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By A. W. Effinger

The Bureau of Mines used regression analysis and applied statistical methods in an effort to rationalize the results of an experiment examining the effects of certain variables on carbon deposition in a reservoir for thermal recovery of petroleum. Although none of the 15 trials of the original experiment resulted in the response of weight-percent of carbon regarded by the experimenter as adequate, values calculated using canonical analysis in two trials yielded responses 33 and 54 percent higher than the minimum acceptable figure. The actual responses differed by less than 3 and 6 percent, respectively, from the predicted responses. Methods are described for defining a path of increasing response based on the minimum point and the response surfaces and for defining a set of values for the parameters in question, which result in increased response, A detailed explanation of the mathematical process used in this analysis is presented in the appendix for ease in computer programing the technique.

Jan 1, 1970

Provide reasonably priced, reliable fire protection for blasthole drills. Approach An automatic fire sensing and suppression system using both dry and gaseous chemicals was developed, and is more shock and vibration resistant than similar industrial fire protection systems. How It Works Temperature sensors mounted in the drill's machinery house, hydraulic room, operator cab, and transformer area detect the heat from a fire, and trigger a sequence of actions. The same fire fighting sequence can be initiated from manual alarm boxes in the cab, hydraulic room, or machinery house. Electrical power to the drill Is immediately cut off, and a horn sounds to warn the drilling crew. After a 40-second, built-in, delay to allow time for drill's ventilating fan to stop, gaseous and dry chemical fire extinguishing agents are piped to and released in various rooms of the drill. The gaseous extinguishing agent (Halon 1301) is released in the machinery house, hydraulic room, and operator cab where dry chemical clean-up from electrical panels and machinery would be difficult and costly. Dry chemical is piped to the transformer room at the rear of the machine. Location of the principal components of the system are shown in the drawing.

Jan 1, 1979

By M. A. Elliott, H. H. Schrenk, L. B. Berger, John C. Holtz

"INTRODUCTION Among the hazards that may attend the use of Diesel engines in mines, tunnels, or other underground operations the presence of harmful or objectionable constituents in the exhaust gas must receive due consideration to prevent the formation of unsafe or unhealthful working environments in these places. Previous reports of this series have presented discussions of the composition of exhaust gas from engines in proper mechanical condition, 6/ the effect of adding some of the exhaust gas to the intake air of the engine, 7/ the effect of operation in atmospheres containing natural gas, 8/ and the effect on exhaust-gas composition of conditions that influence the characteristics of fuel injection in Diesel engines. In all these studies the properties of the fuels used were in general conformity with specifications usually recommended by the manufacturers of Diesel engines. In evaluating the physiological significance of the various components of the exhaust in these experiments, the toxic or objectionable gases determined were carbon monoxide, carbon dioxide, oxides of nitrogen, and aldehydes. Because of the low sulfur content of' these fuels, compounds such as sulfur dioxide and sulfur trioxide were not determined, although in discussion of the test results attention was directed to the fact that if fuels of higher sulfur content were used, the concentration of such compounds in the exhaust would become a significant factor in establishing the quantity of ventilating air required to furnish satisfactory dilut1on of the exhaust gas in underground working places."

Jun 1, 1943

By P. A. Bloom

Arsenic-containing flue dusts are currently being stockpiled by several nonferrous smelters in the United States. These stockpiles are a source of environmental concern since the dusts can be transported by wind and contain water-soluble arsenic. The stockpiles also represent an alternate source of metals. To provide a quality environment, the Bureau of Mines investigated a process to make environmentally acceptable the discard of arsenic obtained from the treatment of arsenical flue dust. The process includes (1) leaching arsenic from a lead smelter copper dross flue dust, (2) fixing arsenic as an insoluble compound, and (3) recovering other metal values. Overall results of acid-leaching tests on lead-smelter flue dusts showed that H2S04 dissolved 80 to 90 percent of the As, Zn, and Cd, and up to 86 percent of the In. Pb, Ag, and Au remain in the residue, which can be recycled to the smelter. Indium was recovered from the strong acid leach solution by solvent extraction; arsenic was fixed in a stable form by precipitation with Fe2(S04)3 and CaO or CaC03.

Jan 1, 1982

By B. W. Madsen

As part of a program to maintain an adequate supply of minerals and metals to meet national economic and strategic needs, the Bureau of Mines conducted research to determine the diffusion coefficients for ferric ions in synthetic copper leach solutions. Determination of ferric ion diffusion coefficients in typical dump leach solutions is necessary for predicting leaching rates of copper from large-scale leaching operations and for optimizing concentrations of ferric iron in solutions to maximize leaching efficiency. Derivative chronopotentiometry, an electroanalytical technique, was used to determine ferric ion diffusion coefficients. The diffusion coefficient decreased dramatically with increasing concentration of iron in solution. An empirical model was used to relate the ferric ion diffusion coefficient to the total amount of sulfate in solution. Measuring the diffusion coefficient dependence on temperature yielded an activation energy of 5.5 kcal/mole of ferric ion. Activity coefficients of ferric ions as a function of concentration were calculated from diffusion coefficient data.

Jan 1, 1981

Provide the technology to remotely control a thin¬-seam continuous mining machine from a safe location hundreds of feet outby the working face in an underground room-and-pillar mine. Background and Approach Hard-wired or radio remote control of continuous mining machine has been commercially available since the early 1970's. This type of remote control, in low and high coal seams, situates the machine operator offboard, but within direct view of the underground coal face, Although positioned under supported roof, the operator can still be exposed to face area hazards that include roof-rib falls, dust, methane explosions, and equipment congestion. The U.S. Bureau of Mines approach has been to put the operator into a protected compartment at a location away from the working face. Since 1979, the Bureau has investigated innovative methods to better protect face area workers in under¬ground room-and-pillar mines. In 1989, the Bureau demonstrated an offboard, computer-based remote con¬trol system in a West Virginia highwall mining operation that stationed the operator hundreds of feet away from the working face. In late 1992, much of this technology, plus improvements, Was used to demonstrate, on the surface, how a thin-scam continuous mining machine could be remotely controlled 200 feet from the machine in a 36-inch working height.

Jan 1, 1992

Detect hazards associated with abandoned mine openings through the use of integrated geophysical technology. Background Many abandoned mines in the U.S. present hazards to the public. The first step in abatement of these hazards usually requires locating the abandoned workings. Recent Colorado legislation resulted in a concerted effort aimed at mitigating the hazards associated with abandoned mine workings. The Colorado Department of Natural Resources-Mine Land Reclamation Division (CDNRMLRD) is responsible for locating and backfilling abandoned mine openings such as shafts, adits and collapsed features. Many shafts and adits can be located by inspection, other openings give little or no surface expression and must be located by drilling, or through the use of geophysical methods. A common method used for locating underground mine workings is to drill throughout the suspected area. However, it is prohibitively expensive to drill holes at the spacing needed to detect backlilled shafts and small voids associated with caving and/or chimneying. It may also be dangerous to move heavy equipment over shallow mined-out workings. Geophysical investigations that employ only a single method have had mixed success in detecting hazardous abandoned mine land cavities.

Jan 1, 1991

By Clarence O. Babcock

ROCK BEHAVIOR has proved of national interest in a variety of fields. The behavior of rock consequent to a nuclear blast was used to detect such blasts, as criteria for the design of underground military defense installations that would resist nuclear blasts, and for judging the feasibility for peaceful uses of nuclear explosives. An obvious peaceful application of nuclear explosives would be for large-scale rock excavation, and plans were presented during the year to improve the present Panama Canal or create a new canal by this method. These plans were based largely on earlier crater tests that demonstrated rock behavior when subjected to a buried nuclear blast. A knowledge of rock behavior under impact was used to evaluate the materials of the moon by means of the geometric configurations visible in the close-up pictures of the moon surface taken by the U.S. rocket Ranger 7. The composition of the moon must be considered in devising methods for taking samples of the surface layers or in designing underground shelters as bases for future explorations of the moon.

Jan 1, 1965

By John H. Scott

At the request of the Mine Safety and Health Administration, U.S. Department of Labor, the Bureau of Mines evaluated the model BT 300 C-D blasting machine tester, manufactured and distributed by Research Energy of Ohio, Inc. (REO), to determine whether the tester performed as stated by the manufacturer and responded satisfactorily to electrical faults introduced into the blasting machine circuit. Tester readings were recorded for 13 blasting machines and for 12 circuits constructed to simulate the electrical parameters of actual machines. The tester readings were acceptable for all of the blasting machines, although the switch position assigned to one machine produced an off-scale reading. The tester responded satisfactorily to the simulated circuits and detected serious voltage or capacitance faults when they were introduced. However, it did not respond accurately to certain resistance faults. Temperature tests were also made, and the tester performed equally well at temperatures of 20°, 42°, and 81° F. This tester was judged a useful accessory for field checking blasting machines for defective batteries and capacitors, despite its limitations. It is recommended that the tester manufacturer specify the lowest acceptable reading at which a blasting machine may be used and below which the blasting machine should be returned to the laboratory or manufacturer for maintenance.

Jan 1, 1981

Reduce face methane concentrations and help prevent miners from working under unsupported roof while moving the curtain. Approach Use water sprays on the continuous mining machine to move and direct air to the face, and also provide appropriate installation guidelines for the most effective use of the system. I n laboratory tests and under actual mining conditions, the spray fan has proved an effective means of ventilation. Recent observations in the field, however, have shown that not enough technical information is widely available on proper installation of the spray fan. This Technology News is designed to rectify that situation by providing a concise guide for spray fan installation. How the System Works Good ventilation is essential for methane control. The spray fan system repositions regular water sprays to help the normal exhaust face ventilation do a more effective job. The various water sprays help in many ways: 1. Side sprays bring clean air along the side of the miner into the off-curtain corner.

Jan 1, 1983

To concentrate coarse mica particles using a dry beneficiation technique. Approach Concentrate coarse, II berated mica particles using a Bureau-designed system of crushers, screens, and a two-stage zigzag air classifier. How It Works Because mica has a flat plate-like crystalline structure, mica particles are significantly lighter than blocky gangue particles of the same size fraction. Thus an air classification technique can separate the flat, light mica particles from the heavier gangue particles. The ore, which Is first run through a standard jaw crusher, a roll crusher, and a hammer mill to liberate the mica, enters the rougher Zig-zag section through a rotating air lock. See photograph and diagram of a 2-stage air classifier. Airflow through the classifier can be varied according to the size of the particles being separated. The gangue material falls through the airstream of the rougher zigzag section and is discarded as tailings. The mica flakes are carried by the air-stream to the cyclone shown on the right side of the diagram, where they are collected. This rougher mica concentrate is fed to the cleaner zigzag section through another rotating air lock. The mica particles are again carried by the airstream but they are now collected In the cyclone on the left side. The cleaner concentrate leaves the left-side cyclone through a third rotating air lock and is rescreened to remove under-size material missed by the first screening. The final product of this pneumatic process is generally a high-grade mica concentrate. A generalized flow diagram for the pneumatic concentration method Is shown In the second diagram.

Jan 1, 1981

By E. K. Kleespies

The Bureau of Mines determined the kinetics of the reaction of titanium-iron alloys with titanium trichloride dissolved in sodium chloride to provide a basis for understanding the reactions occurring in metallurgical processes involving reduction of the metal halides or alloy refining in fused salts. The rate of the heterogeneous reaction was determined between titanium-iron alloys and titanium trichloride to elucidate the effects of alloy composition on the rate. Measurements were made in an inert atmosphere with a high-temperature thermobalance using high-purity reactants. The rates of the reactions were about 1 x 10-5 g Ti/cm2-sec, and the reaction was phase-boundary controlled. Titanium alloys of the body-centered cubic beta structure reacted faster than those with the hexagonal close-packed alpha structure. The inter-metallic compound, TiFe, reacted very slowly, whereas TiFe2 was inert. Alloys containing above 89 atomic percent iron gained weight by reacting with titanium species in the salt solution and depositing titanium in the alloy. The effect of TiCl3 concentration on the reaction rate was determined from 2 to 12 weight-percent TiC13 and at various alloy compositions. At high iron contents, above 50 atomic percent, the TiC13 concentration effect was small. At lower iron contents, the TiC13 concentration effect was greater for beta-crystalline alloys than for alpha-crystalline alloys. The temperature dependence of the reaction between titanium alloy containing 8.7 atomic percent iron and titanium trichloride was measured over the temperature range 1,062° to 1,220° K, and the energy of activation was 7.7 kilocalories for the reaction.

Jan 1, 1967

By Peter F. Steidl

As part of the Bureau of Mines methane control program, the Upper Free-port coalbed was studied in Fayette County, Pa., where this coalbed lies about 650 feet below the Pittsburgh coalbed and contains the largest remaining reserves of any coalbed in the county. Coal and overburden isopachs, structure and joint pattern maps, and a fence diagram were prepared using data from gas and oil exploration logs and coal outcrops. These maps will aid in deter-mining the need and/or feasibility of degasifying the Upper Freeport coalbed in the study area. Much of the coalbed in this area is under 600 to 1,400 feet of overburden. By correlation with data from the Pittsburgh coalbed, the gas content at depths of this order is estimated to be between 140 to 300 cf/ ton of coal, for a total of 190 to 400 billion cubic feet of methane in this coalbed in Fayette County.

Jan 1, 1977

Develop rugged, cost-effective fire protection for hydraulic shovels and backhoes. Approach Automatic fire sensing and suppression systems were designed and built for use on hydraulic shovels and backhoes. How It Works A line-type temperature sensor is mounted in the machine's engine and hydraulic pump areas to detect the heat from a fire while it is still small and easy to control. Two systems were tested. In one, the inside of the sensor consists of two conductors separated by a ceramic material whose electrical resistance decreases with increases in temperature. When heated to a predetermined temperature) the control circuit responds to the resistance drop. In the second system, the detection element of the sensor is comprised of a thin metal tube containing a hydrogen charged metal hydride wire. The tube is sealed at one end and is connected to a sensitive pressure switch at the other end. When exposed to the heat from a fire, hydrogen gas released from the metal hydride wire actuates the pressure switch.

Jan 1, 1980

Provide reasonably priced, reliable fire protection for AN-FO haulers. Approach An automatic fire sensing and suppression system for AN-FO haulers was developed and on-vehicle tested. How It Works The system works in two ways to protect personnel from dangerous and unpredictable AN-FO fires. First the system senses and suppresses fires on the truck before they spread to the AN-FO in the bunker. This design was chosen because AN-FO truck fires generally start when combustible liquids (such as diesel fuel, hydraulic fluid or lubricating oils) are ignited by hot surfaces mainly on three areas: the engine, the transmission or the power take-off. These fires are quickly sensed by a linear temperature sensor strung throughout these three areas. The system then warns the operator and automatically suppresses the fire by discharging 30 pounds of multipurpose dry chemical extinguishing agent through a network of fixed hoses and nozzles. Second, this system includes six spot thermal sensors mounted inside the bunker on the truck to monitor the AN-FO temperature in case a fire does spread to the bunker area. If the bunker temperature rises to 190° F, a loud siren is sounded to warn nearby per-

Jan 1, 1981

By H. H. Dewing

The Bureau of Mines conducted a laboratory-scale investigation of a technique that produces zinc sulfate and elemental sulfur from sphalerite concentrates by reaction with sulfuric acid at 175° to 200° C and ambient pressure. The objective of the investigation was to develop a hydrometallurgical method of producing zinc from sulfide concentrates that does not generate sulfur dioxide pollutants. Reaction with 80-to 85-pct sulfuric acid produced 4 moles of sulfur for every 3 moles of sphalerite reacted, with minimal production of sulfur gases under optimum conditions. More than 98 pct of the zinc was recovered as zinc sulfate after 3 hours at 175° C. The reaction mixture was leached with simulated spent zinc electrolyte containing 13-pct sulfuric acid to recover zinc sulfate from the insoluble, high-sulfur residue. Neutral zinc sulfate, which is required for electrolysis, was separated from the sulfuric acid solution by crystallization as ZnS04?7H20 at -10° C. Up to 80 pct of the water in the recycled electrolysis solution was removed by the crystallization process; evaporation was used to further concentrate the sulfuric acid for reuse in leaching sphalerite. Advantages of the proposed method over conven-tional roasting and leaching include virtual elimination of sulfur dioxide, production of a solid sulfur byproduct, and higher zinc recoveries due to elimination of zinc ferrite losses.

Jan 1, 1978

By R. E. Peterson

The Bureau of Mines has undertaken beneficiation investigations on samples representing large tonnages of oxidized taconites in order to develop and evaluate applicable technologies for producing iron oxide concentrates from these materials. Information derived from the investigations can be used to expand the domestic iron raw-materials base and to establish the impact these taconite deposits may have on future national iron ore requirements. This report describes a process that includes reduction roasting, magnetic separation, and flotation, applied to a western Mesabi Range sample taken near Coleraine, Minn. The sample contained 36.8 pct iron and 46.0 pct silica, and represented 0.5 to 1 billion tons of crude material. An average of 962 lb/hr of oxidized taconite was roasted with 33 lb/hr of lignite in a 35-foot-long rotary kiln. Pulverized lignite and natural gas maintained the kiln operating temperature at 850° C. The roasted taconite was beneficiated by magnetic separation and cationic flotation in a 900-lb/hr pilot plant and yielded a product analyzing 68.1 pct iron and 4.6 pct silica, and containing 82.4 pct of the iron in the kiln feed.

Jan 1, 1981

By David A. Monaghan, Kenneth R. Maser, Adi R. Gurdar, D. Randolph Berry

9. Remote Sealing System Sensitivity 9. 1 Introduction In the previous sections a description of the overall system has been presented along with detailed descriptions of the equipment and techniques employed with the preliminary probing system, the seal em¬placement system and the seal checking system. In addition, the use of these subsystems in a specific mine application has been described in considerable detail. A broad range of parameters of interest was specified in the contract, as summarized in Section 1. 3. Most of these are a function of the general location; i. e. , the location of the mine, and the specific location; i. e. , the location of the boreholes. These parameters of interest include passage size, shape, depth, slope and water con¬ditions. The length, diameter and location of the boreholes within the mine passage and on the surface are critical parameters as well. A few additional parameters may affect one or more of the remote sealing subsystems. These include temperature, topography, rock and soil conditions, and underground water. While variation in these parameters will not render the system inoperative, consideration of them in the planning stages will simplify and expedite the field operation. In the following sections the effect of the various parameters on the remote sealing operation will be discussed. For clarity, the several tasks, borehole drilling and casing, preliminary probing, fly ash delivery, foam topping and seal checking, will each be considered separately.

Jan 1, 1973

By Syd S. Peng

The design of retort interchamber pillars is important in determining surface stability over in situ retort mines and to the health and safety of miners, particularly with respect to possible escape of heat and toxic gases from retort chambers. Stress distribution in retort interchamber pillars, roof, and floor was examined with the aid of linear, finite-element analysis using data from experimentally determined mechanical properties. Properties determined included elastic moduli, strength, and creep constants in laboratory tests on core covering a 100-foot depth interval in the oil shale from the Piceance Basin in Colorado. The most critical stress concentration was found in the rib side of the interchamber pillar at a height above the floor line of 1.25 times the width. Guidelines for pillar design that consider pillar strength, creep, and retorting temperature effects are proposed.

Jan 1, 1981

Provide a means of evaluating the in place structural properties of coal seams and coal measure rocks in advance of mining. Approach Develop a sonic logging probe for use in dry wells, a condition common to shallow wells and semi-arid coal regions. How It Works The Bureaus' sonic probe differs from conventional sonic probes because it does not require fluid in the well to couple sonic vibrations to the drill hole wall. A self-contained hydraulic system forces pistons containing the measurement transducers against the wall and clamps them in position until the sonic waveform information has been recorded. The pistons are then retracted and the probe is raised or lowered in the well as required. In the clamped position, the piezoceramic transmitter emits a sonic pulse which travels along the drill hole wall and is detected at the receivers in the form of compressional (P) and shear (S) wave motion. The receivers are designed to be sensitive to either the (P) wave or (S) wave motion as determined by the operator so that discrimination between the two wave types is improved by comparison of the respective output channels, and the travel time between transmitter and detectors can be accurately determined. Use of two receiver stations eliminates errors in timing of pulse travel because of electronic delays inherent in the probe.

Jan 1, 1981