Stress in Full Deposit Electrowon Nickel

"The Anglo American Platinum’s Rustenburg Base Metals Refinery (RBMR) has the world’s first full deposit nickel plating tankhouse. Impurities in the nickel electrolyte can induce stresses in the electrowon nickel deposits that could lead to delamination of the deposit. Identifying the impurities that contribute to increasing internal stresses in the nickel deposit is key to successful operation and automation of the tankhouse. Impurities were introduced in the plant electrolyte and the effects on the full-scale nickel deposits evaluated. The impurity-adjusted electrolyte solutions were also analyzed using commercially available bench-scale methods to determine the induced stress. A correlation between impurity-induced deposit stress and full-scale delamination was developed. A direct correlation can now be made between feed quality, i.e. impurity concentrations, and degree of delamination in the plant. This methodology has the potential to rapidly predict the effect of new reagents, upstream process upset conditions and synergistic interactions between impurities on deposit stress and delamination of nickel deposits.INTRODUCTION Nickel electrowinning in sulphate media was first pioneered by Outokumpu in its Harjavalta refinery in 1960 (Saarinen and Seilo, 1985). The original process was very manual with starter sheets plated onto “acid resistant” steel for 36 hours and then manually stripped and cut into sheets which could be inserted into the main production cells for a further 4–5 days. The starter sheet stripping and manufacture process was later automated. The same technology was subsequently implemented on a number of plants around the world. Anglo American Platinum’s Base Metal Refinery (BMR) began nickel electrowinning in the early 1980’s. The recent expansion of Anglo American Platinum’s Base Metals Refinery necessitated the construction of a new nickel tankhouse to achieve two primary objectives. The first to increase the capacity to 32 400 tpa nickel and the second to reduce employee occupational exposure to nickel aerosols. The new tankhouse has been commissioned and is in the process of ramp-up; more details are given by Hagemann et al. (2016). Fundamental to lowering employee exposure to aerosols was automating both harvesting and final handling of cathode. In order to accomplish this a bold move was taken to plate up to 10 days on permanent titanium blanks which are harvested by automatic crane and automatically stripped. The original development work for the plating nickel on titanium blanks over a ten day cycle is given by Bryson et al. (2006)."