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By D. Clement

A comparison between hydraulic and pneumatic rockdrills by D. CLEMENT The regulation of compressed-air reticulation systems is very poor compared with that of electrical systems; this means that electrohydraulic rockdrill systems offer greater flexibility, additional power being readily available at the working face. Hydrometallurgy A new journal devoted to all aspects of the aqueous processing of metals is scheduled to appear this year. Entitled Hydrometallurgy, the journal will be published in quarterly issues, one volume per year. Mineral dressing Contributions are invited for the Symposium on Recent Progress in Mineral Dressing in South Africa, which is to be arranged jointly by the South African Institute of Mining and Metallurgy and the National Institute for Metallurgy. Mineraalbereiding Bydraes word verlang tot die Simposium oor Onlangse Vordering met Mineraalbereiding in Suid-Afrika wat gesamentlik deur die Suid- Afrikaanse Instituut vir Mynbou en Metallurgie en die Nasionale Instituut vir Metallurgie gereel gaan word. Rock mechanics The Sixteenth Symposium on Rock Mechanics is to be held at the University of Minnesota from 22nd to 24th September, 1975. The Symposium is the official Symposium for 1975 of the International Society for Rock Mechanics (I.S.R.M.), and the Council for I.S.R.M., consisting of members from 25 countries, will meet during the Symposium. Powder metallurgy The annual meeting on powder metallurgy organized by The Metals Society is this year to be held at the Stratford Hilton Hotel, Stratford-upon-Avon (the notification did not include the date of the meeting). Vacation School The South African Institute of Mining and Metallurgy has great pleasure in announcing its intention of holding a vacation school on the topic of electric-furnace melting. NIM reports Report no. 1681 The determination of sulphur and phosphorus in chromite. Report no. 1687 The viscosities and electrical conductivities of slags associated with the production of high-carbon ferromanganese alloys.

Jan 3, 1975

By L. C. Stilwell

The paper will place into perspective the contribution that platinum makes to the South African economy. It will use statistics from official sources, namely the Department of Minerals and Energy, the Department of Customs and Excise, the South African Reserve Bank and Statistics South Africa. Surprisingly few people are aware of these statistics, especially Supply and Usage tables, published by Statistics South Africa, and trade statistics, published by the Customs and Excise division of the South African Revenue Service. The paper will therefore contain a concise explanation of input-output tables and supply usage tables, as well as the derivation of gross domestic product and an outline of the System of National Accounts, of which Input-Output Tables and supply and usage tables are components. GDP is a commonly used, but poorly understood, measure of the wealth of an economy. The paper will explain the methods used by SSA to calculate this indicator and its place in the System of National Accounts (SNA). South Africa exports almost all its platinum production (87.5% in 2002). Exports are a final demand, as opposed to intermediate demand from secondary industries, and therefore do not enter the value-adding process, which is the essence of GDP. By definition, therefore, platinum on its own is not a major contributor to GDP. The platinum industry does, however, have an impact (known as the multiplier effect) on other sectors of the economy. The paper will explain the meaning and derivation of these multipliers, using a model based on an Inverse Leontief Matrix.

Jan 1, 2004

By G. D. Rosales, P. F. A. Braga, S. C. A. França, C. P. Pinto

The growing market demand for lithium is mainly due to its use in the manufacture of batteries for electric or hybrid vehicles and portable equipment (smartphones, tablets, power tools, notebooks, etc.). Currently there is great interest in finding new sources of lithium and technologies for its utilisation. Li-S batteries have received attention due to their theoretically high specific energy density, which is 3 to 5 times greater than that of Li-ion batteries. Unlike Li-ion batteries, of which the main raw materials are lithium carbonate and lithium hydroxide, the main raw material for Li-S batteries is lithium chloride. The anode used in Li-S batteries is metallic lithium, produced by a molten lithium chloride electrolysis process. The extraction of lithium from pegmatites such as spodumene, previously abandoned in the 1990s for being uneconomical, has become attractive due to the increase in prices as well as the need for greater lithium purity of products made from lithium-bearing minerals. The main methods used for lithium recovery from spodumene ore include the sulfuric acid process, the alkaline process (lime or limestone as raw material) and the chlorination roasting process. Thermodynamic modelling using HSC software 5.1 was conducted to predict different reactions that could occur during chlorination roasting of the spodumene/MgCl2+CaCl2 system. Lithium extraction from the solid obtained after the chlorination roasting was also investigated. The results of thermodynamic analysis provided a better understanding of the chlorination roasting process for lithium extraction. Metallurgical tests with a mass ratio of 1:6 (spodumene:chlorides) and molar ratio of 2:1 (MgCl2:CaCl2) allowed over 95% recovery of the lithium contained in the spodumene concentrate. Keywords: Spodumene, lithium chloride, chlorination roasting

Jan 1, 2020

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

A party of some 60 members of the Institute were welcomed at the Union Junction Works of Scaw Metals Limited on Thursday, 23rd January for a morning visit. Dr J. M. Bereza, the metallurgical Director, gave an informative introductory talk to the assembled visitors, which briefly covered the major activities of the Company. This was followed by refreshments, and the visitors were then allocated to 12 guides for the conducted tour of the Works. The progress of the Company is an impressive saga of the development of heavy industry in this country linked primarily to the expanding mining industry. Many other outlets are now available for Scaw products and the rapidly advancing techniques developed by their own chemists as well as the processes made available from overseas associates indicates the forward looking attitude of the Company. The visitors were impressed by the modern laboratory services, closely linked to rigid quality control, resulting in a high standard of final products. The most fascinating section to many of the visitors was the continuous casting machines and rolling mills recently installed, although the most lucrative section is the large steel foundry. After the tour the parties gathered in a marquee tent for liquid refreshments, followed by a lavish luncheon in the canteen. The visitors were officially welcomed by Mr Richard Boustred, the Deputy Managing Director, and Mr V. C. Robinson replied, thanking the Company on behalf of the South African Institute of Mining and Metallurgy. Arrangements were made for golf in the afternoon at the Germiston Golf Club for those who wished to play. A.E.G.

By J. Ungar, F. X. McGarvey

The selectivity of ion-exchange sites varies with the matrix of the polymer, the nature of the site. and the method of application. The effect of these variables on the recovery of uranium is examined. with particular attention to vinyl pyridine and to symmetrical and asymmetrical quaternary ammonium sites. The effect, on the loading. of high concentrations of chlorides in the liquors is discussed. and other components of the liquors that may cause fouling of the resin are also considered. The discussion is supported by the results of tests conducted on various types of resins. The economics of the process is discussed briefly.

Jan 1, 1981

By W van Drunick, S Naik

To date, Anglo Research has carried out several projects, based on the techniques developed in the AMIRA P9 (AMIRA International Limited), to develop comminution and flotation models for several Anglo Base Metals and, to a lesser degree, Anglo Platinum flotation plants. Plant optimization is thus achieved through steady-state sampling, model-fitting and simulation using the JK SimMet and JK SimFloat software packages. The surveys can vary depending on the needs of the plant/client. The survey can therefore include as little as a single piece of equipment, an entire milling/flotation circuit, or a complete circuit from primary comminution to final flotation concentrate (i.e. the ?integrated survey?). The presence of the AR team on-site usually precipitates in face-value observations that can lead to initial improvements. This stems from the knowledge-sharing on best practice that exists in parallel with the surveys. Numerous (reasonable) changes can then be simulated, thus indicating the optimization step most likely to result in the best efficiency improvements. The simulations can include changes in the flowsheet, ore characteristics, mill loads, grinding media size, change in grind, flotation residence time, air hold-up and several more. Plant surveys can result in process changes that provide the plant with either: higher plant tonnage, improved plant grind, additional flotation recovery and/or improved product grade. The additional benefit of performing an integrated plant survey is that the effects of an optimization change in the comminution circuit can be simulated using the flotation model. This paper describes a number of case studies where individual and integrated plant surveys were conducted by AR for Anglo Base Metals.

Jan 1, 2007

By J. K. E. Douglas

PRESIDENTIAL ADDRESS Given by Mr J. K. E. DOUGLAS, M.Se. (Eng.) (Rand) SYNOPSIS Lime is the most widely used and the cheapest chemical alkali known to man and virtually every product we use or eat has required lime in some phase of its manufacture. Its use goes back to the earliest days of man and many ancient buildings and writings bear testimony to this. The manufacture of lime involves quarrying, crushing and screening of limestone and the burning of the sized stone in kilns of which there are several types. The earliest kilns were of very crude design and only in comparatively recent times have large capacity, automated and scientifically controlled kilns been developed. The history of the South African lime industry is largely that of the three main lime companies and their story is briefly told. No other material used in industry has a greater diversity of uses or more varied functions and lime has applications in most South African industries. The main applications are in the production of gold and uranium, iron, steel and ferrochrome, carbide, sugar and paper and for water treatment, agriculture and building. The Republic is well endowed with high quality limestone and the conclusion is drawn that many other minerals will have been exhausted before we run out of limestone with which to process them. The expansion of the lime industry has in the past kept pace with the requirements of industry and the future demand is expected to grow in parallel with the growth of these industries. Since the war this growth has been phenomenal and with our expanding populations and abundance of raw materials it should continue in the years ahead. Limiting factors are the shortage of skilled labour and the distance from export markets. Confidence is expressed that the challenges of the future will be met and that the lime industry will continue to make an important contribution to the growth and prosperity of South Africa. INTRODUCTION Lime, gentlemen, is known to all of you. Like myself, most of you have undoubtedly found it to be, on the appropriate occasion, a most pleasant flavouring for gin. But this lime, or rather its juice, was in earlier days more than just a flavouring. In the days of sail it was vital to the health of sailors as a deterrant against the scourge of all sea-going men-scurvy. It thus played a small but important role in the opening-up of trade routes around the world on which was based the original wealth of many of today's more advanced nations. I propose to address you on the subject of lime this evening, not the citrus variety I have just mentioned, but the most widely-used and cheapest alkali known to man, which, largely unsung, plays an even more vital part in modern industry than did its namesake in the development of inter-continental trade. In the time at my disposal, I propose to tell you something of the history, geology and technology of lime manufacture. Then I will briefly sketch for you the development of this industry in South Africa and indicate the role it plays in supplying the requirements of many of our important industries. Finally we will attempt to look into the future. The importance of this chemical alkali to our modern civilization is seldom fully appreciated-virtually every product we use or eat has required lime in some phase of its manufacture, either directly or indirectly. It is one of those basic materials, along with iron, coal, sulphur, salt and petroleum without which industry and, in fact, our modern way of living could not exist. Fortunately, nature has endowed the world with a plentiful supply of the limestone from which lime is derived and most countries have deposits adequate for their requirements. As a result, not only has there been little trade in lime products between countries but in the past the widespread occurrences of limestone have set a pattern of numerous small plants each serving a limited area. These plants were generally crude affairs incapable of producing a quality product. It is not surprising that, in an industry comprised of small producers with limited financial resources and in fierce competition with each other, there was little interchange of information. Technological development was therefore slow and the industry tended to be regarded as a backyard operation. Its popularity was not enhanced by the fact that lime is difficult and unpleasant to handle if proper facilities are not provided. In recent years the lime industry has undergone very radical changes to meet the more exacting requirements of today's more sophisticated consumers. Only since the war have the larger companies emerged with proper management, highly mechanized plants and a scientific approach. HISTORY Lime was one of the first chemical reagents used by man and consequently lime burning is one of the oldest of the chemical industries. The use of limestone dates back to the stone age when primitive man used limestone to build fireplaces, construct shelters and make crude tools and weapons. It is probable that lime was first discovered by him when the stone in these fireplaces disintegrated to a white powder which he could use for decorative purposes. The first recorded use of limestone was when huge blocks of limestone were used to build the pyramids of Egypt in 4,000 to 2,000 RC. It was not long after this that the beauty of marble, which is in fact a limestone, came to be appreciated and it found wide application in sculpturing and for decorative wall construction. Originally lime, mixed with sand, was used mainly as a mortar for building purposes, the earliest record of its use for chemical purposes being in 350 B.C. in a report of the wreck near Marseilles of a ship carrying a cargo of linen and lime 'for its bleaching'1. Cato mentioned the burning of lime kilns in 184 B.C. and the Romans made extensive use of both limestone and lime for highway construction. A treatise on architecture by Vitruvius who had an official position in the rebuilding of Rome under the Emperor Augustus remained for nearly two thousand

What is the role of The South African Institute of Mining and Metallurgy at a time when so much is developing and changing in South Africa? The minerals industry is represented through employers, employees, government, education, research, public views, and even pure political interests. The role of the Institute is to represent the mining and metallurgical profession. In this role the Institute has aligned itself with Associated Scientific and Technical Societies, the Council of Scientific Societies and the Engineering Association. The Institute is also active on the Engineering Council of South Africa.

Jan 1, 1996

By M. R. L. Blackwell

Over the period 1964 to 1969 Conzinc Riotinto of Australia undertook and completed an evaluation of a large low-grade copper orebody on Bougainville Island in the Territory of Papua and New Guinea. From the outset it was clear that the geographic, climatic and topographic characteristics of the area would necessitate a heavy capital outlay on production and support facilities. Both the physical problems and the magnitude of the investment amplified the need for a thorough and rigorous evaluation of the various strategies for exploiting the orebody. In view of the number of independent and inter-related variables and the flow of new data, a computer-based evaluation process extended the scope and depth of the analysis considerably. The system used permitted an iterative assessment and re-assessment of the various strategies with the results becoming increasingly refined with time. This process encompassed the modelling of the orebody, the simulation of alternative operating strategies and the determination of the financial profitability of the project,

Jan 1, 2014

By M. J. Deats

INTRODUCTION To prepare the reader adequately, reference should be made to the paper 'The Pioneering of Fully Mechanized Longwall Coal Mining in South Africa' by R. T. Naude and M. J. Deats, published in the February, 1967, edition of the Journal. At the time mechanized longwalling had been proved operationally feasible with encouraging results since its inception in South Africa in mid 1965. Subsequently, further top seam panels were successfully extracted with improved productivity and with some modification to equipment. In 1968, after an overseas visit by mine officials, equipment specific to suit local conditions was acquired and lower seam trials commenced. Despite initial obstacles and difficulties the first panel was successfully mined. Modification and improvements to equipment and techniques resulted in the second lower seam panel being extracted economically during 1969-1970 and with productivity exceeding even that of top seam faces. During extraction of the second lower seam panel, gradual and complete surface subsidence occurred over the panel without affecting face operations. Rock mechanics investigations had originally indicated some uncertainty regarding adverse dolerite sill behaviour which could have caused longwall mining to be hazardous. All such doubts have now been removed. RESUMÉ AS AT FEBRUARY, 1967 Mechanized longwalling was introduced in 1965 on an experimental basis in an effort to improve productivity in the newer area of the mine and to increase the quality of the comparatively dirty run of mine feed to the washing plant. In addition advantages could be predicted in the long term by better utilizing reserves of straight coking coal and increasing the life of the mine. The top seam unit was obtained on a rental basis and by the beginning of 1967, two panels, the first having a face length of 215 m, a panel length of 345 m, seam section of 1 219 mm, and the second the same face length, a panel length of 453 m and a seam section of 1 067 mm had been successfully longwalled. At this stage a best month of 24 602 metric tons with an average of 17 364 metric tons per full working month could be reported. Results were sufficiently encouraging for the company to exercise its right to acquire the equipment as its own asset and from 1967 onward, the unit has operated on this basis. From the point of view of rock mechanics, the dolerite sill over the first two panels was known to have 'bridged', only the material below the base of the sill having truly 'goafed'. No adverse pressure effects had significantly affected face operations except for two 'bumps' towards the end of operations in each panel. Gate road maintenance presented no problem. The strong inflows of water experienced on the first face were now known to be associated with an isolated water bearing fault plane and were not experienced on the second face. TOP SEAM EXPERIENCE - MAY, 1966, TO DATE Panel 2 (February, 1966, to November, 1966) The operations in panel 2 (see Fig. 1 for location of panels) continued uneventfully until the final month in this panel. At this stage, the chocks behaved most inconsistently often lowering under the weight of the canopies alone. Roof trouble became so severe that the unit was unable to produce adequately and blasting of chocks became a daily occurrence. Finally 24 m short of the planned limit it was decided that a complete overhaul was the only solution and the extraction operations commenced. At this time, the only fatal accident associated with longwalling occurred when a Non-White inadvertently fell into the panzer conveyor transfer point at the main gate. Some gate road difficulties in this panel were overcome by bolting tapes to the roof as decking and allowing them to pass over the gate chocks and collapse into the goaf. Two cribbed roof falls were also negotiated by the gate chocks at the face ends without undue difficulties. It was decided in the light of maintenance problems encountered on this face that the best solution would be to appoint a foreman solely in charge of face maintenance crews. This step has to a large extent contributed to success achieved subsequently. Panel 2-face length 213 m panel length 456 m cutting height 1 092 mm average monthly output 16 443 t best month 19 130 t Panel 3 (December, 1966, to June, 1967) By the end of 1966 results were sufficiently encouraging for the company to exercise its right to acquire the equipment. This was negotiated and the unit has operated as such to the present date. Prior to installation in panel 3, all face equipment was thoroughly overhauled underground and the chocks boost-tested to yield-load. The costs of overhauling, including almost complete hose replacement, were much higher than anticipated. Advice had been received that complete hose replacement was common practice after +/- 18 months' operation. Shortly after commencement of operations in panel 3 the chocks again failed as they had towards the end of panel 2. At this stage, the suppliers advised that the valve gear should have been repaired during the overhaul as the needle and seat seals could no longer be relied upon. This operation was impossible to carry out on the face and would have been e1ttremely time consuming. Fortunately a new type of valve gear was then available from the suppliers, termed the capsule-type valve, and a complete change over could be made on the face. The encapsulated valve has a delrin pad sealing over a raised

By J. van Deventer

Ion exchange is widely used in hydrometallurgical operations for the recovery and purification of valuable metals. Special chelating resins have a high affinity for specific elements, allowing the selective removal of low levels of impurities from a background of highly concentrated valuable metal. Solvent-impregnated resins have been added to this group more recently, expanding the treatment options. These products find application in the purification of cobalt-rich liquor prior to the production of high-purity metal or metal salts. Impurities in copper-cobalt circuits that are typically targeted by ion exchange include iron, uranium, copper, zinc, nickel, bismuth, and antimony. Ion-exchange resins can also be used to treat tailings, thereby recovering additional valuable metal and improving the Environmental and Social Governance credentials of the operation. This article takes a look at various applications of ion exchange in copper-cobalt operations

Jan 1, 2023

By J. Manchisi

Laboratory investigations were conducted to establish the feasibility of bioleaching a mixed copper oxide/sulphide rougher concentrate from Nchanga Mine on the Zambian Copperbelt. The objective was to determine the kinetics and extent of copper extraction for this material. Batch experiments were conducted under different solution conditions in stirred tank bioreactors. The progress of (bio)leaching was monitored through measurements of soluble ferrous and ferric iron, copper, pH, and redox potentials, while bacterial activity was monitored online through 02 and C02 gas utilization rates. About 20 per cent copper was solubilized within 2 hours in all cases of non-oxidative (abiotic), oxidative (abiotic), and bioleaching experiments. This was attributed to the dissolution of mainly copper oxides. Subsequently, bioleaching experiments resulted in an overall copper extraction of 93 per cent, with up to 8 g.L-1 copper after six leaching days, compared to 58 per cent copper extraction in the abiotic oxidative acid leaching experiments. However, there was little effect of time (i.e. poor dissolution kinetics) on copper recovery for abiotic non-oxidative acid leaching of the material. Hence, the rate of sulphide leaching increased due to the activity of bacteria. Thus, the material is potentially bioleachable under mesophilic conditions. However, more exhaustive test work needs to be conducted to establish the effect of bioleaching variables and heat requirement.

Jan 1, 2012

By G. P. N. Venter

A method of evaluating the possible effect of an industry on the environment is presented, and the method is illustrated by its application to a hypothetical problem. An analysis is offered based on an actual survey of four industrial sites in the Lydenburg area of the eastern Transvaal. The survey showed that there is a high incidence of potentially unfavourable conditions, and there is a distinct possibility that a topographically induced eddying motion will extend over the town and the industrial sites. This moving air could entrap air pollutants, resulting in high concentrations of pollutants over the town. It is concluded that none of the sites is suitable for industries that pollute the atmosphere.

Jan 1, 1978

The visit which took place on the 18th February, 1972 was a departure in that the places visited had no direct connection with the work in which members of the Institute are normally engaged. It was refreshing and stimulating to see important and involved operations normally outside ones own trend of life and to have experts to speak about technical, financial and matters of general interest concerning their work, not forgetting their troubles and problems and how they overcame them. Carlton Centre The members of the Institute were received by Mr D. Appleton, Public Relations Officer of the Carlton Centre Limited, who introduced Mr L. R. M. Fee of W. Rhodes Harrison, Architect in charge of the project; Mr W. C. E. Skilton of Murray and Roberts, the Engineer in charge of the construction of the complex and Mr A. Home the Senior Operating Engineer of Carlton Centre Limited. Each of these gentlemen addressed the members giving short rundowns on the project with special reference to their particular sphere of the undertaking. A variety of particularly interesting statistics relating to the planning construction and the ultimate operation and maintenance of the complex was given. Mining engineers present had an opportunity to compare the problems encountered by them associated with depth to problems encountered by the civil engineer in the construction of a building rising to such an enormous height. To some of the members a sense of similarity of the labour problems encountered must have been recognised. After tea the visitors were divided into groups, each under the guidance of an official, and then visited the highest floor accessible and thereafter the 19th floor where the internal arrangements for airconditioning, lighting, plumbing, power supply and communication arrangements were explained. Thereafter a visit to one of the seven basements which houses all machinery required to serve this enormous complex enabled the visitors to see the standby power arrangements as well as the refrigeration plant. The visit finished in time to proceed to the Crest Hotel in Hillbrow for lunch. To our hosts for the visit to the Carlton Complex a special vote of thanks is recorded. Strydom Tower In the afternoon the party proceeded to the Strydom Tower where Mr Knight from the Public Works Department who was the Engineer in charge of the construction of the tower gave details on the construction and the extraordinary methods which had to be adopted to achieve the desired objectives and to overcome known as well as unforeseen difficulties. The comparatively short time taken to complete the project and the good safety record appeared to impress the visitors. The final phase of the visit was taken care of by Mr Bothma of Telecommunications Department of the Post Office, who gave an extremely interesting explanation of the telecommunication organization of the Post Office with particular reference to the part the Hillbrow Tower plays in the South African telecommunication system. Both gentlemen answered many questions willingly and interestingly. Following the explanatory talks the visitors were shown the technical equipment housed in the two top levels of the tower. Short explanatory talks gave members an insight into the workings of one of the most important aspects of modern life. Even to the amateur photographer opportunities existed to view and photograph the city from the highest available observation point. We are indebted to Mr Gouws, the Regional Director of the Post Office for granting permission to visit sections of the tower normally not accessible to the general public and to our hosts for the manner in which we were received and entertained on the explanation of the many interesting features of this important installation. In conclusion, the programme for the day can be classified as interesting, of exceptional educational value, and an opportunity to see something of the engineering skills put into two vast and ambitious undertakings and the results achieved.

1. Journals Marine Geotechnology, edited by R.C. Chaney. London, Taylor & Francis (Rankine Road, Basingstoke, Hants RG 24 OPR, OK), 1988. vol. 8, $50. Published quarterly. Mineral Resources Engineering, edited by C.T. Shaw. London, Taylor & Francis (address as above), 1988. vol. 1, $99. Published quarterly. 2. New publication World mining map of non-ferous metals (with 4 regional maps and a booklet). Reinhard Ryborsch (Postfach 2105, D-6053 Obertshausen bei Frankfurt am Main, West Germany). International edition: bilingual, English and German. 7 colour-print: Size (unfolded) 138 X 100 cm. US$ 19 (excl. mailing) for folded map with hard cover (Order No. 61-4); US$ 25 (excl. mailing) for unfolded (flat) map with hanging strip (Order No. 62-2). 3. Mintek reports Report M326 Crevice corosion and other localized corosion behaviour of 3CR12 corosion-resisting steel in synthetic minewaters, by D. Howarth. May 1988. 28 pp.Report M332 The carbon-regeneration furnaces at Mintek, by P.M. Cole and P.J. van Staden. Nov. 1987. 31 pp. Report M344 The flotation of pyrite with amine colectors, by R.D. Hil, E.W. Giesekke, and P.J. Haris. Mar.'1988. 25 pp.Report M345 The substitution for chromium in steels: Progress and trends, by M.B. Cortie. Mar. 1988. 14 pp.Report M346 The direct reduction of sulphur dioxide to elementalsulphur, by I. Henderson. Mar. 1988. 30 pp.Report M349 The optimization of a process using weak-base resin for the recovery of gold from plant solutions and pulps, by A. Mehmet. Apr. 1988. 17 pp. Report M353 The determination, by ion-interaction chromatography, of sulphur species in cyanide solutions, by Pohlandt-Watson, M.J. Hemmings, D.E. Barnes, and a.w. PansL Jun. 1988. 7 pp. Report M355 A laboratory-scale continuous-feed resistance furnace, by K.P.D. Pery, A.S.E. Kleyenstiber, andC.T. Logan. May 1988. 9 pp. Report M357 The determination of minor and trace elements in activated charcoal, by RT. Eddy and G.J. Wal. Jun. 1988. 14 pp. Report M358 The sensitive determination of germanium by atomicabsorption spectrophotometry using electrothermal atomization, by G.D. Marshal. Jun. 1988. 11 pp. Report M92D The recovery of tin and tungsten from various zones of the Van Roois Vley deposit, including setling and filtration, by C.F.B. Coetzee. First issued Apr. 1983; reissued Apr. 1988. 40 pp. World Environment Day Symposium* Mintek auditorium in Randburg was the venue on Thursday, 2nd June, 1988, for more than 200 interested delegates at the annual World Environment Day Symposium, organized jointly by the Federation of Societies of Professional Engineers (FSPE), The Environmental Planning Professions Inter-disciplinary Committee (EPPIC), The Habitat Council, and The Associated Scientific and Technical Societies of South Africa (AS&TS). The theme 'Cultural and Historical Conservation' was adapted from the theme of the Department of Environment Affairs for the 1988 Environment Week.

Jan 1, 1988

By D. Amariei, G. Bartolacci

Preconcentration of precious and base metal ore types is becoming more relevant with the discovery, the development and the operation of many lower grade deposits around the world. Ore preconcentration designates an operation consisting of sorting an ore to reduce the quantity of waste material sent to the concentrator. It can be seen as rejecting waste material as much as possible, without compromising the recovery, or as the recovery of as much valuable metal as possible into an optimum mass yield. Benefits of preconcentration are multiple: grinding energy savings, costs reduction, lower environmental footprint, extension of the reserves, etc. However, all of these benefits do not apply simultaneously and are not applicable to each ore type. Technologies employed for preconcentration are highly dependent on ore properties, especially on the particle size at which the gangue is liberated. Thus, from coarser to finer particle sizes, technologies such as screening, ore sorting, gravity separation (Dense Media Separation (DMS) and jigs) and coarse flotation could be used for the rejection of liberated gangue. The difficulty starts when a benchmark is needed to select a suitable technology, especially for low-grade gold deposits. This paper presents the challenges of comparing lab-scale technologies (DMS versus jig) for gold preconcentration. The experimental data will show to what extent comparing two lab-scale gravity technologies for gold preconcentration can be challenging. An attempt to evaluate the energy savings by assessing the hardness of the tailings after gravity separation will also be presented. Keywords: Challenges in gold preconcentration, gravity separation, jig, dense medium separation

Jan 1, 2020

By S. Fazluddin, K. C. Sole, M. R. Serwale, T. Coetsee

The CSIR-Ti process employs lithiothermic reduction of titanium tetrachloride feedstock to produce titanium sponge. The product is therefore contaminated by a range of lithium and chloride species. In this study we examine the effects of particle size, temperature, and HCl concentration as input leaching variables on the removal of chlorides from the crude titanium sponge. A review of the aqueous chloride chemistry of Li and Ti provided initial conditions for leaching of impurity species from the sponge. Experimental results confirm that the effectiveness of leaching and removal of dissolved impurities from the sponge are dependent on leaching kinetics, which are influenced by temperature, particle size, and morphology. Of the variables tested, reaction temperature had the strongest influence on the oxygen content of the leached product. The HCl lixiviant concentration had a negligible effect under the conditions tested. Leaching of crude titanium sponge (−10 mm size fraction after crushing) at 14°C in either 1 M or 0.032 M HCl yielded a titanium sponge product that met the ASTM standard specification for commercially pure Grade 1 titanium, i.e., oxygen content < 0.18 mass% and chloride content < 0.15 mass%.

Dec 13, 2022

By G. J. McDougall, M. J. Nicol, O. L. Wellington, R. G. Copperthwaites, R. D. Hancock

X-ray photoelectron spectroscopy showed that the adsorption of gold cyanide on carbon in the presence or absence of electrolytes and acids proceeds by the same mechanism. Although the identity of the gold cyanide adsorbate is not known, the mechanism appears to have an initial adsorption stage that involves the adsorption of an ion pair: Mn+[Au(CN)-2]n where Mn+ is a metal ion (for example Na+, K+ and Ca2+) that has a lower solubility than the Au(CN)-2 anion in the adsorption medium, followed by a reduction step in which either a sub-stoichiometric Au(CN)x surface species or a cluster-type compound of gold is formed.

Jan 1, 1980

By N. X. Feng, S. G. Zhou, X. L. Wu, J. P. Peng, Y. Z. Di

"Szaibelyite–suanite type ore is rich in magnesium oxide and boron oxide. We propose a new method to extract both metallic magnesium and valuable residues rich in boron by reduction using metallic aluminium.Thermodynamic analysis of the reactions between aluminum and MgO, Mg2B2O5, and Mg3B2O6 was carried out. The effects of CaF2 addition, temperature, mass of Al, and pellet formation pressure on the extraction of magnesium were also investigated experimentally.The results indicate that the magnesium oxide phase can be displaced from 2MgO-B2O3 and 3MgO·B2O3 by CaO in the reduction system. The reduction ratio of magnesium oxide was 38% without calcium fluoride addition, increasing to 94% with 5.1% calcium fluoride. The reduction ratio increased with increasing temperature and mass of Al. To obtain a higher reduction ratio, the reduction pellet should be formed under a reasonable pressure.IntroductionBoron and its compounds are widely used in textiles, borosilicate glass, metallurgy, fertilizers, and nuclear shielding. Boron resources are mainly found in Turkey, the USA, Russia, and China. In Liaoning, China, there are abundant szaibelyite–suanite type ores that are rich in magnesium oxide and boron oxide. Szaibelyite and suanite ores are used to produce borax by a carbon dioxide– soda process. Annually, 2 Mt of waste materials containing 3–20% B2O3 and 2–25% MgO are produced during the process. It is necessary to make use of these waste materials containing high concentrations of boron oxide and magnesium oxide to avoid environmental problems as well as for economic reasons (Ozdemir and K1pcak, 2007)"

Jan 1, 2016