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By E. L. C. Martins, M. J. Nicol, D. Majuste, A. D. Souza

The effects of organic compounds on the current efficiency (CE), morphology, crystal structure and mechanical properties of the metal deposited during the electrowinning of zinc are described. A flotation collector and lubricating oil were selected based on observations made during the industrial production of zinc from silicate ores, in Brazil. The analysis by Fourier transform infrared spectroscopy of these compounds, which may be present in minor amounts in the electrolyte solution, indicated the presence of a polar amine group in the collector, while the lubricating oil is a non-polar compound. The average CE value obtained from organic-free industrial solution was 91.15 ± 0.26 %. The CE dropped to 54.35 ± 0.73 % in the presence of 100 mg·L-1 of collector in the solution, and a negative effect was also observed in the presence of similar amounts of oil (88.84 ± 0.61 %). The characterization of the deposits by scanning electron microscopy and X-ray diffraction revealed the formation of pores in deposits obtained from solutions containing the oil, while a different growth pattern (perpendicular zinc platelets) was identified when the flotation collector was added to the industrial solution. In the presence of these contaminants in the solution, guided-bend tests revealed that the deposits have a higher resistance to deformation, but lower ductility, properties that may affect the performance of the stripping stage. As a result of this work, simple control and optimization actions were applied in the industrial plant, which resulted in important improvements in the electrowinning process.

Jan 1, 2014

By A. Consigny

New "clean technologies" to treat mining and metallurgical effluents containing dissolved metals have been successfully applied at mine sites in North America and Asia, treating water flows up to 24,000 m3/day. These clean technologies offer significant benefits compared to conventional alternatives and provide a sustainable solution that eliminates residual waste sludge, improves water conservation, generates revenues from wastewater, and delivers overall improvements to the environment. This paper will profile these technologies, and provide best practice case study examples of their application at mining operations, including data for water chemistry, flows, water quality, capital and operating costs, and life cycle costs of treatment.

Jan 1, 2011

By Thomas Genty, Pascal Marcotte, Matthew Gillman, John Baechler

Elevated concentrations of ammonia nitrogen is a common characteristic of mine impacted water and generally results from the dissolution of undetonated explosives (i.e., Ammonium Nitrate and Fuel Oil and emulsion explosives) by contact water. Several active water treatment technologies are commercially available to remove ammonia nitrogen, but reduction of active treatment demand by promoting natural attenuation is considered best industry practice. In this paper, the results of laboratory-scale and full-scale trials of a semi-passive approach (i.e., enhanced algae growth) to remove ammonia nitrogen at the Meliadine mine are presented. Phosphorus was found to be the limiting factor to algae growth at the mine site. The addition of various concentrations of phosphorus was first tested at a laboratory scale. The samples were exposed to in-situ conditions, and ammonia nitrogen removal rates ranging from 40% to 93% were achieved over a period of 24 days. This paper also presents the methodology and results of an in-pond treatment during which a 50% ammonia nitrogen removal rate was observed after 68 days. The studied mine site uses breakpoint chlorination as its primary treatment approach for ammonia nitrogen removal. The results presented in this paper show the potential of using enhanced algae growth as a pre-treatment method, subsequently reducing the quantity of chemicals required for operating the breakpoint chlorination plant. This potential requires further investigation and additional trials are currently under evaluation.

Jan 1, 2023

By H. Arima, Y. Kudo

In general, the iron content of zinc leach residue produced by sulphuric acid leaching from calcine is disposed as jarosite or goethite into a tailing dam. More recently, these iron residues have been treated pyrometallurgically to avoid waste disposal. The Iijima refinery selected a different zinc leach residue treatment process for iron control when it was established in 1971. The Iijima refinery is the only plant in the world that has processed a zinc leach residue by the combination of SO2 pressure leaching and O2 pressure hematite precipitation. The process enhances zinc recovery and recovers gold, silver, copper, lead and rare metals in saleable by-products. This paper focuses on the two stages of autoclave application in the zinc leach residue treatment process. The detailed flowsheet and recent advancements to improve the quality of by-products are discussed.

Jan 1, 2004

By Ifeanyichukwu Nweke

"Aluminium rolling processing from ingots to cold rolled coils comes with a lot of challenges especially in controlling defective products in casting, hot mill and cold mill operations. Hence this study focused on reducing defects at mills and cast-house using six sigma approaches. The use of six sigma approach will help the production experts to determine the gap between its operation and world class process. Practical data from First Aluminium Rolling mills were presented and analysed and mini improvement projects were proposed based on organisation need to achieve excellence. This study encourages aluminium alloy industries to pursue process improvement projects on the basis of analysis on data obtained from their shop floor, hence ensuring that through this, recovery is improved and cost of poor quality is reduced.INTRODUCTION Engineer Bill Smith while working at Motorola in 1986 introduced a new concept in which a set of techniques and tools are used for process improvement by controlling variations (defects). These tools and techniques are explained by an acronym DMAIC. D DEFINE the problem M MEASURE the variables in the problem A ANALYSE the variables of the problem I IMPLEMENT and verify the solution to the problem C CONTROL the solution to sustain it Most times in six-sigma approach, variations in the process that results in defects and customers’ dissatisfaction are targeted at 3.4 defects per million opportunities. There are numerous methods six sigma application use to achieve quality results and innovative strategies. Improving the quality of process through these methods helps identify and reduce variations which paves way for organisational excellence. In this study, it is encouraged to use six sigma techniques to improve aluminium rolling operations and other aluminium processing activities, the benefits of such improvement concept include: • Satisfy the voice of the customer (VOC) • Minimise costs • Maximise Profits • Build Good Team • Implement Profitable Project"

Jan 1, 2018

By M. W. Grabinsky, J. H. Curran

"Characterizing the spatial distribution of rock stresses is a challenge, especially in the geologically complex environments typically found at most metalliferous mines. Therefore, instead of focusing, specifically, on the task of making stress measurements, the engineer should instead attempt to develop a better understanding of the interaction between stress, mining geometry and rock mass behaviour. This paper demonstrates such an approach using a Canadian Shield hardrock mine case study, in which geomechanical models are used to relate stress, mining geometry, and rock mass properties to observed excavation response, and numerical modelling is used to better quantify this interaction.IntroductionUnderstanding how the mine geometry, field stresses and rock mass interact to produce the observed rock mass response to mining can be a significant challenge. Consider our present ability to quantify the basic geomechanical design input data. Mine geometry is normally quantified in more detail than is required for analysis purposes. Our understanding of rock mass strength and stiffness is far from complete, but established procedures do exist to obtain estimates of these parameters based on index and laboratory testing data and field mapping. Our ability to quantify field stresses is probably the most limited, in part because stress measurements are difficult and expensive to carry out, and in part because the stresses vary to an unknown degree from point to point within the rock mass. The engineer must, therefore, consider whether or not stress measurements are justified and, when they are, where the average stress state needs to be quantified and how many of which type of measurements will be required to determine the average stresses.Such was the case at Ansil mine, a massive sulphide deposit in hard rock located at a depth of more than one kilometre in the northern Québec portion of the Canadian Shield. The Ansil orebody was relatively rich, but small, with the potential for significant stress-related problems. As a result, geomechanical design had to be done carefully from the start – there would be little opportunity to modify the mining strategy once production had begun, and the economic consequences of stope dilution and rock mass instability would be severe. An extensive stress measurement campaign was carried out, but the determined stress magnitudes were unexpectedly low. The designers were, therefore, faced with a dilemma:"

Jan 1, 1997

By J. A. Finch

In this paper, the author offers a personal view of what the next 30 years holds for mineral processing. Restating that mineral processing will remain a vibrant industry in raw material production, growth opportunities in waste management are identified. The processing sequence familiar now (mining ?mineral processing ?extraction) will become more interwoven. In situ processing (i.e., milling underground) will evolve from concept to demonstration. Opportunities to exploit physical properties altered in chemical (pyro- and hydro-) processing will present themselves. In primary grinding, the path to AG/SAG milling will progress with little deviation but opportunities in regrinding are wide open. Flotation will see the trend to designing bubble/particle reactors accelerate simultaneously with a vigorous response from mechanical cell suppliers. Gravity separation remains a bastion of the lone inventor but this author anticipates that the new lines will come from the waste management business. The paper concludes with the examination of the “research cycle” and identification of growth in small “high tech” companies and university research centres

Jan 1, 1998

By F. Habashi

Lead is an ancient metal. The alchemists related it to the planet Saturn. It was largely obtained by smelting galena which generally contains small quantities of silver. That is why the metallurgy of lead was closely related to that of silver and in some cases the ore was treated only for its silver content. It was also known during the Roman time that lead vapors were toxic. Lead has been produced exclusively by pryrometallurgical methods. Lead refining is a complex process because of the presence of deleterious impurities such as arsenic, antimony, and bismuth. In the nineteenth century lead played an important role as a material of construction in the manufacture of sulfuric acid. In the twentieth century tetraethyl lead was used exclusively as an anti-knock reagent. In recent years lead is mainly used for making batteries.

Jan 1, 2008

By Fabian Mohr

The methyl substituted binuclear cyclometallated gold(I) complexes [Au2(?-n-MeC6H3PPh2)2] [n = 4, 5 and 6] all undergo oxidative addition reactions with halogens and, in the case of the 4- and 5-methyl substituted analogues, with dibenzoyl peroxide to give metal-metal bonded digold(II) complexes [Au2X2(?-C6H3-n-MePPh2)2]. The 4- and 5-methyl substituted digold(II) compounds on warming or exposure to light undergo carbon-carbon coupling reactions to give gold(I) complexes containing the corresponding 2,2'-n,n'-biphenylyldiphenylphosphines. The 6- methyl substituted digold(II) complexes rapidly isomerise above ca. -20° C to binuclear heterovalent gold(I)/gold(III) compounds [XAu(?-2-Ph2PC6H3-6-Me)AuX{?2-(6-MeC6H3-2-PPh2)}], containing a fourmembered cyclometallated ring on a gold(III) centre. Surprisingly, no carbon-carbon coupling could be induced for any of the 6-methyl substituted compounds, even under forcing conditions. This difference in reactivity of the 6- methyl derivative, compared to that of the 5-methyl and unsubstituted analogues was studied by ab initio calculations using a series of model compounds. The results are in excellent agreement with the experimental findings and suggest that the key-step in the C-C coupling reaction is the partial opening of the Au(III)-P bond in one of the transition states. In the 6-methyl system this transition state is energetically inaccessible and hence no C-C coupling occurs.

Oct 1, 2003

By Kenneth L. Norris

Stonegate Agricom Ltd. is currently conducting exploration and development drilling of the Paris Hills Phosphate Project (Paris Hills Project) located in Bear Lake County, southeastern Idaho, 3.2 km west of the towns of Paris and Bloomington, Idaho. The project is located adjacent to a highway and 19 km by paved highway to Montpelier, Idaho where the Union Pacific Railroad system is located. Power and water are available locally. The nearest metropolitan centre is Salt Lake City, Utah approximately 225 km by road to the south-west of the property. The Paris Hills Project encompasses an area of approximately 856 hectares. Property holdings consist of three (3) patented lode mining claims and 16 contiguous fee parcels (some with federal phosphate leases). Active open pit phosphate mining operations are located in surrounding counties in south-east Idaho and are owned and operated by Agrium Inc., Monsanto Company and J.R. Simplot Company. The Paris Hills Project is located near the centre of the Western Phosphate Field which constitutes the most extensive phosphorite beds in the United States. Phosphate beds of the Western Phosphate Field occur within the Phosphoria Formation of Permian age and extend over an area of more than 350,000 km2 including extensive areas of Idaho, Utah, Wyoming and Montana. At Paris Hills the phosphate mineralized beds occur in the overturned limb and the horizontal limb of the Paris Syncline. Grades and thicknesses in both the western overturned limb and the eastern horizontal limb of the anticline are similar. The vast majority of potential mineralization occurs in the horizontal limb which underlies most of the property holdings. Mineralization in the overturned limb has a strike length of over three (3) kilometres and extends from the surface to a depth exceeding 300 m depending on location along the north-trending strike of outcrops. Depths of the horizontal limb range from surface along the north side of Bloomington Canyon to estimated depths of 915 to 1,035 m at Paris Canyon. The property contains an Inferred resource of 109.6 million tonnes at 23.6% P2O5 over two mineralized horizons. The phosphate zones have a strike length of over 3 km and extend from surface to a depth of at least 900 m. Drilling commenced late in the 3rd quarter of 2010 and is planned to continue through 2011. The drilling was planned to target an area of potentially higher grade phosphate mineralization and better define and upgrade the current resources.

May 1, 2011

By A. Rao, J. A. Davidson, B. L. Jones, K. W. Bowes, D. Craib

Supported by ANSTO, Groundwater Science and Inception Consulting Engineers, Boss has embarked on a series of technical projects aimed at reinforcing the Project’s capability to meet its export permit production capability. This paper will focus on three aspects of this technical program: Reducing the cost of resource expansion through smart use of low cost, surface target generation techniques; Improving the rate of uranium leaching and solution stability (gypsum, jarosite) through lixiviant chemistry modifications; and Development of an ion exchange (IX) process to increase production capacity, and integration of IX and the current solvent extraction circuit with the existing uranium precipitation and product preparation circuits.

Jan 1, 2020

By E. R. Landry

This paper reviews the current state of electric furnace technology, with emphasis on some of the more recent developments. A large section of the paper is devoted to the use of increasingly high power inputs by arc furnace operators. Operating practices are then covered, including some of the newer techniques which have been tried.

Jan 1, 1967

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By Dean S. Rogers

"In February 1980, Dome Mines Limited announced a $50 million expansion program which would result in a 50% increase in mill capacity from the present 1,815 tonnes per day to an eventual production rate of 2, 720 tonnes per day in the year 1984. As an integral and necessary part of this planned expansion, a new vertical production shaft, No. 8 Shaft, would be sunk from surface to a depth of 1,645 metres.Throughout the seventy-year history of mining at the Dome, gold has been found in a number of different rock types and in association with a number of different structural settings. However, the key to successfully locating ore deposits lies in the recognition of the favourable environments in which they generally occur. First and foremost, the exercise of locating the No. 8 shaft became an exercise in geological deduction based on the projection of these favourable lithologic environments.In November 1980, after detailed engineering work was completed, the total cost of the project was estimated at $75.5 million 1980 dollars or $91 million dollars allowing for inflation over a four-year construction period. These estimates include the shaft, significant replacement and alterations to the milling process, and an upgrading of the plant."

Jan 1, 1982

By James H. Cobbs

Blind boring of shafts is becoming an increasingly important part of shaft sinking. Blind-bored shafts have reached diameters of 25 It in Europe and 16-1/2 ft in the United States. Much of the technology developed for blind boring has evolved from the technology of drilling wells for oil and gas production. Blind boring offers economic advantage in a number of situations where conventional shaft sinking either is extremely difficult or very expensive by virtue of large-capacity aquifers which must be penetrated, unstable ground or where very rapid sinking is required. In sedimentary rocks, blind boring is cost competitive with conventional sinking, in diameters of about 12 ft or less. Blind boring is not competitive with raise boring where conditions are favourable for raise boring. Blind boring does, however, offer greater flexibility than raise boring and can be performed in situations where raise boring is inefficient or impossible. Combination machinery has been developed to perform both blind boring and raise boring, so that the machine can be used effectively in situations where only the near-surface portions of the shaft are unfavourable for raise boring. Development work is being supported by the United States Bureau of Mines for blind boring equipment capable of boring shafts up to 30 feet in diameter.

Jan 1, 1979

By S. Nikolic

"Calcium ferrite slags are currently used in a number of copper-converting processes. Despite the industrial importance of this system the phase equilibria have not been fully investigated. Characterization of this slag system is necessary to improve the control of process parameters, including fluxing and operating temperatures. Recently, a modified experimental method has been developed; this involves rapid quenching of slag samples equilibrated at high temperatures with the resulting phase assemblages analysed using electron probe microanalysis (EPMA). In the present study, experiments were completed under controlled temperatures and oxygen partial pressures using CO/C02 or H2/C02 gas mixtures. The investigated slags were supported during equilibration by a substrate of the primary phase. This technique removes the limitations arising from the use of crucibles and facilitates rapid quenching of the melt. Experiments were carried out at 1200°C and 1250°C (1473 Kand 1523 K) and in the composition range 0-40 wt.% Cu20, 0-25 wt. % CaO and 45-80 wt. % Fe203. Liquidus and solidus data are reported for the primary phase field of spinel between the oxygen partial pressures of 10-4.5 to 1 o- 6-5 atm. The analyzed compositions of liquids and solids are used to construct the phase diagram of ""Cu20"" -CaO-""F ez03"" system in equilibrium with metallic copper at fixed oxygen partial pressures."

Jan 1, 2007

By Allan P. Fawley

ONE hundred miles from Vancouver, at an elevation of 4,000 feet, is the Pioneer mine. It is situated on Cadwallader creek, a tributary of Bridge river, and is reached by travelling from Vancouver to Squamish by boat, a distance of thirty-two miles, from there by train to Bridge River (one hundred and seven miles), and finally by automobile across Mission mountain .(7,000 ft. elevation) to the mine (fifty-six miles): a total distance of one hundred and ninety-five miles. Prior to 1924, many Companies had examined the Pioneer, which had been developed by shaft to a depth of 200 feet, but, while values were good, the small size of the ore-shoot discouraged large investors. In July, of that year, opera-tions were re-commenced by the late David Sloan and, on sinking further, the ore-shoot was found to lengthen greatly as well as to ex-tend in depth, while remarkable gold values also were encountered. When, later, the price of gold rose from $20 to $35 per ounce, the mine was in an excellent position to take full advantage of the increase + and not only became an extremely profitable enterprise itself but its success greatly stimulated the search for and development of other 1-gold properties in British Columbia.

Jan 1, 1937

By Q. Liu, P. Katsabanis, J. A. Meech

A thermohydrodynamic computer code has been used to simulate dust explosions. For sulphide dusts, the thermodynamic predictions are used to investigate the effect of dust concentration, mineral content and inert materials as well as the quantity of sulphur dioxide produced. It was found that the amount of oxygen available for the explosion is very important and that the dust concentration which gives maximum explosion pressures is obtained at zero or slightly negative oxygen balance values. The sulphide minerals were found to have the following explosibility sequence: pyrrhotite, pyrite, chalcopyrite, sphalerite, covellite, chalcocite and galena, which is in agreement with mine experience. The results show that theoretical calculations can be used to predict explosion pressures and toxic gases produced by a dust explosion and therefore they can assist in the design of protective measures .

May 11, 1988

By R. G. Eggert

"A critical element, as the term has come to be used, provides essential properties to a modern engineered material and is subject to supply risk. The rare-earth elements became perhaps the most prominent of the critical elements in recent years because of their important uses in permanent magnets, advanced lighting, and military materials; the geographic concentration of production in China; and the dramatic run-up in prices in 2010-2011 followed by price collapse between 2011 and 2016. Yet criticality extends beyond the rare earths. What is critical depends on your perspective – who and where you are, and when you ask. This paper reviews the many perspectives on, or faces of, critical elements. It compares and contrasts perspectives of industry (General Electric), national or regional manufacturing sectors (Japan, European Union), emerging energy technologies (as seen by U.S. Department of Energy and, separately, Joint Research Centre of the European Commission) and the world as a whole (as evaluated by academics). This comparison reveals a diversity of not only perspectives but also methodologies and time frames of concern.INTRODUCTIONRare-earth elements appeared prominently in the news in 2010 and 2011 because of the dramatic increase in their prices; their important uses in permanent magnets, advanced lighting, and military materials combined with the geographic concentration of production in China, which reduced export quotas significantly. Rare earths became the most prominent of what have become known as critical elements or materials – that is, those that provide essential properties to modern engineered materials and yet are subject to supply risks.Yet criticality, the state of being both essential and subject to supply risks, extends beyond rare earths. What is critical depends on your perspective. This paper begins by reviewing a little history and presenting a general conceptual framework from which to think about critical materials. It then reviews the many perspectives on, or faces of, critical elements – corporate, national, and global, as well several that focus on emerging energy technologies. The paper concludes with thoughts on what to do to mitigate the potentially negative effects of the supply risks associated with criticality."

Jan 1, 2016

By J. Beddoes

Many high strength aerospace alloys undergo solution heat treatment (SHT) and aging to develop precipitate strengthening. Most simply, SHT involves an isothermal hold in a single phase region followed by relatively rapid cooling to develop a super-saturated solid solution from which precipitates form during aging. However, subsequent properties are sensitively dependent on the details of the SHT, which frequently also serves a homogenization function. Altering the details of the thermal cycle during SHT significantly improves the properties attained during aging, as presented by examples of SHT design for titanium aluminide intermetallics, polycrystalline and single crystal superalloys, and 7075 aluminum.

Jan 1, 2010