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By M. A. EI Zeky, A. E. El-Nikbaily, M. A. Shahin

"Possible mechanisms of microsilica dust formation and factors affecting its quantity have been discussed. General mathematical models to predict the dust quantity based on electrical and coke consumptions, and flue gas temperature as functions of silicon recovery in the process and silicon content of the alloy have been established. It has also been shown that the flue gas temperature can be used as an additional process control parameter. Comments are made on the effect of the dust formation on the whole process economics and it is pointed out that the formed microsilica dust is a valuable by-product and not an industrial waste. INTRODUCTIONFerrosilicon is produced in electric arc furnaces with submerged electrodes. The charge mixture consist s mainly of quartzite, coke as the reducing agent and iron chips. The products are ferro silicon and carbon monoxide, various other volatile materials, water vapour and silicon monoxide gas. Carbon monoxide and silicon monoxide oxidize at the charge surface when mixed with air entering through the furnace hood openings. The off-gas contains a considerable amount of dust, which is mainly very fine particles of silica formed as a result of oxidation. The emission of dust containing gases to the atmosphere causes serious pollution problems to the environment. Therefore, the control of the formation of the dust, preventing it from escaping to the atmosphere, and dealing with this very fine dust collected from the flue gases represent important technological and economical parameters in the ferrosilicon production industry.This paper is concerned with the relations between the quantity of formed micro silica dust, as a function of both silicon recovery and silicon content in the alloy, and various other technological parameters; and their possible effects on the energy consumption and economics of the whole process."

Jan 1, 1989

By L Tafaghodi Khajavi, M. Barati

The distribution of phosphorus between solid silicon and iron-silicon melt was determined to investigate the degree of phosphorus removal from silicon by solvent refining with iron-silicon alloys. The distribution coefficient which is the ratio of the mole fraction of phosphorus in solid to that of liquid is as follows: 0.22±0.02 (1310°C), 0.29±0.02 (1260°C) and 0.33±0.02 (1210°C). The removal percentage of phosphorus is: 84.2% (1310°C), 72.5% (1260°C), and 63.7% (1210°C). The average phosphorus content of produced silicon in the proposed solvent refining process would be over two times less than that of the conventional directional solidification. The values of interaction coefficient of phosphorus on iron at different temperatures were obtained as -3460±155 (1310°C), -3595±159 (1260°C) and -3694±119 (1210°C). Self interaction parameter of phosphorus at different temperatures are as follows: 68±4 (1310 ?C), 78±10 (1260 ?C) and 103±19 (1210 ?C). The calculated values for distribution coefficient of phosphorus at infinite dilution are: 0.22±0.00 (1310°C), 0.30±0.00 (1260°C) and 0.34±0.00 (1210 °C).

Jan 1, 2015

By G. W. Govier

Measurements of the settling rates and the rheological behaviour of heavy media formed of fine suspensions in water of each of magnetite, ferrosilicon, and galena have been made. For media ranging from 1.6 to 2.8 specific gravity the settling measurements gave initial settling rates of from 0.5 to 0.01 ?cm. 'Per minute for magnetite; from 4.0 to 0.8 cm. per minute for galena; and from 35 to 1.6 cm. 'Per minute for ferrosilicon. These measurements indicate the ?relative stability of the suspensions and should be helpful in establishing the useful specific gravity range for each medium. Measurements of the consistency of the media were made with a Fann Model 35 rotational viscometer. Aibnormal or non-Newtonian behaviour was observed in the case of each media, the apparent viscosity being dependent upon the rate of shear or the intensity of motion. Measurements were made over the rate of shear range of 10? to 1,000 reciprocal seconds. The apparent viscosities of the magnetite media ranged from 450 down to 4?0 centipoise at 2.30 specific gravity, and from 2,450 down to 700 centipoise at 2.80 specific gravity. In the case of the galena media, the variation was from 40, through a minimum of 6, to 10 centipoise at 2.20 specific gravity, and from 950, through a minimum of 180, to 450 centipoise at 3.6 specific gravity. The ferrosilicon suspensions exhibited apparent viscosities ranging from 42, through a minimum of 5.6, to 9 centipoise at 1.9 specific gravity, and from 160, though a minimum of 35, to 85 centipoise at 2.8 specific gravity. The dependency of apparent viscosity or consistency upon intensity of motion is considered to be of particular significance in applications of heavy media where the medium is in rapid motion.

Jan 1, 1957

By J. Lui

At its Copper Cliff Smelter, bulk nickel and copper concentrate is processed in two Inca flash furnaces and Peirce Smith converters to produce Bessemer matte containing 0.6%Fe. After slow cooling and Matte Separation, Bessemer matte is converted into three main products using magnetic separation and flotation technology: (1) a nickel containing chalcocite concentrate (MK); (2) two types of copper containing nickel sulfide (ME and MR); (3) metallics (MYN). MK is further processed in the Inca top blowing bottom stirring MK Reactor to produce semi-blister copper containing ~4%Ni and ~3±1 %S. The semi-blister copper is then purified in the multi-purpose vessels (MPV) to produce blister copper by reducing Ni, Fe and S content through oxidation. High melting point NiO is formed inside the MPVs. The accumulation of solid NiO and other oxides requires periodic cleaning by adding reductant and furnace matte, a unique process called "washout" at Inca. For many years, the reductant used for the "washout" process has been 15%Si Ferro-silicon. With increasing cost and limited suppliers for 15%FeSi, alternative reductants were pursued. This paper summarizes the development and commercialization of new alternative reductants for MPV "washout".

Jan 1, 2007

By A. McLean, A. Hue, K. Le, Y. D. Yang, P. Wu

While the treatment of relatively inexpensive ferrosilicon alloys is a potential refining route in order to generate solar grade silicon, phosphorus is one of the more difficult impurities to remove by conventional processing. In this project, the use of an electromagnetic levitation technique was used to investigate the dephosphorization of ferrosilicon alloy droplets exposed for various times and temperatures to a hydrogen-argon gas mixture. It was found that approximately 40% of the phosphorus was removed from an 85%Si-15%Fe alloy after 20 minutes exposure at approximately 1673K, to a gas mixture containing 48.5% hydrogen. Further dephosphorization is expected with longer reaction times. The effect of increasing temperature was found to be insignificant, although processing at lower temperatures is not only economically advantageous, it also decreases evaporative silicon losses, thus resulting in a more efficient process.

Jan 1, 2015

By L. M. Pidgeon

Introduction The production of magnesium by direct reduction of the oxide has far passed the experimental stage and was responsible for 30 per cent of the recent wartime production of 246,000 tons per annum. This paper describes the small-scale experiments which culminated in a number of the wartime plants. The paper traces the author's early experiments on various direct reduction reactions leading to his choice of the ferrosilicon reduction of dolomite and the realization that this reaction would proceed at a satisfactory rate at temperatures obtainable in metal apparatus. MgO has a standard heat of formation of 146,100 cal. and is therefore one of the most difficult oxides to reduce. However, if advantage is taken of the relative volatility of magnesium metal, thermally unfavourable reactions may be utilized. In reaction MgO + X = XO+ Mg . . . . . . . . . . . . . (1) the removal of Mg as a gas at high temperatures displaces the equilibrium to the right in the face of the unfavourable thermo-chemistry which is inevitable with any X other than calcium metal. If X is carbon, not only is the reaction highly endothermic, but CO is gaseous. A temperature of l,864°C. is required to produce a pressure of one atmosphere of Mg. Between l,900°C. and perhaps 400°C., the back reaction takes place readily and special shock cooling devices are required to recover magnesium from the gaseous mixture. This reaction does not lend itself to small-scale experiments and was not examined by the author. If, in reaction, carbon is replaced by a relatively pan-volatile metal, the oxide of which is also non-volatile and possesses a fairly high heat of formation, a reduction reaction is offered which is free from the difficulties associated with carbon. The typical case of silicon will serve as an example: 2MgO + Si = SiO2 + 2Mg (g) . . . . . . . . . . . . . . . . . . . . . . (2) At temperatures above l,000°C., a positive pressure of magnesium will exist over the system. Removal of the magnesium vapour will displace the reaction to the right in the face .of an unfavourable thermal balance. Since magnesium is the only volatile component at this temperature, it may be evolved and condensed, using attractively simple distillation technique.

Jan 1, 1946

By A. Mitrašinovic, A. Wolf

"The aim of this investigation was to determine the most suitable additive for recovering metals from converter slags generated during Ni extraction. Fluxes analyzed were silica and lime and reductants included pig iron, ferrosilicon and copper-silicon compound. Slag was settled at 1300°C for one hour to simulate the smelting environment. The newly formed matte and slag were characterized by chemical composition and morphology. Microstructural studies showed that slag formed after adding reductants consisted of primarily fayalite, with traces of magnetite. Entrained matte was present in the slag mostly as prills of Ni3S2-FeS matrix and a Cu2S-FeS secondary phase below 10µm in diameter. Kinetic parameters of matte formation, valuable metal recovery rates and partition coefficients were deduced. Silica additions generated higher partition coefficients for copper and nickel than the addition of lime. Additives used as reducing agents had higher valuable metal recovery rates and partition coefficients. Silica additions favoured the formation a higher grade matte while lime additions will hinder metal recovery. Pig iron, ferrosilicon and Cu30Si were the most effective reductants for valuable metals recovery. Cu10Si and coke additions had little to no effect on valuable metals recovery."

Jan 1, 2015

By M. Abdellatif

Successful demonstration of The Mintek Thermal Magnesium Process (MTMP) was achieved in November 2004 at the pilot-scale, About 30 tons of magnesium producing recipe was smelted in the DC arc furnace over a continuous operation of 8-days, Twenty-two furnace batching-tapping operations were carried out at a feed rate of 525kg/h and a smelting temperature of 1600-1700°C, The MgO content in the produced slag was as low as 6,7%, and averaged 9,2% MgO, resulting in an overall magnesium extraction of 77%, which reached 87% during good operating periods, Magnesium vapour was extracted at a rate of 70-85kg/h and was delivered to the condenser that was operated at 680-720°C, The magnesium was captured in the condenser crucible in a liquid state, allowing its prompt tapping, More than 3500kg of crude metal were produced over 15 on-line metal tapping operations, On average, a condensation efficiency of 85% was achieved during the entire testwork, which peaked at 87% during steady operations, The quality of the crude metal was similar to, if not better than, that of the Magnetherm's crude magnesium, A pre-feasibility study has indicated that the MTMP has the potential for lower capital and operating costs as compared to the electrolytic process, and therefore Mintek and its consortium partners are exploring opportunities for a commercial production facility.

Jan 1, 2006

By G. E. Veins

A three-phase, continuously-operated, 250 kv.a. electric smelting furnace has been installed at the Mines Branch, Department of Mines and Technical Surveys, Ottawa, for the experimental treatment of ores and by-products of interest to the Canadian mining, metallurgical, and chemical industries. In the operation of this furnace particular emphasis is placed on the accumulation of quantitative data which will be useful in determining the most suitable smelting technique and the nature of the products, and in arriving at preliminary conclusions regarding the cast of power and electrodes. The results obtained in the experimental smelting of iron, manganese-iron, titanium- iron, nickel, and chromiumiron ores, and of a number of industrial by-products, clearly show the value of such treatment for materials of this type.

Jan 1, 1957

By Alfred W. G. Wilson

THE state of development of its iron and steel industries serves as a 1eading index to the general condition of a nation's business affairs. In this paper, the authors present an economic study of the progress of this group of industries in Canada for the decade 1927-1936. The statistical data and most of the tables which accompany this article have been com-piled by John Casey, Statistician, Bureau of Mines; the text and some of the computations have been prepared by the seni0r author. The principal source of statistical information has been the publications of the Dominion Bureau of Statistics; where other sources have been consulted, they are noted in the text. All weights are given in short tons. Records for the years 1913 and 1918 are also presented in the group of tables dealing with iron ore and pig iron; they will serve as a basis for comparison with nearly normal years in the two decades prior to 1927-36, which included the abnorma1 years of the Great War. GENERAL REVIEW At the beginning of the decade under review, this group of industries had returned to almost normal production, as determined by pre-war conditions. Iron ore consumption showed a steady increase between 1927 and 1930; a marked decline began in 1930 and reached its culmination in 1932, when the recorded consumption of ore was 293,353 to11s, about 16 per cent of the average consumption during the first four years of the decade; the last four years of the decade show a gradual increase in consumption; the amount of ore used in 1936 was still slightly below the amount used ten years before, in 1927 (see Table 1, top).

Jan 1, 1938

By N. K. Jaber

The "Pidgeon Process" for the extraction of magnesium from dolomite ore utilizing ferrosilicon as the reducing agent has been studied extensively by active metallurgists such Mr L,M, Pidgeon the father of this process, Most of the work sited so far has focused on heating the (FeSi/MgO,CaO) briquette mix under vacuum in stainless steel retorts by external fuel hydrocarbon heating, In this work Electrical Induction Heating was employed as the heating method whereby the briquette mix was placed in a steel crucible around which an Induction Heating copper coil was wound and placed inside in a stainless steel vacuum tank, It was observed that by virtue of the fast Induction Heating method utilized in the silicothermic extraction process higher reduction temperatures were reached in shorter periods of time due to fast heat transport into the ore charge mix, This facilitated shorter metal reduction times as compared to the conventional fuel heating methods.

Jan 1, 2006

By L. M. Pidgeon

MAGNESIUM metal, with a specific gravity of 1.73, is two-thirds the weight of aluminium and one-quarter that of steel. It is the lightest metal which is stable in the atmosphere. Before the war it had begun, though somewhat slowly, to take a place among the established metals. In 1939, magnesium production on this continent amounted to some 3,000 tons per annum and was confined to one company. At that time, Germany produced perhaps 20,000 tons. The advent of war, however, increased the demand to fantastic heights and introduced production problems of unprecedented magnitude. By the end of 1943, North American production is expected to reach 300,000 tons per annum (1), an increase of one hundredfold. Such a rate of expansion has not been witnessed previously in the history of metallurgy. It has given the metallurgist an opportunity to try new production methods and to learn in a short time what might otherwise have taken many years. The metallurgy of magnesium is still in its formative years and at this time widely different production methods are in operation side by side. This paper will discuss these methods in so far as information is available for publication at this time. A general description of the new Canadian industry will be included.

Jan 1, 1944

By A. Warczok

Chalcocite concentrate obtained by magnetic separation and flotation of Bessemer matte is processed in the Inca top blowing bottom stirring MK reactor into semi-blister copper. The semi-blister is then converted into blister copper in the multi-purpose vessels (MPV) by oxidation of iron, nickel and sulphur. High melting point NiO and Fe30 4 are formed inside the MPV s, which together with Cu20 and smaller amount of fayalite are the major constituents of the solid mush. The accumulation of solid mush and buildup requires periodic MPV cleaning by adding reductant and copper-nickel matte, a unique process called "washout". Various reductants and their combinations, such as pig-iron, 15%Si Ferro-silicon and 50%Si Ferro-silicon, have been used for the reduction of solid mush and buildup. The possibilities of using calcium carbide as a reductant and slagging flux were examined experimentally at the crucible scale. The rate of reduction of MPV buildup was determined by continuous measurement of CO and C02 contents in the offgas and the flowrate of argon carrier gas. The rate of the buildup reduction with calcium carbide was approximately five times faster than the rate of reduction with coke. Additionally, the formation of CaO results in the melting of reduced buildup and formation of a slag at 1300°C and higher temperatures. It was found that simultaneous silica addition enhanced the melting and slag formation. The results showed the strong dependence of the reduction rate on temperature. Activation energy is approximately 225 kJ/mol. Expected benefits of using calcium carbide are related to cost saving on reductant, significant acceleration of solid mush reduction, and reduced amount iron input from reductant.

Jan 1, 2007

By M. F. Goudge

MAGNESIA refractories and magnesium metal are both essential war commodities. The need for magnesium, which had just made its debut as a commercial metal a few years before the outbreak of the present war, is widely known because this new and valuable light metal has already received much publicity. Less widely known but equally important in the war effort are magnesia refractories. They are indispensable to the efficient functioning of the great metallurgical plants producing steel, nickel, copper, and other metals, where, because of their resistance to extreme high temperature and chemical attack, they are used in lining the furnaces, which are operated at a white heat. The demand for refractories in the metallurgical industries rose rapidly upon the outbreak of war, and now, in consequence of the continued great expansion under way in the manufacture of steel, nickel, copper, and other metals, the need for magnesia is greater than ever. Since 1915, part of the Canadian requirements of basic refractories has been supplied from the deposits of magnesitic dolomite in Argenteuil county, Quebec. The products from these deposits are excellent for many uses, but the magnesitic dolomite has too high a content of silica and lime to be used in making a type of magnesia brick required in nickel converters, and in the roofs of reverberatory furnaces used in the copper and steel industries. There is now a large and growing demand in Canada for bricks and shapes for these uses. This demand has always been supplied from the United States. Makers of these products in the United States, in turn, formerly imported most of the necessary high-grade, dead-burned magnesia from Austria and Manchuria. Not only are these sources closed, but refractory chrome ore from the Philippines is no longer available and chrome refractories may have to be in large part replaced by magnesia.

Jan 1, 1942

By Mark Freberg

"IntroductionThis chapter is intended to provide information on the operation and maintenance of several pieces of equipment used in heavy media separation. Most heavy media separation circuits, particularly those involving bath separators can be considered as high maintenance areas. Because of this the efficient operation and maintenance of these circuits is very important if the cost per ton of material treated is to be kept to an acceptable level.Heavy media separation (HMS), is a process used to separate particles of different specific gravities. Under laboratory conditions the ideal way to separate two types of particles which have different specific gravities is to suspend them in a heavy liquid which has a specific gravity between those of the two types of particles. Those particles with the lower specific gravities will float on top of the liquid while the higher specific gravity material will sink to the bottom. Given enough time and a sufficient volume of heavy liquid this process will be essentially insensitive to the sizes of the particles involved.Heavy media separation circuits make use of the same principles described above. The material to be treated is introduced into a mixture of finely ground solids, called media, and water which takes the place of the heavy liquid; the mixture of solids and water is known as medium. The separating force can be either gravity or centrifugal force. The type of solids used as media varies but it is usually a high specific gravity material such as magnetite, galena or ferrosilicon.Heavy media separation is used extensively in the cleaning of coal and to a lesser extent as a preconcentration step in base metal and iron ore operations."

Jan 1, 1989

By C. M. Offenhauer

Abstract Zirconium markedly affects the formation of graphite in cast iron and may promote the formation of normal flake gaphite, fine flakes of eutectiform graphite, or spheroid nodular graphite, according to the composition of the Iron and the amount of the zirconium addition. Usually, it is employed in the form of a complex addition agent in order to facilitate its introduction and to guide its effect. The reported applications of zirconium as an inoculant for the production of pearlitic high-strength cast iron indicates that it is most effective as a silicon-manganese-zirconium alloy. Added in this form it reduces chill and minimizes zones of ferrite and eutectiform graphite. In low-sulphur cast iron, zirconium in amounts greater than 0.10 per cent tends to promote the development of eutectiform graphite. These irons are characterized by freedom from primary cementite or normal flake graphite and exhibit very little tendency to shrinkage on solidification. In hyper-eutectic low-sulphur cast iron, zirconium causes the formation of a partially nodular graphite structure. A combination of magnesium with silicon-zirconium alloy was found to produce completely nodular graphite structures without the hazards associated with the addition of elemental magnesium.

Jan 1, 1949

By A. McLean, W. Q. Chen, W. Yan, M. Barati, Y. D. Yang

In order to maximally remove the harmful impurities phosphorus and reduce the loss of valuable elements from Si-based alloy for production of solar-grade silicon, thermodynamic properties of the Si-based alloy were studied. In this work a new model, the Molecular Interaction Volume Model (MIVM) derived from statistical thermodynamics, was successfully used in the Si-based and Si-Fe-based alloy. The calculation started from binary Si-Fe, Si-P and Fe-P systems, then the thermodynamic parameters of ternary systems could be derived based sub-binary systems. Using the activity coefficients of the elements in the Si-based alloys and the saturated vapor pressure of the pure substance of the components, mass fraction of P during vapor-liquid equilibrium can be calculated. The calculated thermodynamic parameters were compared with experimental data available in different publications, and it is found that the thermodynamic parameters calculated using MIVM model are in good agreement with the measured results. The calculated result shows that the mass fraction of phosphorus during vapor-liquid equilibrium of Si-Fe-P melt increases with the increasing phosphorus content and decreasing temperature. This is an important direction for experimental practice in vacuum or low-pressure EML refining of ferrosilicon for potential production of solar-grade silicon without significant vaporization loss of valuable element.

Jan 1, 2015

By L. Jones, S. R. Lawrence, A. R. Holloway

Whilst dense medium separation is best known for its ability to concentrate diamond and coal deposits, the process is now being employed in southern Africa as a pre-concentration step to improve the economics of platinum group metal and nickel ores. DMS plants built for these industries (such as the 1600tph unit at Tati Nickel, Botswana), are spearheading an expansion in this area by reducing mine and process operating costs yet maintaining economic metal recoveries. This paper provides an overview of DMS technology and examines the economic benefits available to North American operators and projects, with recent case studies as reference.

Jan 1, 2009

By Z. D. Hora

Sev_eral dozen si lica occurrences have been reported from various parts of Brit ish Columbia. Some represent hydrothermal veins or parts of pegmatite bodies; other are recrystall ized sandstones. Several vein type deposits were mined for smelter flux and as a source of white chips for stucco dash and simi lar products. Some quartzites were studied as potential sources of high-grade silica for ferrosilicon and silicon metal production. The province's only production of silica for ferrosilicon has come from a pegmatitic quartz plug near Oliver in southern British Columbia. Its reserves are now practically depleted.

Jan 1, 1984

By Holt. Grover J.

"IntroductionThe history of iron ore production in the United States has followed a pattern not far different from that set in the production of non-ferrous ores; the first interest of the prospector and miner being the discovery and development of high-grade ores. In the early stages of development of most mining districts, high-cost low-grade ores are usually of slight interest due to the additional capital investment required in concentrating plants, as well as the increased requirements of •power and other facilities. As the reserves of higher grade ores are depleted and the technical knowledge of ore beneficiation is broadened, production of concentrates from the lower grade ores is stimulated.The real stimulus necessary to arouse serious consideration of beneficiated iron ore in the Lake Superior district has been provided by the serious inroads made in the high-grade ore reserves by two World Wars.The first shipment of high-grade iron ore from the Mesabi range in Minnesota was recorded in 1892, and the first token shipment of concentrates was made 15 years later, in 1907. Not until 1910 did the production of concentrates assume any great importance. A steady increase in concentrate production over the years is shown by the fact that, in 1910, concentrates accounted for 8 per cent of the total shipments from the State, whereas by the time of World War II this percentage had increased to 22 per cent and by 1948 had risen to 26 per cent. It seems a safe assumption that the shipment of concentrated iron ore, from the Mesabi range in particular, will continue to increase even more rapidly from now on, with other iron ranges of the Lake Superior district following this lead."

Jan 1, 1950