and other light minerals from hematite that is the main iron oxide mineral. A project was initiated to analyze the operation of the classifier in an attempt to identify the source of the variability in the production results and to assess the potential of increasing iron recovery in the classifier. One possible disturbance for the classifier operation is the change in the classifier feed composition and size distribution, while the other considered disturbance is the operation of the classifier. The paper is divided into five sections. The first section summarizes the ore processing sequence for the production of iron oxide pellets to identify the position of the hydraulic classifier in the process. The second section describes the hydraulic classifier. The third section discusses the sampling campaigns conducted on the hydraulic classifier. The method used to process the data from sampling, the results of the data processing and simulation of the classifier are discussed in the remaining sections."

Jan 1, 2012

By Paul Laframboise, Nigel MacDonald, Mike Hallewell, Robert Thorpe

"Galmoy Mine, owned by Arcon Mines Limited, has operated since 1997, and is one of three operating lead/zinc mines in Ireland. Changes in ore type starting in mid 2002 created challenges to metallurgical operations at Galmoy. This resulted in unacceptable lead and zinc flotation performance, which prompted initiation of a formal plant review and a subsequent stabilization programme. This involved a structured review of operational practices, development of a new Standard Operating Procedure (SOP) which in turn led to significant changes in process control equipment needs in conjunction with extension of zinc flotation cell residence time.This paper will describe the metallurgy of the Galmoy operation. Reasons for the poor metallurgy experienced in 2002 will be described, as well as the solutions identified to overcome these problems. By the second quarter of 2003, these solutions had been implemented and recoveries had risen to record levels.INTRODUCTIONGeneralGalmoy Concentrator is located in County Kilkenny (Refer to Figure 1 below) and was constructed during 1996 and commissioned in 1997.The concentrator at Galmoy had been designed initially to treat 650,000 tonnes per annum of primarily CW ore type. The main mineral of economic significance was sphalerite (Typically 10 to 11% Zn) with some minor galena (0.7%Pb) in a dolomite (Magnesium Carbonate) host rock.The only other competing sulphide mineral was pyrite (Circa 3 to 5% Fe in Mill Feed. This CW ore type predominated the first 6 years of production, but in August 2002, the ore mineralogy changed due to significantly higher levels of pyrite rich G ore body being blended in with CW ore."

Jan 1, 2005

By J. B. Scott

"A computerized cost estimating program developed with the use of the Lotus 1-2-3 spreadsheet program has produced dramatic savings in preparing estimates for operating costs, equipment fleet size and manpower requirements for underground mines.The program is used by Dynatec to support its consulting engineering projects, particularly feasibility studies. The 'first principles' approach is used to prepare detailed estimates under direct labour and supplies categories and maintenance costs for each mining operation . User notes have been developed to guide the estimator and ensure appropriate consideration is given to the specifics of the particular mine.A typical case history is illustrated and the ease by which alternatives and sensitivity analyses can be prepared is demonstrated. IntroductionHistorical MethodsMining engineers have used one or a combination of methods to prepare operating cost estimates for new or existing mine s. Operating companies have access to historical cost data and generally use this for preparing estimates. Consulting engineers do not usually have direct access to such information and must rely on mining companies (the present or previous clients); publications (text books, equipment manufacturers manuals, CMJ reference manual, etc.); annual reports (applicable to public companies); previous studies (to be used with caution as conditions change from mine to mine); and first principles (the subject of this paper), for cost information:Definition of First PrinciplesA first principles approach to cost estimating considers individual primary work elements of an operation. Quantities of work items are developed from the mine plans, production rates, geographic and physical layouts etc. The knowledgeable estimator, assisted by experienced operations personnel, can assign appropriate resources (equipment, labour, supplies and services) to each work element and establish productivities. Completion of the cost estimate is then largely arithmetic."

Jan 1, 1988

By Don Thompson

It isn?t a lie if you don?t tell the whole truth The pictures National Geographic didn?t print Other photos National Geographic didn?t print?

May 1, 2009

By D. M. Doyle

"A study of the various components contributing to energy costs and their relationships to generally trended operating data, such as tonnage, operating costs, etc. over progressively shorter time periods provides information for an energy audit. A study of annual data gives some insight into the importance of various energy components. As the time frame of the study 11rogresses through monthly, daily and finally, into quarter hourly data, the variations become more evident and most important, strategies develop to minimize energy costs. The results of an audit conducted during the summer of 1978 at Wesfrob Mines are reported to illustrate this important phase, prerequisite to a meaningful energy cost avoidance program.The balance of the paper deals with the energy conservation program at Falconbridge Nickel Mines Sudbury Operations, the material and control equipment, the commitment, the new energy accounting practices and lastly, the policies. Examples of successful energy conservation endeavors include automatic peal electrical load control, waste heat recovery from mine air and compressor cooling water, energy reductions resulting from lower building temperatures and curtailmen: of idling loads. The use of pulse meters to measure the flow of gas, steam, compressed air and electrical energy, with their signals interfaced to process computers, allows monthly, daily and if necessary, immediate reporting of energy and energy per unit of production information. The program so reported at Falconbridge’s Sudbury Operations is credited with an annual cost avoidance of .9 million dollars in a 14.0 million dollar annual energy account."

Jan 1, 1979

By Roy McKinstry, Mark Rantapaa, Thomas Bolles

"More efficient drilling and blasting techniques have shown measurable improvements in throughput at the Barrick Goldstrike wet grinding mill.A decrease in throughput at the autoclave, due to increasingly hard ore, was identified in early 2002. A team of individuals from the Open Pit and Process areas participated closely on the Drill-to-Mill (D2M) Continuous Improvement initiative to ensure that it would address the needs of both groups, with the target of improving throughput in future years, despite the projected harder ores. Plant studies were conducted to determine if adjustments to drilling and blasting could positively influence throughput. At the Goldstrike mill the greatest opportunity from the D2M initiative is realized on the hardest ore. Grinding throughput for softer ore, <15 kWh/st, can meet or exceed the downstream pressure oxidation requirements. Grinding throughput for harder ore, >15 kWh/st, is limited by the SAG milling capacity. Better fragmentation in the D2M ore, as demonstrated by image analysis, increased throughput 5% to 10% (25 to 50 stph) compared to the standard mining methods.Better fragmentation and a subsequent increase in mill throughput were achieved through the use of:1) Electronic caps for more precision and flexibility, as well as for allowing extremely fast shots.2) Explosives with a higher velocity of detonation (VOD), to provide for improved shock energy.3) Improved distribution of the explosives by decreasing pattern spacing.INTRODUCTIONThe Barrick Goldstrike Open-Pit group, along with the Process division, began experimenting with novel blasting technology and techniques to improve mill throughput in the spring of 2001. A series of tests were developed to determine if fragmentation and ultimately mill throughput could be influenced by optimizing the drilling and blasting program in known"

Jan 1, 2004

By J. A. Finch, A. R. Laplante, R. Espinosa-Gomez

"The Niobec concentrator rejects up to /5% of the Nb as slimes (-10u.m). The recovery of Nb from these slimes by column flotation is being studied. An essential condition for selective flotation is slimes dispersion. A particle size analyzer, the Sedigraph 5000D, was used to monitor dispersion in plant waters with combinations of organic and inorganic dispersants and flotation reagents. Flotation reagents were particularly detrimental to dispersion with sodium silicate. The best dispersion conditions were selected for column flotation tests. These tests revealed that reagent combination had a pronounced effect on froth stability. Careful frother selection achieved good froth stability under conditions of good dispersion. Plant water increased the required dispersant concentration causing mineral depression.IntroductionSlimes (-10 u.m) rejected at Niobec contain up to 15070 of the over-all Nb content . Recovery of Nb from these slimes would significantly increase over-all recovery. A suggested recovery route involves two phases: (1) carbonate flotation (to remove most of the carbonates) depressing silicates and pyrochlore (as currently done at Niobec); and (2) selective (direct) pyrochlore flotation from the silicates. Phase 2 has been addressed and several routes to achieve selective flotation are available. Phase I was attempted with the selective reagent scheme used at Niobec but a considerable amount of pyrochlore floated with the carbonates due to poor slimes dispersion."

Jan 1, 1987

By John A. Hansuld

Geochemical dispersion of metals under various environmental conditions is discussed within the frame-work of Eh (oxidation potential) and pH (acidity). In general, two aspects are considered -(1) the oxidation of certain primary sulphides in the outcrop or sub-outcrop environment, and (2) the movement of metals in different dispersion media. Practical applications of each are illustrated by means of exploration case histories representing environmental conditions in the Canadian Shield, the southwestern United States and the Caribbean.

Jan 1, 1966

By J. J. Bouillon

"Located in the northwestern portion of the Abitibi greenstone belt, Les Mines Selbaie is a copper-zinc (silver and gold) producer. Felsic tuffs host three are zones. Composed of sulphide veins and breccias, they are not exhalative massive sulphide deposits, except, probably, for the massive pyrite (fragments and lenses) localized close to the top of the volcanic sequence.The total of all (mineable and mined) ore in the three zones presently outlined on the property, is of the order of 29.9 x 106 tonnes with average grade of 0.63 g/t Au, 37.02 g/t Ag, 1.21% Cu, 1.91% Zn.The ore reserve calculations and the daily production procedures are computerized to various degrees. The data handling process is highly computerized.Various geophysical methods are, and have in the past, been successfully used on the property. The ""mise-à-la-masse"" surveys were used to perform the geological interpretation of an underground deposit (A-2 zone). Presently the PULSE-EM surveys are performed in all surface and underground exploration drill holes."

Jan 1, 1990

By Bern Klein, Malcolm Scoble, Justin Widdifield, Andrew Bamber

"It has been suggested that the pre-concentration of ore underground can bring positive economic and environmental benefits to underground mining, particularly at extreme depth. The integration of mineral processing systems for coarse waste rejection and disposal into the underground mining environment has a substantial impact on the economics and operation of the mine. A case study for the integration of underground pre-concentration at Falconbridge’s Thayer Lindsley and Fraser Copper operations in Sudbury, Ontario is discussed, with particular focus on ore evaluation, system design, integration, and impacts on the operation. Conclusions as to the overall feasibility and potential impacts of underground pre-concentration are presented.INTRODUCTIONObjectivesA scoping investigation has been conducted for Falconbridge Ltd on the Fraser Copper Zone and Thayer Lindsley mines in order to develop a better understanding of the operations, and to do a preliminary evaluation of the potential for pre-concentration of the ore underground. The objective was to develop a conceptual design and evaluation of a pre-concentration system for each site. The results are to be used as the basis for a more detailed future study.Underground Pre-ConcentrationThe pre-concentration of ore to reduce the quantity and improve the quality of material transported to the processing plant is not a new concept and has been in practise at several mines including the American Zinc Company in Mascot Tennessee (Munro et al, 1982), the Sullivan Mine in British Columbia and presently at Xstrata’s Mt Isa lead-zinc mine in Australia, as well as at several PGM mines operating in the South African Bushveld. For each of these mines, a high degree of waste rejection was achieved at a coarse particle size with good metallurgical recoveries. The benefits arising from the surface pre-concentration of ore are well documented in the literature (McCullough et al, 1999; Miller et al, 1978; Munro et al, 1982; Schena et al, 1990; Sivamohan & Forssberg, 1991)."

Jan 1, 2006

By C. Schuffeneger

"The design of SAG milling circuits for mining projects requires the incorporation of the energy consumption considerations and the evaluation between different flexibility-adding options to absorb the time-dependent variation in the ore lithology. In order to expand the focus of the engineering design, a higher level of deepness and quality in the baseline information must be achieved to elucidate all of the constraints on throughput, energy consumption and product quality generating a design optimization consistent with an integrated vision of the process. This paper presents a review of a collection of typical examples of the copper and gold mining project in the Chilean Andes, in which both process and energy efficiency criteria are considered when the focus is to deliver an integral solution that incorporate those areas in the design. The intensive use of energy in the SAG milling, the process continuity and the quality of the product are a function of the proper design and selection of grinding equipment and plant layout, aligned with the mining plan and associated with projected future expansions and production increases.INTRODUCTION Autogenous and Semiautogenous grinding technology, large diameter and short length mills, begins with the Handsel design. During the decade of 1930’s, Handsel-Hardinge studies led to cascade mill development. Nowadays, 80 years later, continuous improvements in design and technology have been conducted to a completely new generation of gearless SAG mills that have led to an increasing capacity at the concentrator plants. Considering the existing alternatives, SAG mills are the most implemented option for the grinding circuit today. This work presents a review of the SAG mill implementation parameters and circuit considerations and its correlations in the most recent projects in Chile with an ore treatment capacity above 50 ktpd since the decade of the 90’s up to now. From this period, the tendencies will be analyzed using project design data. Based on process design information, the recent SAG mill history in relevant projects related to the new generation of commercial SAG mills, technical associated considerations and performance will be discussed. Circuit selection based on energy utilization will be revised to bring up a more holistic perspective on the SAG mill circuit design concepts. As is now well known, the heart of every concentrator plant are the grinding mills. Higher demands on throughput, availability and power consumption optimizations require not only high performance electrical equipment but also a well selected grinding circuit. The energy efficiency issues associated to the circuits design will be reviewed."

Jan 1, 2012

By Y. L. Su, S. Vongpaisal, H. A. Smith

"It is extremely difficult for a mine&apos;s central control room operator to control peakpower demands and to maintain normal materials handling operations at the same time. An investigation of the Falconbridge Strathcona Mine &apos;s central control room has revealed that there are more than eight thousand possible combinations of ""situations"" that can arise. For such a circumstance, an expert system can become a very valuable tool to assist the operator in taking the most appropriate and timely action.A forward chaining expert system module has been developed for this application. The module is based on Level 5 ObjectTM software. It is graphics oriented and user-friendly. Training requirement is minimal.ForewordThis paper has arisen out of work carried out by YLS Associates and Falconbridge Limited as part of a contract between Falconbridge and the Department of Energy, Mines and Resources, Government of Canada, on the application of expert systems in mining operations.IntroductionThe electrical bill charged to large consumers by Ontario Hydro is based upon two elements: demand and energy consumption. The demand is the peak kilowatt level that the consumer has required during a monthly period. It is not uncommon for the demand portion to be as much as one third of the monthly bill. Energy consumption is the total kilowatt-hour s (kWh) consumed during the period.Ways to reduce the energy consumption part of the electrical bill involve utilizing energy-efficient equipment and operating machines in off-peak hours when a lower energy rate is charged. Maintaining the peak power below a critical level may require that simultaneous usage of major pieces of equipment be avoided. A 3000 kW skip run at an inopportune time could cost a company an extra $30,000 in that month&apos;s power cost.Potential disadvantages associated with peak power control are lost production due to work stoppage and increased operating costs due to the need to employ extra personnel. Most companies find these matters relatively easy to deal with and with incentives provided by Ontario Hydro, actively pursue this facet of energy savings (Harju , 1991)."

Jan 1, 1993

By P. Dyas, H. Zouitt, D. M. Smith

"Falconbridge Copper's Lac Shortt gold mine is located in northern Quebec approximately 300 km northeast of Val D'Or and 100 km west of Chibougamau (Pig. 1). Engineering for the mill commenced in early 1983 with a feasibility study. The plant was commissioned in the fall of 1984 at a capital cost of approximately $12 million. Design capacity was 750 tpd which was increased in the fall of 1985 to the current level of 1200 tpd.The ore at Lac Shortt is free milling, grading an average of 5.5 g/t gold which is finely disseminated throughout the host rock. Pyrite at 3 to 5% by volume and traces of copper mineralization are also present.Some of the latest gold processing techniques known at the time of design were incorporated into the mill. These include carbon-in-pulp, pressure stripping, electrowinning of pregnant solution and induction furnace refining. The plant also features several innovations such as a unique interstage carbon retention screen in the CIP circuit and the outdoor location of the cyanidation feed thickener, mill solution tank and reagent storage silos despite -40° Celsius winter temperatures.This paper describes the current mill process and discusses some of the problems encountered during the first two years of the plant's operation. CRUSHINGThe Lac Shortt surface crushing facilities are located in a separate building, isolated from the wet processing circuits for dust and noise control reasons. The crushing plant equipment was originally utilized at the Manibridge operation in northern Manitoba where it had been designed to operate at 135 tph. However, at Lac Shortt a rate of only 80 tph has been achievable to date, mainly due to the hardness and frequently slabby breakage characteristics of the ore. Therefore, in order to meet fine ore requirements at the current mill throughput of 1200 tpd, the crushing circuit is run seven days a week. 24 hours a day. Availability has been averaging 65%."

Jan 1, 1987

By Leslie F. Sawatsky

Raw water import requirements for oils sands mines depends mainly on factors such as ore processing rate, ore material characteristics, tailings processing technology, tailings storage systems, process water storage operations, the phase of tailings production, and non-recoverable seepage losses from tailings ponds. These factors can be readily quantified to calculate raw water import needs. Nevertheless, mine water balance continues to be misunderstood by some regulators, stakeholders and possibly even mine operators. Confusion over consumptive uses has led to a focus on recycling which is not necessarily applicable to a closed circuit water management system. Some water conservationists focus attention on raw water intake rules instead of the technical decisions that control consumptive uses. Typical oil sands mine water balances for various types of tailings operations, are analyzed to illustrate the effect of controllable and uncontrollable parameters as well as major options that need to be explored for reducing water demand. Uncontrollable parameters including tailings fines content, oil content of ore, connate water, mine depressurization water inflows and surface water hydrology. Controllable parameters include storage operations, advance water supply ahead of mining operations, type of tailings operation, net tailings pond seepage losses, and tailings impoundment operations. Potential reductions of raw water supply rates may be obtained by providing greater on-site storage to attenuate fluctuation in water demand, advance water accumulation prior to mine start up, early commencement of CT operations, thickened tailings disposal and paste technology. Water conservation measures should be focused on reducing on-site process water storage and water content of tailings material.

May 1, 2004

By V. S. Papezik

Pyrophyllite, an AI silicate used in the production of ceramic materials, is formed mainly by alteration of felsic to intermediate volcanic rocks, either directly (at temperatures of 250-300°C and pressures of 1-2 kbar) or by subsequent low-grade metamorphism of aluminous protoliths produced by thermal fluids or even by prolonged weathering. Most pyrophyllite deposits in North America are concentrated in a belt of Late Precambrian volcanic and sedimentary rocks, the "Avalon Zone ", which extends along the eastern flank of the Appalachian mountain system from Newfoundland to the southeastern U.S.A. The only producing pyrophyllite mine in Canada is an open pit located near the settlement of Foxtrap on the Avalon Peninsula of Newfoundland. It lies in a belt of rhyolitic flows and pyroclastics intruded by a granitoid pluton. The rocks have been leached along a shear- or fracture zone, depleted in silica, alkalies, Ca, Mg and Fe by the action of hydrothermal fluids, and recrystallized to a very fine-grained massive assemblage of pyrophyllite, muscovite ("sericite") and quartz. High-grade pyrophyllite lenses contain small nodules of diaspore with minor barite; rutile is present in trace amounts. The close proximity of all pyrophyllitized zones on the peninsula to the granite contact suggests that the alteration was produced by thermal fluids genetically connected with the granitoid pluton. The fine-grained pyrophyllite-bearing rocks, with their simple mineralogy, are suitable for quantitative modal analysis by X-ray diffraction. Chemically analyzed samples from the alteration zone were used for the construction of working curves by plotting calculated mineral content against the intensity of selected diffraction peaks. The accuracy of the resulting curves is ±4.5% for quartz, ±3.6% for pyrophyllite and ±2.7% for muscovite. Pelletized samples give best results. The XRD method is suitable for a rapid analysis of a large number of grab or core samples to outline higher-grade areas for more detailed sampling.

Jan 1, 1978

By Brian Hart, Roger St. C. Smart, James Francis, Mark Biesinger

"There are a number of challenges involved with the surface analyses of different mineral phases from process streams in a flotation facility. The first of course is to collect samples that are representative of the process and to ensure that they remain in a pristine condition prior to introduction into the instrument. In mineral processing, sample collection from the different streams is done on site and preservation involves simply removing oxygen from the sample by bubbling nitrogen or argon gas through the sample and snap freezing with dry ice.The second challenge in studying the surface chemistry of specific minerals is to find reliable methods of mineral phase recognition. In surface analysis of mineral particles confident mineral selection can be difficult with many multi-metal minerals (e.g. chalcopyrite, pyrite, sphalerite) and with precipitated, adsorbed, reacted and contaminant species in the outermost molecular layers.In this paper we show that principal components analysis (PCA) of ToF-SIMS data provides improvement in phase recognition, particle selection and associated variations in surface species. We will demonstrate, with specific examples, that this technique can be utilized to differentiate surface chemical factors promoting (hydrophobic species) or inhibiting (hydrophilic species) flotation.Species recognition based on the PCA method in a study of Cu transfer between chalcopyrite, pyrite and sphalerite mineral mixture clearly identified a statistical difference in copper intensities between the sphalerite and pyrite phases. A similar ToF-SIMS/PCA based study applied to concentrate and tails samples collected from the Inco Matte Concentrator demonstrated extensive CuOH and NiOH transfer between the chalcocite and heazlewoodite minerals. The statistical analysis has been able to confirm some mechanisms and deny others proposed to control recovery and selectivity giving more focus on the control factors.The ToF-SIMS PCA statistical analysis has elucidated differences in surface chemistries which illustrate the discriminating depressant action of adherent aluminosilicate (gangue) fine particles and adsorbed ions on the surface of sphalerite grains. In the flotation test concentrates, HIC conditioning resulted in the removal of these gangue fines thereby improving surface collector attachment efficiency, promoting a greater recovery of sphalerite."

Jan 1, 2007