Search Documents

By J. C. Barry, J. H. van Laar, P. L. Crouse, H. Bissett, I. J. van der Walt

"Plasma-assisted spheroidisation of metal powders offers several technical advantages with respect to both the ease of materials handling and powder-metallurgical item manufacturing. Advantages include improved flowability, increased powder packing density, elimination of internal component cavities and fractures, changes in morphology resulting in decreased friction between particles and contamination during pneumatic transport and enhanced particle purity. In this empirical study, spherical iron particles were produced using a microwave plasma operating at atmospheric pressure and characterized using optical microscopy and SEM techniques. Iron powders were fed into the system at fixed operating conditions, resulting in particles with spherical structures. The theoretical estimate of the time required for melting to occur is 1.6 ms, an order of magnitude smaller than the actual residence time. IntroductionParticle design and functionalization has become an increasingly popular aspect of materials synthesis and powder-metallurgical item manufacturing. One such technique involves the spheroidisation and densification of feed materials, typically in the form of chemical powders with wide particle size distributions. The major benefits of powder spheroidisation include improved powder flowability, increased powder packing density and powder purity, reductions in internal voids and defects, as well as the ability to manipulate the particles surface morphologies (Boulos, 2004). Thermal plasma processing has the potential for scale-up and for producing industrial quantities of spheroidised powder.Thermal plasma technologies offer a wide spectrum of material synthesis and treatment options, amongst others the synthesis and spheroidisation of nano-sized ceramic and metal particles (Kumar and Selvarajan, 2006). The spheroidisation process occurs within the plasma discharge via in-flight heating and melting of the powder feed material, given high enough plasma temperatures (Fridman, 2008, p. 495). Surface tension in the molten droplets results in spherical, or nearly, spherical, powder particles being formed upon exiting the plasma discharge where the droplet undergoes rapid cooling and freezes. Quite often, the bulk density of these spherical particles is higher than that of the starting material (Boulos, Fauchais and Pfender, 2013, p. 42). The different plasma spheroidisation techniques reported include radio frequency (RF) induction thermal plasmas (Jiang and Boulos, 2006; Karoly and Szepvolgyi, 2005; Yuming, Junjie and Yanwei, 2013), nontransferred direct current (DC) thermal plasmas (Chaturvedi et al., 2014; Kumar and Selvarajan, 2008; Suresh, Selvarajan and Vijay., 2008) and microwave-assisted plasma processing methods (Chen, Gleiman and Phillips, 2001; Vanamu et al., 2004; Weigle et al., 2004)"

Jan 1, 2016

By U. König, N. Norberg

Ore mineralogy defines the properties during processing and metal extraction. Fast and frequent monitoring of the mineral content and related process parameters brings value to the mining operation and material processing. Decreasing ore qualities and increasing prices for raw materials require a better control of processed ore and a more efficient use of energy. Traditionally quality control in mining industries has relied on time consuming wet chemistry or the analysis of the elemental composition. The mineralogy that defines the physical properties is often monitored infrequently, if at all. The use of highspeed detectors has turned X-ray diffraction (XRD) into an important tool for fast and accurate process control. XRD data and their interpretation make the difference in the identification of minerals, in describing their distribution in ore bodies and in their beneficiation during processing. The use of statistical techniques such as Partial Least-Squares Regression (PLSR) or Principal Component Analysis (PCA) on XRD raw data has been successfully trialled to determine raw materials and processed ores, in addition to well established methods for mineral identification and quantification. PLSR can be used to correlate process parameters directly from the XRD pattern without investigating the mineral content. Hidden information present in the XRD pattern but not determined with traditional methods can be used to improve the characterisation of the analysed materials. The practical use for the direct determination of process relevant parameters during exploration and ore beneficiation will be illustrated in several case studies from mining and ore processing. Keywords: Geometallurgy, mineral monitoring, X-ray diffraction, process efficiency

Jan 1, 2020

By J. Fu

"Since it was first identified in 1817, selenium has received considerable interest. Native selenium and a few selenium minerals were discovered several decades later. With the increasing number of selenium minerals, the occurrence of selenium minerals became the focus of much research. A great number of selenium deposits were reported all over the world, although few independent selenium deposits were discovered. Selenium is obtained mainly as a byproduct of other metals, and is produced primarily from the anode mud of copper refineries. This paper presents a comprehensive review of selenium minerals, as well as the treatment of copper refinery anode slimes for the recovery of selenium. Our focus is on the selenium minerals, including their discovery and occurrence, and the distribution of selenium resources. In addition, the main methods of recovering selenium from copper anode slimes are summarized. IntroductionSelenium (Se) was first observed in 1817 in a laboratory (Greenwood et al., 1984). The discovery of selenium was made by the Swedish chemist J.J. Berzelius and J.G. Gahn, who isolated selenium from a red residue in sulphuric acid from pyrite mined at Fahlun, Sweden. Selenium was named from the Greek word selene (moon), since it resembled tellurium, which had been discovered a few years earlier and named from the Latin word tellus (Earth).After the first observation of selenium in the laboratory, selenium received considerable interest. In 1954, E.P. Kaiser pointed out that Se is enriched in sulphide ores and often associated with Bi, Co, Sn etc. (Kaiser 1954). In 1959, Hawley and Nichol investigated selenium in Canadian sulphide minerals, and presented the content of selenium in sulphide from several deposits of different types. They also proposed that Se is enriched in lowtemperature hydrothermal pyrite (Hawley and Nichol, 1959). The thermodynamic conditions for forming native selenium and selenium minerals in sedimentary rocks were discussed, as well as geochemical behaviour of selenium near the oxidation zones of sulphides in the 1970s (Howard III, 1977; Zhu et al., 2003). Zhu et al. examined the morphology, features, and genesis of native selenium from Yutangba, Enshi City, Hubei Province, China in 2004, and pointed out, from the different forms of native Se, that selenium can be activated,transformed, remobilized, and enriched at sites such as in the unsaturated subsurface zone or in the saturated zone (Zhu et al., 2005). The transport and deposition of selenium in felsic volcanic-hosted massive sulphide deposits of the Yukon Territory, Canada was studied and reported by Layton- Matthews et al. (2005)."

Jan 1, 2016

By K. Sasaki, S. Kuroiwa, H. Miki, Y. Aoki, T. Hirajima, Y. Orii, G. P. W. Suyantara

Selective flotation to separate copper minerals from, for example, Mo- and/or As-bearing minerals is a continuing problem because the selectivity of current systems is imperfect. Selective Cu-As flotation is currently difficult, and the most common Cu-Mo selective flotation method uses NaHS; this must be done in an enclosed system because, under acidic conditions, this method produces hydrogen sulfide. In this paper, some novel alternative flotation processes that use redox reactions are discussed; these methods have a much lower environmental impact. Oxidation and reduction reactions can be used to make copper minerals more hydrophilic and Mo-bearing minerals more hydrophobic. X-ray photoelectron spectroscopy (XPS) analyses indicated that the copper minerals became hydrophilic because hydrophilic iron precipitated and several hydroxides covered the copper minerals’ surfaces, whereas the molybdenum minerals remained hydrophobic because their sulfide surfaces were not covered. Flotation experiments on these minerals after redox treatments indicated that excellent separation of Cu-minerals from Mo-minerals can be achieved. Possible mechanisms for this separation were investigated using detailed surface analyses and thermodynamic calculations. The additives used to initiate the redox reactions are easy to handle and make these new flotation procedures better than current processes because the new methods do not emit effluent gas and because they are commercially viable. Keywords: Flotation; chalcopyrite; molybdenite; oxidation; reduction

Jan 1, 2020

By K. L. Morton, R. .. J. Connelly, P. C. Bouw

Uncertainties in the forecasting of the volume of groundwater likely to enter underground workings present difficulties for mine management in planning and costing the water-related activities of mining. This paper describes a technique that was developed to assess future inflows into a gold mine in the Orange Free State. The approach employed was based on the interactive operation of two separate computer models: a regional-flow model and an inflow model. As a first stage, a regional finite-element model of groundwater flow was set up and calibrated. Predictive runs were made to establish the influence of mining on the water levels from base-line conditions. This step was necessary since observations of the regional water levels were sparse. The predicted water levels were transferred to the inflow model, and the future flowrates were calculated. Both models were calibrated by trial and error until a satisfactory match was obtained between historical records and the values predicted by modeling. In this way, an improved monitoring system to record regional water levels and pressure heads within a mine was established. By the use of information, the initial model predictions can be refined as mining progresses. The models used are based on a non-linear relationship between the area mined and the inflows. A phased behaviour in the rates of inflow increase was noted. In conclusion, the modeling approach can provide mine management with guidelines for dewatering requirements. The confidence levels depend upon the records that have been collected during the mine's history.

Jan 1, 1988

By S. W. Robertson, M. T. Golela, S. Mxinwa

South Africa has one of the largest Cr-related industries in the world and generates large amounts of Cr-containing smelter dusts. It is normal practice to scrub Cr from the furnace off-gas in water, and to recover the Cr by adsorption, followed by recycling of the loaded adsorbent into the furnace. A study was conducted to find a low-cost adsorbent that is capable of removing sufficient Cr from the solutions generated by scrubbing. The test work focused on the evaluation of different clay minerals (attapulgite, bentonite, and kaolinite) as adsorbents for Cr. Cr(VI) could only be adsorbed after prereduction with e.g. ascorbic acid (ASA). An 80% removal of Cr(VI) could be achieved from a solution containing 20 mg/L Cr using bentonite clay after reduction with ASA. Attapulgite and kaolinite adsorbed less than 55% Cr after reduction with ASA. Both ASA and ferrous salts were found to be suitable reducing agents. The use of acid mine drainage (AMD) was also investigated as a low-cost alternative reducing agent, as AMD usually contains iron. The Cr(VI) reduction potential of the AMD was determined by redox titration against a solution containing 50 mg/L Cr(VI). Studies show that AMD can potentially be used as a reducing agent in a Cr removal process if it is available on site.

Feb 12, 2024

By J. Rabe

Tasked with developing a flow sheet for a new resource, one typically turns the experts for help. The advice of an expert can be invaluable in reducing the time and costs associated with characterizing an ore (not to mention extracting maximum information from limited samples). While guiding and optimizing a metallurgical concept study requires a certain skill set, selling a project is something different. The metallurgical specialist is usually not responsible for sharing the results of investigations with potential investors. However, the person responsible for selling the project can ensure that a metallurgical concept study is conducted thoroughly and responsibly without having the ability to do the work, while being sufficiently familiar with the metallurgical aspects to authoritatively sell the project. The process of identifying suitable process routes through to constructing a concept flow sheet and mass balance is discussed as a basic example. From basic mineralogical information and a thorough literature survey, the most likely beneficiation routes can be identified and targeted testing conducted. The final top size will depend on the required product properties (mainly grade), the selected beneficiation technology, and the ore?s liberation properties. Once the required top size has been identified, comminution options can be evaluated. Once again, literature surveys can be used to supplement concept-level comminution property information, and select possible equipment and circuit configurations. Marketing, material handling, and logistics-related information can be used to determine required dewatering technologies. At this stage, enough information is available to develop a concept mass balance and conduct basic equipment sizing..

Jan 1, 2014

By H. C. Voges

The concentration of cassiterite at Iscor's Uis Mine is described, and information is given on aspects of the concentration of iron ore at Thabazimbi and Sishen Mines. At Uis, a very Iow-grade tin ore is concentrated by three-stage jigging, spiral concentration, and tabling to give a high-grade concentrate with a recovery of 80 per cent of the tin. A Iow-grade tantalite-columbite concentrate is also produced. The possibility of recovering mica, the use of sluice boxes instead of spirals, and the recovery of cassiterite from minus 45 µm material are being investigated. At the two iron-ore mines, heavy-medium separation is applied to size fractions larger than 0,5 mm. The types of ferrosilicon and the circuits used for the recovery of ferrosilicon from the various dilute-medium circuits are described. The spiral-concentration plant being installed at Thabazimbi for the treatment of the minus 0,5 mm portion of the ore is described.

Jan 1, 1982

By R. D. Alorro, B. Tadesse, E. Aghaei

Cinnabar (HgS) and native mercury (Hg) are the most common naturally occurring forms of mercury found in most gold ores subsequently released into the environment during processing. Mercury and its compounds are extremely toxic and recognised as serious health and environmental hazards. This research investigates the possibility of mercury (Hg) removal from waste solutions from gold processing using iron-aluminium (Fe-Al) bimetallic particles. The synthesis of Fe-Al bimetallic particles using zero-valent aluminium and ferric chloride as precursors were performed following the optimisation of influencing factors. The presence of both metals in the prepared bimetals was confirmed by XRD analysis. The experiments for mercury removal by bimetals were designed using the central composite design and Minitab software based on two variables including contact time and adsorbent dosage. The best result of Hg(II) removal (>90%) was achieved using 4 g/L bimetals and contact time of 75 min. However, the statistical analysis of results indicated that these parameters have only a minor contribution to the removal of Hg(II) by Fe-Al bimetals. Higher bimetal dosage and contact time resulted in a higher Fe dissolution from the Al surface which can be attributed to the presence of nitrate (# $) ions in the solution. However, adding 0.1 M NaCl to the Hg solution had a positive impact on Hg removal by improving the conductivity and electron transfer within the solution. The Fe-Al bimetallic particles are promising substances for further testing of Hg removal from gold processing waste solutions with different conditions and constituents. Keywords: Mercury removal, gold processing, Fe-Al bimetals, optimisation

Jan 1, 2020

By B. P. Watson, D. Hoffmann, D. P. Roberts

Potholes on the Merensky and UG2 reefs in the Bushveld Complex occur as near-circular to elliptical depressions or slumps on the reef horizon, normally presenting as severe disruptions which prevent economic extraction. Within the pothole, the reef and other strata may either be attenuated, absent, or highly deformed, this being the result of the overlying hangingwall strata having slumped down. The hypotheses for pothole formation involve several mechanisms, including downward erosion, upward fluid movement, or synmagmatic deformation. When potholes are exposed in mine workings, significant fracturing is often observed. This fracturing is particularly evident in anorthosite rock types. Stress measurements were conducted in a pothole on the Merensky Reef to determine if the fracturing was due to high stress conditions. The paper describes the measurement results and numerical modelling that was done to determine the influence of depth and mining on the stress condition at the site. The results show that high stresses do exist in at least some potholes, and that current formation theories do not adequately explain the measured stresses. In support of understanding the high local stress associated with the pothole, the study explored several rock engineering modelling processes to validate the conditions of the study site and enclosing excavations. A better understanding of the stress conditions in potholes with additional data could lead to more appropriate support design and avoidance of potential rockbursts in these structures.

Jan 1, 2021

By E. K. Mutinda, D. K. Maina, R. M. Kasomo, B. O. Alunda

Assessment of blast fragment size distribution is critical in mining operations because it is the initial step towards mineral extraction. Different empirical models and techniques are available for predicting and investigating the consequences of blasting, one of which is the Kuznetsov Cunningham-Ouchterlony (KCO) model. In this paper we summarize the advances in the empirical models from inception until now, and explore the improvements that have been made so far with particular emphasis is on the most recent KCO model. Utilization of the model and the errors that arise between expected and the actual outcomes are analysed. The results indicate that the KCO model remains useful for predicting the blast fragmentation at limestone mine sites, despite the availability of other advanced prediction models. It is also a valuable instrument for pre-surveying the impact of varying certain parameters of a blast plan.

Mar 1, 2021

By E. Kumar, L. A. Kumar

"A methodology is proposed to develop an optimization model to understand the impact of transporting minerals, from mines to the final destination, on air quality. Recently, there has been increasing concern about the combined effects of multiple activities over many years, and the regional environmental changes brought about by a single project. Environmental issues in the iron ore industry have highlighted the need to broaden the cumulative impact assessment. In this study, we simulated the optimal routes and quantity of materials needed to meet the destination plant demand based upon environment constraints (level of air pollution), as well as the cost of transportation and availability of materials. Multiple scenarios were developed to analyse the effects of changes in routes, alternative transport system (or multi-modal split), traffic congestion, and the cumulative impacts on air quality. The air quality impact zones of the study area were demarcated using a GIS technique. The expected outcome of the study is the selection of a suitable transport system for a particular site with the least impact on air quality, including the transportation route, relative to the minimum cost of transportation of the minerals from the mines to their final destination. The proposed methodology is evaluated with a case study. IntroductionIn India, the process of environmental impact assessment (EIA) has been focused primarily on the local impacts of projects, without considering regional environmental effects. Environmental clearances for proposed projects are based on reports of local impacts. However, any developmental project poses a potential risk to the environment as a whole, and not just in the immediate vicinity of the project. Recently, there has been increased concern about the combined effects of multiple activities over many years—the regional environmental changes due to development of a single project (Dutta, Mahatha, and De, 2004). Environmental issues throughout the country, particularly in the iron ore industry, have emphasized the need to broaden the analysis to include the combined impacts, or those forecast for a proposed region, on an existing environment. The most significant adverse environmental consequences of iron ore transportation are the deterioration of biodiversity and air quality (Kumar and Ajay, 2015)."

Jan 1, 2017

By G. A. Bezuidenhout, S. Bradshaw, W. Malan

"Currently, the matted-based collection process is most widely used for platinum group metal (PGM) recovery. However, because PGM-containing concentrates are becoming more enriched with UG2 (Upper Group 2) low-grade concentrates, this is expected to be integrated or replaced with an alloy collection process.The reduction LG (low-grade) concentrates with silicon carbide (SiC) was investigated. The purpose of the study was to ascertain the feasibility of using SiC as reductant with regard to metal fall, PGM grade in the alloy, slag composition, and overall PGM recovery, and if possible, the integration of such a process in the current matte-based collection process. Rowland and Easterns LG concentrate samples from Lonmin were analysed by Xray diffraction (XRD), X-ray fluorescence (XRF), and inductively coupled plasma mass spectrometry (ICP-MS). It was found that SiO2 and MgO are the most abundant oxides and Pd is the most abundant of the PGMs. Sulphide-bearing minerals such as chalcopyrite were detected in low concentrations (below 1%), and Cr2O3 concentrations are between 2-4%. SiC reduction of Rowland and Easterns concentrate were conducted at 1600°C with reductant to concentrate ratios ranging from 2.5 to 3.5 kg SiC per 100 kg concentrate.The reduction experiments revealed that PGM recoveries from Rowland concentrate were poor. SEM images showed entrained metal prills in the slag phase. The slag viscosity at the end of the melt was calculated by using FactSage, and the results indicated that the viscosity was higher than 4 poise, which is above that of Easterns slag. PGM recoveries for Easterns concentrate were significantly better. More than 85% of the Ir and Pd and almost 60% of the Pt were recovered in a test with a reductant to concentrate ratio of 3.5 kg SiC per 100 kg Easterns concentrate. At this reductant to concentrate ratio, Fe recovery was also the highest, at 66%. SEM imaging of a slag sample revealed few or no metal prills entrained. The FeO content in the initial concentrate charge was then increased by adding Peirce-Smith converter slag in order to decrease the slag viscosity and further increase PGM recovery. A test was conducted with the addition of 10 kg converter slag per 100 kg Easterns concentrate. The reductant to concentrate ratio was kept at 3.5 kg SiC per 100 kg Easterns concentrate. The Ir and Pd recoveries were more than 95%, while Pt recovery was almost 70%. Fe recovery increased to 76%. On the basis of these results an optimum feed ratio between Easterns and Rowland concentrates and Peirce-Smith converter slag were calculated. FactSage predicted that the concentrate charge should consist of 70-80% Easterns concentrate with 20-30 kg converter slag per 100 kg LG concentrate. SiC reduction of this optimum LG concentrate charge is expected to recover more than 90% of all PGMs. Cr and Si concentrations in the alloy will be below 1% in total.The effectiveness of SiC as reductant was also compared to carbon reduction. Carbon reduction of an optimum concentrate charge at the same reductant to concentrate ratio resulted in a marginally higher metal fall than SiC reduction. However, gas emissions and energy requirements are higher for carbon reduction.The study has shown that base metals and PGMs can be recovered in an iron alloy by SiC reduction of LG concentrate with converter slag additions. Integration of such a process into the matte-based collection process could be considered as a future alternative for smelting UG2 LG concentrates."

Jan 1, 2014

By A. Modi, C. Li, R. Kabwit, W. Y. Xinchao, R. Joshi

The KIMIN copper project can treat 1.7 million dry t/a copper-cobalt ore. It has three mills in operation, two using conventional milling in water and the third in raffinate. We introduce the project process circuit and the capital and operating costs of using the raffinate process compared with conventional milling in water. There is a capital saving of approximately 11.5% for major equipment by removing the pre-leach thickener. In addition, it also achieves an annual operating cost saving of USD 2.1 million due to an increase in 49% of acidic raffinate recycled and reduction in lime consumption. The features of CITIC’s new duplex stainless-steel ball mill ,as the key equipment of the system, are also introduced

Jan 1, 2023

The June General Meeting of the Branch was held in the St. Helena Club on Wednesday, 18th June, 1969. Mr J. G. Kirchner (Chairman of the O.F.S. Branch) was in the chair. There were also present: Eight Members: Messrs A. F. Leger, J. N. Saunders, T. Zadkin (Committee Members), Messrs M. G. Cullen, M. S. Grobler, C. J. Isaac, S. L. S. Swart, P. S. Turner. Eight Associate Members: Messrs R. Campbell, D. E. Couperthwaite, J. D. Couperthwaite, A. Hepburn, P. A. Hoffman, H. J. Reeders, R. B. Sutherland, P. R. Wheeler. Two Graduates: Messrs M. T. G. Davies, B. D. Goodwin. Two Affiliates: Messrs L. D. Hulley, K. L. Wilson. Three Visitors. Total Present: 24. Apologies were received from Mr L. O. W. Leimer. The Chairman declared the meeting open and, after extending a welcome to all visitors, said that it was his sad duty to announce the recent death of Mr. R. Jack, Associate Member. As a mark of respect to the deceased and in sympathy with the bereaved, those present stood in silence for a few moments. MINUTES OF PREVIOUSGENERALMEETING The Minutes of the Previous General Meeting held on the 19th February, 1969, which were published in the April Journal, were taken as read and their adoption proposed by Mr J. N. Saunders and seconded by Mr D. E. Couperthwaite. MA TTERS ARISING FROM THESE MINUTES There were no matters arising from these minutes. ELECTION OF SCRUTINEERS Mr V. J. Isaac proposed and Mr M. S. Grobler seconded a motion that Messrs J. G. Kirchner, J. N. Saunders and M. G. Cullen be elected scrutineers in the forthcoming election of Committee Members. GENERAL BUSINESS The Chairman announced that a visit to the South African Railways Workshops in Bloemfontein had been arranged for the 23rd July, 1969 and expressed the hope that this would be well patronised. TALKS The Chairman called first on Mr D. E. Couperthwaite to present his paper on 'Heavy media separation' and then on Mr A. F. Leger to present his paper on 'Engineering plastics'. Both presentations, which were illustrated with diagrams, proved of great interest to all members. A vote of thanks to both speakers was proposed by Mr T. Zadkin. CLOSURE After thanking the speakers, the Chairman thanked all present for their attendance and declared the Meeting closed at about 9.30 p.m. Refreshments were then served.

By M. J. Deats

INTRODUCTION To prepare the reader adequately, reference should be made to the paper 'The Pioneering of Fully Mechanized Longwall Coal Mining in South Africa' by R. T. Naude and M. J. Deats, published in the February, 1967, edition of the Journal. At the time mechanized longwalling had been proved operationally feasible with encouraging results since its inception in South Africa in mid 1965. Subsequently, further top seam panels were successfully extracted with improved productivity and with some modification to equipment. In 1968, after an overseas visit by mine officials, equipment specific to suit local conditions was acquired and lower seam trials commenced. Despite initial obstacles and difficulties the first panel was successfully mined. Modification and improvements to equipment and techniques resulted in the second lower seam panel being extracted economically during 1969-1970 and with productivity exceeding even that of top seam faces. During extraction of the second lower seam panel, gradual and complete surface subsidence occurred over the panel without affecting face operations. Rock mechanics investigations had originally indicated some uncertainty regarding adverse dolerite sill behaviour which could have caused longwall mining to be hazardous. All such doubts have now been removed. RESUMÉ AS AT FEBRUARY, 1967 Mechanized longwalling was introduced in 1965 on an experimental basis in an effort to improve productivity in the newer area of the mine and to increase the quality of the comparatively dirty run of mine feed to the washing plant. In addition advantages could be predicted in the long term by better utilizing reserves of straight coking coal and increasing the life of the mine. The top seam unit was obtained on a rental basis and by the beginning of 1967, two panels, the first having a face length of 215 m, a panel length of 345 m, seam section of 1 219 mm, and the second the same face length, a panel length of 453 m and a seam section of 1 067 mm had been successfully longwalled. At this stage a best month of 24 602 metric tons with an average of 17 364 metric tons per full working month could be reported. Results were sufficiently encouraging for the company to exercise its right to acquire the equipment as its own asset and from 1967 onward, the unit has operated on this basis. From the point of view of rock mechanics, the dolerite sill over the first two panels was known to have 'bridged', only the material below the base of the sill having truly 'goafed'. No adverse pressure effects had significantly affected face operations except for two 'bumps' towards the end of operations in each panel. Gate road maintenance presented no problem. The strong inflows of water experienced on the first face were now known to be associated with an isolated water bearing fault plane and were not experienced on the second face. TOP SEAM EXPERIENCE - MAY, 1966, TO DATE Panel 2 (February, 1966, to November, 1966) The operations in panel 2 (see Fig. 1 for location of panels) continued uneventfully until the final month in this panel. At this stage, the chocks behaved most inconsistently often lowering under the weight of the canopies alone. Roof trouble became so severe that the unit was unable to produce adequately and blasting of chocks became a daily occurrence. Finally 24 m short of the planned limit it was decided that a complete overhaul was the only solution and the extraction operations commenced. At this time, the only fatal accident associated with longwalling occurred when a Non-White inadvertently fell into the panzer conveyor transfer point at the main gate. Some gate road difficulties in this panel were overcome by bolting tapes to the roof as decking and allowing them to pass over the gate chocks and collapse into the goaf. Two cribbed roof falls were also negotiated by the gate chocks at the face ends without undue difficulties. It was decided in the light of maintenance problems encountered on this face that the best solution would be to appoint a foreman solely in charge of face maintenance crews. This step has to a large extent contributed to success achieved subsequently. Panel 2-face length 213 m panel length 456 m cutting height 1 092 mm average monthly output 16 443 t best month 19 130 t Panel 3 (December, 1966, to June, 1967) By the end of 1966 results were sufficiently encouraging for the company to exercise its right to acquire the equipment. This was negotiated and the unit has operated as such to the present date. Prior to installation in panel 3, all face equipment was thoroughly overhauled underground and the chocks boost-tested to yield-load. The costs of overhauling, including almost complete hose replacement, were much higher than anticipated. Advice had been received that complete hose replacement was common practice after +/- 18 months' operation. Shortly after commencement of operations in panel 3 the chocks again failed as they had towards the end of panel 2. At this stage, the suppliers advised that the valve gear should have been repaired during the overhaul as the needle and seat seals could no longer be relied upon. This operation was impossible to carry out on the face and would have been e1ttremely time consuming. Fortunately a new type of valve gear was then available from the suppliers, termed the capsule-type valve, and a complete change over could be made on the face. The encapsulated valve has a delrin pad sealing over a raised

By R. Dehghan, M. Zarei, A. Tohry, S. C. Chelgani

Typical depressants for selective reverse flotation of iron oxides from complex silicates do not generally show high levels of efficiency. Therefore, as a hot topic, there are several ongoing investigations in this area. The main aim of this paper is exploring the potential of using humic acid (HA) as a depressant in reverse cationic flotation of hematite from complex silicates. For such a process, the wettability and flotation behaviour of pure minerals (hematite and silicates) was investigated at pH 10 in the presence of HA and cationic collector. Adsorption mechanism of HA on these minerals was measured by zeta-potential and FTIR. Results of flotation tests showed that at the lower concentrations of HA, selective separation of silicates from hematite is beneficial, where the floatability of amphibole was higher than pyroxene. A higher separation efficiency of hematite through reverse flotation was observed in the presence of amphibole, in comparison with the presence of pyroxene. Wettability studies showed that HA has a significant effect on reducing the hydrophobicity of treated minerals with the collector. The adsorption, ZPC and FTIR test results indicated that HA was adsorbed on both silicates and hematite. However, the absorption intensity onto hematite was much higher than silicates. It was found that the adsorption mechanism of HA on hematite takes place through both strong H-bonding and ligand exchange. Keywords: Reverse cationic flotation, humic acid, iron oxide, complex silicates, surface adsorption

Jan 1, 2020

By G. B. Abaka-Wood, J. Addai-Mensah, W. Skinner

Recently, coal fly ash has become a potential candidate as a secondary resource of rare earth elements (REE). In this investigation, we studied the recovery of REE from fly ash from a commercial power plant. The specific aim was to assess the technical feasibility of recovering REE from the coal fly ash using conventional preconcentration methods, including gravity separation, magnetic separation, and froth flotation. The experimental results revealed that flotation achieved major gains in REE recovery and upgrading. However, during gravity and wet magnetic separation tests, the bulk of REE reported to the tailings. The results showed significant variations in the performance of the various beneficiation methods investigated. This study has confirmed that existing physical separation methods could be used to recover REE from coal fly ash prior to hydrometallurgical and pyrometallurgical processing, although some challenges persist.

Jan 2, 2022

Statistical summary of the mineral industry world production, exports and imports 1964-1969 Published by Her Majesty's Stationery Office, London, on behalf of the Institute of Geological Sciences (1971) The Statistical Summary contains a wealth of care fully garnered information on the production, exports and imports of the principal minerals and mineral products throughout the world for the period 1964-1969, and it should therefore be of particular interest to economic geologists and others concerned with marketing and selling minerals. In view of the intractable nature of the source data it is quite an achievement to have published figures for 1969 so expeditiously. On picking up the Summary this reviewer instinctively compared it with the Annual Yearbook published by the United States Department of the Interior. The Yearbooks have been issued annually since 1882, and today each consists of a set of three separate books containing five volumes. Apart from abundant statistics on the domestic and international mineral industries, the Yearbooks are known for their perspicacious reviews and articles on a host of different facets of the world's minerals industry. Physically the Summary is a much slimmer publication than the Yearbook, and it contains no commentary whatsoever other than occasional footnotes. The principal contents are a series of tables showing production, exports and imports of fifty-nine of the world's more important minerals and mineral products. Each table shows the weight of the material produced or traded, by countries, with figures for each of the six years in adjoining columns. In some cases (e.g. diamonds) values in British currency are quoted in addition to weights. Most of the data have been abstracted from national reports and returns, although in some instances estimates are quoted where national sources are silent--as for example the production of platinum in South Africa. One wonders in passing if any useful purpose is served by the continued suppression of this particular figure. The four South African producers must surely be able to estimate each other's production fairly accurately by now, and one imagines that the national export figures can likewise be synthesised. This reviewer has two minor criticisms of an otherwise praiseworthy publication. Firstly it seems an unnecessary anachronism to perpetuate the split between 'Commonwealth' and 'Other' countries-the split can have little practical significance today. Secondly, what is one to make of the statement that the 1966-1969 figures for exports from Rhodesia of chrome ore and copper, to take two examples only, are 'not available'? It seems improbable that no estimates of these figures have been made since the imposition of sanctions, and inevitably one suspects that the figures have been excluded on policy grounds. Hopefully this problem will have been solved when the next Summary is published. M.J.M. South Africa, land of Challenge by Maurice Tyack France Interpresse, 323 pages, price R18-00. Is South Africa God's richest acre? In its mineral wealth it certainly is, but what of the many other complex overlays of emotions, traditions and racial problems? South Africa, Land of Challenge, provides the background. This is reported to be the first comprehensive documentary work of its kind on South Africa. It is a handsome volume measuring 12ft by 9f', is illustrated by at least 600 photographs of South Africa, more than half of which are in colour, and contains 21 original maps and charts. The book covers the full spectrum of South Africa's very existence, its geography, pre-history, its customs, countryside, natural resources and its cities. The more controversial categories are thoroughly discussed, the people, their policies and politics. Mr Tyack is eminently qualified to write on South Africa, being the author of over 20 books on other African countries and having spent more than three years of research, in the field, in South African archives and also in various libraries and museums, in preparation for this book. The book claims to be free of any party political bias and appears to be an honest attempt at a factual survey. However, a work of this magnitude will undoubtedly leave an impression on the reader and the tone of this book is decidedly patriotic. This is a useful reference work on South Africa that most South Africans will be proud to own. J.P.H. Ergonomics and physical environmental factors This publication by I.L.O. of a symposium in Rome in September 1968 has much useful information for the mining industry in regard to the health and productivity of its labour force. The first subject dealt with is mechanical vibrations. From this section it is clear that men who drive, for many hours each day, vehicles which vibrate in the 6 Hz range are subject to serious physiological and psychological effects. The former may show as changes to the vertebral column (which has a resonance in the 4-5 Hz range). The circulatory system is adversely effected by values in the 6-10 Hz range and the vision is impaired at between 40-100 Hz. Less definite knowledge exists of the effects of vibration on the hand-arm system from mechanical drills etc, although Raynauds disease of the blood vessels of the hand and degenerative diseases of the elbow and shoulder joints occur in men using drills which vibrate, respectively, in the higher and low frequency ranges. Industrial noise is extremely well dealt with and the latest knowledge is summarized. Clear information is given on the relationship between time of exposure to

By Z. L. Xue, J. L. Li, X. Y. Wang

"In low-carbon energy-efficient basic oxygen furnace (BOF) steelmaking processes, limestone partly or completely replaces the active lime. The effects of limestone calcination temperature (1200–1500°C) and time (5–15 minutes) on lime reactivity and CaO grain size were investigated. The reactivity was evaluated by titration with hydrochloric acid, and the CaO grain size was analysed using scanning electron microscopy. The results revealed that for calcination temperatures higher than 1300°C, the reactivity reached a maximum and then decreased . The higher the temperature, the earlier the peak of reactivity appears. The CaO grains grow with increasing temperature and time, which leads to the decrease of reactivity. Notably, the effects of temperature on CaO grain size and reactivity are more marked than that of time. To obtain active lime calcined at ultra-high temperature by flash heating, the calcination conditions should be 1300–1400°C for 10–15 minutes, or 1400–1500°C for 8–10 minutes. IntroductionLime is one of the most important slag-making materials for dephosphorization and desulphurization in the basic oxygen furnace (BOF) steelmaking process. The reactivity of lime is a measure of its capability to take part in slag-making. Lime having a reactivity of more than 300.0 mL (4 N HCl), determined by hydrochloric acid titration is generally referred to as active lime (Rusjan et al., 2007; Zeman, 2008). At present, the active lime used for BOF processes comes primarily from a kiln or shaft kiln, where limestone is preheated at 700– 900°C, and then calcined at 1050–1200°C (Drenhaus et al., 2010; Oates, 2007)."

Jan 1, 2016