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By A Jyoti, J R. Black, R R. Haese, E O. Ansah

Copper (Cu) is a critical metal in the transition to a low-carbon power supply. Presently, low-grade copper sulfide ores account for almost 80 per cent of the global reserves. Large amounts of water are required to process these low-grade copper ores. The mining industry utilises lixiviants from recycled water from different sources to conserve water, whilst enhancing Cu recovery. Some utilise intermediate to pregnant leach solutions, sea water, and processed water from electrowinning circuits with highly variable concentrations of ions. Previous studies have highlighted the formation of precipitates that passivate the surfaces of minerals in these low-grade copper ores and/or block flow paths for lixiviant during heap leaching. In this study, we utilised concepts of phase replacement to devise an innovative means of controlling precipitation and increasing copper recovery using industrial brine as opposed to freshwater. We propose the formation of Al-rich phases (such as AlSO4 + or alunite) to replace iron sulfate and iron hydroxysulfates (such as jarosite) during the chalcopyrite dissolution-precipitation mechanism. The rationale is to have available Fe3+ throughout the chalcopyrite leaching process. We tested this method by carrying out various batch experiments using CaCl2, AlCl3, and NaCl industrial brine types compared to freshwater and explored the capacity to leach Cu from chalcopyrite. There is higher Cu recovery during oxidative leaching of chalcopyrite in industrial brine with 91 per cent recovery using AlCl3-rich brine, 84 per cent with NaCl-rich brine, and 56 per cent with CaCl2-rich brine as compared to 35 per cent recovery using freshwater. In the absence of Al3+, various forms of iron sulfates, and jarosite are formed, reducing the availability of Fe3+ for chalcopyrite dissolution. The introduction of Al3+ leads to the formation of AlSO4 + species, thus lowering sulfate activity and the tendency for K-jarosite formation.

Aug 24, 2022

By Han Kook-Nam, Lawson F

The recoveries of the three cobalt minerals in the Mount Cobalt deposit, cobaltite CoAsS, erythrite CO3(AS04)8H20, and new cobalt mineral with a composition approximating 2CoO.CaO.Fe203.2As205.11H2O were investigated using physical and surface-chemical processes.Over 80 per cent cobalt recovery was achieved by tabling a cobaltite-mineralized sample, while about 76 per cent cobalt recovery was obtained by dry feed magnetic separation of a sample containing erythrite and the new cobalt mineral. The resultant primary magnetic concentrate with a cobalt grade of 5.5 per cent, was able to be upgraded to 14.4 per cent cobalt by regrinding .and a further magnetic separation.Electrophoretic mobility - pH responses for each of the three cobalt minerals were found to be similar. Each mineral remained negative over the pH range 3 to 11 and was most negative at mildly alkaline pH values.Cobaltite was floated effectively with amyl and ethyl xanthate collectors under acidic conditions at collector concentrations of 10-2M to 10-5M. Erythrite showed a similar flotation response using 10-sM amyl xanthate. The practical application of these laboratory separations to an industrial process is suggested.

Jan 1, 1976

By Hinrichsen H. D, Rathburn D. R, Stieger W

The present situation in the field of iron ore pelletizing is briefly described with particular view of the Lurgi/Dravo travelling grate process. To meet todays pellet quality requirements with regard to physical and metal- lurgical properties it is often necessary to add basic fluxing materials. It has been de- monstrated that for certain ores, basic addi- tives provide a considerable improvement in fired pellet quality. The production of self- fluxing pellets is becoming increasingly attractive. One Lurgi/Dravo plant is now in operation and another is under construction which were designed for the production of self- fluxing pellets. Self-fluxing pellets may be considered as the primary or exclusive blast furnace burden and the installation of a sinter plant is not necessary if the pellet plant-can handle all in-plant fines. Reference is made to the first pellet plant utilizing iron ore concentrate, in-plant fines and basic flux. The use of solid fuel for pellet indura- tion is discussed because of the increasing prices and possible shortages of heavy oil and natural gas. Since there is a strong tendency to increasing plant capacities, the design fea- tures of travelling grate pelletizing plants for productions up to 6 million tonnes are Discussed.

Jan 1, 1974

Types of structure found in 'Jest Australian beach sands are described. Their recognition by geostatistical methods follows nth a discussion of the effectiveness of sampling patterns. Examples of structures are given, and an account of their effect on valuation procedures.

Jan 1, 1977

Average annual growth in consumption of primary energy in Australia over the past 10 years has been 5·5 per cent compared to a world average of 4·1 per cent.Over the next 10 years growth rate is expected to increase to 6 per cent per annum due largely to the rapid development in the mineral processing industry.By the end of the 19705 natural gas is expected to supply more than 9 per cent of Australia's primary energy market. Coal will supply 40 per cent and petroleum products 47 per cent. Nuclear energy will make its appearance but will make only a small contribution in the period.Australia has adequate reserves of natural gas and coal to supply its needs in the 1970s and beyond. However the newly developed reserves of crude oil, while supplying 60-70 per cent of requirements in the initialyears, will need regular and sizable additions if they are to keep pace with the expanding consumption. For Australia to become self sufficient in the period 1970-1990 it is estimated that new discoveries will need to approximate ten times the volume of recoverable reserves found in Australia to date.

Jan 1, 1971

By Grieveson P, Terry B. S

Carbothermic reduction of sulphide minerals for achieving a selective separation of metallic species from complex minerals has been discussed by considering the prevailing oxygen potential during the course of reaction. Construction of univariant plots for the reduction of sulphides with carbon monoxide gas or carbon and in the presence of either lime or anhydrous calcium sulphate is the key feature of this work. The theoretical calculations for univariants in the Cu-Fe-S-O system indicated a preferential separation of metallic copper and iron by imposing a chemical potential. This is evident from a logarithmic plot of sulphur dioxide partial pressure against reciprocal temperature. The results are compared with empirical data for the reduction equilibrium. The reduction behaviour of the constituent sulphides are also discussed together with the experimental results and theoretically predicted phase stability diagrams.

Jan 1, 1992

By Baafi EY, Appiah HK

The Prestea Goldfields Ltd of Ghana, West Africa has produced over 170 t of gold with average grade of 11 g/t since 1912. The deposits occur in a wide shear zone which closely follow the Birimian-Tarkwaian contact. Both the Birimian and Tarkwaian systems are of Precambrian age. Underground exploration is carried out to delineate ore bodies by means of AX size diamond drilling at 50 m sampling intervals. After the orebody has been delineated, development work is carried out by exposing the gold reef. Channel sampling is then carried out at about 3 m intervals in both the stope and stope drives. A channel sample length is commonly 0.6 in, but may vary depending on physical characteristics of the reef. The values of channel samples are linearly combined to obtain the average reef or slope values and/or widths of the exposed sections. The sampling practice and methods of improving the efficacy of sampling at the mine are described.

Jan 1, 1976

By Taylor R. K A, Berglin C. I K

The manganese ore deposits at Groote Eylandt are quite variable both in regard to grade and physical cond- ition. In order to treat a wider range of these ores and to increase production a new primary-crusher and' concentrator complex costing $8 million has been installed and commissioned to treat ore at the rate of 12,000 tonnes per day. The initial testwork carried out to determine the method of the ore treatment required, and on which the design of the concentrator was based, is detailed. The flowsheet and equipment used is discussed together with the operation of the plant. The production achieved and product qualities obtained are given.

Jan 1, 1973

By Pratt V

The economic, social and political environment of the mining and minerals industries is, as we all know, volatile and affected by constantly changing international forces. In addition, the outcome of negotiations with overseas customers is often uncertain for long periods, or even unfavourable. The industries and companies represented at this Conference are in an arena of high competition, risk taking and enormous capital outlay. They are industries which our overseas markets (rightly or wrongly) have criticised for industrial relations problems, unreliable production and uncertain deliveries. They are industries which have an urgent need to be cost effective and competitive at all levels of activity.A critical factor in the mining and metallurgy industries is, therefore, its human resources and its human resource management. It requires the full use of available talent, innovation, skills and qualifications within its workforce, and the appropriate management of these resources.

Jan 1, 1985

By G Bournival, Y Pan, S Ata

A custom-made set-up that measures bubble coalescence time and the thin film balance (TFB) technique were used to explore the role of residual xanthate (potassium amyl xanthate, PAX) and salt (NaCl) on the adsorption of two frothers (methyl isobutyl carbinol-MIBC, and di-propylene glycolDPG) at the air-water interface. This paper is primarily focused on the comparison of these two techniques in studying the interaction between the flotation reagents and salt emphasizing their capabilities and limits. The results from the coalescence rig showed that the presence of PAX improved the stability of bubbles in both frother solutions and led to a bubble coalescence inhibition at 50–500 ppm DPG. These measures were compared with the results from the TFB. Findings from the TFB were overall in good agreement with the bubble coalescence time, but a higher stability level was observed in thin films under the same condition. The effect of salt on the frother and PAX mixture was also explored, and the results showed an adverse impact of the salt on the interaction of frother and PAX with both techniques. However, variations were found between them in some cases. The TFB is much more sensitive to the presence of dissolved gas and oil droplets.

Aug 24, 2022

Western Mining Corporation has grown from a small gold exploration and mining company, funded by large established mining companies, into a large multi-commodity and multi-national mining company with shareholders who no longer have the same understanding of mining as the founders. Ore reserve calculation methods and reporting procedures have gradually changed throughout the group during this growth. These changes have been led by the newer mines, in particular the Kambalda nickel mines, where the need for more global, less conservative reserves were required to justify capital and forward sales contracts and to inform shareholders of the true worth of their company. This change in attitude to reserves has flowed back to the gold mines and has allowed a better informed management and investing public to plan for the future. Management of the calculation of reserves remains the responsibility of individual mining operations, but a corporate reporting and management structure exists through the office of the Director of Exploration and divisional chief geologists who strive to maintain standards of calculation and reporting. Specialist ore reserve geologists are starting to justify their place in the organisation, particularly at the larger operations. Reporting to the new AusIMM Standards is fully supported, although the amount of supplementary information requested will need to be considered carefully because of the large number of factors that make up even the simplest reserve.

Jan 1, 1990

Sizing is fundamental technology for each step of ironmaking process. The progress of sizing technology has greatly contributed to the development of ironmaking technology. As the purposes of ironmaking operations diversified particularly since the oil crisis of 1973, the sizing technology made new advance- ment, as represented by pulverization of ser- pentine, dezincification and classification of secondary blast furnace dust, pulverized coal injection, size-segregated sinter charging and a coal preparation control process. These techniques are mostly characterized by the fine grinding of a given type of mineral or coal to heighten the degree of reaction con- trol. This trend is expected to continue Further.

Jan 1, 1984

Politicians and economists talk glibly about the so-called knowledge revolution. The reality is that knowledge is fundamental to economic progress. Consequently there have been many technological revolutions. The global impacts of the invention of the steam engine and the development of the frozen meat industry are well known. Another less publicised technological advance occurred in Central Otago late in the nineteenth century. This was the adaptation of the bucketladder dredge to the mining of placer deposits. A product of over 30 years experimentation and innovation, New Zealand dredging technology was taken to the Risdon Iron and Locomotive Works, San Francisco by R H Postlethwaite, a Dunedin based mining engineer. New Zealand-style dredges built by Risdon operated successfully in California, Alaska and the Yukon. Californian engineers assimilated the best features of the New Zealand dredges with American (Bucyrus) designs to produce a standard for the worldwide placer mining industry.

Jan 1, 2003

The Kunwarara magnesite deposit is the largest known magnesite (MgCO3) deposit in Australia. It is located under black soil plains to the north of Rockhampton in Queensland. The deposit consists of magnesite nodules set in a fine-grained sandstone, siltstone and mudstone matrix. The magnesite is derived from weathering of serpentinite in adjacent hills and transport of magnesium in solution to a Tertiary/Quaternary river system. The magnesium has come out of solution in the active river system, and combined with atmospheric and biogenic CO2 to form magnesite nodules. The magnesite can be very pure with certain varieties up to 98 per cent MgO (LOI free). The deposit has been mined since 1991 and processed into magnesia (MgO) which is sold into refractory, agricultural and other markets. The geologist is an integral part of the small mine technical team. The role of the geologist includes characterisation of the ore through drilling and bulk sampling, supervision of geological aspects of mining and assistance in the optimisation of ore processing.

Jan 1, 2000

By Osborn G

The bulk flotation behaviour of an industrial rougher bank has been determined with a view to characterising the size iepend ent behaviour of the identifiable nineral groups present. A relatively simple flotation model, based on first order kinetics and the assumption of perfect mixers in series ias been used to provide a fit to the operation of the cells. The adequacy of the model is discussed in relation to the characteristics of the ore and the size iependancy of the parameters. It is shown that improved fits are possible if the model accounts explicitly for this size dependancy and demonstrated how the model may be of use in prediction of the grade recovery relationships for different operating conditions as an aid to plant optimisation.

Jan 1, 1986

By Nava-Vasquez E, Torres-Torres J, Mendez-Nonell J

The ZA-27 zinc base alloy was poured into cylindrical moulds and solidified under different conditions ie normal freezing and unidirectional freezing. In addition a cylindrical ingot with rheocast material was obtained by stopping the stirring action and, at a specific solid fraction, gravity casting it into a graphite mould. It was observed that the material obtained under normal freezing conditions is likely to present both segregation and inverted pipe. In contrast, the unidirectional solidified and the rheocast cylinders showed the absence of inverted pipe. The segregation pattern was quite irregular in the rheocast ingot while such segregation was more uniform in the unidirectional solidified cylinder. By virtue of these observations, the inverted pipe formation may be ascribed to the interdendritic flow, while the irregular segregation pattern in the rheocast ingot may be attributed to an irregular distribution of the liquid and solid fraction along such a cylinder.

Jan 1, 1993

By M D. Melville, B C. T Macdonald, T D. W

The surface waters in regions with acid sulfate soils (ASS) can contain high concentrations of acidity and dissolved metals. These soils cause problems for agriculture, construction and development. The water can be neutralised through many techniques, however a technique that is low in maintenance and low in cost is most desirable. Due to the vast spread of ASS along AustraliaÆs coastline an expensive and high maintenance solution would not be cost-effective. In this study, a passive treatment system that has been used to neutralise acid rock drainage has been applied to treat ASS water. This system is commonly referred to as an oxic limestone drain (OLD) or an anoxic limestone drain (ALD) depending on the waters dissolved oxygen concentration. The system that has been developed for ASS has a similar closed system to the OLD or ALD, that traps the carbon dioxide which forms when limestone reacts with acidic water. It has been called a closed tank reactor (CTR) and is constructed by placing limestone into an airtight tank. A common problem that will occur when acidic water with a high concentration of dissolved metals reacts with limestone is the formation of metal oxy-hydroxide precipitates. These precipitates can coat or armour the limestone and reduce its reactivity. To minimise the accumulation of precipitates in the CTR, perforated subdrains have been installed. It is anticipated that high water pressure and flow through the subdrains will remove some precipitates. A sump has also been installed at the base of the tank to collect precipitates that settle under gravity. The CTR has been tested for 70 days at a sugar cane farm located at McLeods Creek, NSW. Within this time the sump and subdrains have been used to flush the system. An orange solution was produced during flushing and it is believed to contain iron and aluminium precipitates. The initial performance of the CTR raised pH by at least one unit. Almost all dissolved aluminium was removed and more than half the dissolved iron. The total titratable acidity ranged from 17 - 92 mg/L CaCO3 in the initial month of monitoring. After passing through the CTR the acidity was reduced to zero. The performance of the CTR during the last few days of monitoring decreased. This is believed to be due to a pulse of water with higher acidity and dissolved metal content that lasted a week. In this pulse, the acidity reached 307 mg/L CaCO3 and the total dissolved aluminium reached a maximum of 24 mg/L. Higher concentrations of dissolved metals may have been the cause for lower performance due to increased precipitation and coating on the limestone.

Jan 1, 2003

Thank you for this opportunity to address your conference on The role of coal in the New Zealand energy market".New Zealand's energy market has, in common with much of New Zealand, undergone major change following the market reforms of the Labour Government.As far as the energy sector is concerned this change has been for the better, as it has created for the first time in a very long time a "true economic market" for energy in New Zealand.

Jan 1, 1990

By Sandvik

Fine grinding in an air-swept ball mill working in closed circuit with a forced vortex air classifier has been investigated first in continuous laboratory and then in industrial scale. Results from the laboratory circuit have shown significant influence of mill load (powder filling) on the capacity of the circuit. In laboratory scale the mill load was measured and controlled by a weighing platform placed under the complete mill set-up. The mill load of the industrial air-swept ball mill has till now been controlled by measuring the power consumption of the mill motor. Thus, it was necessary to operate far from the range of optimal mill filling. To improve the circuit performance, alternative ways of mill load measurement were investigated. An important factor was investment cost, as many fine grinding mills operate in relatively small circuits that do not wan-ant large investment. In this case the task was accomplished by using a piezoelectric strain transducer, which detected strain changes in the mill shell. It was installed in the midpoint of the shell, where the highest deformation was obtained. As the transducer was on the top position, it indicated compression, and on the bottom position it measured tension. By taking the difference between the readings, it was possible to calculate total strain variations, directly proportional to the mill load. The signal from the transducer was sent to a control room via a cordless infrared communication system, employing a microprocessor control card, which could further regulate other operating parameters of the circuit according to the software model. The installation required very low investment cost and provided simplicity of application as well as stability and reliability of characteristics under severe industrial condition. The measurement system made it possible to optimise the mill load and thus increase the production from 3.2 to 3.7 dh (15 per cent), and stabilise the circuit operation.

Jan 1, 1995

By V S. Vutukuri, K Shariar

This paper present a modification of selected strength criteria for coal and rocks containing weakness planes. The three strength criteria, namely, Murrell (1965), Bieniawski (1974a, 1983) and Hoek and Brown (1980) have been assessed for coal (containing weakness planes) by using triaxial strength tests. Triaxial test results indicated that the strength of coal specimens depends on the weakness plane inclination with respect to the principal stress direction. However it is shown that with increasing confining pressure, the effect of weakness planes inclination on the strength of coal specimens is reduced. The constant parameters in the three failure criteria for coal are determined for each weakness plane inclination by using the Datafit computer program (nonlinear regression analysis) and the results are compared with other rock types.

Jan 1, 1999