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By A. O. Dufresne

A Step which, it is believed, will prove extremely beneficial to the Quebec asbestos-mining industry was taken during 1931, when the asbestos mine operators of the Province assembled to work out a uniform method of naming the products of their mines. The outcome of several meetings was the drawing-up of a classification which defined, limited, and designated anew the numerous grades of asbestos marketed. It entailed no drastic departure from the existing processes of grading, nor any revolutionary changes in methods of testing, but aimed rather to perfect existing methods. The classification proposed has been accepted by all operators in the Province, who, from January first of this year, began introducing the new nomenclature. Unless one is conversant with the properties and mode of occurrence of chrysotile asbestos, with the unique milling methods devised for its recovery, and with the history of the development of their technique, he may not readily understand the basis of the new classification. For information on these and other data concerning the industry, the reader is referred to a recent publication, Chrysotile Asbestos in (Canada, by James Gordon Ross, issued by the Mines. Branch of the Department of Mines, Ottawa. The object of this paper is to present briefly some of the phases in the evolution of the classification of Canadian chrysotile asbestos, in the hope that the recent effort to standardize the marketable products of one of Canada's most important non-metallic mineral industries will open a field for discussion, fruitful in new ideas and constructive suggestions. The necessity for the grading of asbestos results fundamentally from the fact that the price per ton depends on the length of fibre. At all times in the history of the industry, the very limited available supply of the longer grades, as well as the requirements of the trade, have caused relatively very high prices to be paid for fibre over half an inch in length, while for the shorter grades the price decreases rapidly, and at a rate which bears no proportionate relation to the length of fibre.

Jan 1, 1932

By R. Viljoen, K. Manns

"The mining industry instinctively follows rule-of-thumb design velocities often based on very simplistic theoretical “economic velocity” optimization calculations to determine airway sizes. Although these are important building blocks in ventilation planning it should be recognized that mines are far more complex and various, often opposing factors, are at play. Therefore, it is important that each ventilation situation be analyzed on a case-by-case basis to determine the best-fit solution for an operation. The ventilation design process should not necessarily be constrained by theoretical optimal economic velocities that become rules-of-thumb. In some cases, this could lead to unrealistic infrastructure requirements and exorbitant capital expenditure. This type of design often lacks corporate support leading to a scenario where no ventilation upgrades are implemented. Economic velocities typically consider the cost of power, development costs and operational risk. These typical rules-of-thumb work reasonably well as a starting off point when considering feasibility of greenfield projects. For established mines that are looking at expansion these rules may not be appropriate due to capital expenditure constraints or geotechnical ground conditions. The theoretical optimum should be reviewed in the case of an established mine where existing infrastructure could perhaps be maximized. For example, the geotechnical risk of large diameter raises at depth may require multiple small diameter raise to maintain the theoretical economic velocity. If a mine has a life of less than 5 years, then the cost of power is an insignificant proportion of the total owning cost. For these mines, operating the ventilation raises at an increased velocity to avoid a complicated and expensive capital upgrade might be the more appropriate option, even though it opposes the traditional rules-of-thumb. Mines which are capital constrained may be better off accepting a higher operating cost for the interim or settle for minor infrastructure upgrades rather than run the risk of the entire ventilation upgrade not being approved at all. This paper explores a number of examples derived from case studies undertaken by the authors for several deep mechanized mining projects in Australasia. The examples explore conditions under which higher than the economic norm would be applicable."

Jan 1, 2019

En quoi consistent les études de suivi des effets sur l?environnement (ESEE)? Les ESEE constituent une méthode de suivi scientifique que l?on peut employer pour déterminer la santé des écosystèmes aquatiques (qui peuvent être touchés par l?activité humaine) et l?efficacité des mesures de protection de l?environnement. Les ESEE sont des évaluations scientifiques itératives du poisson, de l?habitat du poisson et des ressources halieutiques. Le programme comporte des phases séquentielles de deux à six ans de suivi, d?interprétation et de compte rendu au cours desquelles la fréquence et le type de suivi dépendent des résultats des études précédentes. Le programme des ESEE pour les mines de métaux est fondé sur un accord conclu à l?unanimité entre les intervenants. Les exigences du programme et les guides techniques connexes ont été élaborés à la suite d?une consultation multilatérale à laquelle ont participé les représentants du secteur privé, du gouvernement et des collectivités. Toutes les mines assujetties au Règlement sur les effluents des mines de métaux (REMM), aux termes de la Loi sur les pê ches, doivent procéder à une ESEE dans le cadre de l?autorisation qu?ils ont reç ue de rejeter des effluents. Le REMM a été enregistré le 6 juin 2002 et publié dans la Partie II de la Gazette du Canada le 19 juin 2002 (SOR/DORS/2002-222).

Nov 1, 2002

"An unparalleled growth in the Canadian coal industry in 1970 coincided with increasing awareness by Canadians of their environment and their geography with its accompanying transportation factors. R and D on coal moved with greater emphasis toward solving problems in these areas as well as continuing with strong interest in coal preparation, carbonization, combustion, ""weathering'', spontaneous ignition, storage, exploration and geology. Long-range ""basic"" research was not forgotten in that work continued on coal-based carbons, coal chemistry and agrobiological uses for coal. This paper reviews the status of these many areas of coal research at the beginning of the seventies and takes note of some of the more significant legislation and projects brought to the author's attention. No attempt is made to itemize or to describe in detail all the worthwhile projects, many of which are reported elsewhere."

Jan 1, 1971

By R. D. Corrans

"Africa is endowed with a number of the world's giant ore deposits which have contributed significantly to the development of their host countries. Mineral exploration has a long history in the continent, but mining on an unprecedented scale took off during the latter part of the 19th century, accompanied by the development of lines of communication and other infrastructure to service the major mining centres.The ""Winds of Change"" which swept Africa in the 19505 and 1960s brought in new styles of government and economic management to a number of regions, often with demise of economic viability and infrastructure. In recent years, with the end of the cold war, collapse of communism and changes in South Africa, new opportunities for mineral exploration are opening up rapidly in Africa. However, due to the large cost, long lead-in time, and high risk of developing new mineral ventures in the continent, it is necessary for the host countries to draft realistic and favorable mineral laws and fiscal codes in order to attract, and not deter, potential mineral investors. There will be an on-going role in mineral exploration throughout Africa for the artisanal miner, the smaller entrepreneurs and mining companies, exploration aid programs funded by the developed countries through African governments, as well as the major mining houses who have the resources to develop larger viable mineral deposits."

Jan 1, 2008

By H. Paudyal, K. Ohto, H. Kawakita, S. Alam, B. Pangeni

The orange waste after lime water modification was converted into promising adsorbents for fluoride by metal loading reaction. The effectiveness and mechanism of fluoride adsorption on metal loaded orange waste gel from synthetic and real plating solution were investigated. Amount of zirconium(IV), aluminium(III), cerium(III), lanthanum(III), titanium(IV), vanadium(IV) and tin(IV) loaded on orange waste from aquearegia dissolution were evaluated to be 1.62, 1.16, 0.93, 0.95, 1.20, 1.12, 0.97 mmol/g respectively. The maximum adsorption capacity (qmax) of zirconium(IV), cerium(III), lanthanum(III), iron(III) and aluminium(III) loaded orange waste for fluoride ions were evaluated to be 1.74, 0.91, 1.07, 0.98 and 1.01 mmol/g from aqueous solution. The mechanism of fluoride adsorption by metal loaded orange waste was inferred to be ligand exchange reaction. Application of zirconium(IV) loaded saponified orange juice residue(SOJR) for real plating solution showed effective removal of trace concentration of fluoride down to the accepted standard. The negligible interference of co existing anions like nitrate, carbonate, sulphate and chloride makes zirconium(IV) loaded SOJR a promising sorbent for waste water treatment. The adsorbed fluoride from fluoride loaded zirconium(IV)-SOJR was effectively desorbed by using alkali solution for its regeneration. This work shed light on the potential application of metal loaded SOJR to remediate fluoride contaminated water for environmental relevance.

Jan 1, 2012

By J. R. Fisher

"Uranium may be leached to some extent in situ from the Blind River conglomerate uranium ores by using the products of bacterial activity from the bacterium Thio-bacillus ferrooxidans his paper describes some of the laboratory techniques used to investigate the characteristics of the bacteria, and to utilize their properties in uranium leaching. The application of some of the laboratory results underground at the Milliken mine of Rio Algom Mines Limited are de-scribed, along with the method of uranium recovery from the mine waters."

Jan 1, 1966

By S. G. Shabestari

Thermal analysis is a tool that is generally employed to predict the structure of the alloy before the actual casting is carried out. By cooling a sample of the molten alloy and recording the temperature-time curve, important solidification events may be analyzed by using the first derivative-cooling curve. In this research, strontium is added to (AS5U3G) 319 aluminum alloy and its influence on the formation of intermetallic compounds e.g. Al15(Mn,Fe)3Si2, Al2Cu, Al5Mg8Cu2Si6 formed during pre- and post-eutectic reaction have been investigated. Also any changes in solidification parameters such as temperature of Al-Si eutectic under cooling and temperatures of nucleation and growth of each phases caused by strontium addition, have been determined via the first derivative cooling curves. The effect of strontium on the formation of various intermetallic compounds has been studied by using very accurate thermal analysis equipment and the microstructures were analyzed using an optical microscope. The various phases reported in this paper were identified using Scanning Electron Microscopy (SEM) and linked to Energy Dispersive Spectroscopy (EDS). Formation of all pre- and post-eutectic phases was interpreted by comparing the phases formed in the microstructure and the reactions detected by using cooling curves. The results of this research indicate that thermal analysis technique can be used as an on-line process control in the production lines in aluminum casting industries.

Jan 1, 2004

By D. B. Dreisinger, M. R. Tavakoli

"Vanadium has been produced from a variety of sources. This metal is known to make aqueous solutions of complex speciation as a function of vanadium concentration and pH. Considering the method of leaching, the impurities in the pregnant leach solution, and the planned vanadium product, different extractants and flowsheets can be applied for solution purification. This paper reviews the purification of vanadium leaching solution using organophosphorus, solvating, and amine extractants. This review focuses on vanadium separation from iron, molybdenum, and uranium, which are often present in vanadium resources such as primary ores, fly ashes, and spent catalysts.RÉSUMÉ Le vanadium est produit à partir de diverses sources. Ce métal est connu pour permettre des solutions aqueuses de spéciations complexes en fonction de la concentration du vanadium et du pH. En tenant compte de la méthode de lixiviation, des impuretés dans la solution mère de lixiviation et du produit de vanadium planifié, divers agents d’extraction et schémas de traitement peuvent être mis en oeuvre pour purifier la solution. Le présent article étudie la purification de la solution de lixiviation du vanadium au moyen d’extractants organophosphorés, solvants et aminés. L’étude cible la séparation du vanadium du fer, du molybdène et de l’uranium, lesquels sont souvent présents dans les ressources de vanadium telles que les minerais primaires, les cendres volantes et les catalyseurs usés."

Jan 1, 2016

By B. Yu, Y. O. Oyediran, M. Robart

"This paper presents the latest flotation development testwork conducted in 2015 on the ‘B Zone’ samples from the Strange Lake Alkalic Complex (SLAC). Since the discovery by Iron Ore Company of Canada (IOC), metallurgical development has been under taken by a number of mining companies targeting various value metals, including yttrium, zirconium, niobium, and rare earths.Most recent, Quest Rare Minerals Ltd. (Quest) completed a Pre-Feasibility Study (PFS) in 2013 where the flowsheet was relatively complex and led Quest to explore alternative options. In 2014, the PFS flowsheet was simplified and one of the features introduced was pre-concentration by rougher flotation. The combined rougher flotation concentrate and slimes successfully recovered >90% TREE in 60% mass thus reducing capital cost and technical risks of the downstream hydrometallurgical processes. The latest flotation development testwork focused on achieving a pre-concentrate in which >80% TREE are recovered in 20% mass. Two separate reagent schemes, based on an ester phosphate collector (Clariant 1682) and a benzoylhydroxamic acid collector (Florrea 7510), were developed. Parameters evaluated in the development testwork included desliming, secondary yttrium and zircon collectors, depressants, temperature, conditioning temperature, time, and density, pH, sodium silicate type, cleaning, and flowsheet configuration. Both developed reagent schemes achieved the targeted metallurgy.INTRODUCTIONThe Strange Lake Alkalic Complex (SLAC) was discovered after geological survey and mapping studies by Geological Survey of Canada and Newfoundland and Labrador Department of Natural Resources between 1967 and 1980. Subsequent exploratory drilling programs by Iron Ore Company (IOC) in the 1980s found that the REE and high field strength element (HFSE) mineralization were within the central region of the SLAC which was named A Zone by IOC and later renamed Main Zone by Quest Rare Minerals Ltd. (Quest). Additional exploratory drilling outside the Main Zone by IOC and later by Quest, led to the discovery of B Zone, which was recognized as the most significant deposit of rare earth elements, yttrium, and zirconium in the SLAC. The B Zone Indicated Resources are estimated at 278.13 Mt at 0.93% total rare earth oxide (TREO) and Inferred Mineral Resources are estimated at 214.35 Mt at 0.85% TREO (Oyediran et al., 2014)."

Jan 1, 2016

By A. C. A. Howe, J. C. Rowntree

"The Bernie Lake pegmatite near Lac Du Bonnet in southern Manitoba is a complexly zoned pegmatite containing several lithium-bearing units in addition to the western world's largest known reserve of cesium. The pegmatite forms a flat-lying ellipsoidal body within an east-west-trending Precambrian amphibolite. The pegmatite enclosed by this vertically schistose amphibolite lies near the eastern tip of a granitic intrusive. The relationship of this intrusive to the pegmatite is obscured by Bernie lake. To date, the pegmatite body has been delineated aver an area of approximately 80 acres; it attains a maximum thickness of 280 feet. Several distinct zones, including three assemblages of economic importance, comprise the pegmatite itself. The combined spodumene and lepidolite assemblages provide a recoverable defined lithium ore reserve of almost 5 million tons averaging more than 2 per cent lithium oxide. The recoverable cesium ore of the pollucite assemblage provides 300,000 tons averaging more than 20 per cent cesium oxide; this represents more than half of the western world's pollucite reserve. The Bernie Lake pegmatite deposit, owned by Chemalloy Minerals Limited, is well located with respect to the growing United States markets, and its reserves of cesium are large enough to enable it, under favourable economic circumstances, to become the major producer of this metal in North America."

Jan 1, 1967

By E. A. Brown

"IntroductionBACK IN THE nineteen-thirties, when Eldorado was a private company and was preparing to become Canada's first radium producer, the Mines Branch in Ottawa did much work on the development of chemical processes for the Port Hope refinery (1).In 1945, after the Canadian Government had taken over Eldorado for •atomic energy reasons, the Mines Branch was called upon again, this time to help out by looking into ways and means of improving ore treatment methods for the mine at Great Bear Lake. A group of technical men was assembled to devote full attention to this work, which was known as the Eldorado Project.Three years later, in 1948, the Government decided to reopen the development and operation of uranium properties to private enterprise.Since it is a function of the Mines Branch to assisit private development of Canadian mineral resources, this new uranium policy made it important for the Branch to be in a position where it could provide up-to-date services, technical assistance, and information relating to treatment of radioactive ores, mineralogy of radioactive ores, and assay methods for radioactive ores.At the same time, .because of the demand for increased uranium production, lower grade ores had definitely come into the picture, ores that might be of decidedly lower grade than, say, Eldorado pitchblende, and of entirely different nature."

Jan 1, 1953

By K. Howard Poulsen

Shear zones are tabular tructures which tend to occur either discordantly within, or concordantly along the margins of, competent rock masse uch as plutons, sill or flows. They contain deformed equivalents of their host rock and are common sites for gold mineralization localized in tructure oriented y tematically relative to the shear zones and internal linear fabric. Apan from genetic implications, hear zone analysis proves useful in exploration for this type of deposit because the zones are generally wider and more continuous than associated mineralization and because there is an element of predictability to mineralization geometry (i.e. vein orientation. plunge).

Jan 1, 1986

By Chr. Krause

Within the scope the collaborative research centre 599 (Medical University of Hanover, University of Veterinary Medicine Hanover, University of Hanover) the behaviour of the degradation of magnesium materials as implants are investigated by using animal experiments (rabbits). Thus extruded cylindrical pins from the magnesium alloys MgCa0.8%, WE43 and LAE 442 were implanted intramedullary in the tibiadiaphyses. The implantation duration was 3 and 6 month. After the explantation 3 point bending tests were carried out to investigate the possible changes of the mechanical properties. Clearly changes in dependence of the implantation duration could be determined. The three magnesium alloys show a decrease of the mechanical resistance with an increasing implantation time. To evaluate the degradation process, wich is the reason for the changes, micrographs and element analyses (EDX) have been accomplished after the 3 point bending tests. The micrographs show for all used magnesium alloys corroded surfaces but no preferred corrosion on the grain boundarys. The element analyses show beside a layer which is rich in calcium and phosphorus an agglomeration of rare earth elements in this layer. With these results a using of magnesium alloys as a material for implants can be announced.

Jan 1, 2006

By J. Ouellet

"ABSTRACTA brief background on in-situ testing of mine backfill, as well as pressuremeter testing is briefly described, and results from an in-situ testing on paste backfill are presented. A series of self-boring pressuremeter tests were done from the top of a backfilled stope in an underground mine. The tests were conducted along a 20-metre vertical line in the centre of the stope. Some 14 tests were performed along this depth. The instrument used was a Camkometer built by Cam Insitu, Cambridge. The instrument proved to be efficient and reliable for underground testing in a cemented paste backfill. The testing program was conducted within the planned schedule with a high success rate. The test done in this study permitted the measurement of paste backfill strength, stiffness and in-situ horizontal stress within the backfill. RésuméUn bref historique des essais in situ dans le remblai minier est présenté. L’essai pressiométrique est décrit succinctement et des résultats d’une campagne d’essai dans un remblai en pâte sont présentés. Un programme d’essais au pressiomètre auto-foreur a été réalisé à partir du sommet d’un chantier remblayé sous terre. Les essais ont été réalisés le long d’un ligne vertical d’environ 20 mètres pour un total de 14 mesures. Le Camkometer de la firme Cam Insitu de Cambridge a été utilisé. Cet instrument s’est avéré efficace et fiable pour tester le remblai en pâte cimenté sous terre. Le programme d’essai s’est déroulé à l’intérieur de l’échéancier prévu avec un taux de réussite élevé. Ces essais ont permis de déterminer la résistance, la rigidité de ce remblai ainsi que les pressions in-situ prévalant dans le remblai."

Jan 1, 2000

By F. Ebbutt

The copper-bearing waters now treated successfully at Britannia for the recovery of their copper content are almost entirely derived from what is known as the Fairview mine; this was the first extensive copper producer of the Britannia ore-bodies, and consisted of a number of almost parallel veins, carrying good copper values, the ore consisting of chalcopyrite and pyrite in a quartz gangue. These veins occur in what is known as the ?Britannia shear zone' (Schofield, S. J., G.S.C. Sum. Rept., 1918, Pt. B), developed for roughly five miles in a roof-pendant in the well-known Coast Range batholith. This .pendant is made up of Palxozoic rocks known as the 'Britannia Formation' (LeRoy, O.E., Portion of Main Coast of B.C. and Adjacent Islands; G.S.C. Memoir No. 996, 1908). These consist of dark carbonaceous slates, quartzites; and tuffs or basic flows, and within them are large quartz porphyry siJls. These Britannia rocks are sheared and altered, the resultant rock being a fissile quartz-sericite or quartz-chlorite schist. The mineralization invariably occurs in this chlorite schist, which in the more productive areas has mottles or blobs of chlorite developed. A narrow, though persistent, band of grey slate forms the footwall of the productive portions of the shear zone.

Jan 1, 1928

By M. S. Badollet

"IntroductionASBESTOS FLOATS may be defined briefly as blends of air-borne particles of fibrous asbestos and dusts produced during the milling stages and collected by Cottrell precipitators, dust sheds, or bag-houses.The various grades of asbestos floats on the market contain fibrous asbestos particles ranging in length from microscopic to approximately 1/4-inch. The fines or dusts present in the floats are from 40 microns to 2 microns or less in cross-section.Airborne asbestos particles are of diverse length because they are collected at numerous places in the mill. There are: (1) dusts removed from dry rock storage bins, (2) dusts removed from rock and fiber screens, (3) particles from the tops of collectors, and (4) fines removed by suction from the processing equipment. Sometimes the airborne particles are kept segregated, so that there is a partial separation by gravity. This is accomplished by a series of dust chambers enclosed in a long, rectangular building. The longest and heaviest particles fall nearest to the air flow entrance, the smallest at a point farthest away and nearest the exit. Sometimes the air from the dust chamber building is passed through a series of bag-houses or electric :precipitators ,to collect the extremely fine particles which normally escape to the atmosphere."

Jan 1, 1952

By A. S. Eve

The detection of magnetic dykes by using magnetic variometers is the oldest application of. geophysics to mining, and is also one of the more simple and certain methods 0f locating such deposits. As a result of recent improvements in the instruments, it is now possible to find the dyke, deter-mine with magnetic variometers its strike and dip', with fair accuracy, and to estimate the approximate depth of overburden when there is no outcrop. The application of electrical methods may be used to distinguish mineral from diabase dykes. The authors have had an opportunity of making surveys with the modern Askania types of vertical and horizontal variometers over magnetic dykes in the Sudbury region. The interpretation of the results has been confirmed by diamond drilling in some cases, and by experiments over models. The variometers used were the standard form of Askania instruments (1). The sensitivity of the horizontal type was 17.2 gammas per division, and that of the vertical variometer double this quantity. To make a preliminary survey of the district, parallel lines were laid off two hundred feet apart running north and south, and readings were taken with the vertical variometer every 100 feet along these lines. This can be done very rapidly, and when an indication of a magnetic deposit is found, the readings may be taken every hundred feet, or less if the size of the deposit warrants smaller intervals. If the deposit is a vein or dyke, the readings along the adjacent lines immediately indicate the strike of the body. Thus the presence and strike of a magnetic dyke, whether of mineral value like the pyrrhotite and nickel deposits of the Sudbury district, or simply a worth-less diabase dyke, is simply and rapidly found.

Jan 1, 1932

By L. J. Han, Y. J. Zong, S. Y. Wen, J. J. Wei

"Stress strain curves characteristics, deformation and strength properties, and failure process and characteristics of sandstone samples under different stress states were analyzed through triaxial compression tests carried on using TAW-2000 microcomputer control electro-hydraulic servo rock triaxial test system. The experimental results reveal that peak strength, residual strength, elasticity modulus and deformation modulus increase linearly with confining pressure, and failure models transform from fragile failure under low confining pressure to ductility failure under high confining pressure. Macroscopic failure forms of samples under uniaxial compression was split failure paralleling to the axis of samples, while macroscopic failure forms under uniaxial compression was shear failure, the shear failure angle of which decreased linearly with confining pressure. There were significant volume dilatation properties in the loading process of sandstone under different confining pressure, and then based on acoustic emission damage and volumetric dilatation damage the damage evolution properties of samples were analyzed, and damage constitutive model were established, realizing the real-time quantitative evaluation of samples damage state in loading process. INTRODUCTIONDamage is a phenomenon that micro defects in material under monotonic loading or reloading will lead to progressive decrease of the cohesion and damage of volume units. Many scholars at home and abroad have carried out systematic researchers on damage evolution characteristics and constitutive model of rock, and have achieved a series of remarkable results in this field. Lu Y.D. (2004) studied the complete stress-strain curve’s characteristics of marble under triaxial compression, and established the bilinear elastic-linear strain softening-residual ideal plastic damage constitutive model. Ren J.X. (2001) studied the damage evolution laws of coal and rock mass by computerized tomography triaxial loading system, realizing the quantitative evaluation of damage state. Zhang Z.L. (2011) studied the deformation and failure mechanism of strong weathered sandstone by triaxial compression test, and analyzed the damage evolution processes and established the damage evolution equations based on the density method. Li X.J. (2012) studied the microscopic damage characteristics of siltstone under triaxial compression by scanning electron microscope and digital image technology, and analyzed the statistical distribution characteristics of cracks azimuth angle, length, width. Zhou J.W. (2012) studied the strength, deformation and fracture damage characteristics of sandstone by uniaxial cyclic loading and unloading tests, and defined damage variable based on linear damage mechanics theory and acoustic emission (AE). Cao W.G. (2006) established a new damage model and a statistical damage constitutive model of rock under specific confining pressure according to the force of damaged part and undamaged part in rock on the base of statistical damage theory. Li S.C. (2014) studied the damage evolution characteristics in the whole uniaxial compression process of sandstone by electrical resistivity and AE, and proposed a status qualitative criterion for rock damage."

Jan 1, 2015

By Derrin A. Auerswald, Jacolien P. Wyethe, Nanne M. \/egter

Base and precious metal refineries often produce effluent solution and slurry streams containing between 50 mg/L and several grams per liter of base metals. Metals have historically been precipitated from these streams with lime to produce effluent streams at pH values between 8 and 9. This effluent treatment process generally does not remove alkali and alkali-earth metals or halides efficiently and with more stringent environmental legislation, more sophisticated effluent treatment plants must be considered which could for example incorporate sulphate removal with ultra-filtration, or the SavminTM process, followed by reverse osmosis for the removal of halides. The flowrates of effluents are often high and if base metals can be recovered before neutralization, the revenue generated from this stream can reduce the cost to produce clean water significantly, and in the case where high concentrations are disposed of, result in a profitable operation. As an add-on to an existing the plant the recovered metal is upgraded and recycled to the plant, but the production of a saleable metal can also be considered. Technology selection for metal recovery depends on the composition and flowrate of the effluent, but could incorporate resin-in¬pulp or other ion-exchange technology; precipitation as sulphides, hydroxides or carbonates; or solvent extraction. This paper describes, as a case study, the technology selection process and uses data from Zincor. Zincor is a division of Exxaro Base Metals (Pty) Limited, a subsidiary of Exxaro Resources Limited.

Jan 1, 2011