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By F. L. Pellet, S. Maiolino

"The determination of rock bolt contribution to reinforced joint shear strength is still a challenge, especially for assessing reinforced rock mass stability. For this purpose, several experimental studies have been performed during the last decades, mostly on small scale rock joint and bolt specimens. However, to accurately assess the rock bolt contribution, scale effect has to be accounted for. For this reason full scale lab tests are required as an alternative to in situ tests for which boundary conditions are more difficult to control.In this paper the results of an experimental program carried out with a large shear box, dedicated to test bolts in full scale conditions is presented. Different rock bolt diameters and different rock bolts inclination with respect to the shear plane were tested Experimental results were satisfactorily compared with an analytical model which is able to compute the contribution of the rock bolt to the shear strength of the joint as well the associated displacement of the joint. These conclusions allows us to validate the model in order to help the designer of reinforced rock engineering structures, such as slope or underground openings, to precise the optimum installation of rock bolts. INTRODUCTIONFully grouted rock bolts are commonly used for rock masses reinforcement to ensure the stability of rock slopes and underground cavities. For this purpose, the determination of rock bolt contribution to reinforced joint shear strength is of the utmost importance. During the last decades, several experimental studies have been performed to investigate the behavior of bolted rock joint. For obvious reasons, almost all the experiments were achieved on small scale bolted rock joint specimens (Bjurström, 1974; Azuar, 1977; Dight, 1983; Egger & Fernandes, 1983; Schubert, 1984; Spang & Egger, 1990; Egger & Zabuski, 1991). These studies made it possible to assess the influence of different parameters such as the bolt’s diameter, the number of bolts, the angle between the bolt and the joint, the nature of the rock, the friction and the dilatation angle of the joint. However, to accurately assess the rock bolt contribution, scale effect has to be accounted for (Vallier et al., 2010). For this reason full scale lab tests have been performed as an alternative to in situ test for which boundary conditions are more difficult to control."

Jan 1, 2015

By George R. Pratt

Although the title of this paper focuses attention to the Winnipeg coal market the following remarks should be considered applicable not only to conditions in Winnipeg but to the whole western coal industry. Technical descriptions of coal and coal-burning have been omitted. These details are already covered in other numerous publications. In discussing a market the first consideration must be the product which is required to be sold. The class, quality and price at the point of origin must be taken into account and therefore this feature will be discussed before proceeding to outline conditions in the Winnipeg local market. The writer thinks of coal as a manufactured article, not, as it is generally considered, a fuel to be dug from the ground and dumped into the consumer's bin. The work of manufacturing must be considered in detail:- 1. Consider first the coal as it is in the ground: (a) What is its fuel value? (b) Where is its market? © With what will it be in competition? 2. Consider secondly: (a) What it will cost to mine the coal. (b) What has to be done to prepare the coal for market after it is mined. This must be considered in conjunction with the answer to question 1 ©. 3. Thirdly, consider the method of business to be adopted by the producer:- (a) Is it proposed to build a market on price? Or (b) On quality?

Jan 1, 1925

By M. E. Wilson

"The property of McWatters Gold Mines, Limited, is in the east-central part of Rouyn township and about 6 miles east-southeast of the town of Rouyn. It includes 35 claims, the group of 5, staked originally, and 30 claims acquired in later years. The Rouyn-Val d'Or road and the Noranda Senneterre branch of the Canadian National railway both pass within a few hundred feet of the mine.The group of claims in which the mine occurs was first staked in 1922, but gold was not discovered until August 1932 when a schistose zone including veins of quartz carrying considerable free gold was laid bare in a stripped area in the northeastern part of claim R.11604. Diamond drilling undertaken in 1932, and continued into 1933, shouwd that the gold extended for at least 1,000 feet along the strike. A 3-compartment shaft was sunk to 418 feet in 1933. A mill having a capacity of 50 tons a day was constructed in 1934, and enlarged to 150 tons in 1935. Production began in 1934 and continued without interruption to June 1944. Except for a few diamond drill holes, there have been no operations on the property since that time. The maximum depth of the mine workings is 1,50) feet. A total of 368,013 tons of ore having a value of $3,946,752 and an average grade of $11.04 was mined during the years of operation.GEOLOGYThe ore mined from the property occurred within the south limb of an eastward plunging syncline of volcanics and sediments cut off on the north by the Cadillac-Bouzan Lake fault. Because the rock formations within the syncline have been severed from those outside with which they were originally continuous, their correlation is based almost wholly on lithological similarity. They include an irregular middle zone of conglomerate and greywacke underlain by north and south bands of andesite agglomerate and andesite tuff, in which lenticular bands of pillowed andesite are included."

Jan 1, 1954

By Wael Abdellah

Mine haulage drifts are the primary access to the mining blocks of an orebody in a multilevel mining system of a tabular ore deposit. The stability and functionality of haulage drifts are thus crucial to the success of a mining operation. Drift instability could lead to serious consequences such as injuries, production delays and higher operational cost. In this paper, the performance of the haulage drift stability is evaluated on the basis of the primary rock support system comprising 1.8 m resin grouted rebars in the drift walls and 2.1 m long bolt in the back. Two failure criteria namely the extent of Mohr-Coulomb yield zones around the drift, and linear elastic brittle shear failure are adopted and compared, with respect to lower level and same-level mining and filling sequence in the vicinity of the haulage drift. The case study is one of the #1 Shear East zone of the Garson Mine in Sudbury, Ontario. Random Monte Carlo (RMC) technique, which has been previously established to assess the haulage drift stability, is employed in this investigation. The RMC technique is used in conjunction with finite difference modelling software FLAC for random assignment of model input parameters in the FLAC grid. Deterministic model results reveal the drift behaviour in terms of deformation (convergence) and mining-induced stress distribution. Comparison between the two different criteria is carried out to determine which method is most suitable in evaluating unsatisfactory drift performance. The results are presented in terms of probability of instability and categorized with respect to failure condition and mining step. It is shown that the brittle shear failure condition based on linear elastic response calls for enhanced support system at a later mining step than what Mohr- Coulomb yielding condition does. The paper presents a detailed discussion of the stochastic analysis results.

Jun 1, 2012

This paper presents the results of research aimed at proposing new solutions in the area of belt conveyor elements. Many factors, such as energy consumption costs, and operating costs of belt conveyor elements, including belts, idlers and drives have an impact on the operational costs of conveyors. The paper presents special tests of new materials for the bottom cover of an energy-saving belt conveyor, which decrease rolling resistance. It also presents large-scale in-situ tests of a high-output belt conveyor for the purpose of simultaneous measurements of various types of conveyor belts (standard vs several energysaving types) under typical operating conditions of a lignite surface mine. Improvements in materials used for the bottom belt covers, supported by specially developed comprehensive tests of the new types of belts have provided valuable results of various proposed solutions. Since the tests of belts were done at exactly the same time and in the same operating conditions, direct comparison of the results is valid and should lead to a substantial decrease in the conveyors? drives? energy consumption, which will improve the effectiveness of belt transport and minimize its negative influence on the environment.

Aug 1, 2013

By C. R. Edwards, D. G. Feasby

"Over the last 50 years disposal of uranium mill tailings has evolved from dumping untreated tailings into the nearest depression to depositing chemically-stabilized tailings into highly engineered management facilities. This paper describes the evolution of disposal methods and the criteria which have determined the development path followed. Remediation techniques to bring older and now unacceptable tailings deposits into satisfactory compliance with today's· regulations are reviewed.With the closure of the uranium mines in Elliot Lake, Ontario, considerable effort is being made on decommissioning the tailings areas by developing long term maintenance of water covers. The innovative methods being used to develop these water covers are detailed. Methods now under development in Saskatchewan for subaqueous deposition of high density or paste tailings for permanent disposal in mined out open pits are described.SummaryThe technology for uranium mill tailings disposal in Canada has evolved considerably over the past 51 years. This evolution has been driven by an improving understanding of how best to safely and permanently store tailings, in conjunction with stricter environmental protection regulations. Old sites are being decommissioned in situ, but may require long term care and maintenance. The use of water covers is an important technique in eastern Canada to prevent intrusion, radon evolution and, for the Elliot Lake tailings, acid generation. The major drawback of water covers in any above ground disposal method is the requirement that a long term maintenance and monitoring plan be put into effect for each site.New higher grade mines in Saskatchewan will increasingly use disposal in mined-out pits using the pervious surround method and/or paste tailings technology as a method to permanently dispose of these wastes and to permit “walkaway” after a few years of monitoring."

Jan 1, 1996

By S. Gregory

Many gold treatment plants have sulphides and coarse particle gangue components that contain gold in their tailings (cyanide leach residues and flotation tailings). Coarse and very fine liberated gold may also be present in some tailings streams. Two issues usually govern the economics of recovering additional gold from gold occluded in sulphide and gangue particles. The liberation characteristics of the gold in the sulphide and coarse gangue (gold liberation versus grind size) is the first and most important of the two. If fine grinding can liberate a reasonable amount of the gold, then the next important issue is how effectively these two constituents can be concentrated. Flotation will achieve high sulphide recovery but is usually costly. Selectivity is also an issue because of entrainment. Continuous centrifugal gravity concentration offers a viable solution to the recovery of both sulphides and coarse gangue however selectivity is also likely to be a problem. The possibility of improving concentrate grade by using a Falcon B separator was investigated. This paper describes a program of test work carried out on a gold leach tailings using a laboratory Falcon '13' separator. The program involved three different bowl angles: 10, 12 and 14 degrees and two bowl speeds (giving 250 and 350G accelerations). A number of tests were also performed on samples that had free gold present to ascertain the size-by-size recovery of gold in these samples.

Jan 1, 2005

By J. E. Moran

A groupd of French capitalists, La Compagnie Française des Mines d'Or du Canada, has undertaken the considerable task of developing Otter creek, in the Atlin district, B.C., by hydraulic mining methods. It has long been known that the gravels of this stream carry sufficiently high values in gold to make it attractive as a mining venture, but it was impossible to ignore the existence of formidable natural obstacles to hydraulicing them, and these needed to be taken into serious account before embarking upon any costly programme of development. The tide to the Otter Creek leases was originally held by Mr. H. Maluin, a French engineer well known throughout the north, to whom was to fall the task of financing whatever programme might be decided upon. It was he, too, who would have to assume the responsibility of finally passing judgment upon the practicability of the various devises for overcoming the adverse natural conditions. With an infinite attention to detail, which I believe to be a characteristic of the French people generally, he studied his problem and was finally able to submit to his financial backers a programme which left the very minimum possible to the hazard of accident or chance. Dr. Mandy, on his visit to Otter creek this season, expressed the opinion that our method of opening this difficult creek presented certain features which might be successfully applied in placer operations elsewhere in British Columbia, and it is largely for this reason that the present paper has been prepared. I shall set forth, as well as I can, the practices which have enabled us to overcome rather easily some of the obstacles which nature had unkindly placed in the path which we must take. The natural flow of water in Otter creek is far too little to deal success-fully with the rather excessive amount of glacial drift overburden which lies directly over the gold-bearing gravels. For this natural defect, the only remedy was to procure more water. This we have clone through a system of flumes and ditches, totalling between ten and eleven miles in length, which bring to the mine a supply of water adequate for our needs.

Jan 1, 1932

By D. L. Griffith

THE realization by metallurgists of the important effect that traces of impurity may have upon the properties of a metal, and their steady demand for purer and still purer metals, have made the special cools for 'trace' analysis of increasing value. In the United States at least, spectrographic analysis is becoming the standard method for determining the impurities in zinc die-casting alloys. The Hudson Bay Mining and Smelting Company, as a producer of virtually pure zinc, uses the spectrograph to control the purity of its products, and-as the electrolytic method is employed here-to control both the impurities in the electrolyte and those 'trace' elements, which, while they do not contaminate the zinc, have a great effect on the plating efficiency. The general plan of the laboratory is shown in Figure l; the housing for air purification, which is on the roof, is indicated by broken lines. One of the chief factors affecting the layout was the easy way in which a spectrographic assay can be spoiled by contamination. To minimize the quantity of dust tracked in, the laboratory was made separate from the general research laboratories, and an office was placed between the two. This arrangement has its drawback because of the traffic through the office, but it has effectively cut down dust. For similar reasons, the available space was subdivided into a number of small rooms, and the air currents in the laboratory were so arranged that dust would be carried where it would do least harm. Air is drawn in at the roof over a 50-kilowatt bank of Calrod heaters, through Annis air filters, by a No. 4 Sirocco fan. Most of it is forced into the spectrograph room, but some goes to the office and darkroom. The air flow is from the spectrograph room, through the plate-measuring room, into the chemical laboratory, where it is exhausted by a No. 1% Sirocco fan on the fume hood. Air can also re-circulate from the plate-measuring room back to the heater. The arrangement is such that the air in the laboratory is maintained at higher pressure than the outside air; consequently, no dirt enters through cracks about the windows and doors. A thermo-regulator holds the temperature constant within one or two degrees; only on the hottest days in summer does the temperature rise enough to affect the focus of the instrument.

Jan 1, 1940

By T. S. Li, D. Ilievski, I. Livk

Micromixing of the fluid and the particulate phases in a continuous gibbsite precipitator was investigated for three different micromixing states, namely maximum mixedness (MM), complete segregation (CS), and maximum mixedness of the fluid but complete segregation of the particulates (MMF-CSP). The influence of the micromixing on continuous precipitation of gibbsite was studied at different precipitation conditions via simulation. Three different cases were considered with respect to the precipitation kinetics: (1) gibbsite secondary nucleation is favoured with slow crystal growth and agglomeration rates; (2) gibbsite crystal agglomeration and growth are dominant mechanisms with secondary nucleation suppressed; and (3) gibbsite crystal growth is the only relevant phenomenon. Simulation results for the cases (1) and (3) showed that the crystalline products for both the MM and MMF-CSP micromixing states were very similar, but the product obtained from the CS micromixing state was considerably different. This indicates that at those precipitation conditions the fluid micomixing has the dominant effect on the product properties, and the particulates micromixing effect is insignificant. However, when operated under the conditions of fast crystal growth and agglomeration kinetics, i.e. case (2), both the fluid and the particulates micromixing were found to affect the precipitation process, resulting in a significantly different product. Computational Analysis in Hydrometallurgy 35th Annual Hydrometallurgy Meeting held in conjunction with the 44th Annual Conference of Metallurgists ofCIM Calgary, Alberta, Canada Edited by

Jan 1, 2005

By A. H. Duffield

"Forming part of the Prairie Evaporites, the sylvinite layer mined at Alwinsal underlies the Blairmore quicksands and the water-bearing Devonian formations. Production is achieved by a method of trackless, continuous mining of rooms, leaving pillars for natural support. The paper describes the development of the mine, and the equipment and organization employed in the operation and maintenance of the underground facilities."

Jan 1, 1972

By E. M. Hillary, D. F. Sangster

"Abstract - As a contribution to the World Minerals Geoscience Database Project, an index-level database comprising information on 142 SEDEX Pb-Zn deposits and occurrences was constructed in Microsoft Access 95 format. Although consisting of only basic information, the compilation, with full referencing of all data, is possibly the largest non-corporate SEDEX Pb-Zn database in the world. It thus provides an opportunity to make geoscience queries of SEDEX Pb-Zn deposits on a scale not previously available. This report provides a summary of the results of a few such queries both as a contribution to a better understanding of SEDEX lead-zinc deposits and as a demonstration of what even such a simple database can offer.During the compilation process, it became apparent that SEDEX Pb-Zn deposits could be assigned to one of the following three sub-types: Type 1 (53.5% of total) in which sulfide minerals are the only exhalative components; Type 2 (33.1%) in which the exhalative components are sulfides plus chert, siderite/ankerite, and/or barite; Type 3 (13.4%) which contains any components of Types 1 and 2 plus abundant iron-oxide minerals (commonly magnetite) and/or is associated with iron oxide-rich sedimentary rocks.Highlights of systematic queries of the database reveal that:1. a majority (84%) of the world’s SEDEX Pb-Zn deposits are not underlain by a discordant footwall feeder zone or vent complex;2. 63.6% of deposits occur in Proterozoic strata followed by a second peak in the Devonian (16.8%). Of those in the Proterozoic, 83% of Type 3 deposits occur in the Gondwanaland supercontinent, whereas only 42% of Type 2 and 39% of Type 1 are located in this large paleo-landmass;3. median (Pb+Zn) grades in Types 1 and 2 fall between 9% and 10% with a majority clustering within this range. Type 3 grades, however, range from ~1% to ~20% (Pb+Zn) with a median of 5%; 4. median size of Type 3 deposits is ~33 Mt, whereas Type 1 and 2 median sizes are ~7 Mt and ~8 Mt, respectively.The report concludes with a brief discussion of how an index-level database such as this can be used in conjunction with other, similar databases to reveal interesting and instructive relationships for guiding both research and exploration."

Jan 1, 1998

By J. Dubinski

Poland is the ninth largest coal producer in the world and Coal Company is the largest Polish producer of this deposit yielding 51% of national production. Coal Company mines are located in the Upper Silesian Coal Basin. These are underground mines which operate in difficult geological conditions at great depths of up to 1200 m. One of the most common natural hazards in Polish mines are rockburst and seismic hazard impacting on surface infrastructure and habitants. In the assessment of the rockburst and seismic hazard methods of mining seismology play a leading role. This paper presents progress that was achieved in the last few years in the implementation of new seismic monitoring systems and seismic interpretation methods for the prevention of hazard deriving from seismicity induced by mining. This progress in assessment of rockburst hazard and impact of seismic activity on the surface infrastructure was achieved through close cooperation between the Coal Company and Central Mining Institute ? the country?s leading scientific institute in the field of mining seismology. New theoretical solutions are in the process of testing in mines of Coal Company where seismic monitoring systems are installed and controlled by well-qualified personnel. Some directions of further joint actions to increase the effectiveness of rockburst and seismic hazard assessment are presented as well.

Aug 1, 2013

By Nelson Hogg

"THE NOR-ACME gold mine is located close to the north shore of Snow Lake, at 54°53' north latitude and 100°03' west longitude. It is about 75 air miles east of Flin Flon, and 36 miles by road from Wekusko at Mile 81 from The Pas on the Hudson Bay Railway.The claims which contain the Nor-Acme orebodies were staked in 1927 by C. R. Parres, who, with his sons, held the ground until 1938 when Nor-Acme Mines Limited was incorporated. In 194 l, on the recommendation of F. Ebbutt (1), this property was optioned by the Howe Sound Exploration Company, Ltd. A program of 50,000 feet of diamond drilling resulted in the outlining of two orebodies containing an estimated 5,000,000 tons with an average grade of 0.15 ounces per ton to a depth of 1,000 feet.A period of inactivity during the war years was followed by the construction of a mining plant capable of treating 2,000 tons of ore per day. Milling started in March 1949, and to the end of 1954 has resulted in the production of 383,793 ounces of gold and 32,906 ounces of silver from 3,331,403 tons of ore.General GeologyThe general geology of the Snow Lake area is described by J. M. Harrison (2), and will not be discussed here except insofar as it affects the Nor-Acme orebodies. The orebodies occur in rocks of Precambrian age that have been classified by Harrison as the Snow group, comprising meta-morphosed sediments interbedded with acid and basic volcanic rocks. The volcanic rocks include pyroclastic types which are unique in the region, a fact which led to their classification in the Snow group rather than the more widespread Missi group that generally occupies the same stratigraphic position above the Amisk group (Figure 1)."

Jan 1, 1949

By Peter Lighthall

What is an engineering firm?s role? ? The ideal situation is a life of mine service alliance with the owner ? Engineering firms are long term custodians of information ? Maintain consistency with established closure objectives, adjust closure plans to meet changing situations and technologies ? Develop range of solutions and present owners with risk profile The mine closure planning process ?new mines ? For metal mining, geochemistry is the issue ? The planning process: ?Sampling ?Waste characterization ?ARD prediction ?ARD control strategies ?Life of mine waste management planning ?Assessment of residual impacts ?Development of strategies for dealing with residual impacts ?Estimate closure costs ?One time decommissioning and reclamation costs ?Ongoing treatment/maintenance costs

May 1, 2006

By Kazutoshi Haga, Batnasan Altansukh, Yasushi Takasaki, Mohd Yazid Bin Abdul Razak, Atsushi Shibayama

"In this study, the volatilization behaviour of arsenic (As) and antimony (Sb) from arsenicantimony bearing minerals such as tennantite (Cu12As4S13)/tetrahedrite (Cu12Sb4S13) in copper ore was investigated using a roasting process. Specifically, the thermal decomposition of tennantite and the arsenic volatilization were investigated under nitrogen and air atmosphere. The roasting experiments were performed at temperatures ranging from 500 to 1,200oC and different retention times using a laboratory electric furnace. The results indicated that over 95% volatilization was achieved at 700oC. On the other hand, when the temperature increased to 1,200oC, volatilization rate of Sb reached to 90%. Therefore, volatilization of Sb requires high temperature compared to As. It suggests that As and Sb can be separated using temperature difference. Selective removal of As is possible at 700oC, subsequently Sb can be recovered as a volatilized product by increasing the temperature to 1,200oC. Meanwhile, volatilization of Cu and Fe was not observed on these conditions. The content of As and Sb in the residues obtained from roasting at 700 and 1,200oC was less than 0.3 and 0.75 mass%, respectively. The Cu content in solid residue at 1,200oC increased to 34 mass%. The clean copper concentrate with lower amounts of arsenic and antimony was obtained from the process. INTRODUCTIONRecently, arsenic (As) and antimony (Sb) contents in copper (Cu) concentrates are increasing year by year. Arsenic and antimony are present with Cu minerals such as enargite (Cu3AsS4), tennantite (Cu12As4S13) and tetrahedrite (Cu12Sb4S13) that associate with copper sulfides [chalcopyrite (CuFeS2) and bornite (Cu5FeS4)]. They are normally concentrated by flotation and treated in copper smelters. However, treatment of copper concentrates containing high amounts of arsenic and antimony by a smelting process is difficult due to environmental implications of toxic arsenic and antimony. As demand for copper continues to grow, the need to source copper from several types of resources including those that contain high levels of As/Sb becomes necessary. Therefore, a novel processes for the treatment of As/Sb bearing Cu concentrates are required. Reviews on copper resources such as enargite, tennantite and tetrahedrite containing high amounts of arsenic and antimony are covered widely in literatures by many researchers (Padilla et al., 1998; Welham, 2001; Vinals et al., 2003; Guo & Yen, 2005; Balaž & Achimovicova, 2006a; Filippou et al., 2007; Mihajlovic et al., 2007; Lattanzi et al., 2008)."

Jan 1, 2016

By Nelson Lawrence

An Electrical Risk Management/Inspection Program has been designed specifically for the mining sector in order to provide electrical code expertise and systemic gaps in electrical systems. Goals include improved safety and productivity, reduced injuries and help to enable businesses to better comply with the electrical codes and regulations that govern them. The Electrical Risk Management/Inspection Program is now recognized by some of the world?s largest mining organizations. Since June, 2001 these electrical safety advisory services have been available to underground and surface mine sites throughout Ontario and are now offered throughout Canada and around the globe. This program is also currently being applied to review new electrical installations for mine construction projects thus improving the safety and reliability of mine site electrical systems.

May 1, 2006

By A. B. Irwin

"Discussion at MeetingDR. D. DERRY (Ventures Limited) referring to the diagram (Figure 15) which shows a transverse structure section across the Central Slocan area, asked what the assumed structure at depth was, remarking that dips are steeper and more uniform at depth and that the contortions with gently-dipping axial planes are at higher elevations. He wondered whether the section represented ,part of a very large fold with steeply-dipping axial plane.MR. J. D. LITTLE (Canadian Exploration, Limited) replied that E. B. Mayo (Kelowna Exploration Company) and others had considered that the entire section illustrated faces to the southwest and represents part of the lower limb of a great overturned •syncline which is concave toward the southwest.DR. R. DEWIT (Geological Survey) remarked that the photograph of a ripple mark (Figure 7) showed internal lamination conformable to the ripple mark and wondered if the structure was not due to slumping during consolidation, since the normal mode of formation of ripple mark would seem to preclude the possibility of such internal stratification.MR. LITTLE remarked that in his opinion such structures should not be depended upon alone with-out other confirmatory evidence of the direction of tops of beds."

Jan 1, 1952

By L. G. Bergh

The experience developing a supervisory control and information systems in a SX pilot plant is presented. The plant is located at the Process Control Laboratory, Santa Maria University, in Chile. In this work, the problem of controlling this process is discussed and related literature is briefly reviewed. Then, an innovative control scheme organized in three levels, local, hydrodynamic, and metallurgical supervisory controls is presented in an architecture including field controllers, PLC, and PC networks. Operating decisions in the metallurgical supervisory control are taken with incomplete information from on-stream analyzers. The control proposed is based on metal and acid concentration predictions of intermediate and exiting streams through the use of dynamic and static models and flow rates and input concentration measurements. Preliminary results are presented. The main objectives are to develop and test intelligent techniques in a hybrid system, and to study measurement and supervisory control problems. It is expected to produce reliable results that will contribute to improve the efficiency of this emerging and important process.

Jan 1, 2007

By W. S. Szolga, M. Moser, M. D. Soderstrom, L. Cohen

"CYANEX® 272 is a phosphinic acid-based solvent extraction reagent used commercially since the early 80’s to recover and purify cobalt from sulfate solutions. Historically, the design of CYANEX 272 circuits has involved the selection of an optimal pH profile during pilot-scale testing using mixbox pH control. The desired pH profile is required to be carefully controlled in the same manner during commercial operation. To assist operators in the design and optimization of their circuits, Solvay developed CYANEX 272-specific solvent extraction modeling software, which has enabled determination of the ideal pH profile and staging configuration. Solvay’s recent advances in modeling capabilities have allowed the simulation of circuits without direct mixbox pH control. Modeling has indicated that circuits operated without direct pH control can achieve the desired metal separation while simplifying the commercial operation significantly. This paper reviews a number of potential circuit configurations for the use of CYANEX 272 and demonstrates the separations achievable under the right design and operational conditions, some of which have historically been considered too difficult.INTRODUCTION CYANEX® 272 is a phosphinic-acid based reagent designed specifically for the separation of cobalt from nickel by solvent extraction from weakly acidic sulfate solutions (Rickelton, Robertson, & Burley, 1982; Rickelton, Flett, & West, 1984; Rickelton & Nucciarone, 1997). Following commercial introduction in the 1980’s, CYANEX 272 has been used in a number of hydrometallurgical flowsheets for cobalt purification and/or recovery. CYANEX 272 metal extraction occurs by means of a cation exchange mechanism. Extraction of a divalent metal ion M2+ is represented by the following equation where RH represents the CYANEX 272 ligand and MR2 represents the ligand-metal complex."

Jan 1, 2017