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By C. A. Young, H-H. Huang, L. G. Twidwell

Equilibrium calculational software programs can be effectively utilized to model important parameters in aqueous and aqueous/solid systems, e.g., activity or concentration, solubility, temperature, solution pH, solution potential, and ligand complexation. In this regard, the calculational program ST ABCAL will be demonstrated. Illustrative examples for the creation of diagrams such as potential-pH, and activity or concentration-pH will be presented to demonstrate the fundamentals in real hydrometallurgical systems. Speciation, titration and mixing will be used to simulate or predict operational processes. Berkeley Pit water from a flooded abandoned copper open-pit mine will be used to illustrate the modeling process. According to analytical results the water contains about 20 important constituents. In addition to measured potential and dissolved oxygen, there are two distinctive oxidation/reduction couples. Concentration and other experimental parameters are seldom matched to each other and 12 different conditions have been identified. Water for each condition must be speciated in order to find the best-fit model. The STABCAL program will be used for the modeling calculations and the implication of the water chemistry to defining treatment opportunities will be discussed.

Jan 1, 2005

By W G. Forbes

SOME 20 years ago, upon finishing second year at the University of Manitoba, I was faced with the choice of whether I wanted to be a geologist or a chemist. Accordingly, I sought out Professor Brownell, Head of the Department of Geology, to ask him what a geologist did. His reply contained the statement that following graduation one went out into the field in northern Canada for 5 to 15 years to reduce to practice what had been learned at university. To a young man, very socially conscious, even one year, let alone 5 to 10, in a small mining community sounded like being banished to a monastery in the Himalayas and thus I turned to chemistry. Moving to the present, last month I asked a geologist, and then a mining engineer, what does the fresh graduate in their field do these days? The reply was: usually serve an apprenticeship for an indeterminate period either underground or in the field learning the job.

Jan 1, 1965

By Dharmendr Kumar, Pradip, Sivakumar Subramanian, Beena Rai, Venugopal Tammishetti

The separation efficiency in a mineral processing plant is generally assessed and reported in terms of elemental assays constituting the minerals of interest. However, different minerals comprising of same elements behave differently under similar process conditions. Thus, it is imperative to track the mineral composition thank elemental composition of different streams in a processing plant. The availability of automated mineral analyzers such as QEMSCAN and TESCAN in recent times has made it possible. However, due to the high cost and expertise required, their adaptation in day to day monitoring of operations is not yet a common place. X-ray diffraction (XRD) profile fitting (Rietveld Refinement) is another technique which can provide estimates of mineral proportions in a sample. The results of Rietveld Refinement however are affected by coating of fines on coarse particles, method of sample preparation, particle size distribution of sample, elemental substitution in mineral crystal lattice. In the present work, we propose a simple and efficient method for quantitative estimation of minerals in iron ores using elemental assays and thermo-gravimetry analysis data. The minerals (hematite, goethite, gibbsite, kaolin and quartz) are identified using powder XRD analysis. It is also observed that goethite contains Al substitution in the crystal lattice. The samples were analyzed for %Fe, %Al2O3 and %Silica using chemical analysis. The measured Loss on Ignition (LOI) in the sample is contributed from goethite, gibbsite and kaolinite phases. LOI from gibbsite and goethite occur in temperature range 250–350°C and LOI from kaolinite occur in temperature range 400–700°C. According, LOI are determined in two different temperature ranges that are 100–400°C and 400–850°C. We have used the data to successfully determine the mineral compositions of iron ore samples. We have also employed a data reconciliation algorithm on the calculated data for further improvement and consistency of our results. Our method is very convenient for quick estimation of mineral proportions in a sample. The proposed method can also be used for quantitative phase estimation in bauxite ores and red muds.

Jan 1, 2016

By T. Bhambhani, Mukund Vasudevan, Partha Patra, D. R. Nagaraj, P. Somasundaram

Selective Ni separation from ultramafic ores rich in serpentines has been a huge challenge in the mineral processing industry, and therefore highly inefficient. Analysis of the root causes of the challenges and consequent development of robust processing solutions were the main goals of the Cytec-Columbia. University-Vale Joint Development Program. In this context, the subject of this paper is limited to one of the key findings of this research program which is the influence of fibrous serpentines on grade-recovery characteristics. Specifically, the poor flotation behavior is characterized by an atypical reverse C-shaped grade-recovery curve.

Jan 1, 2011

By L. Bryson, J. H. W. M. Brits, K. Voogt

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."

Jan 1, 2017

By M. H. Ali

Codelco, a multi-process primary copper producer, is undertaking a full life cycle inventory (LCI) of all its commercial products based on copper and molybdenum. During this work, many questions have surfaced regarding the contribution of process unit design to specific aspects of a product's LCI and, more importantly, how such designs could be improved using a life cycle perspective. Management strategy efforts were undertaken to improve the LCI footprint, however it was found that the corrective actions were almost impossible to apply at the operation level in plant, given the ongoing timing pressures of extractive mining, and costs saving priorities. Additionally, it was found that most of the important comparative differences between operations had structural reasons. In this circumstance, the LCI practitioner group from 1M2, and the environmental managers from Codelco, decided to shift its efforts to place the critical LC1 aspects to the design process of future developments. Hatch Associates has developed unique tools in their Sustainable Plant Design (SPD) package that compliment and enhance LCA methods; these effectively drive sustainability into the heart of the design process. By using LCA and SPD in a project design phase, you cannot only address potential hotspots, but also decide on materials, location and size of certain facilities to optimize for energy efficiency. Moreover, you can avoid the shifting of environmental burdens upstream or downstream within the plant and finally it is extremely useful in identifying opportunities for greenhouse gas reduction.

Jan 1, 2007

By J. H. Parliament

"The 15,000-tpd Similkameen open-pit copper mine, 10 miles south of Princeton, B.C., started production during 1972. The two main ore zones are separated by the deep canyon of the Similkameen River, with the Ingerbelle or western deposit being mined first. The location, design and construction of the plant were complicated by the steep terrain and the situation of the orebodies. Mining, utilizing 10-cu.yd electric shovels and 100-ton electric-wheel trucks, is conventional. Closely integrated with the preproduction mining was the construction of a 4-mile section of main highway to bypass the Ingerbelle pit. This entailed a very large fill, placed with mine equipment. Ore is crushed to minus 9 inches, stockpiled and reclaimed for direct delivery to three 32-ft-diameter by 14• ft single-stage autogenous grinding mills, each driven by two 4000-hp motors. Because of the friable ore in the upper part of the mine, 4-inch balls are added, with higher than design throughput attained. Classification is by 91>-inch spiral classifiers and cyclones. The flotation section comprises three parallel lines of ten 400-cu.ft rougher- scavenger cells and a single line of 100-cu.ft cleaner and recleaner cells. Concentrate is transported in end dump, closed trucks to Vancouver for dockside storage prior to shipment to the smelter. Tailings are piped across the canyon on a suspension bridge and through a tunnel to an empoundment area. Water is reclaimed and returned to the concentrator, forming a closed system. Dams are raised with cycloned ands, with the downstream section compacted."

Jan 1, 1973

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to assist the mining industry in implementing continual improvement in management of major unwanted events so maximising health and safety performance. A comprehensive body of knowledge has been compiled from diverse mining industry experts for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This paper presents an overview of the RISKGATE body of knowledge captured specifically for the management of unwanted events that stem from the handling and use of explosives (drill and blast) within surface coal mining operations. The knowledge presented is divided into a series of initiating events (listed below) within which there are further degrees of classification based on design, operation, and management concerns. Initiating events: ? Loss of control of explosives and associated chemicals in storage on site ? Loss of control of explosives and associated chemicals during transport ? Loss of control of explosives and associated chemicals during manufacture ? Loss of control of explosives and associated chemicals during handling and blast operations ? Loss of control of explosives and associated chemicals during disposal The system guides the user in generating substantive and leading-edge controls to assist in the design, management and reporting of drill and blast operations to meet stringent internal and external requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry.

Aug 1, 2013

By V. Aitken

Line-of-sight radio control has received widespread acceptance for use in many mining methods because today’s technology offers improved economics and personnel safety. Significant advances in higher autonomy for mining machines are not currently seeing widespread use even though they offer great future potential. With autonomous capabilities being a longer-term goal, a logical sequence of advances based on TeleRemote control is proposed. Under Tele - Remote control, the operator is in direct control of the machine at all times. Three levels of Tele - Remote control systems are presented including line-of-sight, extended line-of-sight, and full load-haul-dump applications. Distributed control and sensing subsystems arranged in a vehicle control area network support incremental system expansion through the three levels of TeleRemote control and prepare the machine for integration of higher levels of automation as mature technology becomes available. This approach allows full exploitation of today’s mining automation technology with a flexible future growth path.

Jan 1, 1998

By J. D. Corbett

The spatial coincidence of the seven anomalies is obvious, even though the self-potential is offset northward. Because the ratio, as an indicator of conductivity, is a relative estimate at best, concise interpretation is limited in almost every instance to the location of a conductor or conductor axis. When related to the initial phase of an exploration program, magnitudes and ratios similar to those obtained from any one of the methods described, would be sufficiently attractive to warrant further investigation. The compilation shown is an empirical comparison of actual field results and no emphasis has intentionally been placed on the relative merits of one method in respect to another. Too many additional factors, i.e., size, depth and conductivity of overburden, etc., that cannot unequivocally be answered, enter into such a comparison before a relative evaluation can be made.

Jan 1, 1961

By L. Rosato

In the past decade, as a result of increasing iron loads, Canadian Electrolytic Zinc (CEZinc) has become a pioneer in understanding the critical factors that affect the roasting of concentrates with high pyrite contents as well as those factors governing the effects of high iron loads on the leaching circuit. De-bottlenecking efforts in the roaster and acid plant section of CEZinc have given rise to a better appreciation of the impact of iron on roaster productivity. High standards for impure solution quality, zinc recoveries and residue disposal have all led to an increased comprehension of the limits of the leaching circuit and the optimization potentials with respect to iron and ferrites. In this paper, the impact of iron on the roasting and leaching circuits of CEZinc will be reviewed and special emphasis will be given to some of the more recent process optimization and improvement activities.

Jan 1, 2006

By P. Karimi, G. Mollataheri, A. Amini, H. Abdollahi, A. Mirzaeian

"Chah-Palang tungsten deposit is one of the two tungsten indexes in Iran. Based on ore characterization techniques (including optical mineralogy and XRD analysis), quartz, chlorite, atacamite, azurite, malachite, ferberite, illite, goethite and calcite were distinguished as major minerals. The representative sample was analyzed qualitatively by using X-ray fluorescence and chemical assay. Results showed that grade of tungsten oxide and copper were 1.76 and 7%, respectively. Also precious metals such as gold with grade of 1 ppm was reported in the sample. By using the mineralogical studies on the prepared sample, the liberation degree of tungsten minerals in –0.6 mm size fraction was obtained 80%. Several tabling tests were carried out on the original sample which at the optimum conditions and as a result, the grade and recovery of tungsten in concentrate reached to proximately 23 and 59%, respectively. To increase the grade of tungsten in the final concentrate, acidic leaching were performed on the tabling concentrate and its appropriate results indicated that the grade of tungsten increased to 27%. Also more than 90% of copper was extracted as a byproduct in the fallowed process.INTRODUCTIONTungsten, a unique hard, heavy heat-resistant metal, is distributed erratically in economic concentrations throughout most continents, occurring mostly as small irregular deposits that are not readily adaptable to large-scale, low-cost mining methods. The diverse physical characteristics and mineral composition of tungsten ores also present problems in beneficiation, requiring complex hydro- and pyrometallurgical treatment to yield high-purity concentrates suitable for the production of ferro alloys, carbides and super alloys in the steel industry (Hausen, 1989; Kholmogorov & Kononova, 2005). Tungsten is most frequently used as tungsten monocarbide, which has hardness close to diamond, in cemented carbides. The most well-known use of tungsten is in lighting filaments, and other important applications include improving steel properties and use in tungsten alloys, electronics, and chemical products (Hausen, 1989; Kholmogorov & Kononova, 2005)."

Jan 1, 2016

By Henrik Saxén, Mikko Helle

The operation of hot stoves used for preheating the blast in the ironmaking blast furnace has a strong effect on the consumption of reductants, economic performance of and CO2 emissions from the steelmaking site. Generally, it is recommended to maintain as high blast temperature as possible, because this minimizes the rate of reductants in the blast furnace. The blast temperature is affected in a complex way by the time periods of heating and cooling of the stoves, and by the amount of gas combusted in the stoves. Furthermore, as the hot stoves show degraded performance with age, it is a non-trivial task to select optimal operation parameters for the stoves. The paper addresses this computationally by applying a one-dimensional heat-transfer model of the hot stoves for optimization of the performance of the system. The complexity and strong coupling of the decision variables is demonstrated by numerical examples, where the blast temperature is maximized under different constraints.

Jan 1, 2015

By Tim C. Webb

For almost 350 years, industrial rocks and minerals have been produced, used locally and exported from New Brunswick to markets throughout the world. Up until the early 1960s, commodities like grindstone, building stone, gypsum, and limestone served as the foundation of the province's non-fuel mining industry. The importance and high level of activity surrounding industrial rock and mineral development in New Brunswick is reflected in a multimillion dollar industry generating substantial revenue and providing a valuable service to its people. New Brunswick's varied geology is reflected not only by the diversity of industrial rock and mineral resources presently under development but also in several promising exploration and potential development opportunities. The province also hosts several industrial rock and mineral processing facilities, each with established technologies ensuring high-quality products and each with sufficient flexibility to supply customized products for various specialized niche markets. With the imminent availability of natural gas to parts of the province, the prospects for additional value-added processing and re-examination of known, yet presently undeveloped deposits, appear excellent. These variables coupled with the province's advantageous geographical location, highlighting tidewater access to global markets and within one day's trucking distance to a regional market of several million people, guarantee prompt delivery of high-quality products at competitive prices.

Jan 1, 2001

By N. Manopulo, J. Maier, L. Tong, C. Becker, P. Hora

The contribution presents a new finite element approach in which the common updated Lagrangian formulation is replaced by a spatial flow formulation applying a special arbitrary Lagrangian-Eulerian for-mulation (ALE). The description separates spatially the process in a die inside zone and in a profile zone. For the description of the inside zone, where the filling process occurs, a special Euler time independent mesh is applied. By this formulation the mesh has to be generated only once, which simplifies the generation of spatially optimized meshes. For mapping of the material flow during the filling process the method uses a flow surface traction method as applied in casting simulations. A further strength of the new method is the computational efficiency which allows the modelling of extrusion process with the highest complexity with a response time of 12 hours, which is important for the industrial optimization process.

Jan 1, 2015

By L. Li, K. Jiang

China is the world largest producer and consumer of zinc. Beijing General Research Institute of Mining and Metallurgy (BGRIMM) is one of major research and engineering institutes for nonferrous metallurgy in China. This paper (presentation) introduces the development of China’s zinc smelting industry, key production processes and main producers. The process research and development are reviewed as well as BGRIMM’s R&D activities in the last decade. China's refined zinc production was 4,829kt in 2012, accounting for 38.6% of world production. Primary production was 4,722kt. There are around 150 refined zinc producers in China. The traditional fluid bed roasting - leaching jarosite is still a dominant process for primary production and its production accounts for about 60% of country's total production. However, the direct leaching process is gaining market share. Seven direct leaching plants with 330kt/a capacity, including autoclave leaching and the Outotec direct leaching, have been put into production by June 2013. Five autoclave leaching projects with 590kt/a capacity are in the pipe line and are expected to be commissioned in 2014 and 2015. To cut the production cost and improve smelter economics, process research to optimize the production flow sheet, to improve the iron removal and to enhance the recovery of co-existed rare metals were carried out. The development trends of China’s zinc smelting industry from the view of cutting production cost, improving energy efficiency, increasing comprehensive utilization are discussed accordingly.

Jan 1, 2014

By L. Hacini

The start-up is the most critical phase of the cell life, as an uncontrolled start-up could lead to early infiltrations, instabilities, and in some cases to the cell death. Lots of efforts are put to increase the lifespan of cells, as it has a major impact on both the operating costs and the environmental footprint of the aluminum industry. Obviously, a true size test on a cell is a resources- and time-consuming approach that could be used only to validate mature concepts. Moreover, numerical modelling is a low-cost and versatile tool capable to test a wide range of potential ideas and concepts. In the present article, a thermal electrical mechanical slice model is presented. This model describes the preheating and bath periods of a P155 aluminum cell start-up, as used at the Grande Baie smelter. The impact of sodium diffusion and expansion is also included in the model. This model will be useful to study different problematical issues such as the global behaviour of lining materials, shell and cradle deformations during start-up and several start-up scenarios. Such a model will also be able to answer some interrogations regarding early infiltrations and their impact on the lifespan of the electrolysis cell.

Jan 1, 2011

By K. Lillkung, J. Kourunen, M. Latva-Kokko

"Carbon-in-leach (CIL) and carbon-in-pulp (CIP) processes utilize activated carbon to adsorb solubilized gold for recovery. Due to carbon attrition and non-ideal carbon management, however, some of the gold is lost in carbon fines and to the solution. The carbon attrition mechanism inside CIL/CIP reactors is mainly abrasion-related. This is critical to gold loss since gold loading takes place predominantly in the outer shell of the carbon particles. Thus fine carbon dust has a relatively high gold content and such a small particle size that it cannot be captured with safety screens. The attrition rate depends on ore and carbon characteristics, but it is always proportional to the mixing power intensity. This rate can be minimized by continuous suspension level measurement and control of agitation speed. In addition, a novel tank bottom structure can significantly reduce the required mixing power input compared to a flat bottom tank. A major challenge in carbon management is infrequent and inaccurate measurement of carbon concentration in the reactors. In order to reduce soluble gold losses by means of improved carbon management, Outotec has been developing a continuous in-situ measurement for carbon concentration that is tolerant to changes in slurry density.INTRODUCTION Cyanide leaching has been utilized since the late 19th century as a standard technology for hydrometallurgical gold production. Since then, gold and silver recovery rates have increased due to technological development, but very similar recovery methods are still being used. The original recovery method was to use zinc precipitation – similar to the Merrill-Crowe process, which is still common for feed materials with low throughput and high silver content. However, in most cases, activated carbon recovery is preferred due to its improved efficiency. The carbon-in-pulp process (CIP) and its modification, carbon-in-leach (CIL), have a lower residual soluble gold level and are not similarly affected by soluble base metals. The main alternative for the use of carbon is ion exchange resins. The principle of resin processes is similar to the CIL/CIP processes, with a different type of adsorbent material. Carbon processes are usually preferred over resin processes due to the significantly higher cost of resin material and the possibility to use simpler, well-established technology with carbon processes."

Jan 1, 2017

By I. Murray, N. Geoffroy

"Buried pipelines, tanks and other similar equipment are almost always present on large scale industrial sites, including in the oil and gas fields. However, as the proverb “out of sight, out of mind” suggests, it is easy to overlook proper maintenance procedures and simply assume that corrosion protection measures in place are working correctly. Unfortunately, this is not always the case, leading to significant environmental damage and loss of production. This paper describes several cases from various industries where buried equipment failed because of corrosion, sometimes with catastrophic results. It also presents various strategies, based on experience and new research, to help predict and prevent damage to underground metallic structures.INTRODUCTION Metallic underground structures are extremely common in industrial and commercial settings for numerous reasons. Burying pipes, tanks, wires and other similar equipment has numerous advantages: it provides significant protection from mechanical damage, frees up ground space that can be used for other purposes, requires little to no support structure and is generally more esthetically pleasing. However, this last benefit can also be considered the most significant disadvantage of underground equipment: becoming invisible and forgotten. While every engineer is aware of the importance of preventive maintenance, it is also human nature to somewhat forget about equipment that is hard to inspect and assume that everything is fine. This is unfortunately not always the case and failures in industrial settings can have extremely serious consequences. While economic aspects immediately come to mind (loss of production, cleanup cost, etc.), failure of underground equipment also results in an environmental and therefore public relations nightmare, especially in the oil and gas field. Leaks that would have been considered negligible in the past can now make national headlines and perfect reliability, while probably impossible to achieve, is now the goal of most companies. While environmental damage (real or perceived) is most often associated with leaks in the oil and gas industry, it can also affect the mining world. For example, the authors have worked on a project where a buried slurry pipeline had ruptured in the ground, causing a release of perfectly inert tailings. While the economic loss was low, the leak was reported in local media and caused a public relations problem."

Jan 1, 2017

By W. Beres

Many non-commercial operators are currently faced with the need to operate fleets of legacy gas turbine engines. How long such engines can be kept in service safely, without replacing a significant portion of their aging structural components, has become a growing concern to engine life-cycle managers, due to uncertainties in the remaining lives of critical components of these engines. This paper describes the application of the damage tolerance methodology to predict safe inspection intervals (SII) for critical components of gas turbine engines, using components of a turboprop engine for a transport aircraft as examples. High temperature components of this engine are made of advanced aerospace alloys. The methods of predicting three-dimensional fatigue crack growth at the critical location of turbine discs and spacers using both commercial and in-house developed algorithms are presented. Sensitivity analyses are performed to determine the effect of variations in material parameters on the predicted safe inspection intervals. In addition, spin rig tests performed for both turbine discs and spacers are described. Finally, crack growth rates predicted by numerical analyses are compared to those obtained from spin rig testing and the damage tolerance of the turbine components is assessed.

Jan 1, 2015