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By M. Lahtinen, B. Saxén, M. Latva-Kokko

The conventional jarosite precipitation process with neutralization by zinc calcine is widely utilized in the zinc industry. However, it has a significant drawback of causing losses of valuable metals like zinc, lead and silver to the jarosite. This comes mainly from the content of these metals in the calcine used for neutralization. As the zinc plants today want to maximize metal recoveries and minimize the amount of residues, this matter has become more and more relevant for zinc producers. Outotec developed and patented in early 2000 an improved version of the jarosite precipitation process in which the need for neutralization can be minimized, thus the metal losses to the jarosite also can be minimized. At the same time, the iron content of the jarosite increases and the amount of produced jarosite is smaller. The main feature of this process is to start the precipitation from ferrous iron after having reduced all the iron by zinc concentrate in a separate step before jarosite precipitation. Iron is then oxidised back to the ferric form simultaneously with jarosite precipitation. By this method, the formation of sulphuric acid is only half that compared to the conventional method and the need for calcine for neutralization can be avoided. High mixing and oxygen dispersion capability are needed in this jarosite precipitation process. Such capabilities are found in the Outotec OKTOP® reactor series. High performance reactors are not only needed to generate high quality precipitates, but also to maximize oxygen utilization; i.e., to minimize operation costs. Outotec’s latest development in this area is the OKTOP® plant product in which not only the reactors, but also all the accessories are designed, manufactured and delivered by Outotec. One responsible supplier ensures efficient and fast delivery and can provide mechanical and performance guarantees for the entire plant unit.

Jan 1, 2016

By Redhead Robert J.

"In 1991, the Canadian Council of Ministers for the Environment (CCME) charged its Waste Management Task Group with developing a nationally coordinated strategy to measure, monitor, and achieve the objective of decreasing the generation of waste (solid and hazardous) by50% from 1988 levels by the year 2000.With the encouragement of the CCME, which viewed hazardous waste as largely an industry problem, a committee, the “Industry Action Group”, representing eleven industry trade associations with a strong interest and involvement in hazardous waste was recruited.The Municipality of Markham, Ontario was also recruited (Appendix 1)."

Jan 1, 1996

By J. A. Russell

"UNTIL the last few years, the collieries of the Dominion Coal Company, Limited, while highly mechanized as to the cutting and transportation of the coal, still relied on the hand-loading of coal from the seam onto face conveyors. In these circumstances it was possible to assure that no large proportion of extraneous materials would be loaded with the coal, and the product could be quite well cleaned for the market by screening and hand-picking.Within the past few years, however, the Company has introduced an intensive programme of mechanization which will result in the virtual elimination of hand-loading .of coal. It has been the experience of other producers that mechanical loading inevitably leads to a very large increase in the amount of impurities in the product. This is occasioned by the fact that, at least up to the present, all types of loading machines have relied on the coal being broken from the seam by under-cutting and shooting. In this operation, a certain amount of roof and pavement material inevitably becomes mixed with the coal and, since selective loading is impossible with a loading machine, all this foreign material is loaded out with the product."

Jan 1, 1952

By M. Fafard, D. Picard, J. -F. Bilodeau, G. Soucy

To simulate adequately the behaviour of a Hall-Heroult electrolysis cell, a finite element model must take into account the properties of each material. However, it has some lacking knowledge on the mechanical behaviour of materials, like the long-term visco-elastic (creep/relaxation) behaviour of cathode. A three-dimensional model is then proposed in this paper and will be ready to be implemented in the finite element code FESh++. The model was developed using the three-dimensional model based on thermodynamic of irreversible processes where the choice of the internal variables is based on a phenomenological approach. All parameters of the model are represented by constant constitutive tensors and the temperature and chemical dependencies are taking into account through scalar functions multiplying the constant constitutive tensor. The goal of the first part of this project was to determine the parameters of the threedimensional visco-elastic model at the reference state (virgin material at ambient temperature) of three different cathode materials. This paper presents the theoretical model and the results of creep tests at ambient temperature for the semi-graphitic carbon cathode.

Jan 1, 2006

By T. H. Chuang, Y. Y. Shiue

"Rapid whisker growth was significantly alleviated in a Sn-58Bi alloy doped with 0.5 wt.% La. Experimental results showed that many thin, plate-form intermetallic phases appeared in the solder matrix. The absence of tin whiskers was correlated to the shape effect of RE-containing intermetallic plates. After reflowing, Cu6Sn5 intermetallic compounds appeared at the solder/pad interfaces of Sn-58Bi and Sn-58Bi- 0.5La packages with OSP pads, which grow linearly during the aging at 75 and 100? for various times ranging from 100 to 1000 h. In addition, the interfacial intermetallics layers in Sn-58Bi-0.5La solder joints were also observed thinner than those in undoped Sn-58Bi joints. However, RE-containing interfacial intermetallic compounds in Sn-58Bi-0.5La solder joints led to lower bonding strengths in both ball shear tests (0.4 mm/s) and high speed ball shear tests (2000 mm/s). All the reflowed and aged solder joints of both packages were ruptured through the solder balls indicating brittle characteristic INTRODUCTIONIt has been widely reported that solder alloys doped with rare earth (RE) elements reveal many beneficial effects, such as higher strength, lower melting point, improved wettability, and longer creep life (Wu et al., 2004; Ma et al., 2002; Chen et al., 2002). In addition, Dudek et al. reported that the alloying with 0.5 wt.% La in Sn-3.8Ag-0.7Cu solders resulted in an increase of rupture strain, up to 150% over undoped solders (Dudek et al., 2006). However, Chuang and Yen observed that a large amount of long, fiber-shaped tin whiskers were extruded out of the oxidized CeSn3 intermetallic clusters in the matrix of a Sn-3Ag-0.5Cu-0.5Ce solder air-stored at room temperature for several days (Chuang & Yen, 2006). Furthermore, many coarse hillocks appeared around the CeSn3 clusters in the RE-doped alloy after storage in an air furnace at 150? for several minutes. Chuang proposed a mechanism for the phenomenon of rapid whisker growth, which the predominate oxidation of CeSn3 intermetallics in Sn-3Ag-0.5Cu-0.5Ce solders induced compressive stress and extruded the tin atoms out of the specimen in the form of tin whiskers (Chuang, 2007). However, further investigation showed that Sn-9Zn-0.5Ce solders, after long term exposure at room temperature and 150?, were immune to the whisker growth; the immunity was attributed to the refining of the CeSn3 intermetallic phase in the alloy (Chuang & Lin, 2008). The inhibition of tin whiskers through the refining of rare earth containing intermetallics was further observed in Sn-3Ag- 0.5Cu-0.5Ce solders doped with 0.5 wt. Zn (Chuang & Lin, 2009). In addition to the size effect, the thin plate shape of intermetallic compounds was also shown in this study to inhibit the whisker growth on the surface of Sn-58Bi-0.5La solders."

Jan 1, 2012

By Wm. L. Giachino

"Over the last 10 years, C-1-L has played a significant role in the major advances that have taken place in blasting technology, among them the following: development and introduction of capsensitive slurries; development of bulk slurry systems both for underground and open-pit operations; development of the TOE-DET and ANODET systems of delay blasting;introduction of the NONEL system of initiation;development of the Vertical Crater Retreat (VCR) system of mining.This paper identifies areasin which we foresee further developments in blasting technology over the next 10 years and outlines how and to what extent C-1-L will become involved."

Jan 1, 1980

By R. Pot

"IntroductionTHE PURPOSE of this paper is to discuss briefly the main logging and testing devices presently at our disposal, to point out some of their limitations, and to suggest possible improvements of the techniques.Some of the more important devices .are those that are used in:(1) Coring(2) Formation testing(3) Electric well logging(4) Radioactive well logging(5) Measuring of bottom hole pressures(6) Sampling of reservoir fluidsThe first four of these procedures are concerned with the well while it is in the process of drilling. The last two are carried out as soon as possible after a well has been brought into production and .at intervals during its life. My remarks will be concerned mostly with certain aspects of formation testing. The reservoir engineer is dependent on the information derived from these operations in order to obtain a clear picture of the conditions in a reservoir and to enable him to assess and forecast its future behaviour.Since any calculation is no better than the data on which it is based, not enough emphasis can be placed on the necessity for the testing and logging equipment to be of the highest quality and for the analysis of the results obtained to be thorough."

Jan 1, 1952

This paper details a brief history of the Australian gold industry from the 1980s gold boom to the present day, highlighting an industry characterised by innovation in plant design and junior companies prepared to "have a go", in contrast to the conservatism of many larger mining companies. Design flexibility, the innovation of new processes, the preparedness to exchange "process know how" and technology singularly differentiated the gold industry from other sectors during the 1980s to the present. The introduction of two stage crushing, semi autogenous (SAG) milling, and pebble crushing, mill innovations, carbon in pulp (CIP) and carbon in leach (CIL) and the North Kalgoorlie screen etc were all exciting changes in the industry.

Jan 1, 2011

By A. J. Baer

"DEFINITION OF THE REGION AND ITS BOUNDARIESTHE EXPOSED PART OF THE GRENVILLE PROVINCE is the southeastern part of the Canadian Shield, characterized by crystalline rocks with K-Ar ages of about 1,000 million years. Its Canadian portion is bounded on the southwest by Georgian Bay •and by Paleozoic sediments south of a line passing through Orillia and Kingston, on the southeast by the St. Lawrence River valley and the north shore of the Gulf of the St. Lawrence, on the east by the coast of Labrador and on the northwest by the Grenville front, a linear tec-tonic feature that is a metamorphic transition zone and/or a fault. Rocks located to the southeast of the front have younger K-Ar radiom€tric ages than rocks located to the northwest of it.The region is formed of complexly deformed and highly metamorphosed crystalline rocks and in part differs from other areas of the Canadian Shield by the presence of large amounts of crystalline limestone and bodies of anorthosite."

Jan 1, 1970

By J. Stachulak

In recent years more emphasis has been placed on the control of nitrogen dioxide (NO2) emissions from mining diesel equipment. Worldwide, diesel engine regulations to control emission and protect the environment are also driving the development of the diesel engine technology to reduce oxides of nitrogen NOx (Nitric oxide, NO + NO2). NOx are toxic gases produced in mines during the operation of diesel equipment. Most of the diesel equipment used in underground operations are equipped with Diesel Oxidization Catalysts (DOCs) designed to reduce carbon monoxide (CO) and hydrocarbons (HC). The effects of DOCs on NO2 production from diesel powered equipment is not well understood. DOCs do not alter NOx concentration, but may promote the oxidization of engine exhaust NO to the more toxic NO2, thus increasing the undesirable NO2 exposure of workers in the mine environment. In 2012, the ACGIH reduced the NO2 TLV concentration value from 3 ppm to 0.2 ppm. Vale and CanmetMINING have been involved in several research projects to reduce diesel emissions exposure to workers. One aspect of the current program is to determine the effects of in-use DOCs on NO2 production. Several in-use DOCs taken from mining equipment were selected for testing in the laboratory using ISO 8178-C1 and mine LHD transient test cycles. The paper presents the laboratory test results and effects of DOCs on NO2 production. The results indicate significant reductions in CO concentration, by over 77%, while increases in NO2 varied from 46% to 315% based on the ISO 8178-C1 8-mode steady state test cycle. The mine LHD transient test cycle showed the same pattern, although the magnitude of CO reduction was less. Consequently, it is recommended the use of only those DOCs that have been properly evaluated and shown not to significantly increase NO2 emission in the environment be used on mine equipment.

Aug 1, 2013

By K. Bachmann, M. Rudolph, U. A. Peuker, H. H. Duong, T. Heinig, T. Leißner, H. Schubert, Helmholtz-Institute Freiberg for Resource Technology, Technische Universität Bergakademie Freiberg

"Minerals can be liberated by random fracture of particles into smaller fragments or by detachment along phase boundaries. These two mechanisms represent borderline cases. When ores get comminuted the liberation of minerals is achieved to some extent by both mechanisms. This article describes a method to determine the extent of transgranular and intergranular fracture on surface exposure of minerals based on 2-dimensional liberation analysis.The approach uses the non-biased surface information like phase specific surface area (PSSA), phase specific free surface (PSFS) and phase specific locked surface (PSLS) of minerals and their change with comminution. The amount of transgranular and intergranular fracture on surface exposure can be calculated using the phase specific surface parameters.A sedimentary rock (apatite ore), an igneous rock (nepheline-syenite) and an artificial material (copper slags) were ground to different fineness. Based on the mineral liberation analysis (MLA) of feed and products, the extent of phase boundary fracture on the surface exposure of the minerals is studied.INTRODUCTIONMinerals can be liberated ether by comminution or by detachment (Gaudin, 1939). Liberation by comminution is a random fracture mechanism, which is not being influenced by ore texture, grain boundaries and mineral features (transgranular fracture). Liberation by detachment represents a fracture along grain boundaries (intergranular fracture). Random fracture often is named as the dominating mechanism for the liberation of ore minerals. This has been the basis to simplify models for liberation modelling (Barbery, 1991; King, 1979; Meloy, 1984) assuming that the probability of cracks moving along grain boundaries is zero. Thus, no interfacial area is lost during comminution."

Jan 1, 2016

By M. Fairman

The effect of welding speed on the microstructure of friction stir processed (FSPed) AZ31B-H24 magnesium alloy was studied using light microscopy, image analysis, and microhardness tests. The grain size of the magnesium alloy was observed to increase after FSP from about 3.5 µm in the base alloy to about 8 µm in the stir zone. The aspect ratio decreased from 1.60 to 1.55 towards the center of the stir zone. The changes in the grain size and shape caused the microhardness of the samples to drop significantly across the FSPed region from 75 HV in the base alloy to below 55 HV in the stir zone. Decreasing the welding speed increased the grain size due to a greater input of heat energy. The faster heating rate due to the lower welding speed caused a deeper penetration of the annealing effects of FSP. It was also observed that the annealing effects caused by FSP were less pronounced with increasing distance from the interface between the sample and pin tool shoulder. The Hall-Petch type relationship of the micro-indentation hardness as a function of the grain size was observed to hold true after FSP.

Jan 1, 2007

By John Lund

INTRODUCTION GOLD-BEARING placers of Alaska and the Yukon Territories are buried under a layer of permanently frozen alluvial overburden, or 'muck', which varies in depth from twenty to one hundred feet. The placers, and the decomposed bedrock layers upon which they are deposited, are also permanently frozen. During the summer, surface muck which is exposed to the sun will thaw, but only to a depth of a few feet. To reach a valuable deposit, the frozen overburden must be either penetrated with shafts, or stripped from the deposit entirely. In either case, before the placer can be mined, it must be thawed. At modern dredging operations, the frozen muck is stripped from the placer by powerful jets of water from hydraulic giants. The placer, and several feet of decomposed bed-rock, are then thawed by forcing water through narrow pipes which have been driven into the deposit. Other methods of thawing frozen placers were used extensively during the early years of the Klondike 'gold rush', but experimentation later proved that creek water at its natural summer temperature was a more effective and economical thawing medium than any other which had been used. EVOLUTION OF COLD WATER THAWING Early prospectors of the far north reached placers by digging shafts through the frozen muck. They then thawed the placer sand and gravel by building wood fires at the bottom of the shafts.

Jan 1, 1951

By C. A. Morais, L. V. Resende

"The technological development observed in recent years has stimulated the application of rare earth (RE) elements. Amongst their various applications it is well worth mentioning their use in electronics, superconductors, nuclear medicine, as well as in special inks - as those used in radar invisible airplanes. TV and computer monitor screens present as coating a powder containing some rare earth elements, mainly Europium and Yttrium. The recovery of the RE elements from electronic scrap is extremely important as the economic and environmental issues are concerned. This paper describes the study of the Eu and Y recovery from e-scraps. The first step of the process was the leaching of the powder obtained by manually scraping the inside surface of the screen. After the optimization of the leaching, the dissolution of Eu and Y was higher than 98 w/t% and a pregnant sulfuric liquor containing 11.9 g L-1 Y and 0.72 g L-1 Eu was obtained. The second step was the separation of the metals found in the liquor by the solvent extraction technique. The separation of Eu and Y was carried out in a counter current circuit compound of 3 extraction stages, 7 scrubbing stages and 15 stripping stages. DEHPA was used as the extractant, whereas a diluted sulfuric acid solution was applied as scrubbing agent and a hydrochloric acid solution at high concentration was used as the stripping agent.INTRODUCTIONThe rare earths (RE) are a moderately abundant group of 17 elements composed of lanthanides, scandium and yttrium. Amongst the RE, promethium (Pm) is extremely rare, however several of the RE elements are not very rare and occur dispersed in a variety of forms (Greenwood & Earnshaw, 1984; Tyler, 2004).The innumerable applications of the RE elements are based on their particular properties, mainly their spectroscopic and magnetic properties (Martins & Isolani, 2005). The technological development observed in recent years has stimulated the application of rare earth (RE) elements. They have been used in agriculture, electronics, superconductors, nuclear medicine, automobile industry, special inks – as those used in radar invisible airplanes, X-ray screens, high intensity mercury vapour light bulbs, neutron scintilators, charged-particle detectors and optical memory reading systems (Maestro & Huguenin, 1995; Nagaosa & Binghua, 1997; Sánchez et al., 1999)."

Jan 1, 2012

By Vahid Faghihi

SatraPM is a web-based software package, aiming to help project managers to easily handle their construction projects via internet. This software is capable of handling all projects of an organization, in which all projects can be defined in EPS the same as users in OBS. A 3D accessing module links EPS, OBS and inherent functions in order to provide a secure environment for the data to be processed throughout the system. This paper intends to take a deeper look at capabilities of SatraPM in helping project managers to keep track of and control their construction projects as well as its potential future features.

Aug 1, 2013

By H. W. McGerrigle

The St. Lawrence Valley of Quebec lies in an earthquake danger zone, the main centers of which appear to be Murray Bay, Montreal and Quebec City. This paper compares conditions in this "earthquake zone" with those of other, currently more active, earthquake zones of the Earth, deals briefly with the mechanics of earth movements and outlines the means by which earthquakes are re-corded. An account is then given of the earthquakes which have occurred in the Province of Quebec -from that of 1534-35 to the earthquake of 1925. A 50-year frequency cycle is implied. The general conclusion is that the 11robability of future earthquakes should be given more consideration in the construction of buildings in the St. Lawrence Valley region.

Jan 1, 1966

By T. Newton, G. A. Bezuidenhout, P. J. Tauetsile, F. Trask

The technology to selectively leach gold, silver and base metals from ores, concentrates, and wastes, using an alkaline glycine solution, has initiated significant interest in using the new technology in various environments such as in-situ, in-place, dump, heap, and vat and agitated tank leaching. It has been shown that glycine acts synergistically with a number of other lixiviants to lower the net consumption of the other lixiviants while allowing low cost glycine solution recovery. Glycine is a non-toxic, stable, environmentally benign reagent that is available in bulk industrial quantities. It has the ability to dissolve most copper oxide and sulfide minerals, as well as native copper, whilst not interacting with acid consuming gangue nor dissolving iron and various or ubiquitous gangue elements. It acts synergistically with small amounts of cyanide to leach gold-copper ores at leach rates higher than either glycine or cyanide on their own, while significantly reducing cyanide consumption and eliminating detoxification requirements. The leaching behaviour of various glycine based systems will be reviewed, followed by the evaluation of the adsorption of gold onto activated carbon. Where the economics merit it, copper can be easily recovered using solvent extraction or sulfide precipitation.

Jan 1, 2017

By A. Dahi Taleghani, A. Shojaei

Continuum damage mechanics (CDM) of rocks is studied together with their elastic and plastic behaviors to develop simulation tools for hydraulic fracturing jobs in naturally fractured formations. The model is constituted based upon pressure sensitive inelastic deformation of porous rocks and their damage mechanisms in the cases of drained and undrained conditions. The CDM model is formulated within Fracture mechanics framework. The performance of the developed elastoplastic and CDM models are compared with the available test data of a specific shale play. The hydraulic fractures growth in the reservoir scale is then simulated; in which the effect of fluid viscosity, natural fractures characteristics and differential stresses on induced fracture network is studied. The simulation results are compared with the available solutions in the literature. The developed CDM model outperforms the traditional fracture mechanics approaches by removing stress singularities at the fracture tips and simulation of progressive fractures without any essential need for remeshing.

Jan 1, 2015

By P. H. Shipway, D. G. McCartney, H. Saghafifar

The microstructural changes during thermal ageing at 650ºC in the interfacial region of Alloy 625 weld overlay on a 2.25Cr-1Mo steel was evaluated. Optical microscopy, scanning electron microscopy in SE and BSE modes, electron probe microanalysis and hardness mapping were used to characterize as-welded microstructure and its changes during thermal ageing and precipitates of interfacial region. Carbon migration across the interface was recognised as a major issue. A region of 300 µm wide adjacent to the fusion line, which was found harder in the as-welded condition decarburized during thermal exposure. Studies revealed that this region transformed to a soft region containing large ferrite grains and micron-sized carbides. In the weld overlay, a 50 µm wide hard band (over 650 Kgf mm-2) adjacent to the fusion line formed and carbide precipitates were observed along grain boundaries. Carbide precipitation mostly occured in the 150 µm wide region close to fusion line.

Jan 1, 2017

By Asfahani. Jamal, Randa Mohamad

"Abstract - Electrical and structural characteristics of formations favorable for sulfur occurrences in northeast Syria are described using geo-electrical prospecting methods. Simple (VES) and combined (CVES) Schlumberger vertical electrical soundings and geo-electrical profiling using a Wenner configuration were applied to the Teshreen structure. Six profiles (A, B, C, D, E, and F) at the borders of anticlines, where positive and negative structures are joined and salt formations have a tendency to disappear, were studied.Secondary structures, characterized by high apparent resistivity exceeding 3000 Ohm.m were located on each profile using a Wenner profiling configuration. These secondary structures are demonstrated to be favorable for sulfur prospecting by both drilled wells and vertical electrical soundings. Traditional interpretation of the 84 VES measurments is supported by data from 14 CVES measurments. The CVES technique is a powerful tool, due to its improved resolution of the electrical boundaries.Thicknesses and resistivities of the Lower Al-Fares, Al-Garibeh, and Al-Dibbaneh formations were determined through the interpretation of VES measurments. The same VES measurments were then interpreted using the Pichgin method, whereby all the subsurface tectonic features were determined for depth penetration corresponding to AB/2 = 1000 m. The integration of the first and second VES phases creates a clear picture of the subsurface, including tectonic, geometric, and geoelectrical information. In summary, the sulfur occurrences in the research area are controlled by tectonic paths that are well defined by geo-electrical methods. These diverse geo-electrical methods could be used successfully for sulfur prospecting in similar environments."

Jan 1, 2002